CN1128174C - 基于多硫化烷氧基硅烷、二硫代磷酸锌和胍衍生物的偶联体系及其应用,包含该偶联体系的橡胶组合物及其应用 - Google Patents
基于多硫化烷氧基硅烷、二硫代磷酸锌和胍衍生物的偶联体系及其应用,包含该偶联体系的橡胶组合物及其应用 Download PDFInfo
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- CN1128174C CN1128174C CN99810989A CN99810989A CN1128174C CN 1128174 C CN1128174 C CN 1128174C CN 99810989 A CN99810989 A CN 99810989A CN 99810989 A CN99810989 A CN 99810989A CN 1128174 C CN1128174 C CN 1128174C
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- China
- Prior art keywords
- rubber combination
- white filler
- zinc dithiophosphate
- organoalkoxysilane
- guanidine derivative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Images
Classifications
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- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
- C08K5/31—Guanidine; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10495—Pneumatic tire or inner tube
Abstract
Description
组合物编号: | 1 | 2 | 3 | 4 | 5 |
SBR(1)二氧化硅(2)TESPT(Si69)DTPZn(3)ZnO硬脂酸抗氧剂(4)DPG(5)硫磺CBS(6) | 10050--2.521.91.51.12 | 100504-2.521.91.51.12 | 100502.8-2.521.91.51.12 | 100502.812.521.91.51.12 | 10050-12.521.91.51.12 |
组合物编号: | 1 | 2 | 3 | 4 | 5 |
固化前性质:Mooney粘度(MU)TBR(%)固化后性质:HL(%)断裂应力(Mpa)断裂时伸长率(%) | 120234020650 | 95352617320 | 105303318400 | 95402418320 | 120253920670 |
组合物编号: | 6 | 7 | 8 |
SBR(1)BR(1bis)二氧化硅(2)芳香油TESPT(Si69)DTPZn(3)ZnO硬脂酸抗氧剂(4)DPG(5)硫磺CBS(6) | 75258039.56.4-2.521.91.51.12 | 75258039.54.50.752.521.91.51.12 | 75258039.53.20.752.521.91.51.12 |
组合物编号: | 6 | 7 | 8 |
固化前性质:Mooney粘度(MU)TBR固化后性质:M10(MPa)M100(Mpa)M300(Mpa)M300/M100HL(%)断裂应力(Mpa)断裂时伸长率(%) | 114525.32.03.21.62823570 | 108545.72.33.91.72523490 | 130545.32.03.21.62823570 |
组合物编号: | 9 | 10 |
天然橡胶二氧化硅(2)芳香油TESPT(Si69)DTPZn(3)ZnO硬脂酸抗氧剂(4)DPG(5)硫磺CBS(6) | 10080356.4-2.521.91.51.12 | 10080354.50.752.521.91.51.12 |
组合物编号: | 9 | 10 |
固化前性质:Mooney粘度(MU)TBR固化后性质:M10(MPa)M100(Mpa)M300(Mpa)M300/M100HL(%)断裂应力(Mpa)断裂时伸长率(%) | 50376.42.12.00.952620530 | 48486.01.92.01.052420550 |
组合物编号: | 11 | 12 | 13 | 14 |
SBR(1)BR(1bis)二氧化硅(2)芳香油TESPT(Si69)DTPZn(3)ZnO硬脂酸抗氧剂(4)DPG(5)硫磺CBS(6) | 57.542.58039.56.4-2.521.91.51.12 | 57.542.58039.54.50.752.521.91.51.12 | 57.542.58039.54.50.752.521.91.51.12 | 57.542.58039.54.50.752.521.9-1.12 |
组合物编号: | 11 | 12 | 13 | 14 |
固化前性质:Mooney粘度(MU)TBR固化后性质:M10(MPa)M100(Mpa)M300(Mpa)M300/M100HL(%)断裂应力(Mpa)断裂时伸长率(%) | 84435.41.72.11.242720560 | 100475.61.82.21.222620510 | 82505.81.952.51.282620490 | 110435.11.61.91.192920620 |
组合物编号: | 15 | 16 | 17 |
SBR(1)BR(1bis)二氧化硅(2)芳香油TESpT(Si69)DTPZn(3)ZnO硬脂酸抗氧剂(4)DPG(5)硫磺CBS(6) | 70308039.54.512.521.91.50.71 | 70308039.54.512.521.91.50.71 | 70308039.54.512.521.91.50.71 |
组合物编号: | 15 | 16 | 17 |
固化前性质:Mooney粘度(MU)TBR固化后性质:M10(MPa)M100(Mpa)M300(Mpa)M300/M100HL(%)断裂应力(Mpa)断裂时伸长率(%) | 100515.82.13.01.402619410 | 101505.92.12.91.352619415 | 104446.31.92.21.203019520 |
组合物编号: | 18 | 19 | 20 |
SBR(1)BR(1bis)二氧化硅(2)芳香油TESPT(Si69)TESPD(Si266)DTPZn(3)ZnO硬脂酸抗氧剂(4)DPG(5)硫磺CBS(6) | 57.542.58039.56.4--2.521.91.51.12 | 57.542.58039.5-5.6-2.521.91.51.12 | 57.542.58039.5-5.60.752.521.91.51.12.0 |
组合物编号: | 18 | 19 | 20 |
固化前性质:Mooney粘度(MU)TBR(%)固化后性质:M10(MPa)M100(Mpa)M300(Mpa)M300/M100HL(%)断裂应力(Mpa)断裂时伸长率(%) | 89435.71.71.91.102919600 | 96405.31.31.20.903519800 | 90425.81.71.951.153019.5600 |
组合物编号: | 21 | 22 |
SBR(1)BR(1bis)二氧化硅(2)芳香油TESPT(Si69)DTPZn(3)ZnO硬脂酸石蜡油(7)抗氧剂(4)DPG(5)硫磺CBS(6) | 703080356.4-2.521.51.91.51.12 | 703080354.40.752.521.51.91.51.12 |
Claims (45)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR98/09393 | 1998-07-22 | ||
FR9809393 | 1998-07-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1318086A CN1318086A (zh) | 2001-10-17 |
CN1128174C true CN1128174C (zh) | 2003-11-19 |
Family
ID=9528922
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN99810989A Expired - Lifetime CN1128174C (zh) | 1998-07-22 | 1999-07-20 | 基于多硫化烷氧基硅烷、二硫代磷酸锌和胍衍生物的偶联体系及其应用,包含该偶联体系的橡胶组合物及其应用 |
Country Status (12)
Country | Link |
---|---|
US (1) | US6536492B2 (zh) |
EP (1) | EP1102812B1 (zh) |
JP (1) | JP4596646B2 (zh) |
KR (1) | KR20010072049A (zh) |
CN (1) | CN1128174C (zh) |
AT (1) | ATE226229T1 (zh) |
AU (1) | AU5161699A (zh) |
BR (1) | BR9912343A (zh) |
CA (1) | CA2338150A1 (zh) |
DE (1) | DE69903563T2 (zh) |
ES (1) | ES2186389T3 (zh) |
WO (1) | WO2000005301A1 (zh) |
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-
1999
- 1999-07-20 WO PCT/EP1999/005155 patent/WO2000005301A1/fr not_active Application Discontinuation
- 1999-07-20 AU AU51616/99A patent/AU5161699A/en not_active Abandoned
- 1999-07-20 JP JP2000561255A patent/JP4596646B2/ja not_active Expired - Fee Related
- 1999-07-20 ES ES99936572T patent/ES2186389T3/es not_active Expired - Lifetime
- 1999-07-20 EP EP99936572A patent/EP1102812B1/fr not_active Expired - Lifetime
- 1999-07-20 DE DE69903563T patent/DE69903563T2/de not_active Expired - Lifetime
- 1999-07-20 BR BR9912343-6A patent/BR9912343A/pt not_active IP Right Cessation
- 1999-07-20 AT AT99936572T patent/ATE226229T1/de not_active IP Right Cessation
- 1999-07-20 CN CN99810989A patent/CN1128174C/zh not_active Expired - Lifetime
- 1999-07-20 CA CA002338150A patent/CA2338150A1/fr not_active Abandoned
- 1999-07-20 KR KR1020017001022A patent/KR20010072049A/ko not_active Application Discontinuation
-
2001
- 2001-01-22 US US09/767,044 patent/US6536492B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ATE226229T1 (de) | 2002-11-15 |
US6536492B2 (en) | 2003-03-25 |
ES2186389T3 (es) | 2003-05-01 |
US20010034389A1 (en) | 2001-10-25 |
JP4596646B2 (ja) | 2010-12-08 |
KR20010072049A (ko) | 2001-07-31 |
DE69903563T2 (de) | 2003-06-05 |
AU5161699A (en) | 2000-02-14 |
BR9912343A (pt) | 2001-04-17 |
CA2338150A1 (fr) | 2000-02-03 |
DE69903563D1 (de) | 2002-11-21 |
WO2000005301A1 (fr) | 2000-02-03 |
EP1102812A1 (fr) | 2001-05-30 |
EP1102812B1 (fr) | 2002-10-16 |
JP2002521516A (ja) | 2002-07-16 |
CN1318086A (zh) | 2001-10-17 |
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Assignee: Shanghai Michelin tire Limited by Share Ltd. Assignor: MICHELIN RECHERCHE ET TECHNIQUE S.A.|Michelin Soc Tech Contract fulfillment period: 2007.01.31 to 2026.12.13 Contract record no.: 2007990000027 Denomination of invention: Coupling system based on polysulfide alkoxysilane, zinc dithiophosphate and guanidine derivative and application thereof, rubber composition comprising the coupling system and application thereof Granted publication date: 20031119 License type: Common License Record date: 20070813 |
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