CO6141471A2 - Proceso de fabricacion de particulas a base de carbonato de calcio natural y de sales de acido etileno acrilico, suspensiones y pigmentos secos obtenidos y sus utilizaciones - Google Patents

Proceso de fabricacion de particulas a base de carbonato de calcio natural y de sales de acido etileno acrilico, suspensiones y pigmentos secos obtenidos y sus utilizaciones

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Publication number
CO6141471A2
CO6141471A2 CO08075572A CO08075572A CO6141471A2 CO 6141471 A2 CO6141471 A2 CO 6141471A2 CO 08075572 A CO08075572 A CO 08075572A CO 08075572 A CO08075572 A CO 08075572A CO 6141471 A2 CO6141471 A2 CO 6141471A2
Authority
CO
Colombia
Prior art keywords
stage
pigment
calcium carbonate
aqueous medium
mineral matter
Prior art date
Application number
CO08075572A
Other languages
English (en)
Inventor
Matthias Buri
Patrick A C Gane
Phillipp Hunziker
Rene Burkhalter
Beat Karth
Original Assignee
Omya Development Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Omya Development Ag filed Critical Omya Development Ag
Publication of CO6141471A2 publication Critical patent/CO6141471A2/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04—Homopolymers or copolymers of ethene
    • C09D123/08—Copolymers of ethene
    • C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09D123/0869—Acids or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/50—Mixing liquids with solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • C01F11/185—After-treatment, e.g. grinding, purification, conversion of crystal morphology
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C09C1/021—Calcium carbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/385—Oxides, hydroxides or carbonates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/32—Thermal properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2244—Oxides; Hydroxides of metals of zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Dispersion Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

La presente invención consiste en un proceso de preparación de al menos una materia mineral y/o de al menos un pigmento, que incluye un carbonato de calcio hecho a la vez parcialmente organofílico y parcialmente hidrófilo, en el cual el carbonato es mezclado y/o molido y/o concentrado en medio acuoso, en presencia de al menos una sal del ácido etileno acrílico, siendo un agente dispersante y/o de ayuda a la molienda introducido antes y/o durante esta etapa de tratamiento. Otro objeto de la invención radica en las dispersiones y las suspensiones acuosas de carbonato de calcio así obtenidas. Pueden ser secadas y los pigmentos secos obtenidos también constituyen un objeto de la invención. El uso de estas dispersiones acuosas y de estos pigmentos secos en el ámbito del plástico, de las pinturas y del papel constituye otro objeto de la invención. 1.- Proceso de preparación de al menos una materia mineral y/o de al menos un pigmento que incluye carbonato de calcio natural y/o precipitado, preferentemente natural, a la vez parcialmente organofílico y parcialmente hidrófilo y que incluye las etapas de: a) suministrar al menos una materia mineral y/o un pigmento que incluye carbonato de calcio natural y/o precipitado, preferentemente natural, en forma seca o en forma de una dispersión y/o de una suspensión acuosa, b) eventualmente moler en seco y/o en medio acuoso la materia mineral y/o el pigmento resultante de la etapa a) c) tratar la materia mineral y/o el pigmento resultante de la etapa a) y/o de la etapa b) d) eventualmente secar la materia mineral y/o el pigmento resultante de la etapa a) y/o b) y/o c) Caracterizado en que: - la etapa c) de tratamiento corresponde a una etapa de mezcla en medio acuoso y/o de molienda en medio acuoso, y/o de concentración en medio acuoso, de la materia mineral y/o del pigmento procedente de la etapa a) y/o de la etapa b), en presencia de al menos una sal del ácido etileno acrílico, - un agente dispersante y/o de ayuda a la molienda es introducido antes y/o durante la etapa de tratamiento c).2.- Proceso según la reivindicación 1, caracterizado en que la sal de ácido etileno acrílico es una sal soluble en medio acuoso.
CO08075572A 2006-01-19 2008-07-22 Proceso de fabricacion de particulas a base de carbonato de calcio natural y de sales de acido etileno acrilico, suspensiones y pigmentos secos obtenidos y sus utilizaciones CO6141471A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0600491A FR2896171B1 (fr) 2006-01-19 2006-01-19 Procede de fabrication de particules a base de carbonate de calcium naturel et de sels d'acide ethylene acrylique, suspensions et pigments secs obtenus, leurs utilisations.

Publications (1)

Publication Number Publication Date
CO6141471A2 true CO6141471A2 (es) 2010-03-19

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Family Applications (1)

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CO08075572A CO6141471A2 (es) 2006-01-19 2008-07-22 Proceso de fabricacion de particulas a base de carbonato de calcio natural y de sales de acido etileno acrilico, suspensiones y pigmentos secos obtenidos y sus utilizaciones

Country Status (26)

Country Link
US (3) US9944815B2 (es)
EP (1) EP1979420B1 (es)
JP (1) JP5384116B2 (es)
KR (1) KR101339488B1 (es)
CN (2) CN104312210A (es)
AR (1) AR059041A1 (es)
AU (1) AU2007206647B2 (es)
BR (1) BRPI0706680B1 (es)
CA (1) CA2636474C (es)
CO (1) CO6141471A2 (es)
DK (1) DK1979420T3 (es)
EG (1) EG26372A (es)
ES (1) ES2428542T3 (es)
FR (1) FR2896171B1 (es)
HK (1) HK1124357A1 (es)
IL (1) IL192659A (es)
NO (1) NO341106B1 (es)
NZ (1) NZ569705A (es)
PL (1) PL1979420T3 (es)
PT (1) PT1979420E (es)
RU (1) RU2433153C2 (es)
SI (1) SI1979420T1 (es)
TW (1) TWI421311B (es)
UA (1) UA100494C2 (es)
WO (1) WO2007083208A1 (es)
ZA (1) ZA200806109B (es)

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PT2626388T (pt) * 2012-02-09 2016-08-17 Omya Int Ag Uma composição e método para o controlo da molhabilidade de superfícies
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CN103450860A (zh) * 2012-06-01 2013-12-18 天津中油渤星工程科技有限公司 一种改善水泥浆与钻井液相容性的分散剂
CN102702843B (zh) * 2012-06-07 2014-12-03 林庆福 水性车线糊及其制备方法
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GB201322840D0 (en) 2013-12-23 2014-02-12 Imerys Minerals Ltd Aqueous suspension of inorganic particulate material
CN103923489A (zh) * 2014-03-26 2014-07-16 江西广源化工有限责任公司 一种超分散性悬浮碳酸钙乳液的制备方法
ES2691797T3 (es) * 2014-04-16 2018-11-28 Omya International Ag Reducción de la captación de humedad en productos de carga mineral que contienen poliol
TR201808703T4 (tr) 2014-11-07 2018-07-23 Omya Int Ag Kalsiyum karbonat içeren bir malzeme ihtiva eden bir süspansiyonun üretimine yönelik yöntem.
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NZ569705A (en) 2011-08-26
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EP1979420A1 (fr) 2008-10-15
KR101339488B1 (ko) 2013-12-10
CA2636474A1 (en) 2007-07-26
JP5384116B2 (ja) 2014-01-08
PL1979420T3 (pl) 2013-11-29
US9944815B2 (en) 2018-04-17
AR059041A1 (es) 2008-03-12
PT1979420E (pt) 2013-10-02
EP1979420B1 (fr) 2013-06-26
TW200745273A (en) 2007-12-16
JP2009523882A (ja) 2009-06-25
ES2428542T3 (es) 2013-11-08
US20170015859A1 (en) 2017-01-19
RU2433153C2 (ru) 2011-11-10
HK1124357A1 (en) 2009-07-10
AU2007206647B2 (en) 2012-09-27
US20100222484A1 (en) 2010-09-02
BRPI0706680A2 (pt) 2011-04-05
TWI421311B (zh) 2014-01-01
UA100494C2 (ru) 2013-01-10
NO20083428L (no) 2008-10-07
US10011731B2 (en) 2018-07-03
WO2007083208A1 (fr) 2007-07-26
IL192659A0 (en) 2009-02-11
BRPI0706680B1 (pt) 2016-10-04
WO2007083208A8 (fr) 2008-09-18
US10011732B2 (en) 2018-07-03
US20150284530A1 (en) 2015-10-08
ZA200806109B (en) 2009-11-25
KR20080090514A (ko) 2008-10-08
CA2636474C (en) 2015-11-17
CN104312210A (zh) 2015-01-28
SI1979420T1 (sl) 2013-11-29
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AU2007206647A1 (en) 2007-07-26
IL192659A (en) 2016-03-31
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NO341106B1 (no) 2017-08-28
FR2896171A1 (fr) 2007-07-20

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