CN1886451A - 橡胶组合物以及降低正切δ值和磨损指数的方法 - Google Patents
橡胶组合物以及降低正切δ值和磨损指数的方法 Download PDFInfo
- Publication number
- CN1886451A CN1886451A CNA2004800350902A CN200480035090A CN1886451A CN 1886451 A CN1886451 A CN 1886451A CN A2004800350902 A CNA2004800350902 A CN A2004800350902A CN 200480035090 A CN200480035090 A CN 200480035090A CN 1886451 A CN1886451 A CN 1886451A
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- Prior art keywords
- rubber combination
- silica
- rubber
- described rubber
- alkyl
- Prior art date
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 209
- 239000005060 rubber Substances 0.000 title claims abstract description 208
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title description 21
- 238000005299 abrasion Methods 0.000 title description 18
- 230000003247 decreasing effect Effects 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 141
- -1 nitrogen-containing compound Chemical class 0.000 claims abstract description 89
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 66
- 239000007822 coupling agent Substances 0.000 claims abstract description 47
- CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical compound NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000000945 filler Substances 0.000 claims abstract description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 28
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 15
- 229920000768 polyamine Polymers 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- 239000011593 sulfur Substances 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 150000007524 organic acids Chemical class 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 229920003052 natural elastomer Polymers 0.000 claims description 6
- 229920001194 natural rubber Polymers 0.000 claims description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims description 5
- BVMWIXWOIGJRGE-UHFFFAOYSA-N NP(O)=O Chemical compound NP(O)=O BVMWIXWOIGJRGE-UHFFFAOYSA-N 0.000 claims description 4
- 230000005540 biological transmission Effects 0.000 claims description 4
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 4
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 claims description 4
- IEYHAWUTWZRCGE-UHFFFAOYSA-N S(=O)(=O)(O)P(O)(=O)N Chemical compound S(=O)(=O)(O)P(O)(=O)N IEYHAWUTWZRCGE-UHFFFAOYSA-N 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 2
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims description 2
- HUGXNORHVOECNM-UHFFFAOYSA-N 3-chloro-2-methylprop-1-ene;2-methylbuta-1,3-diene Chemical compound CC(=C)CCl.CC(=C)C=C HUGXNORHVOECNM-UHFFFAOYSA-N 0.000 claims description 2
- 229920002943 EPDM rubber Polymers 0.000 claims description 2
- 235000004443 Ricinus communis Nutrition 0.000 claims description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 2
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 claims description 2
- RTACIUYXLGWTAE-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene;styrene Chemical compound C=CC=C.CC(=C)C=C.C=CC1=CC=CC=C1 RTACIUYXLGWTAE-UHFFFAOYSA-N 0.000 claims description 2
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical group CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 claims description 2
- 125000000000 cycloalkoxy group Chemical group 0.000 claims description 2
- 125000005265 dialkylamine group Chemical group 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- 239000005350 fused silica glass Substances 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- UORVCLMRJXCDCP-UHFFFAOYSA-N propynoic acid Chemical compound OC(=O)C#C UORVCLMRJXCDCP-UHFFFAOYSA-N 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- 125000002843 carboxylic acid group Chemical group 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 81
- 239000006229 carbon black Substances 0.000 description 21
- 235000019241 carbon black Nutrition 0.000 description 21
- 239000000463 material Substances 0.000 description 21
- 230000000704 physical effect Effects 0.000 description 19
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 13
- 238000013329 compounding Methods 0.000 description 13
- 230000008569 process Effects 0.000 description 11
- 241001441571 Hiodontidae Species 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 238000005096 rolling process Methods 0.000 description 9
- 238000007711 solidification Methods 0.000 description 9
- 230000008023 solidification Effects 0.000 description 9
- 239000002585 base Substances 0.000 description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 235000021355 Stearic acid Nutrition 0.000 description 6
- 150000003973 alkyl amines Chemical class 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 6
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 6
- 239000008117 stearic acid Substances 0.000 description 6
- NESLVXDUKMNMOG-UHFFFAOYSA-N triethoxy-(propyltetrasulfanyl)silane Chemical compound CCCSSSS[Si](OCC)(OCC)OCC NESLVXDUKMNMOG-UHFFFAOYSA-N 0.000 description 6
- 102000005606 Activins Human genes 0.000 description 5
- 108010059616 Activins Proteins 0.000 description 5
- 239000000488 activin Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 230000004087 circulation Effects 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000006884 silylation reaction Methods 0.000 description 5
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- UEZWYKZHXASYJN-UHFFFAOYSA-N cyclohexylthiophthalimide Chemical compound O=C1C2=CC=CC=C2C(=O)N1SC1CCCCC1 UEZWYKZHXASYJN-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 4
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 125000001118 alkylidene group Chemical group 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000012763 reinforcing filler Substances 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VZFUCHSFHOYXIS-UHFFFAOYSA-N Cycloheptanecarboxylic acid Chemical compound OC(=O)C1CCCCCC1 VZFUCHSFHOYXIS-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 2
- JBDSSBMEKXHSJF-UHFFFAOYSA-N cyclopentanecarboxylic acid Chemical compound OC(=O)C1CCCC1 JBDSSBMEKXHSJF-UHFFFAOYSA-N 0.000 description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 2
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 2
- 229940043276 diisopropanolamine Drugs 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 229910052621 halloysite Inorganic materials 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004646 sulfenyl group Chemical group S(*)* 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- WGRZHLPEQDVPET-UHFFFAOYSA-N 2-methoxyethoxysilane Chemical compound COCCO[SiH3] WGRZHLPEQDVPET-UHFFFAOYSA-N 0.000 description 1
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 1
- CJNRGSHEMCMUOE-UHFFFAOYSA-N 2-piperidin-1-ylethanamine Chemical class NCCN1CCCCC1 CJNRGSHEMCMUOE-UHFFFAOYSA-N 0.000 description 1
- KJWMCPYEODZESQ-UHFFFAOYSA-N 4-Dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=C(O)C=C1 KJWMCPYEODZESQ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
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- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical group Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 description 1
- KORAJTACFWEGPU-UHFFFAOYSA-N triethoxy-[6-(6-triethoxysilylhexyltetrasulfanyl)hexyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCCCCSSSSCCCCCC[Si](OCC)(OCC)OCC KORAJTACFWEGPU-UHFFFAOYSA-N 0.000 description 1
- XQCNPXMIHJAHGO-UHFFFAOYSA-N trimethoxy-[(trimethoxysilylmethyltetrasulfanyl)methyl]silane Chemical compound CO[Si](OC)(OC)CSSSSC[Si](OC)(OC)OC XQCNPXMIHJAHGO-UHFFFAOYSA-N 0.000 description 1
- SVNJQEIWNMNTBW-UHFFFAOYSA-N trimethoxy-[18-(18-trimethoxysilyloctadecyltetrasulfanyl)octadecyl]silane Chemical compound CO[Si](OC)(OC)CCCCCCCCCCCCCCCCCCSSSSCCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SVNJQEIWNMNTBW-UHFFFAOYSA-N 0.000 description 1
- IPBOZRUUILDBBF-UHFFFAOYSA-N trimethoxy-[2-methyl-1-[(2-methyl-1-trimethoxysilylpropyl)tetrasulfanyl]propyl]silane Chemical compound CO[Si](OC)(OC)C(C(C)C)SSSSC(C(C)C)[Si](OC)(OC)OC IPBOZRUUILDBBF-UHFFFAOYSA-N 0.000 description 1
- WUMASLCNJBRHDA-UHFFFAOYSA-N trimethoxy-[4-(4-trimethoxysilylbutyltetrasulfanyl)butyl]silane Chemical compound CO[Si](OC)(OC)CCCCSSSSCCCC[Si](OC)(OC)OC WUMASLCNJBRHDA-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/40—Thiurams, i.e. compounds containing groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5398—Phosphorus bound to sulfur
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/548—Silicon-containing compounds containing sulfur
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
ASTM标号(D-1765-82a) | 表面积(m2/g)(D-3765) |
N-110 | 126 |
N-234 | 120 |
N-220 | 111 |
N-339 | 95 |
N-330 | 83 |
N-550 | 42 |
N-660 | 35 |
对比例/实施例 | A | B | C | D | 1 | 2 |
SIR-201 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 |
N-220BLACK2 | 59.00 | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
ZEOSIL 11653 | 0.00 | 60.00 | 60.00 | 60.00 | 60.00 | 60.00 |
SUNDEX 7904 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 |
SILQUEST A-12895 | 000 | 4.80 | 3.60 | 3.60 | 3.60 | 3.60 |
KETTLITZ AKTIOL6 | 0.00 | 0.00 | 1.50 | 2.50 | 0.00 | 0.00 |
KETTLITZACTIVIN7 | 0.00 | 0.00 | 0.00 | 0.00 | 1.50 | 2.50 |
MB-1:总计 | 166.00 | 176.80 | 177.10 | 178.10 | 177.10 | 178.10 |
对比例/实施例 | A | B | C | D | 1 | 2 |
MB-18 | 166.00 | 176.80 | 177.10 | 178.10 | 177.10 | 178.10 |
KADOX 911C9 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 |
FLEXZONE 7P10 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
硬脂酸 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
SUNPROOF IMP.蜡11 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
MB-2:总计 | 174.50 | 185.30 | 185.60 | 186.60 | 185.60 | 186.60 |
对比例/实施例 | A | B | C | D | 1 | 2 |
MB-212 | 174.50 | 185.30 | 185.60 | 186.60 | 185.60 | 186.60 |
DELAC NS13 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 |
DPG14 | 0.00 | 0.50 | 0.00 | 0.00 | 0.00 | 0.00 |
ROYALAC 15015 | 0.00 | 0.00 | 0.25 | 0.25 | 0.25 | 0.25 |
硫21-1016 | 2.00 | 2.00 | 2.25 | 2.25 | 2.25 | 2.25 |
总计 | 177.50 | 188.80 | 189.10 | 190.10 | 189.10 | 190.10 |
对比例/实施例 | A | B | C | D | 1 | 2 |
在160℃获得的固化特性 | ||||||
ML(lb-in.) | 6.78 | 6.77 | 6.85 | 6.87 | 6.85 | 6.26 |
MH(lb-in.) | 40.34 | 30.86 | 33.36 | 37.28 | 33.76 | 38.40 |
焦烧安全性t51(min) | 2.37 | 2.48 | 3.07 | 2.53 | 3.12 | 2.68 |
焦烧安全性t52(min) | 2.69 | 3.08 | 3.77 | 3.27 | 3.85 | 3.24 |
固化时间t50(min) | 3.92 | 5.54 | 5.54 | 5.15 | 5.69 | 4.86 |
固化时间t90(min) | 5.41 | 9.07 | 6.95 | 651 | 7.31 | 6.05 |
在160℃固化 | ||||||
固化时间@160℃(min) | 7.00 | 11.00 | 9.00 | 9.00 | 9.00 | 8.00 |
拉伸强度(Mpa) | 27.73 | 22.44 | 26.95 | 26.95 | 26.14 | 27.95 |
伸长率,断裂时的% | 519.00 | 565.00 | 606.00 | 603.00 | 618.00 | 614.00 |
100%模量(Mpa) | 2.93 | 1.72 | 2.03 | 2.10 | 1.88 | 2.35 |
200%模量(Mpa) | 8.52 | 4.46 | 5.45 | 5.81 | 4.93 | 6.44 |
300%模量(Mpa) | 15.20 | 8.64 | 10.28 | 10.78 | 9.32 | 1156 |
400%模量(Mpa) | 21.44 | 13.47 | 15.73 | 16.17 | 14.39 | 16.76 |
500%模量(Mpa) | 26.85 | 18.97 | 21.44 | 21.74 | 20.02 | 22.43 |
硬度,肖氏A | 63.00 | 62.00 | 64.00 | 61.00 | 65.00 | 64.00 |
门尼粘度(在100℃的ML1+4)ML1+4 | 62.00 | 61.00 | 59.00 | 57.00 | 60.50 | 58.00 |
门尼烧焦(在135℃的MS) | ||||||
3Pt.上升时间(min) | 9.46 | 11.30 | 17.42 | 15.33 | 17.17 | 13.07 |
18Pt.上升时间(min) | 11.77 | 16.84 | 20.61 | 18.75 | 20.54 | 16.44 |
在70℃熟化2个星期 | ||||||
拉伸强度(Mpa) | 29.09 | 26.92 | 28.53 | 28.09 | 27.77 | 28.94 |
伸长率,断裂时的% | 453.00 | 523.00 | 506.00 | 494.00 | 506.00 | 501.00 |
对比例/实施例 | A | B | C | D | 1 | 2 |
100%模量(Mpa) | 4.97 | 3.00 | 3.90 | 3.81 | 3.64 | 4.36 |
200%模量(Mpa) | 12.98 | 7.97 | 10.17 | 10.43 | 9.50 | 11.27 |
300%模量(Mpa) | 20.71 | 14.15 | 17.13 | 17.48 | 16.20 | 18.28 |
400%模量(Mpa) | 26.60 | 20.28 | 23.30 | 23.55 | 22.42 | 24.22 |
500%模量(Mpa) | 25.03 | 27.62 | 26.97 | |||
硬度,肖氏A | 73.00 | 72.00 | 71.00 | 72.00 | 74.00 | 76.00 |
正切δ60℃(10Hz)[RPA-2000]%应变 | ||||||
0.7 | 0.101 | 0.086 | 0.087 | 0.072 | 0.088 | 0.062 |
1.0 | 0.124 | 0.098 | 0.093 | 0.079 | 0.094 | 0.074 |
2.0 | 0.172 | 0.119 | 0.113 | 0.106 | 0.111 | 0.101 |
5.0 | 0.199 | 0.145 | 0.137 | 0.125 | 0.136 | 0.124 |
7.0 | 0.199 | 0.148 | 0.140 | 0.130 | 0.140 | 0.127 |
14.0 | 0.188 | 0.157 | 0.147 | 0.149 | 0.146 | 0.139 |
动态模量(G’,kPa)%应变 | ||||||
0.7 | 5324.8 | 3366.2 | 3259.1 | 4016.5 | 3488.6 | 3817.6 |
1.0 | 4792.5 | 3175.0 | 3114.9 | 38034 | 3306.1 | 3672.3 |
2.0 | 3549.3 | 2751.5 | 2713.2 | 3281.5 | 2868.9 | 3142.2 |
5.0 | 2457.7 | 2163.4 | 2178.3 | 2551.2 | 2245.2 | 2462.0 |
7.0 | 2199.5 | 1967.7 | 1980.7 | 2300.5 | 2042.7 | 2202.6 |
14.0 | 1738.2 | 1535.5 | 1564.9 | 1617.7 | 1610.1 | 1723.7 |
Monsanto弯曲疲劳至失效的千次循环 | ||||||
1 | 121.6 | 258.5 | 194.4 | 154.4 | 165.9 | 226.8 |
2 | 134.4 | 287.0 | 211.9 | 242.2 | 185.3 | 278.8 |
3 | 136.8 | 299.9 | 213.5 | 250.0 | 243.9 | 329.2 |
4 | 155.3 | 341.1 | 218.8 | 283.2 | 250.9 | 378.3 |
5 | 161.8 | 358.2 | 220.7 | 288.4 | 265.4 | 473.9 |
6 | 166.0 | 386.3 | 222.9 | 307.1 | 312.3 | 475.1 |
对比例/实施例 | A | B | C | D | 1 | 2 |
六个的平均值 | 146.0 | 321.8 | 213.7 | 253.7 | 237.3 | 360.4 |
四个的平均值 | 147.0 | 321.6 | 216.2 | 266.0 | 236.4 | 365.1 |
Din磨损指数 | ||||||
1 | 98.4 | 87.3 | 86.1 | 92.7 | 94.2 | 89.4 |
2 | 96.3 | 87.7 | 85.1 | 93.0 | 93.1 | 92.8 |
3 | 96.8 | 86.2 | 85.1 | 94.6 | 88.2 | 94.2 |
平均值 | 97.2 | 87.1 | 85.4 | 93.5 | 91.8 | 92.1 |
对比例/实施例 | E | F | G | H | 3 | 4 |
SIR-20 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 |
N-220BLACK | 59.00 | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
ZEOSIL 1165 | 0.00 | 60.00 | 60.00 | 60.00 | 60.00 | 60.00 |
SUNDEX 790 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 |
SILQUEST A-158917 | 0.00 | 4.30 | 3.23 | 3.23 | 3.23 | 3.23 |
KETTLITZ AKTIOL | 0.00 | 0.00 | 1.50 | 2.50 | 0.00 | 0.00 |
KETTLITZ ACTIVIN | 0.00 | 0.00 | 0.00 | 0.00 | 1.50 | 2.50 |
MB-3:总计 | 166.00 | 176.30 | 176.73 | 177.73 | 176.73 | 177.73 |
对比例/实施例 | E | F | G | H | 3 | 4 |
MB-318 | 166.00 | 176.30 | 176.73 | 177.73 | 176.73 | 177.73 |
KADOX 911C | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 |
FLEXZONE 7P | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
硬脂酸SUNPROOF IMP. | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
蜡 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
MB-4:总计 | 174.50 | 184.80 | 185.23 | 186.23 | 185.23 | 186.23 |
对比例/实施例 | E | F | G | H | 3 | 4 |
MB-419 | 174.50 | 184.80 | 185.23 | 186.23 | 185.23 | 186.23 |
DELACNS | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 |
DPG | 0.00 | 0.50 | 0.00 | 0.00 | 0.00 | 0.00 |
ROYALAC 150 | 0.00 | 0.00 | 0.25 | 0.25 | 0.25 | 0.25 |
SULFUR 21-10 | 2.00 | 2.25 | 2.40 | 2.40 | 2.40 | 2.40 |
总计 | 177.50 | 188.55 | 188.88 | 189.88 | 188.88 | 189.88 |
对比例/实施例 | E | F | G | H | 3 | 4 |
在160℃获得的固化特性 | ||||||
ML(lb-in.) | 7.24 | 8.28 | 8.79 | 8.85 | 8.13 | 7.82 |
MH(lb-in.) | 41.36 | 33.24 | 38.89 | 42.47 | 38.36 | 40.45 |
焦烧安全性t51(min) | 2.36 | 2.46 | 1.93 | 1.70 | 1.95 | 2.20 |
焦烧安全性t52(min) | 2.71 | 3.43 | 2.65 | 2.19 | 3.82 | 3.84 |
固化时间t50(min) | 4.02 | 6.29 | 6.20 | 6.08 | 6.34 | 6.17 |
固化时间t90(min) | 5.55 | 11.05 | 779 | 7.49 | 7.89 | 7.53 |
在160℃固化 | ||||||
固化时间@160℃(min) | 8.00 | 13.00 | 10.00 | 10.00 | 10.00 | 10.00 |
拉伸强度(Mpa) | 28.82 | 22.66 | 26.17 | 26.52 | 28.08 | 27.20 |
伸长率,断裂时的% | 537.00 | 619.00 | 637.00 | 627.00 | 644.00 | 635.00 |
100%模量(Mpa) | 2.98 | 1.32 | 170 | 1.85 | 1.64 | 1.80 |
200%模量(Mpa) | 8.64 | 3.21 | 4.53 | 5.05 | 4.28 | 4.75 |
300%模量(Mpa) | 15.36 | 6.71 | 8.62 | 9.40 | 8.68 | 9.01 |
400%模量(Mpa) | 21.68 | 11.20 | 13.44 | 14.37 | 13.99 | 14.03 |
500%模量(Mpa) | 26.98 | 16.35 | 18.72 | 19.85 | 19.95 | 19.84 |
硬度,肖氏A | 65.00 | 60.00 | 64.00 | 65.00 | 61.00 | 65.00 |
门尼粘度(在100℃的ML1+4)ML1+4 | 64.00 | 68.50 | 71.00 | 68.00 | 70.00 | 68.50 |
门尼烧焦(在135℃的MS) | ||||||
3Pt.上升时间(min) | 11.63 | 17.52 | 20.78 | 19.54 | 20.58 | 19.48 |
18Pt.上升时间(min) | 13.70 | 22.32 | 23.05 | 2159 | 22.81 | 21.89 |
在70℃熟化2个星期 | ||||||
拉伸强度(Mpa) | 28.53 | 27.59 | 27.99 | 28.69 | 29.20 | 28.45 |
对比例/实施例 | E | F | G | H | 3 | 4 |
伸长率,断裂时的% | 439.00 | 565.00 | 504.00 | 531.00 | 508.00 | 517.00 |
100%模量(Mpa) | 4.86 | 2.80 | 3.85 | 3.78 | 3.63 | 4.01 |
200%模量(Mpa) | 12.60 | 7.53 | 10.00 | 9.92 | 10.09 | 10.15 |
300%模量(Mpa) | 20.55 | 13.57 | 16.88 | 16.76 | 17.55 | 16.91 |
400%模量(Mpa) | 26.92 | 19.53 | 22.97 | 22.72 | 23.99 | 22.93 |
500%模量(Mpa) | 24.70 | 27.20 | 27.39 | 28.95 | 27.60 | |
硬度,肖氏A | 74.00 | 68.00 | 74.00 | 72.00 | 70.00 | 69.00 |
正切δ60℃(10Hz)[RPA-2000]%应变 | ||||||
0.7 | 0.099 | 0.082 | 0.072 | 0.060 | 0.070 | 0.064 |
1.0 | 0.127 | 0.091 | 0.086 | 0.075 | 0.082 | 0.079 |
2.0 | 0.179 | 0.135 | 0.123 | 0.108 | 0.106 | 0.104 |
5.0 | 0.212 | 0.166 | 0.161 | 0.t46 | 0.147 | 0.141 |
7.0 | 0.210 | 0.171 | 0.164 | 0.151 | 0.151 | 0.147 |
14.0 | 0.200 | 0.186 | 0.179 | 0.172 | 0.164 | 0.157 |
动态模量(G’,kPa)%应变 | ||||||
0.7 | 5653.7 | 5531.3 | 6242.8 | 7176.2 | 5982.7 | 6724.8 |
1.0 | 5120.4 | 5267.9 | 5934.6 | 6759.8 | 5535.7 | 6262.5 |
2.0 | 3814.3 | 4276.1 | 4866.3 | 5653.2 | 4579.4 | 5196.9 |
5.0 | 2553.4 | 2984.8 | 3411.9 | 3848.6 | 3274.8 | 36436 |
7.0 | 2235.5 | 2562.2 | 2904.9 | 3253.0 | 2800.9 | 3093.9 |
14.0 | 1756.6 | 1831.5 | 2009.4 | 2198.8 | 1954.3 | 2148.6 |
Monsanto弯曲疲劳至失效的千次循环 | ||||||
1 | 45.5 | 219.1 | 190.9 | 75.3 | 128.2 | 167.9 |
2 | 69.1 | 231.5 | 203.4 | 269.7 | 139.9 | 185.9 |
3 | 126.3 | 248.3 | 229.9 | 271.7 | 165.3 | 208.9 |
4 | 137.1 | 267.8 | 250.7 | 279.2 | 166.5 | 227.9 |
5 | 149.8 | 291.2 | 251.0 | 280.7 | 170.9 | 229.7 |
对比例/实施例 | E | F | G | H | 3 | 4 |
6 | 154.6 | 323.2 | 263.7 | 287.0 | 183.3 | 230.3 |
六个的平均值 | 113.7 | 263.5 | 231.6 | 243.8 | 159.0 | 208.4 |
四个的平均值 | 120.6 | 259.7 | 233.8 | 275.3 | 160.7 | 213.1 |
Din磨损指数 | ||||||
1 | 90.6 | 89.5 | 95.1 | 90.9 | 90.4 | 91.7 |
2 | 94.9 | 88.2 | 96.3 | 91.9 | 91.9 | 89.0 |
3 | 99.7 | 81.5 | 96.5 | 91.6 | 87.9 | 91.2 |
平均值 | 951 | 86.4 | 96.0 | 91.4 | 90.1 | 90.6 |
对比例/实施例 | I | J | K | L | 5 | 6 |
SIR-20 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 |
N-220BLACK | 59.00 | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
ZEOSIL 1165 | 0.00 | 60.00 | 60.00 | 60.00 | 60.00 | 60.00 |
SUNDEX 790 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 0.00 |
NXT(Y-15099)20 | 0.00 | 55 | 4.13 | 4.13 | 4.13 | 4.13 |
KETTLITZ AKTIOL | 0.00 | 0.00 | 1.50 | 2.50 | 0.00 | 0.00 |
KETTLITZ ACTIVIN | 0.00 | 0.00 | 0.00 | 0.00 | 1.50 | 2.50 |
MB5:总计 | 166.00 | 177.00 | 177.63 | 178.63 | 177.63 | 171.63 |
对比例/实施例 | I | J | K | L | 5 | 6 |
MB-521 | 166.00 | 177.00 | 177.63 | 178.63 | 177.63 | 171.63 |
KADOX 911C | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 |
FLEXZONE 7P | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
硬脂酸 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
SUNPROOF IMP.蜡 | 0.00 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
MB-6:总计 | 173.00 | 185.50 | 186.13 | 187.13 | 186.13 | 180.13 |
对比例/实施例 | I | J | K | L | 5 | 6 |
MB-622 | 173.00 | 185.50 | 186.13 | 187.13 | 186.13 | 180.13 |
DELAC NS | 1.00 | 100 | 1.00 | 1.00 | 1.00 | 1.00 |
DPG | 0.00 | 0.50 | 0.00 | 0.00 | 0.00 | 0.00 |
ROYALAC 150 | 0.00 | 0.00 | 0.25 | 0.25 | 0.25 | 0.25 |
SULFUR 21-10 | 2.00 | 2.25 | 2.40 | 2.40 | 2.40 | 2.40 |
总计 | 176.00 | 189.25 | 189.78 | 190.78 | 189.78 | 183.78 |
对比例/实施例 | I | J | K | L | 5 | 6 |
在160℃获得的固化特性 | ||||||
ML(lb-in.) | 6.94 | 5.88 | 6.83 | 8.18 | 7.58 | 6.45 |
MH(lb-in.) | 40.63 | 28.54 | 33.87 | 39.28 | 36.25 | 37.34 |
焦烧安全性t51(min) | 231 | 3.28 | 4.16 | 2.10 | 399 | 3.45 |
焦烧安全性t52(min) | 2.65 | 4.00 | 5.25 | 4.46 | 4.89 | 3.93 |
固化时间t50(min) | 3.94 | 6.19 | 6.90 | 6.31 | 6.48 | 5.23 |
固化时间t90(min) | 5.43 | 9.76 | 8.18 | 7.45 | 7.74 | 6.47 |
在160℃固化 | ||||||
固化时间@160℃(min) | 8.00 | 12.00 | 10.00 | 10.00 | 10.00 | 10.00 |
拉伸强度(Mpa) | 28.69 | 22.35 | 25.94 | 26.09 | 27.10 | 27.73 |
伸长率,断裂时的% | 518.00 | 631.00 | 668.00 | 658.00 | 657.00 | 643.00 |
100%模量(Mpa) | 2.89 | 1.48 | 1.75 | 1.64 | 1.86 | 2.00 |
200%模量(Mpa) | 858 | 3.59 | 4.44 | 4.08 | 4.63 | 5.26 |
300%模量(Mpa) | 15.62 | 6.85 | 8.22 | 8.00 | 8.80 | 9.64 |
400%模量(Mpa) | 22.19 | 10.89 | 12.64 | 12.60 | 13.40 | 14.56 |
500%模量(Mpa) | 27.84 | 15.70 | 17.74 | 17.95 | 18.86 | 20.21 |
硬度,肖氏A | 65.00 | 57.00 | 60.00 | 61.00 | 61.00 | 63.00 |
门尼粘度(在100℃的ML1+4)ML1+4 | 64.00 | 59.00 | 62.00 | 66.00 | 68.00 | 64.50 |
门尼烧焦(在135℃的MS) | ||||||
3Pt.上升时间(min) | 11.37 | 17.77 | 24.15 | 22.37 | 20.60 | 15.25 |
18Pt.上升时间(min) | 13.61 | 23.10 | 26.52 | 24.80 | 23.05 | 17.61 |
对比例/实施例 | I | J | K | L | 5 | 6 |
在70℃熟化2个星期 | ||||||
拉伸强度(Mpa) | 28.70 | 26.07 | 26.83 | 26.70 | 27.86 | 27.16 |
伸长率,断裂时的% | 445.00 | 619.00 | 554.00 | 555.00 | 567.00 | 547.00 |
100%模量(Mpa) | 4.64 | 2.32 | 3.21 | 2.90 | 3.23 | 3.36 |
200%模量(Mpa) | 12.72 | 6.11 | 8.30 | 7.81 | 8.46 | 8.67 |
300%模量(Mpa) | 20.63 | 10.79 | 14.04 | 13.65 | 14.31 | 14.44 |
400%模量(Mpa) | 26.54 | 15.80 | 19.61 | 19.34 | 20.02 | 20.06 |
500%模量(Mpa) | 20.82 | 24.52 | 24.33 | 25.10 | 25.03 | |
硬度,肖氏A | 72.00 | 64.00 | 70.00 | 70.00 | 70.00 | 69.00 |
正切δ60℃(10Hz)[RPA-2000]%应变 | ||||||
0.7 | 0.009 | 0.095 | 0.093 | 0.074 | 0.083 | 0.063 |
1.0 | 0.119 | 0.101 | 0.098 | 0.091 | 0.084 | 0.073 |
2.0 | 0.163 | 0.119 | 0.128 | 0.116 | 0.112 | 0.092 |
5.0 | 0.203 | 0.141 | 0.149 | 0.143 | 0.132 | 0.114 |
7.0 | 0.200 | 0.141 | 0.150 | 0.148 | 0.137 | 0.116 |
14.0 | 0.184 | 0.143 | 0.158 | 0.158 | 0.141 | 0.117 |
动态模量(G’,kPa)%应变 | ||||||
0.7 | 5531.3 | 2731.2 | 4131.3 | 5516.0 | 4337.8 | 3871.2 |
1.0 | 4929.1 | 2595.7 | 3890.8 | 5114.9 | 4104.0 | 3650.4 |
2.0 | 3778.8 | 2213.2 | 3270.6 | 4300.7 | 3467.3 | 3120.3 |
5.0 | 2556.6 | 1784.1 | 2433.3 | 3159.0 | 2594.8 | 2416.3 |
7.0 | 2282.2 | 1630.3 | 2198.8 | 2722.8 | 2318.9 | 2177.3 |
14.0 | 1808.6 | 1331.6 | 1666.7 | 1970.4 | 1772.2 | 1734.4 |
Monsanto弯曲疲劳至失效的千次循环 | ||||||
1 | 107.2 | 185.7 | 173.0 | 228.5 | 190.1 | 233.0 |
2 | 113.8 | 199.6 | 188.3 | 238.7 | 202.0 | 261.4 |
3 | 125.8 | 202.0 | 193.9 | 239.5 | 249.9 | 296.0 |
对比例/实施例 | I | J | K | L | 5 | 6 |
4 | 138.9 | 203.3 | 206.2 | 248.6 | 251.8 | 307.3 |
5 | 141.0 | 228.7 | 217.0 | 259.1 | 309.7 | 311.8 |
6 | 161.8 | 231.4 | 247.6 | 259.7 | 314.7 | 347.6 |
六个的平均值 | 134.1 | 208.5 | 204.3 | 245.7 | 253.0 | 292.9 |
四个的平均值 | 129.9 | 208.4 | 201.4 | 246.5 | 253.4 | 294.1 |
未熟化Din磨损指数 | ||||||
1 | 94.5 | 52.3 | 77.2 | 77.9 | 71.2 | 85.3 |
2 | 99.1 | 56.6 | 41.9 | 81.5 | 71.8 | 77.6 |
3 | 98.8 | 58.8 | 73.7 | 74.2 | 67.7 | 77.9 |
平均值 | 97.5 | 55.3 | 77.6 | 77.9 | 70.3 | 80.2 |
在70℃熟化2个星期Din磨损指数 | ||||||
1 | 90.6 | 63.6 | 80.0 | 77.8 | 80.1 | 81.2 |
2 | 91.0 | 69.1 | 77.1 | 75.7 | 89.2 | 83.4 |
3 | 91.7 | 72.9 | 70.2 | 78.0 | 78.5 | 82.7 |
平均值 | 91.4 | 68.6 | 78.8 | 77.2 | 79.6 | 82.7 |
对比例/实施例 | M | N | O | P | Q | 7 |
SIR-20 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 |
N-220BLACK | 59.00 | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
ZEOSIL 1165 | 0.00 | 60.00 | 60.00 | 60.00 | 60.00 | 60.00 |
SUNDEX 790 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 |
SILQUEST A-1289 | 0.00 | 4.80 | 3.60 | 3.60 | 3.60 | 3.60 |
CARBOWAX 335023 | 0.00 | 0.00 | 2.50 | 3.00 | 0.00 | 0.00 |
KETTLITZ AKTIOL | 0.00 | 0.00 | 0.00 | 0.00 | 3.00 | 0.00 |
KETTLITZ ACTIVIN | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 2.50 |
MB-7:总计 | 166.00 | 176.80 | 178.10 | 178.60 | 178.60 | 178.10 |
对比例/实施例 | M | N | O | P | Q | 7 |
MB-724 | 166.00 | 176.80 | 178.10 | 178.60 | 178.60 | 178.10 |
KADOX 911C | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 |
FLEXZONE 7P | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
硬脂酸 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
SUNPROOF IMP.蜡 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
MB-8:总计 | 174.50 | 185.30 | 186.60 | 187.10 | 187.10 | 186.60 |
对比例/实施例 | M | N | O | P | Q | 7 |
MB-825 | 174.50 | 185.30 | 186.60 | 187.10 | 187.10 | 186.60 |
DELAC NS | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 |
DPG | 0.00 | 1.00 | 0.00 | 0.00 | 0.00 | 0.00 |
ROYALAC 150 | 0.00 | 0.00 | 0.40 | 0.40 | 0.40 | 4.00 |
SANTOGARD PVI26 | 0.20 | 0.20 | 0.00 | 0.00 | 0.00 | 0.20 |
SULFUR 21-10 | 2.00 | 2.00 | 2.25 | 2.25 | 2.25 | 2.25 |
总计 | 177.70 | 189.50 | 190.25 | 190.75 | 190.75 | 194.05 |
对比例/实施例 | M | N | O | P | Q | 7 |
在160℃获得的固化特性 | ||||||
ML(lb-in.) | 6.12 | 7.57 | 9.45 | 9.85 | 8.19 | 6.15 |
MH(lb-in.) | 38.81 | 37.06 | 46.24 | 47.16 | 41.95 | 38.39 |
焦烧安全性t51(min) | 3.33 | 2.49 | 0.91 | 0.72 | 2.24 | 3.07 |
焦烧安全性t52(min) | 4.02 | 3.26 | 2.69 | 2.40 | 3.27 | 3.90 |
固化时间t50(min) | 6.12 | 5.97 | 4.72 | 4.57 | 5.27 | 6.17 |
固化时间t90(min) | 7.87 | 8.37 | 5.66 | 5.52 | 6.38 | 7.24 |
在160℃固化 | ||||||
固化时间@160℃(min) | 10.00 | 11.00 | 8.00 | 8.00 | 8.00 | 9.00 |
拉伸强度(Mpa) | ||||||
伸长率,断裂时的% | 28.86 | 26.73 | 27.35 | 28.16 | 27.86 | 28.43 |
100%模量(Mpa) | 550.00 | 630.00 | 620.00 | 660.00 | 629.00 | 630.00 |
200%模量(Mpa) | 2.69 | 197 | 2.06 | 212 | 2.15 | 2.30 |
300%模量(Mpa) | 7.85 | 5.03 | 5.23 | 5.29 | 5.58 | 6.19 |
400%模量(Mpa) | 14.24 | 9.43 | 9.88 | 9.60 | 10.30 | 11.26 |
500%模量(Mpa) | 20.67 | 14.44 | 15.09 | 14.46 | 15.60 | 16.56 |
硬度,肖氏A | 26.37 | 19.97 | 20.91 | 20.06 | 21.22 | 21.64 |
门尼粘度(在100℃的ML1+4)ML1+4 | 63.00 | 64.00 | 64.00 | 66.00 | 65.00 | 65.00 |
门尼烧焦(在135℃的MS) | ||||||
3Pt.上升时间(min) | 17.90 | 14.91 | 15.21 | 13.88 | 17.37 | 18.69 |
18Pt.上升时间(min) | 21.16 | 21.18 | 18.03 | 16.50 | 20.56 | 24.73 |
对比例/实施例 | M | N | O | P | Q | 7 |
正切δ60℃(10Hz)[RPA-2000]%应变 | ||||||
0.7 | 0.090 | 0.058 | 0.056 | 0.050 | 0.062 | 0.056 |
1.0 | 0.120 | 0.076 | 0.072 | 0.069 | 0.074 | 0.066 |
2.0 | 0.179 | 0.099 | 0.092 | 0.097 | 0.097 | 0.086 |
5.0 | 0.204 | 0.124 | 0.117 | 0.119 | 0.126 | 0.104 |
7.0 | 0.201 | 0.129 | 0.129 | 0.127 | 0.130 | 0.104 |
14.0 | 0.189 | 0.140 | 0.157 | 0.156 | 0.145 | 0.111 |
动态模量(G’,kPa)%应变 | ||||||
0.7 | 4835.1 | 4728.0 | 6235.2 | 6717.2 | 4965.2 | 3289.7 |
1.0 | 4366.3 | 4502.9 | 5918.2 | 6453.8 | 4705.1 | 3131.3 |
2.0 | 3232.3 | 3838.9 | 5246.1 | 5740.6 | 4073.9 | 2759.7 |
5.0 | 2283.5 | 2844.5 | 3810.4 | 4080.3 | 3065.5 | 2226.1 |
7.0 | 2021.3 | 2533.9 | 3219.3 | 3530.7 | 2722.8 | 2051.9 |
14.0 | 1611.6 | 1913.8 | 2176.2 | 2327.3 | 1978.4 | 1665.5 |
Monsanto弯曲疲劳至失效的千次循环 | ||||||
1 | 138.8 | 332.0 | 275.5 | 151.8 | 202.9 | 189.0 |
2 | 168.1 | 332.5 | 307.9 | 304.1 | 207.2 | 288.6 |
3 | 181.7 | 339.6 | 350.7 | 307.7 | 233.4 | 308.3 |
4 | 192.1 | 343.6 | 351.6 | 389.7 | 234.8 | 336.5 |
5 | 192.7 | 416.0 | 381.1 | 392.5 | 241.8 | 336.5 |
6 | 207.2 | 430.1 | 385.6 | 416.3 | 264.3 | 363.9 |
六个的平均值 | 180.1 | 365.6 | 342.1 | 327.0 | 230.7 | 303.8 |
四个的平均值 | 183.6 | 357.9 | 347.8 | 348.5 | 229.3 | 317.5 |
未熟化Din磨损指数 | ||||||
1 | 98.1 | 94.5 | 94.3 | 87.5 | 85.7 | 99.2 |
2 | 98.7 | 94.3 | 98.6 | 86.0 | 82.6 | 95.2 |
3 | 99.5 | 96.3 | 95.4 | 82.3 | 83.8 | 99.3 |
对比例/实施例 | M | N | O | P | Q | 7 |
平均值 | 98.8 | 95.0 | 96.1 | 85.3 | 84.0 | 97.9 |
在70℃熟化2个星期Din磨损指数 | ||||||
1 | 96.8 | 98.1 | 89.3 | 85.5 | 86.9 | 89.7 |
2 | 99.6 | 102.3 | 91.1 | 84.7 | 84.9 | 91.3 |
3 | 98.1 | 98.6 | 91.6 | 85.2 | 89.4 | 90.3 |
平均值 | 98.2 | 99.7 | 90.7 | 85.1 | 87.0 | 90.4 |
对比例/实施例 | R | 8 | 9 | 10 | 11 | 12 |
SIR-20 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 |
N-220 BLACK | 59.00 | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
ZEOSIL 1165 | 0.00 | 60.00 | 60.00 | 60.00 | 60.00 | 60.00 |
SILQUEST A-1289 | 0.00 | 3.60 | 2.60 | 2.00 | 0.00 | 0.00 |
SILQUEST A-189127 | 0.00 | 0.00 | 1.00 | 1.00 | 0.00 | 0.00 |
SILQUEST A-1589 | 0.00 | 0.00 | 0.00 | 0.00 | 3.23 | 0.00 |
NXT(Y-15099) | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 4.13 |
KETTLITZ ACTIVIN | 0.00 | 2.50 | 2.50 | 2.50 | 2.50 | 2.50 |
SUNDEX 790 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 |
MB-9:总计 | 166.00 | 178.10 | 178.10 | 177.50 | 177.73 | 178.63 |
对比例/实施例 | R | 8 | 9 | 10 | 11 | 12 |
MB-928 | 166.00 | 178.10 | 178.10 | 177.50 | 177.73 | 178.63 |
KADOX 911C | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 |
FLEXZONE 7P | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
硬脂酸 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
SUNPROOF IMP.蜡 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
MB-10:总计 | 174.50 | 186.60 | 186.60 | 186.00 | 186.23 | 187.13 |
对比例/实施例 | R | 8 | 9 | 10 | 11 | 12 |
MB-1029 | 174.50 | 186.60 | 186.60 | 186.00 | 186.23 | 187.13 |
DELACNS | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 |
ROYALAC 150 | 0.00 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 |
SANTOGARD PVI | 0.20 | 0.20 | 0.20 | 0.20 | 0.20 | 0.20 |
SULFUR 21-10 | 2.00 | 2.25 | 2.25 | 2.40 | 2.40 | 2.40 |
总计 | 177.70 | 190.55 | 190.55 | 190.10 | 190.33 | 191.23 |
对比例/实施例 | R | 8 | 9 | 10 | 11 | 12 |
在160℃获得的固化特性 | ||||||
ML(lb-in.) | 6.9 | 7.0 | 6.7 | 6.9 | 7.4 | 6.7 |
MH(lb-in.) | 39.6 | 40.0 | 38.3 | 39.3 | 37.0 | 36.8 |
焦烧安全性t51(min) | 3.1 | 3.0 | 3.4 | 3.5 | 4.3 | 4.4 |
焦烧安全性t52(min) | 3.7 | 3.7 | 4.2 | 4.3 | 5.6 | 5.0 |
固化时间t50(min) | 5.7 | 6.0 | 6.4 | 6.5 | 8.2 | 6.8 |
固化时间t90(min) | 7.5 | 7.0 | 7.3 | 7.4 | 9.4 | 7.6 |
在160℃固化 | ||||||
固化时间@160℃(min) | 9.0 | 9.0 | 9.0 | 9.0 | 11.0 | 10.0 |
拉伸强度(Mpa) | 26.1 | 27.1 | 28.4 | 26.8 | 25.1 | 24.7 |
伸长率,断裂时的% | 512.0 | 591.0 | 598.0 | 587.0 | 625.0 | 616.0 |
100%模量(Mpa) | 2.8 | 2.3 | 2.2 | 2.1 | 1.9 | 17 |
200%模量(Mpa) | 80 | 6.3 | 5.8 | 5.7 | 4.7 | 4.3 |
300%模量(Mpa) | 14.2 | 11.3 | 10.5 | 10.7 | 8.6 | 8.2 |
400%模量(Mpa) | 20.3 | 16.7 | 15.8 | 16.2 | 13.2 | 12.9 |
500%模量(Mpa) | 25.7 | 22.4 | 21.5 | 22.1 | 18.6 | 18.4 |
硬度,肖氏A | 65.0 | 62.0 | 64.0 | 60.0 | 63.0 | 57.0 |
门尼粘度(在100℃的ML1+4)ML1+4 | 59.0 | 62.0 | 61.0 | 62.0 | 65.0 | 63.0 |
门尼烧焦(在135℃的MS) | ||||||
3Pt.上升时间(min) | 16.2 | 17.0 | 20.1 | 20.6 | 29.5 | 25.5 |
18Pt.上升时间(min) | 19.3 | 23.0 | 25.5 | 25.0 | 34.7 | 29.1 |
在70℃熟化2个星期 | ||||||
拉伸强度(Mpa) | 25.1 | 27.0 | ~26.2 | 26.4 | 24.7 | 25.6 |
对比例/实施例 | R | 8 | 9 | 10 | 11 | 12 |
伸长率,断裂时的% | 402.0 | 456.0 | 455.0 | 450.0 | 472.0 | 492.0 |
100%模量(Mpa) | 4.7 | 4.2 | 4.2 | 4.0 | 3.8 | 3.2 |
200%模量(Mpa) | 12.2 | 11.2 | 10.8 | 10.7 | 8.9 | 8.8 |
300%模量(Mpa) | 19.5 | 18.3 | 17.7 | 17.8 | 15.1 | 15.3 |
400%模量(Mpa) | 24.5 | 24.3 | 23.6 | 23.9 | 21.0 | 20.8 |
硬度,肖氏A | 72.0 | 69.0 | 71.0 | 67.0 | 70.0 | 64.0 |
正切δ60℃(10Hz)[RPA-2000]%应变 | ||||||
0.7 | 0.103 | 0.059 | 0.062 | 0.062 | 0.060 | 0.061 |
1.0 | 0.130 | 0.060 | 0.067 | 0.069 | 0.073 | 0.069 |
2.0 | 0.182 | 0.082 | 0.089 | 0.084 | 0.092 | 0.086 |
5.0 | 0.203 | 0.090 | 0.098 | 0.098 | 0.108 | 0.098 |
7.0 | 0.200 | 0.093 | 0.099 | 0.099 | 0.109 | 0.099 |
14.0 | 0.186 | 0.103 | 0.109 | 0.110 | 0.118 | 0.103 |
动态模量(G’,kPa)%应变 | ||||||
0.7 | 4965.2 | 3129.1 | 3083.2 | 3228.5 | 3289.7 | 2371.7 |
1.0 | 4486.5 | 2989.2 | 2950.9 | 3076.6 | 3147.6 | 2295.2 |
2.0 | 3281.5 | 2595.7 | 2587.5 | 2721.4 | 2726.9 | 2043.8 |
5.0 | 2343.0 | 2191.0 | 2127.3 | 2188.9 | 2162.3 | 1721.4 |
7.0 | 2074.8 | 2024.3 | 1958.5 | 2006.7 | 1959.3 | 1607.4 |
14.0 | 1662.8 | 1664.4 | 1592.8 | 1609.7 | 1558.0 | 1385.1 |
Monsanto弯曲疲劳至失效的千次循环 | ||||||
1 | 140.4 | 116.2 | 156.8 | 205.5 | 170.4 | 124.1 |
2 | 150.6 | 178.5 | 169.8 | 217.4 | 191.8 | 180.8 |
3 | 162.2 | 195.5 | 195.5 | 223.1 | 220.0 | 186.0 |
4 | 167.7 | 2332.0 | 233.2 | 228.4 | 220.6 | 200.0 |
5 | 173.7 | 245.7 | 245.7 | 246.4 | 234.6 | 205.1 |
6 | 199.6 | 282.5 | 282.5 | 248.3 | 260.9 | 208.4 |
对比例/实施例 | R | 8 | 9 | 10 | 11 | 12 |
六个的平均值 | 165.7 | 208.6 | 210.2 | 228.2 | 216.4 | 184.1 |
四个的平均值 | 163.6 | 213.2 | 210.8 | 228.8 | 216.8 | 193.0 |
未熟化Din磨损指数 | ||||||
1 | 109.8 | 104.4 | 97.5 | 98.5 | 71.5 | 68.7 |
2 | 103.0 | 104.1 | 101.7 | 93.4 | 80.4 | 62.0 |
3 | 104.5 | 97.3 | 103.0 | 89.6 | 80.6 | 68.6 |
平均值 | 105.8 | 101.9 | 100.7 | 93.8 | 77.5 | 66.5 |
在70℃熟化2个星期Din磨损指数 | ||||||
1 | 99.7 | 89.8 | 88.3 | 83.3 | 85.6 | 83.3 |
2 | 100.8 | 90.7 | 90.4 | 90.4 | 84.8 | 85.4 |
3 | 97.6 | 93.1 | 92.0 | 92.0 | 85.2 | 81.3 |
平均值 | 99.4 | 91.2 | 90.2 | 90.2 | 85.2 | 83.4 |
对比例/实施例 | S | 13 | 14 | 15 | 16 | T |
SIR-20 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 | 100.00 |
N-220BLACK | 59.00 | 5.00 | 5.00 | 5.00 | 5.00 | 5.00 |
ZEOSIL 1165 | 0.00 | 60.00 | 60.00 | 60.00 | 60.00 | 60.00 |
SUNDEX 790 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 |
SILQUEST A-1289 | 0.00 | 6.00 | 4.80 | 3.60 | 2.40 | 4.80 |
KETTLITZ ACTIVIN | 0.00 | 2.50 | 2.50 | 2.50 | 2.50 | 0.00 |
MB-11:总计 | 166.00 | 180.50 | 179.30 | 178.10 | 176.90 | 176.80 |
对比例/实施例 | S | 13 | 14 | 15 | 16 | T |
MB-1130 | 166.00 | 180.50 | 179.30 | 178.10 | 176.90 | 176.80 |
KADOX 911C | 3.00 | 300 | 3.00 | 3.00 | 3.00 | 3.00 |
FLEXZONE 7P | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
硬脂酸 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
SUNPROOF IMP.蜡 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
MB-12:总计 | 174.50 | 189.00 | 187.80 | 186.60 | 185.40 | 185.30 |
对比例/实施例 | S | 13 | 14 | 15 | 16 | T |
MB-1231 | 174.50 | 189.00 | 187.80 | 186.60 | 185.40 | 185.30 |
DELAC NS | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 |
ROYALAC150 | 0.00 | 0.40 | 0.40 | 0.40 | 0.4 | 0.00 |
PVI32 | 0.20 | 0.20 | 0.20 | 0.20 | 0.20 | 0.20 |
DPG | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 1.00 |
SULFUR 21-10 | 2.00 | 2.00 | 2.00 | 2.25 | 2.40 | 2.00 |
总计 | 177.70 | 192.60 | 191.40 | 190.45 | 189.00 | 189.50 |
对比例/实施例 | S | 13 | 14 | 15 | 16 | T |
在160℃获得的固化特性 | ||||||
ML(lb-in.) | 6.18 | 5.99 | 6.46 | 6.54 | 7.68 | 6.82 |
MH(lb-in.) | 38.62 | 38.11 | 37.41 | 36.78 | 38.85 | 36.24 |
焦烧安全性t51(min) | 2.88 | 2.58 | 2.72 | 2.92 | 2.44 | 2.47 |
焦烧安全性t52(min) | 3.54 | 3.26 | 3.49 | 3.75 | 3.71 | 3.18 |
固化时间t50(min) | 5.50 | 5.32 | 5.72 | 6.01 | 6.27 | 5.42 |
固化时间t90(min) | 7.21 | 6.29 | 6.70 | 6.98 | 732 | 7.28 |
在160℃固化 | ||||||
固化时间@160℃(min) | 9.00 | 8.00 | 9.00 | 9.00 | 9.00 | 9.00 |
拉伸强度(Mpa) | 28.80 | 29.00 | 28.51 | 28.87 | 28.15 | 27.97 |
伸长率,断裂时的% | 566.00 | 588.00 | 586.00 | 623.00 | 647.00 | 620.00 |
100%模量(Mpa) | 2.65 | 2.71 | 2.23 | 2.24 | 2.09 | 2.14 |
200%模量(Mpa) | 7.63 | 7.22 | 6.29 | 6.16 | 5.39 | 5.46 |
300%模量(Mpa) | 13.78 | 12.66 | 11.81 | 10.92 | 9.82 | 10.02 |
400%模量(Mpa) | 19.91 | 18.50 | 17.81 | 16.28 | 14.91 | 15.39 |
500%模量(Mpa) | 25.50 | 24.34 | 23.89 | 22.08 | 20.53 | 21.34 |
硬度,肖氏A | 64.00 | 63.00 | 61.00 | 62.00 | 59.00 | 62.00 |
门尼粘度(在100℃的ML1+4)ML1+4 | 56.00 | 58.00 | 62.00 | 61.00 | 64.50 | 59.00 |
对比例/实施例 | S | 13 | 14 | 15 | 16 | T |
门尼烧焦(在135℃的MS) | ||||||
3Pt.上升时间(min) | 17.06 | 11.80 | 14.17 | 17.55 | 22.35 | 14.95 |
18Pt.上升时间(min) | 21.11 | 19.67 | 22.08 | 25.25 | 27.45 | 21.14 |
正切δ60℃(10Hz)[RPA-2000]%应变 | ||||||
0.7 | 0.116 | 0.054 | 0.059 | 0.058 | 0.067 | 0.064 |
1.0 | 0.129 | 0.062 | 0.067 | 0.069 | 0.076 | 0.068 |
2.0 | 0.172 | 0.068 | 0.073 | 0.076 | 0.095 | 0.079 |
5.0 | 0.190 | 0.080 | 0.093 | 0.095 | 0.108 | 0.103 |
7.0 | 0.193 | 0.082 | 0.094 | 0.099 | 0.113 | 0.106 |
14.0 | 0.179 | 0.086 | 0.097 | 0.103 | 0.122 | 0.113 |
正切δ60℃(10Hz)[MTS] | ||||||
1.0 | 0.144 | 0.099 | 0.079 | 0.068 | 0.095 | 0.092 |
2.0 | 0.169 | 0.101 | 0.085 | 0.085 | 0.101 | 0.123 |
3.0 | 0.182 | 0.108 | 0.087 | 0.089 | 0.102 | 0.125 |
4.0 | 0.180 | 0.103 | 0.093 | 0.093 | 0.113 | 0.124 |
5.0 | 0.178 | 0.105 | 0.092 | 0.093 | 0.113 | 0.125 |
6.0 | 0.174 | 0.108 | 0.091 | 0.094 | 0.112 | 0.125 |
8.0 | 0.158 | 0.105 | 0.093 | 0.091 | 0.114 | 0.122 |
10.0 | 0.154 | 0.101 | 0.092 | 0.086 | 0.113 | 0.121 |
动态模量(G’,kPa)%应变 | ||||||
0.7 | 4277.0 | 2571.0 | 2724.0 | 2655.0 | 3313.0 | 3244.0 |
1.0 | 3891.0 | 2465.0 | 2612.0 | 2541.0 | 3164.0 | 3071.0 |
2.0 | 2984.0 | 2246.0 | 2355.0 | 2298.0 | 2768.0 | 2719.0 |
5.0 | 2172.0 | 1975.0 | 2016.0 | 1957.0 | 2279.0 | 2230.0 |
7.0 | 1935.0 | 1856.0 | 1883.0 | 1826.0 | 2081.0 | 2052.0 |
14.0 | 1579.0 | 1626.0 | 1607.0 | 550.0 | 1669.0 | 1671.0 |
对比例/实施例 | S | 13 | 14 | 15 | 16 | T | |
未熟化Din磨损指数 | |||||||
1 | 99.0 | 103.8 | 106.8 | 94.5 | 82.3 | 80.3 | |
2 | 92.3 | 98.8 | 91.4 | 85.5 | 93.1 | 30.2 | |
3 | 95.2 | 100.0 | 79.2 | 91.2 | 88.5 | 81.8 | |
平均值 | 95.5 | 101.0 | 92.5 | 90.4 | 88.0 | 80.8 |
Claims (17)
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US51261103P | 2003-10-20 | 2003-10-20 | |
US60/512,611 | 2003-10-20 | ||
US10/964,855 | 2004-10-13 | ||
PCT/US2004/034415 WO2005040264A1 (en) | 2003-10-20 | 2004-10-13 | Rubber compositions and methods for decreasing the tangent delta value and abrasion index |
US10/964,855 US7714050B2 (en) | 2003-10-20 | 2004-10-13 | Rubber compositions and methods for decreasing the tangent delta value and maintaining the abrasion resistance index |
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CN1886451B CN1886451B (zh) | 2011-01-26 |
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US (1) | US7714050B2 (zh) |
EP (1) | EP1675900B1 (zh) |
JP (1) | JP4427060B2 (zh) |
KR (1) | KR101129824B1 (zh) |
CN (1) | CN1886451B (zh) |
BR (1) | BRPI0415547A (zh) |
WO (1) | WO2005040264A1 (zh) |
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- 2004-10-13 EP EP04795559.6A patent/EP1675900B1/en not_active Not-in-force
- 2004-10-13 CN CN2004800350902A patent/CN1886451B/zh not_active Expired - Fee Related
- 2004-10-13 WO PCT/US2004/034415 patent/WO2005040264A1/en active Application Filing
- 2004-10-13 KR KR1020067007579A patent/KR101129824B1/ko active IP Right Grant
- 2004-10-13 BR BRPI0415547-5A patent/BRPI0415547A/pt not_active Application Discontinuation
- 2004-10-13 JP JP2006536696A patent/JP4427060B2/ja not_active Expired - Fee Related
- 2004-10-13 US US10/964,855 patent/US7714050B2/en not_active Expired - Fee Related
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CN1886451B (zh) | 2011-01-26 |
EP1675900B1 (en) | 2016-12-14 |
BRPI0415547A (pt) | 2006-12-26 |
WO2005040264A1 (en) | 2005-05-06 |
KR101129824B1 (ko) | 2012-03-26 |
EP1675900A1 (en) | 2006-07-05 |
JP4427060B2 (ja) | 2010-03-03 |
US7714050B2 (en) | 2010-05-11 |
JP2007509226A (ja) | 2007-04-12 |
US20050085583A1 (en) | 2005-04-21 |
KR20060096485A (ko) | 2006-09-11 |
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