DE10027768A1 - Verzweigte Copolymere auf Basis von ungesättigten Nitrilen und konjugierten Dienen - Google Patents
Verzweigte Copolymere auf Basis von ungesättigten Nitrilen und konjugierten DienenInfo
- Publication number
- DE10027768A1 DE10027768A1 DE10027768A DE10027768A DE10027768A1 DE 10027768 A1 DE10027768 A1 DE 10027768A1 DE 10027768 A DE10027768 A DE 10027768A DE 10027768 A DE10027768 A DE 10027768A DE 10027768 A1 DE10027768 A1 DE 10027768A1
- Authority
- DE
- Germany
- Prior art keywords
- copolymers
- production
- chain
- regulator
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 229920001971 elastomer Polymers 0.000 title claims description 9
- 239000000806 elastomer Substances 0.000 title claims description 6
- 238000002347 injection Methods 0.000 title description 3
- 239000007924 injection Substances 0.000 title description 3
- 235000012438 extruded product Nutrition 0.000 title 1
- 150000002825 nitriles Chemical class 0.000 claims abstract description 22
- 239000000178 monomer Substances 0.000 claims abstract description 19
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920005605 branched copolymer Polymers 0.000 claims abstract description 15
- 150000001993 dienes Chemical class 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 238000001746 injection moulding Methods 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 3
- 229920006168 hydrated nitrile rubber Polymers 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract description 3
- 229920000459 Nitrile rubber Polymers 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 13
- 238000001495 thermal field-flow fractionation Methods 0.000 description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 241001441571 Hiodontidae Species 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- -1 fatty acid esters Chemical class 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical class CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- QISOBCMNUJQOJU-UHFFFAOYSA-N 4-bromo-1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1NN=CC=1Br QISOBCMNUJQOJU-UHFFFAOYSA-N 0.000 description 1
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical class CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 150000001356 alkyl thiols Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical class CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229920005684 linear copolymer Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical class CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical class CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009718 spray deposition Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10027768A DE10027768A1 (de) | 2000-06-07 | 2000-06-07 | Verzweigte Copolymere auf Basis von ungesättigten Nitrilen und konjugierten Dienen |
| EP01938236A EP1297037A1 (de) | 2000-06-07 | 2001-05-25 | Verzweigte copolymere auf basis von ungesättigten nitrilen und konjugierten dienen |
| AU2001263939A AU2001263939A1 (en) | 2000-06-07 | 2001-05-25 | Branched copolymers based on unsaturated nitriles and on conjugated dienes |
| PL358983A PL199382B1 (pl) | 2000-06-07 | 2001-05-25 | Rozgałęzione kopolimery na podstawie nienasyconych nitryli i sprzężonych dienów, sposób ich wytwarzania i ich zastosowanie |
| PCT/EP2001/005970 WO2001094432A1 (de) | 2000-06-07 | 2001-05-25 | Verzweigte copolymere auf basis von ungesättigten nitrilen und konjugierten dienen |
| BR0111517-0A BR0111517A (pt) | 2000-06-07 | 2001-05-25 | Copolìmeros ramificados à base de nitrilas insaturadas e dienos conjugados |
| MXPA02012109A MXPA02012109A (es) | 2000-06-07 | 2001-05-25 | Copolimeros ramificados a base de nitrilos insaturados y de dienos conjugados. |
| JP2002501979A JP4903973B2 (ja) | 2000-06-07 | 2001-05-25 | 不飽和ニトリルと共役ジエンとをベースとする分枝鎖コポリマー |
| CA2411680A CA2411680C (en) | 2000-06-07 | 2001-05-25 | Branched copolymers based on unsaturated nitriles and conjugated dienes |
| KR1020027016650A KR20030010669A (ko) | 2000-06-07 | 2001-05-25 | 불포화 니트릴 및 공액 디엔을 기재로 한 분지 공중합체 |
| RU2003100394/04A RU2003100394A (ru) | 2000-06-07 | 2001-05-25 | Разветвленные сополимеры на основе ненасыщенных нитрилов и сопряженных диенов |
| US10/297,292 US20030171518A1 (en) | 2000-06-07 | 2001-05-28 | Branched copolymers based on unsaturated nitriles and on conjugated dienes |
| TW090113636A TWI307347B (en) | 2000-06-07 | 2001-06-06 | Branched copolymers based on unsaturated nitriles and conjugated dienes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10027768A DE10027768A1 (de) | 2000-06-07 | 2000-06-07 | Verzweigte Copolymere auf Basis von ungesättigten Nitrilen und konjugierten Dienen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE10027768A1 true DE10027768A1 (de) | 2001-12-13 |
Family
ID=7644732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE10027768A Withdrawn DE10027768A1 (de) | 2000-06-07 | 2000-06-07 | Verzweigte Copolymere auf Basis von ungesättigten Nitrilen und konjugierten Dienen |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20030171518A1 (enExample) |
| EP (1) | EP1297037A1 (enExample) |
| JP (1) | JP4903973B2 (enExample) |
| KR (1) | KR20030010669A (enExample) |
| AU (1) | AU2001263939A1 (enExample) |
| BR (1) | BR0111517A (enExample) |
| CA (1) | CA2411680C (enExample) |
| DE (1) | DE10027768A1 (enExample) |
| MX (1) | MXPA02012109A (enExample) |
| PL (1) | PL199382B1 (enExample) |
| RU (1) | RU2003100394A (enExample) |
| TW (1) | TWI307347B (enExample) |
| WO (1) | WO2001094432A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004035669A1 (en) | 2002-10-17 | 2004-04-29 | Bayer Inc. | Hydrogenated nitrile rubber composites with improved processability |
| WO2004035679A1 (en) * | 2002-10-17 | 2004-04-29 | Bayer Inc. | Polymer blends comprising low molecular weight nitrile rubber |
| WO2004035670A1 (en) | 2002-10-17 | 2004-04-29 | Bayer Inc. | Polymer composites comprising low molecular weight nitrile rubber |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6899500B2 (en) * | 2001-06-19 | 2005-05-31 | Illinois Tool Works Inc. | Fastner having multiple-bossed lead |
| JP2007503385A (ja) * | 2003-08-22 | 2007-02-22 | ファルマシア・アンド・アップジョン・カンパニー・エルエルシー | Ｎ−アリール−２−シアノオキサゾリジノンおよびその誘導体 |
| DE102007024008A1 (de) * | 2007-05-22 | 2008-11-27 | Lanxess Deutschland Gmbh | Nitrilkautschuke |
| EP2423234A1 (de) * | 2010-08-31 | 2012-02-29 | LANXESS Deutschland GmbH | Kautschukblends aus verschiedenen Nitrilkautschuken |
| EP3026067A4 (en) * | 2013-09-30 | 2016-12-28 | Zeon Corp | NITRIL COPOLYMER RUBBER AND MANUFACTURING METHOD THEREFOR |
| EP2860196A1 (de) | 2013-10-14 | 2015-04-15 | LANXESS Deutschland GmbH | Nitrilkautschuke mit niedrigen Emissionswerten |
| JP6864471B2 (ja) * | 2016-12-26 | 2021-04-28 | マクセルホールディングス株式会社 | 熱接着テープおよび熱接着テープの製造方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD124526A1 (de) * | 1975-11-17 | 1977-03-02 | Werner Hufenreuter | Verfahren zur herstellung von copolymeren mit verbesserten eigenschaften aus konzentrierten dienen und polaren vinylmonomeren |
| DD154702A1 (de) * | 1980-11-25 | 1982-04-14 | Joerg Stricker | Verfahren zur herstellung von butadien-acrylnitril-copolymerisaten |
| DE3329974A1 (de) * | 1983-08-19 | 1985-02-28 | Bayer Ag, 5090 Leverkusen | Herstellung von hydrierten nitrilkautschuken |
| DE3529252A1 (de) * | 1985-08-16 | 1987-02-19 | Bayer Ag | Verfahren zur selektiven hydrierung ungesaettigter verbindungen |
| DE69415969T2 (de) * | 1993-03-30 | 1999-06-10 | Nippon Zeon Co., Ltd., Tokio/Tokyo | Ungesättigtes nitril/konjugiertes dien-copolymer, verfahren zu dessen herstellung sowie kautschukzusammensetzung |
| JP3603344B2 (ja) * | 1994-09-07 | 2004-12-22 | 日本ゼオン株式会社 | 不飽和ニトリル−共役ジエン共重合体、その製造方法および加硫性ゴム組成物 |
| JP3579929B2 (ja) * | 1994-08-29 | 2004-10-20 | 日本ゼオン株式会社 | 不飽和ニトリル−共役ジエン共重合体、その製造方法および加硫性ゴム組成物 |
| WO1996006869A1 (en) * | 1994-08-29 | 1996-03-07 | Nippon Zeon Co., Ltd. | Unsaturated nitrile-conjugated diene copolymer, process for producing the same, and vulcanizable rubber composition |
| US5651995A (en) * | 1994-09-30 | 1997-07-29 | Nippon Zeon Co., Ltd. | Highly saturated nitrile rubber, process for producing same, vulcanizable rubber composition, aqueous emulsion and adhesive composition |
| JP3391116B2 (ja) * | 1994-09-30 | 2003-03-31 | 日本ゼオン株式会社 | ニトリル基含有高飽和共重合体ゴム、その製造方法および加硫性ゴム組成物 |
-
2000
- 2000-06-07 DE DE10027768A patent/DE10027768A1/de not_active Withdrawn
-
2001
- 2001-05-25 MX MXPA02012109A patent/MXPA02012109A/es unknown
- 2001-05-25 WO PCT/EP2001/005970 patent/WO2001094432A1/de not_active Ceased
- 2001-05-25 JP JP2002501979A patent/JP4903973B2/ja not_active Expired - Fee Related
- 2001-05-25 RU RU2003100394/04A patent/RU2003100394A/ru not_active Application Discontinuation
- 2001-05-25 PL PL358983A patent/PL199382B1/pl unknown
- 2001-05-25 BR BR0111517-0A patent/BR0111517A/pt not_active Application Discontinuation
- 2001-05-25 CA CA2411680A patent/CA2411680C/en not_active Expired - Fee Related
- 2001-05-25 AU AU2001263939A patent/AU2001263939A1/en not_active Abandoned
- 2001-05-25 EP EP01938236A patent/EP1297037A1/de not_active Withdrawn
- 2001-05-25 KR KR1020027016650A patent/KR20030010669A/ko not_active Withdrawn
- 2001-05-28 US US10/297,292 patent/US20030171518A1/en not_active Abandoned
- 2001-06-06 TW TW090113636A patent/TWI307347B/zh not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004035669A1 (en) | 2002-10-17 | 2004-04-29 | Bayer Inc. | Hydrogenated nitrile rubber composites with improved processability |
| WO2004035679A1 (en) * | 2002-10-17 | 2004-04-29 | Bayer Inc. | Polymer blends comprising low molecular weight nitrile rubber |
| WO2004035670A1 (en) | 2002-10-17 | 2004-04-29 | Bayer Inc. | Polymer composites comprising low molecular weight nitrile rubber |
| CN1322041C (zh) * | 2002-10-17 | 2007-06-20 | 兰科瑟斯有限公司 | 具有改进可加工性的氢化丁腈橡胶复合材料 |
| CN1325546C (zh) * | 2002-10-17 | 2007-07-11 | 兰科瑟斯有限公司 | 包含低分子量丁腈橡胶的聚合物复合材料 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2411680A1 (en) | 2002-12-04 |
| JP4903973B2 (ja) | 2012-03-28 |
| PL358983A1 (en) | 2004-08-23 |
| MXPA02012109A (es) | 2003-06-06 |
| TWI307347B (en) | 2009-03-11 |
| PL199382B1 (pl) | 2008-09-30 |
| BR0111517A (pt) | 2003-05-06 |
| JP2003535931A (ja) | 2003-12-02 |
| EP1297037A1 (de) | 2003-04-02 |
| RU2003100394A (ru) | 2004-07-10 |
| US20030171518A1 (en) | 2003-09-11 |
| WO2001094432A1 (de) | 2001-12-13 |
| CA2411680C (en) | 2011-07-26 |
| AU2001263939A1 (en) | 2001-12-17 |
| KR20030010669A (ko) | 2003-02-05 |
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