CS231980B2 - Manufacturing process of a catalytic system for production poly-alfa-olefines - Google Patents
Manufacturing process of a catalytic system for production poly-alfa-olefines Download PDFInfo
- Publication number
- CS231980B2 CS231980B2 CS811435A CS143581A CS231980B2 CS 231980 B2 CS231980 B2 CS 231980B2 CS 811435 A CS811435 A CS 811435A CS 143581 A CS143581 A CS 143581A CS 231980 B2 CS231980 B2 CS 231980B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- solid product
- polymerization
- iii
- reaction
- product
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 22
- 230000003197 catalytic effect Effects 0.000 title claims description 5
- 239000012265 solid product Substances 0.000 claims abstract description 135
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 128
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 118
- 239000003054 catalyst Substances 0.000 claims abstract description 107
- 238000000034 method Methods 0.000 claims abstract description 103
- 229920000642 polymer Polymers 0.000 claims abstract description 95
- 150000001875 compounds Chemical class 0.000 claims abstract description 61
- 239000004711 α-olefin Substances 0.000 claims abstract description 60
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 55
- 230000008569 process Effects 0.000 claims abstract description 45
- 238000006243 chemical reaction Methods 0.000 claims description 62
- 239000002904 solvent Substances 0.000 claims description 47
- -1 azosooueeniiins Chemical class 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 20
- 239000000047 product Substances 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 13
- 150000002170 ethers Chemical class 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 6
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- 239000000460 chlorine Chemical group 0.000 claims description 5
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 150000001299 aldehydes Chemical class 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 4
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 159000000032 aromatic acids Chemical class 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000002513 isocyanates Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 150000003003 phosphines Chemical class 0.000 claims description 3
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 3
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 claims description 3
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims description 3
- 239000005049 silicon tetrachloride Substances 0.000 claims description 3
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical group ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 2
- 230000009471 action Effects 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 229910052740 iodine Chemical group 0.000 claims description 2
- 229920013639 polyalphaolefin Polymers 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims 2
- 229910021549 Vanadium(II) chloride Inorganic materials 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 claims 1
- OXPWHPCCUXESFQ-UHFFFAOYSA-N tert-butyl 4-(3-hydroxypropyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCC(CCCO)CC1 OXPWHPCCUXESFQ-UHFFFAOYSA-N 0.000 claims 1
- 238000012685 gas phase polymerization Methods 0.000 abstract description 39
- 239000002245 particle Substances 0.000 abstract description 17
- 230000008901 benefit Effects 0.000 abstract description 13
- 229920000098 polyolefin Polymers 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 10
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 88
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 88
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 87
- 230000000052 comparative effect Effects 0.000 description 81
- 230000008859 change Effects 0.000 description 38
- 238000007792 addition Methods 0.000 description 32
- 229910052757 nitrogen Inorganic materials 0.000 description 27
- 230000004913 activation Effects 0.000 description 25
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 24
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 20
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 19
- 239000001257 hydrogen Substances 0.000 description 18
- 229910052739 hydrogen Inorganic materials 0.000 description 18
- 239000005977 Ethylene Substances 0.000 description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 16
- 239000007789 gas Substances 0.000 description 14
- 239000002002 slurry Substances 0.000 description 13
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 11
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
- 239000000725 suspension Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000010908 decantation Methods 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 238000012673 precipitation polymerization Methods 0.000 description 9
- 239000012295 chemical reaction liquid Substances 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 238000001556 precipitation Methods 0.000 description 8
- 239000000370 acceptor Substances 0.000 description 7
- 229920001585 atactic polymer Polymers 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000007872 degassing Methods 0.000 description 6
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 230000037048 polymerization activity Effects 0.000 description 6
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 238000002441 X-ray diffraction Methods 0.000 description 5
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
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- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
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- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 238000002329 infrared spectrum Methods 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N n-hexene Natural products CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluenecarboxylic acid Natural products CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 239000011949 solid catalyst Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
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- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229920006125 amorphous polymer Polymers 0.000 description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 2
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- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
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- 230000006866 deterioration Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
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- 238000009826 distribution Methods 0.000 description 2
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 2
- 125000004494 ethyl ester group Chemical group 0.000 description 2
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
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- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
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- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- ZEYHEAKUIGZSGI-UHFFFAOYSA-N para-methoxy benzoic acid Natural products COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 2
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 2
- 125000005538 phosphinite group Chemical group 0.000 description 2
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- 229910052719 titanium Inorganic materials 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
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- 238000000605 extraction Methods 0.000 description 1
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- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
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- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
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- OLXYLDUSSBULGU-UHFFFAOYSA-N methyl pyridine-4-carboxylate Chemical compound COC(=O)C1=CC=NC=C1 OLXYLDUSSBULGU-UHFFFAOYSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
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- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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- 238000012216 screening Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
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- 235000011150 stannous chloride Nutrition 0.000 description 1
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- 239000011593 sulfur Chemical group 0.000 description 1
- HBBBDGWCSBWWKP-UHFFFAOYSA-J tetrachloroantimony Chemical compound Cl[Sb](Cl)(Cl)Cl HBBBDGWCSBWWKP-UHFFFAOYSA-J 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- PGAPATLGJSQQBU-UHFFFAOYSA-M thallium(i) bromide Chemical compound [Tl]Br PGAPATLGJSQQBU-UHFFFAOYSA-M 0.000 description 1
- VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical compound C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 description 1
- 229910052861 titanite Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
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- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Natural products C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- USJZIJNMRRNDPO-UHFFFAOYSA-N tris-decylalumane Chemical compound CCCCCCCCCC[Al](CCCCCCCCCC)CCCCCCCCCC USJZIJNMRRNDPO-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/902—Monomer polymerized in bulk in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55023785A JPS6023764B2 (ja) | 1980-02-27 | 1980-02-27 | α−オレフイン重合体を製造する方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS143581A2 CS143581A2 (en) | 1984-01-16 |
| CS231980B2 true CS231980B2 (en) | 1985-01-16 |
Family
ID=12119972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS811435A CS231980B2 (en) | 1980-02-27 | 1981-02-27 | Manufacturing process of a catalytic system for production poly-alfa-olefines |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US4309521A (cg-RX-API-DMAC7.html) |
| JP (1) | JPS6023764B2 (cg-RX-API-DMAC7.html) |
| AU (1) | AU545468B2 (cg-RX-API-DMAC7.html) |
| BE (1) | BE887678A (cg-RX-API-DMAC7.html) |
| CA (1) | CA1142698A (cg-RX-API-DMAC7.html) |
| CS (1) | CS231980B2 (cg-RX-API-DMAC7.html) |
| DE (1) | DE3107334C2 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2476656A1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB2070630B (cg-RX-API-DMAC7.html) |
| IT (1) | IT1170758B (cg-RX-API-DMAC7.html) |
| NL (1) | NL185456C (cg-RX-API-DMAC7.html) |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS591723B2 (ja) * | 1980-01-17 | 1984-01-13 | チッソ株式会社 | α−オレフイン重合体を製造する方法 |
| JPS6023764B2 (ja) * | 1980-02-27 | 1985-06-10 | チッソ株式会社 | α−オレフイン重合体を製造する方法 |
| JPS6042807B2 (ja) * | 1980-04-11 | 1985-09-25 | チッソ株式会社 | エチレンプロピレンα−オレフイン三元共重合体の製造方法 |
| US4405769A (en) * | 1980-08-12 | 1983-09-20 | Capshew Charles E | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
| US4410671A (en) * | 1980-08-12 | 1983-10-18 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
| JPS5759902A (en) * | 1980-09-29 | 1982-04-10 | Chisso Corp | Preparation of alpha-olefinic polymer |
| CA1185400A (en) * | 1981-07-23 | 1985-04-09 | Akihiro Sato | PROCESS FOR PRODUCING .alpha.-OLEFIN POLYMERS |
| JPS5823806A (ja) * | 1981-08-04 | 1983-02-12 | Chisso Corp | α−オレフイン重合体を製造する方法 |
| JPS5817104A (ja) * | 1981-07-23 | 1983-02-01 | Chisso Corp | α−オレフイン重合体の製造方法 |
| DE3144312A1 (de) * | 1981-11-07 | 1983-05-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von propylen-ethylen-polymerisaten vom typ der sogenannten block-copolymerisate |
| GB2114581B (en) * | 1981-12-17 | 1985-08-14 | Chisso Corp | Ziegler catalyst for producing polypropylene |
| JPS58189206A (ja) * | 1982-04-30 | 1983-11-04 | Chisso Corp | α−オレフイン重合用触媒成分 |
| JPS58201816A (ja) * | 1982-05-19 | 1983-11-24 | Chisso Corp | 高剛性成形品用プロピレンエチレンブロツク共重合体とその製造法 |
| JPS58213006A (ja) * | 1982-06-03 | 1983-12-10 | Chisso Corp | α−オレフイン重合用触媒成分とその製造法 |
| JPS58219207A (ja) * | 1982-06-15 | 1983-12-20 | Chisso Corp | 高剛性高溶融粘弾性ポリプロピレンとその製造法 |
| JPS5922913A (ja) * | 1982-07-15 | 1984-02-06 | Chisso Corp | 高剛性成形品用ポリプロピレン樹脂 |
| FR2541683B1 (fr) * | 1983-02-28 | 1986-05-09 | Ato Chimie | Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme |
| IL71357A (en) * | 1983-03-29 | 1987-03-31 | Union Carbide Corp | Process for producing low density ethylene copolymers |
| JPS6028405A (ja) * | 1983-07-27 | 1985-02-13 | Sumitomo Chem Co Ltd | α−オレフィン重合体の製造法 |
| JPS60135409A (ja) * | 1983-12-23 | 1985-07-18 | Chisso Corp | オレフイン重合用触媒とその製造法 |
| US4563512A (en) * | 1984-02-28 | 1986-01-07 | Shell Oil Company | Olefin polymerization process utilizing a combination of selectivity control agents |
| US5330949A (en) * | 1985-06-17 | 1994-07-19 | Idemitsu Petrochemical Company, Ltd. | Method for producing polyolefin |
| US4657883A (en) * | 1985-10-07 | 1987-04-14 | Amoco Corporation | Ester-modified olefin polymerization catalyst |
| JPS62209104A (ja) * | 1985-12-05 | 1987-09-14 | Chisso Corp | α−オレフイン重合用固体触媒成分及びその製造方法 |
| EP0279863B1 (en) * | 1986-08-26 | 1992-10-14 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefin and polymerization process |
| CA1284549C (en) * | 1986-09-26 | 1991-05-28 | Fathi David Hussein | Process for the polymerization of propylene |
| FI86867C (fi) * | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
| US5587436A (en) * | 1992-11-12 | 1996-12-24 | Quantum Chemical Corporation | Process for controlling the polymerization of propylene and ethylene and copolymer products |
| US5705576A (en) * | 1992-11-12 | 1998-01-06 | Quantum Chemical Corporation | Process for controlling production of in-situ thermoplastic polyolefins and products |
| US5314746A (en) * | 1992-11-12 | 1994-05-24 | Quantum Chemical Corporation | Soft, puncture- and tear-resistant polyolefin films |
| BE1007698A3 (fr) * | 1993-11-04 | 1995-10-03 | Solvay | Systeme catalytique utilisable pour la polymerisation des alpha-olefines et procede pour cette polymerisation. |
| FI96216C (fi) * | 1994-12-16 | 1996-05-27 | Borealis Polymers Oy | Prosessi polyeteenin valmistamiseksi |
| EP0774489B1 (en) | 1995-11-17 | 2001-09-19 | Japan Polychem Corporation | Thermoplastic resin composition |
| US6130305A (en) * | 1996-09-19 | 2000-10-10 | Idemitsu Petrochemical Co., Ltd. | Propylenic copolymer and its film |
| DE19635503A1 (de) | 1996-09-02 | 1998-03-05 | Basf Ag | Weißbrucharme, zähmodifizierte Propylenpolymerisate |
| KR100240519B1 (ko) * | 1997-09-11 | 2000-01-15 | 유현식 | 새로운 올레핀 중합용 킬레이트 촉매 및 이를 이용한 올레핀중합 방법 |
| US6046126A (en) * | 1998-05-12 | 2000-04-04 | Kelly; Mark | Titanium process for making catalyst |
| KR100524293B1 (ko) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| JP3689671B2 (ja) | 1999-10-23 | 2005-08-31 | サムソン ジェネラル ケミカルズ カンパニー リミテッド | 改善されたオレフィン重合及び共重合用触媒 |
| KR100361224B1 (ko) * | 1999-12-01 | 2002-11-29 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매의 제조방법 |
| KR100359932B1 (ko) | 2000-06-15 | 2002-11-07 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100387734B1 (ko) * | 2000-06-17 | 2003-06-18 | 삼성종합화학주식회사 | 올레핀 중합용 촉매 및 중합방법 |
| KR100389475B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| KR100389476B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
| KR100389477B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
| KR100389962B1 (ko) * | 2000-11-10 | 2003-07-02 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| KR100421551B1 (ko) * | 2000-12-16 | 2004-03-09 | 삼성아토피나주식회사 | 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법 |
| US7067576B2 (en) * | 2000-12-22 | 2006-06-27 | Samsung Atofina, Co., Ltd. | Flame retardant polypropylene resin composition |
| US6872683B2 (en) * | 2000-12-22 | 2005-03-29 | Samsung Atofina Co., Ltd. | Method for preparing chelated catalyst for olefin polymerization |
| WO2002051933A1 (en) * | 2000-12-22 | 2002-07-04 | Samsung General Chemicals Co., Ltd. | Polypropylene resin composition with improved surface hardness and scratch resistance properties |
| DE60022915T2 (de) * | 2000-12-22 | 2006-06-29 | Samsung General Chemicals Co. Ltd., Seosan | Polyolefinharzzusammensetzung |
| KR100496776B1 (ko) * | 2001-06-21 | 2005-06-22 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100530794B1 (ko) * | 2001-06-21 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| WO2007105344A1 (ja) | 2006-03-10 | 2007-09-20 | Mitsubishi Chemical Corporation | 樹脂分散体、塗料、積層体及びその製造方法 |
| KR101141494B1 (ko) * | 2007-09-05 | 2012-05-03 | 에스케이이노베이션 주식회사 | 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법 |
| KR101152413B1 (ko) * | 2008-09-12 | 2012-06-05 | 에스케이이노베이션 주식회사 | 에틸렌 공중합체 및 이의 제조방법 |
| EP2186833B8 (en) | 2008-11-17 | 2012-08-08 | Borealis AG | Multi-stage process for producing polytheylene with lowered gel formation |
| US8877310B2 (en) | 2010-09-14 | 2014-11-04 | Japan Polypropylene Corporation | Propylene resin multi-layer sheet, and packaging body for heat treatment using same |
| EP2642008B1 (en) | 2010-11-16 | 2016-10-05 | Adeka Corporation | Method for stabilizing polymer for long term, method for producing nonwoven fabric, and method for producing elastomer composition |
| WO2012117823A1 (ja) | 2011-03-02 | 2012-09-07 | 株式会社Adeka | ラミネートフィルムおよび塗装部材用樹脂組成物の製造方法 |
| EP2570455A1 (en) | 2011-09-16 | 2013-03-20 | Borealis AG | Polyethylene composition with broad molecular weight distribution and improved homogeneity |
| JP2013199551A (ja) | 2012-03-23 | 2013-10-03 | Adeka Corp | 家電材料用及び自動車内装材料用オレフィン樹脂組成物の製造方法 |
| JP6330302B2 (ja) | 2012-12-07 | 2018-05-30 | 日本ポリプロ株式会社 | 繊維強化ポリプロピレン系樹脂組成物及びその成形体 |
| EP3053948A4 (en) | 2013-09-30 | 2017-05-24 | Sekisui Chemical Co., Ltd. | Crosslinked polyolefin resin foam sheet |
| JP6579955B2 (ja) | 2013-10-21 | 2019-09-25 | 株式会社Adeka | 安定化されたポリマーの製造方法 |
| CN108291047B (zh) | 2015-11-30 | 2020-07-03 | 积水化学工业株式会社 | 聚烯烃系树脂发泡片材及粘合胶带 |
| BR112018077454A2 (pt) * | 2016-06-30 | 2019-04-02 | Dow Global Technologies Llc | composições de procatalisador úteis para baixa incorporação de comonômero e processo para preparar as mesmas |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB885869A (en) * | 1960-06-22 | 1961-12-28 | Sun Oil Co | Improvements in or relating to the preparation of solid polymers of olefins |
| GB1299863A (en) * | 1969-01-23 | 1972-12-13 | Shell Int Research | Improvements in or relating to the catalytic polymerisation of olefins |
| CH543546A (fr) * | 1971-03-23 | 1973-10-31 | Solvay | Système catalytique de polymérisation des alpha-oléfines |
| LU65954A1 (cg-RX-API-DMAC7.html) * | 1972-08-25 | 1974-03-07 | ||
| IE40215B1 (en) * | 1973-12-04 | 1979-04-11 | Ici Ltd | Olefine polymer, olefine polymerisation process and catalyst |
| JPS5132493A (en) * | 1974-09-13 | 1976-03-19 | Mitsubishi Chem Ind | Arufua orefuinjugoyoshokubai no seiho |
| GB1548573A (en) * | 1975-06-16 | 1979-07-18 | Ici Ltd | Polymerisation catalyst and process |
| GB1557329A (en) * | 1975-10-16 | 1979-12-05 | Exxon Research Engineering Co | Reduction of tici with reducing agents with lewis bases |
| US4200717A (en) * | 1977-04-06 | 1980-04-29 | Mitsubishi Chemical Industries, Ltd. | Preparation of propylene polymer-containing solid titanium trichloride and propylene polymers using same |
| JPS5835525B2 (ja) * | 1978-04-28 | 1983-08-03 | 株式会社トクヤマ | ポリオレフィンの製造方法 |
| US4295991A (en) * | 1978-09-26 | 1981-10-20 | Exxon Research & Engineering Co. | Titanium trichloride catalyst component and the process for the production thereof |
| US4395358A (en) * | 1979-02-12 | 1983-07-26 | Exxon Research & Engineering Co. | Titanium trichloride catalyst complex and process for the production thereof |
| JPS6023764B2 (ja) * | 1980-02-27 | 1985-06-10 | チッソ株式会社 | α−オレフイン重合体を製造する方法 |
| US4324693A (en) * | 1980-10-10 | 1982-04-13 | Standard Oil Company (Indiana) | Olefin polymerization catalyst |
-
1980
- 1980-02-27 JP JP55023785A patent/JPS6023764B2/ja not_active Expired
- 1980-05-14 US US06/149,684 patent/US4309521A/en not_active Expired - Lifetime
-
1981
- 1981-02-13 CA CA000370888A patent/CA1142698A/en not_active Expired
- 1981-02-19 NL NLAANVRAGE8100824,A patent/NL185456C/xx not_active IP Right Cessation
- 1981-02-25 BE BE0/203922A patent/BE887678A/fr not_active IP Right Cessation
- 1981-02-25 FR FR8103725A patent/FR2476656A1/fr active Granted
- 1981-02-26 DE DE3107334A patent/DE3107334C2/de not_active Expired
- 1981-02-26 AU AU67671/81A patent/AU545468B2/en not_active Ceased
- 1981-02-26 IT IT47897/81A patent/IT1170758B/it active
- 1981-02-26 GB GB8106084A patent/GB2070630B/en not_active Expired
- 1981-02-27 CS CS811435A patent/CS231980B2/cs unknown
-
1984
- 1984-04-12 US US06/599,741 patent/US4514513A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NL185456B (nl) | 1989-11-16 |
| US4309521A (en) | 1982-01-05 |
| IT8147897A0 (it) | 1981-02-26 |
| DE3107334A1 (de) | 1981-12-10 |
| CS143581A2 (en) | 1984-01-16 |
| DE3107334C2 (de) | 1986-06-19 |
| GB2070630B (en) | 1984-04-26 |
| GB2070630A (en) | 1981-09-09 |
| FR2476656B1 (cg-RX-API-DMAC7.html) | 1984-02-17 |
| AU545468B2 (en) | 1985-07-18 |
| CA1142698A (en) | 1983-03-08 |
| JPS6023764B2 (ja) | 1985-06-10 |
| NL8100824A (nl) | 1981-09-16 |
| JPS56120712A (en) | 1981-09-22 |
| US4514513A (en) | 1985-04-30 |
| BE887678A (fr) | 1981-06-15 |
| AU6767181A (en) | 1981-09-03 |
| FR2476656A1 (fr) | 1981-08-28 |
| NL185456C (nl) | 1990-04-17 |
| IT1170758B (it) | 1987-06-03 |
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