DE1191375C2 - Verfahren zur Herstellung von CO- und NO-freien Komplexverbindungen der UEbergangsmetalle - Google Patents

Verfahren zur Herstellung von CO- und NO-freien Komplexverbindungen der UEbergangsmetalle

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Publication number
DE1191375C2
DE1191375C2 DE1960ST016427 DEST016427A DE1191375C2 DE 1191375 C2 DE1191375 C2 DE 1191375C2 DE 1960ST016427 DE1960ST016427 DE 1960ST016427 DE ST016427 A DEST016427 A DE ST016427A DE 1191375 C2 DE1191375 C2 DE 1191375C2
Authority
DE
Germany
Prior art keywords
benzene
solution
compounds
nickel
crystals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1960ST016427
Other languages
German (de)
English (en)
Other versions
DE1191375B (de
Inventor
Dipl-Chem Dr Heinz Breil
Dipl-Chem Dr Paul Heimbach
Dipl-Chem Dr Michael Kroener
Dipl-Chem Dr Ernst Wil Mueller
Dipl-Chem Dr Guenther Wilke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Studiengesellschaft Kohle gGmbH
Original Assignee
Studiengesellschaft Kohle gGmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL129643D priority Critical patent/NL129643C/xx
Priority to IT649440D priority patent/IT649440A/it
Priority to NL263960D priority patent/NL263960A/xx
Priority to BE603146D priority patent/BE603146A/xx
Application filed by Studiengesellschaft Kohle gGmbH filed Critical Studiengesellschaft Kohle gGmbH
Priority to DE1960ST016427 priority patent/DE1191375C2/de
Priority to CH451061A priority patent/CH436284A/de
Priority to CH1371167A priority patent/CH471837A/de
Priority to CH1529365A priority patent/CH464915A/de
Priority to GB14157/61A priority patent/GB935716A/en
Priority to FR859904A priority patent/FR1320729A/fr
Priority to SE4462/61A priority patent/SE307577B/xx
Publication of DE1191375B publication Critical patent/DE1191375B/de
Application granted granted Critical
Publication of DE1191375C2 publication Critical patent/DE1191375C2/de
Priority to US755508A priority patent/US3450732A/en
Priority to US867394A priority patent/US3641175A/en
Priority to US00373525A priority patent/US3848015A/en
Priority to US05/573,198 priority patent/US4017526A/en
Priority to US05/798,199 priority patent/US4120882A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/38—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of dienes or alkynes
    • C07C2/40—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of dienes or alkynes of conjugated dienes
    • C07C2/403—Catalytic processes
    • C07C2/406—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/42—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion
    • C07C2/44—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion of conjugated dienes only
    • C07C2/46—Catalytic processes
    • C07C2/465—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C07C2/52—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE1960ST016427 1959-12-22 1960-04-28 Verfahren zur Herstellung von CO- und NO-freien Komplexverbindungen der UEbergangsmetalle Expired DE1191375C2 (de)

Priority Applications (16)

Application Number Priority Date Filing Date Title
NL129643D NL129643C (OSRAM) 1959-12-22
IT649440D IT649440A (OSRAM) 1959-12-22
NL263960D NL263960A (OSRAM) 1959-12-22
BE603146D BE603146A (OSRAM) 1959-12-22
DE1960ST016427 DE1191375C2 (de) 1959-12-22 1960-04-28 Verfahren zur Herstellung von CO- und NO-freien Komplexverbindungen der UEbergangsmetalle
CH1371167A CH471837A (de) 1959-12-22 1961-04-17 Verfahren zur Herstellung von Komplexen der Übergangsmetalle ohne Carbonyl-Liganolen
CH1529365A CH464915A (de) 1959-12-22 1961-04-17 Verfahren zur Herstellung von Übergangsmetallkomplexen ohne Carbonyl-Liganden
CH451061A CH436284A (de) 1959-12-22 1961-04-17 Verfahren zur Herstellung von kohlenoxydfreien Komplexen der Übergangsmetalle mit C-C-Mehrfachbindungen enthaltenden Stoffen
GB14157/61A GB935716A (en) 1959-12-22 1961-04-19 Complexes of transition metals and the production thereof
FR859904A FR1320729A (fr) 1959-12-22 1961-04-26 Nouveaux complexes de métaux de transition et procédé pour leur préparation
SE4462/61A SE307577B (OSRAM) 1959-12-22 1961-04-28
US755508A US3450732A (en) 1959-12-22 1968-08-21 Process for the production of carbon monoxide-free complex compounds of the transition metals
US867394A US3641175A (en) 1959-12-22 1969-10-17 Process for the production of dimers and trimers of conjugated dienes
US00373525A US3848015A (en) 1959-12-22 1973-06-25 Process for the production of dimers and trimers of conjugated dienes
US05/573,198 US4017526A (en) 1959-12-22 1975-04-30 Metal complexes
US05/798,199 US4120882A (en) 1959-12-22 1977-05-18 Metal complexes

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DEM0069381 1959-12-22
DE1960ST016427 DE1191375C2 (de) 1959-12-22 1960-04-28 Verfahren zur Herstellung von CO- und NO-freien Komplexverbindungen der UEbergangsmetalle
US53290066A 1966-03-09 1966-03-09
US05/573,198 US4017526A (en) 1959-12-22 1975-04-30 Metal complexes

Publications (2)

Publication Number Publication Date
DE1191375B DE1191375B (de) 1965-04-22
DE1191375C2 true DE1191375C2 (de) 1965-12-16

Family

ID=27437240

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1960ST016427 Expired DE1191375C2 (de) 1959-12-22 1960-04-28 Verfahren zur Herstellung von CO- und NO-freien Komplexverbindungen der UEbergangsmetalle

Country Status (8)

Country Link
US (2) US3450732A (OSRAM)
BE (1) BE603146A (OSRAM)
CH (2) CH436284A (OSRAM)
DE (1) DE1191375C2 (OSRAM)
GB (1) GB935716A (OSRAM)
IT (1) IT649440A (OSRAM)
NL (2) NL263960A (OSRAM)
SE (1) SE307577B (OSRAM)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4120882A (en) * 1959-12-22 1978-10-17 Studiengesellschaft Kohle M.B.H. Metal complexes
DE1297600B (de) * 1960-06-30 1969-06-19 Studiengesellschaft Kohle Mbh Verfahren zur Cyclodimerisation von 1, 3-Diolefinen in Gegenwart eines Katalysators aus kohlenoxydfreien Verbindungen des Nickels und Metallalkylen und Triphenylphosphin
DE1521253A1 (de) * 1966-05-05 1969-07-24 Hoechst Ag Verfahren zum Vernickeln von Kunstst stoffen
US3507926A (en) * 1967-12-28 1970-04-21 Columbian Carbon Process for cyclooligomerizing conjugated dienes
US3622644A (en) * 1968-11-25 1971-11-23 Phillips Petroleum Co Oligomerization of olefins using a rhenium complex catalyst system
US3997579A (en) * 1975-10-15 1976-12-14 E. I. Du Pont De Nemours And Company Selected phosphorus complexes of zerovalent iron
US4529553A (en) * 1981-12-14 1985-07-16 General Electric Company Nickel complex catalyst for hydrosilation reaction
DE3205550A1 (de) * 1982-02-17 1983-08-25 Studiengesellschaft Kohle mbH, 4330 Mülheim Herstellung von uebergangsmetallkomplexen
US4550152A (en) * 1983-10-28 1985-10-29 General Electric Company Nickel complex catalyst for hydrosilation reactions
US5041574A (en) * 1990-08-09 1991-08-20 E. I. Du Pont De Nemours And Company Process for the preparation of phosphine containing cobalt carbonyl complexes
US8940940B2 (en) 2012-06-13 2015-01-27 Basf Se Process for preparing macrocyclic ketones
DE202020005813U1 (de) 2019-07-30 2022-10-13 Studiengesellschaft Kohle mit beschränkter Haftung Luftstabile Ni(0)-Olefin-Komplexe und ihre Verwendung als Katalysatoren oder Vorkatalysatoren
EP3771707A1 (en) 2019-07-30 2021-02-03 Studiengesellschaft Kohle mbH Air-stable ni(0)-olefin complex and its use as catalyst and precatalyst

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2916505A (en) * 1957-11-18 1959-12-08 Ethyl Corp Manufacture of cyclopentadienyl-manganese carbonyl compounds
FR1215360A (fr) * 1957-11-27 1960-04-19 Union Carbide Corp Procédé de fabrication de cyclopentadiénylmanganèse-tricarbonyles

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE551488A (OSRAM) * 1955-10-05
NL134223C (OSRAM) * 1960-12-05 1900-01-01

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2916505A (en) * 1957-11-18 1959-12-08 Ethyl Corp Manufacture of cyclopentadienyl-manganese carbonyl compounds
FR1215360A (fr) * 1957-11-27 1960-04-19 Union Carbide Corp Procédé de fabrication de cyclopentadiénylmanganèse-tricarbonyles

Also Published As

Publication number Publication date
US3450732A (en) 1969-06-17
GB935716A (en) 1963-09-04
NL129643C (OSRAM) 1900-01-01
BE603146A (OSRAM) 1900-01-01
CH436284A (de) 1967-05-31
US4017526A (en) 1977-04-12
SE307577B (OSRAM) 1969-01-13
IT649440A (OSRAM) 1900-01-01
DE1191375B (de) 1965-04-22
NL263960A (OSRAM) 1900-01-01
CH464915A (de) 1968-11-15

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