DE102006025847A1 - Verwendung von Phosphinsäure in der Galvanotechnik - Google Patents
Verwendung von Phosphinsäure in der Galvanotechnik Download PDFInfo
- Publication number
- DE102006025847A1 DE102006025847A1 DE102006025847A DE102006025847A DE102006025847A1 DE 102006025847 A1 DE102006025847 A1 DE 102006025847A1 DE 102006025847 A DE102006025847 A DE 102006025847A DE 102006025847 A DE102006025847 A DE 102006025847A DE 102006025847 A1 DE102006025847 A1 DE 102006025847A1
- Authority
- DE
- Germany
- Prior art keywords
- galvanic
- galvanic baths
- baths
- salts
- electroplating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000009713 electroplating Methods 0.000 title claims abstract description 13
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 title abstract description 4
- 150000003839 salts Chemical class 0.000 claims abstract description 18
- 239000011651 chromium Substances 0.000 claims description 31
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 26
- 238000007747 plating Methods 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 19
- 150000007513 acids Chemical class 0.000 claims description 17
- 229910052804 chromium Inorganic materials 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- WAZIDHPTVNFDQG-UHFFFAOYSA-N bis(1,1,2,2,3,3,4,4,4-nonafluorobutyl)phosphinic acid Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)P(=O)(O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F WAZIDHPTVNFDQG-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 abstract description 12
- 238000005259 measurement Methods 0.000 description 9
- 238000000576 coating method Methods 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 3
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical class [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 3
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- -1 alkali metal dichromate Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 238000005323 electroforming Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Chemical compound [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 101710134784 Agnoprotein Proteins 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000000899 Gutta-Percha Substances 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 240000000342 Palaquium gutta Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- KJQNGFYTIRHEIL-UHFFFAOYSA-M bis(1,1,2,2,2-pentafluoroethyl)phosphinate;1-ethyl-3-methylimidazol-3-ium Chemical compound CC[N+]=1C=CN(C)C=1.FC(F)(F)C(F)(F)P(=O)([O-])C(F)(F)C(F)(F)F KJQNGFYTIRHEIL-UHFFFAOYSA-M 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000002894 chemical waste Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910000743 fusible alloy Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229920000588 gutta-percha Polymers 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical group 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 125000005496 phosphonium group Chemical group 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 239000001120 potassium sulphate Substances 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 231100000721 toxic potential Toxicity 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
- C25D11/10—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing organic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
- C25D3/10—Electroplating: Baths therefor from solutions of chromium characterised by the organic bath constituents used
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006025847A DE102006025847A1 (de) | 2006-06-02 | 2006-06-02 | Verwendung von Phosphinsäure in der Galvanotechnik |
| EP07724891A EP2027310A1 (de) | 2006-06-02 | 2007-05-04 | Verwendung von phosphinsäuren und/oder phosphonsäuren in redoxprozessen |
| JP2009512443A JP5586951B2 (ja) | 2006-06-02 | 2007-05-04 | 酸化還元法におけるホスフィン酸および／またはホスホン酸の使用 |
| KR1020087032128A KR101367503B1 (ko) | 2006-06-02 | 2007-05-04 | 산화환원 과정에서 포스핀산 및/또는 포스폰산의 용도 |
| PCT/EP2007/003966 WO2007140850A1 (de) | 2006-06-02 | 2007-05-04 | Verwendung von phosphinsäuren und/oder phosphonsäuren in redoxprozessen |
| CN2007800204191A CN101460664B (zh) | 2006-06-02 | 2007-05-04 | 次膦酸和/或膦酸在氧化还原法中的用途 |
| US12/303,006 US8282808B2 (en) | 2006-06-02 | 2007-05-04 | Use of phosphinic acids and/or phosphonic acids in redox processes |
| TW096119790A TWI443230B (zh) | 2006-06-02 | 2007-06-01 | 次膦酸及／或膦酸在氧化還原方法中之用途 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006025847A DE102006025847A1 (de) | 2006-06-02 | 2006-06-02 | Verwendung von Phosphinsäure in der Galvanotechnik |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102006025847A1 true DE102006025847A1 (de) | 2007-12-06 |
Family
ID=38336886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102006025847A Withdrawn DE102006025847A1 (de) | 2006-06-02 | 2006-06-02 | Verwendung von Phosphinsäure in der Galvanotechnik |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8282808B2 (enExample) |
| EP (1) | EP2027310A1 (enExample) |
| JP (1) | JP5586951B2 (enExample) |
| KR (1) | KR101367503B1 (enExample) |
| CN (1) | CN101460664B (enExample) |
| DE (1) | DE102006025847A1 (enExample) |
| TW (1) | TWI443230B (enExample) |
| WO (1) | WO2007140850A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011102052A1 (de) | 2011-05-19 | 2012-11-22 | Anke Gmbh & Co. Kg | Netzmittel für elektrolytische Anwendung und dessen Verwendung |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2789714B1 (en) * | 2011-12-07 | 2018-03-28 | Think Laboratory Co., Ltd. | Processing unit having condenser, and fully automatic gravure platemaking processing system using same |
| DE102012022441A1 (de) | 2012-11-15 | 2014-05-28 | Merck Patent Gmbh | Neue Phosphinsäureamide, deren Herstellung und Verwendung |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1004009B (de) * | 1953-08-13 | 1957-03-07 | Dehydag Gmbh | Galvanische Baeder zur Herstellung von Metallueberzuegen |
| BE540564A (enExample) | 1954-10-28 | |||
| DE1521066A1 (de) | 1963-09-11 | 1969-08-07 | Udylite Corp | Bad zur galvanischen Abscheidung von Chromueberzuegen |
| US3334033A (en) | 1964-09-11 | 1967-08-01 | Udylite Corp | Chromium plating |
| US3310480A (en) | 1966-04-25 | 1967-03-21 | Udylite Corp | Chromium electroplating |
| US3432408A (en) | 1966-08-03 | 1969-03-11 | Udylite Corp | Chromium plating electrolyte and method for preventing mist therein |
| US3745097A (en) * | 1969-05-26 | 1973-07-10 | M & T Chemicals Inc | Electrodeposition of an iridescent chromium coating |
| DE2110767C3 (de) | 1971-03-06 | 1974-02-14 | Farbwerke Hoechst Ag, Vormals Meister Lucius & Bruening, 6000 Frankfurt | Perfluoralkyl-Phosphorverbindungen |
| DE2233941C3 (de) | 1972-07-11 | 1978-03-02 | Cassella Farbwerke Mainkur Ag, 6000 Frankfurt | Verwendung von Perfluoralkylphosphorverbindungen als schaumdämpfende Mittel |
| GB1482747A (en) * | 1973-10-10 | 1977-08-10 | Bnf Metals Tech Centre | Chromium plating baths |
| DE2508708C2 (de) * | 1975-02-28 | 1982-07-01 | Bayer Ag, 5090 Leverkusen | Elektrolytlösungen auf Cr (VI)-Basis zur galvanischen Abscheidung von Chromschichten |
| JPS5476443A (en) * | 1977-11-30 | 1979-06-19 | Dainippon Ink & Chem Inc | Fluorine type surfactant mixture suitable for preventing planting mist |
| US4466865A (en) | 1982-01-11 | 1984-08-21 | Omi International Corporation | Trivalent chromium electroplating process |
| JPS61217595A (ja) * | 1985-03-22 | 1986-09-27 | Kawasaki Steel Corp | めつき鋼板の製造方法 |
| JPS63103099A (ja) | 1986-10-17 | 1988-05-07 | Kao Corp | 有機高分子複合亜鉛および亜鉛合金めつき皮膜およびその製造方法 |
| DE3723198A1 (de) | 1987-07-14 | 1989-02-16 | Bayer Ag | Schaumhemmender zusatz in sauren beizen und galvanischen baedern |
| US5126210A (en) | 1989-08-23 | 1992-06-30 | Aluminum Company Of America | Anodic phosphonic/phosphinic acid duplex coating on valve metal surface |
| US5277788A (en) * | 1990-10-01 | 1994-01-11 | Aluminum Company Of America | Twice-anodized aluminum article having an organo-phosphorus monolayer and process for making the article |
| JP3111614B2 (ja) * | 1992-03-05 | 2000-11-27 | 上村工業株式会社 | 無電解ニッケルめっき浴の再生方法 |
| DE4241478A1 (de) * | 1992-12-09 | 1994-06-16 | Bayer Ag | Fluorierter Carbonsäureester von Phosphono- und Phosphinocarbonsäuren sowie deren Verwendung |
| FR2727983B1 (fr) * | 1994-12-07 | 1997-01-24 | Atotech France | Bain de chromatation et procede pour la finition de surfaces de zinc, d'alliage de zinc, ou de cadmium |
| DE19828545C1 (de) | 1998-06-26 | 1999-08-12 | Cromotec Oberflaechentechnik G | Galvanisches Bad, Verfahren zur Erzeugung strukturierter Hartchromschichten und Verwendung |
| JP2000258923A (ja) * | 1999-03-05 | 2000-09-22 | Yokohama Yushi Kogyo Kk | 酸化錫導電性パタ−ンを形成させる方法 |
| US20030189193A1 (en) | 2002-03-26 | 2003-10-09 | Mininni Robert M. | Fluorinated and halogenated phosphinic acids and their active metal derivatives |
| JP3792216B2 (ja) * | 2003-06-30 | 2006-07-05 | 古河サーキットフォイル株式会社 | 薄膜抵抗層の形成方法、薄膜抵抗層付き導電性基材及び抵抗層付き回路基板材料 |
-
2006
- 2006-06-02 DE DE102006025847A patent/DE102006025847A1/de not_active Withdrawn
-
2007
- 2007-05-04 US US12/303,006 patent/US8282808B2/en not_active Expired - Fee Related
- 2007-05-04 EP EP07724891A patent/EP2027310A1/de not_active Withdrawn
- 2007-05-04 KR KR1020087032128A patent/KR101367503B1/ko not_active Expired - Fee Related
- 2007-05-04 WO PCT/EP2007/003966 patent/WO2007140850A1/de not_active Ceased
- 2007-05-04 JP JP2009512443A patent/JP5586951B2/ja not_active Expired - Fee Related
- 2007-05-04 CN CN2007800204191A patent/CN101460664B/zh not_active Expired - Fee Related
- 2007-06-01 TW TW096119790A patent/TWI443230B/zh not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011102052A1 (de) | 2011-05-19 | 2012-11-22 | Anke Gmbh & Co. Kg | Netzmittel für elektrolytische Anwendung und dessen Verwendung |
| WO2012156102A2 (de) | 2011-05-19 | 2012-11-22 | Anke Gmbh & Co. Kg | Netzmittel für elektrolytische anwendungen und dessen verwendung |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5586951B2 (ja) | 2014-09-10 |
| US20090166212A1 (en) | 2009-07-02 |
| CN101460664B (zh) | 2013-01-16 |
| TWI443230B (zh) | 2014-07-01 |
| WO2007140850A1 (de) | 2007-12-13 |
| US8282808B2 (en) | 2012-10-09 |
| EP2027310A1 (de) | 2009-02-25 |
| KR101367503B1 (ko) | 2014-02-28 |
| CN101460664A (zh) | 2009-06-17 |
| KR20090027691A (ko) | 2009-03-17 |
| JP2009538982A (ja) | 2009-11-12 |
| TW200806817A (en) | 2008-02-01 |
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