CN1715466A - 含铝连续碳化硅纤维的制备方法 - Google Patents
含铝连续碳化硅纤维的制备方法 Download PDFInfo
- Publication number
- CN1715466A CN1715466A CN 200510031778 CN200510031778A CN1715466A CN 1715466 A CN1715466 A CN 1715466A CN 200510031778 CN200510031778 CN 200510031778 CN 200510031778 A CN200510031778 A CN 200510031778A CN 1715466 A CN1715466 A CN 1715466A
- Authority
- CN
- China
- Prior art keywords
- polyaluminocarbosilane
- silicon carbide
- fiber containing
- carbide fiber
- continuous silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 66
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 34
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 229910010271 silicon carbide Inorganic materials 0.000 title claims abstract description 29
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000004411 aluminium Substances 0.000 title claims description 28
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000548 poly(silane) polymer Polymers 0.000 claims abstract description 16
- 238000002360 preparation method Methods 0.000 claims abstract description 16
- 238000005245 sintering Methods 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- 206010061592 cardiac fibrillation Diseases 0.000 claims description 14
- 230000002600 fibrillogenic effect Effects 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 9
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 6
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- KILURZWTCGSYRE-LNTINUHCSA-K (z)-4-bis[[(z)-4-oxopent-2-en-2-yl]oxy]alumanyloxypent-3-en-2-one Chemical compound CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O KILURZWTCGSYRE-LNTINUHCSA-K 0.000 claims description 5
- 150000001399 aluminium compounds Chemical class 0.000 claims description 5
- 238000000578 dry spinning Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- -1 carbonyl aluminium Chemical compound 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 abstract description 7
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 229910008045 Si-Si Inorganic materials 0.000 abstract description 2
- 229910006411 Si—Si Inorganic materials 0.000 abstract description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 4
- 229920005594 polymer fiber Polymers 0.000 abstract 3
- 238000009987 spinning Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 238000002074 melt spinning Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229920000555 poly(dimethylsilanediyl) polymer Polymers 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 229920003257 polycarbosilane Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 229910000951 Aluminide Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910002796 Si–Al Inorganic materials 0.000 description 1
- KMWBBMXGHHLDKL-UHFFFAOYSA-N [AlH3].[Si] Chemical compound [AlH3].[Si] KMWBBMXGHHLDKL-UHFFFAOYSA-N 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000007500 overflow downdraw method Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Inorganic Fibers (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB200510031778XA CN1330805C (zh) | 2005-06-29 | 2005-06-29 | 含铝连续碳化硅纤维的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB200510031778XA CN1330805C (zh) | 2005-06-29 | 2005-06-29 | 含铝连续碳化硅纤维的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1715466A true CN1715466A (zh) | 2006-01-04 |
CN1330805C CN1330805C (zh) | 2007-08-08 |
Family
ID=35821613
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB200510031778XA Active CN1330805C (zh) | 2005-06-29 | 2005-06-29 | 含铝连续碳化硅纤维的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1330805C (zh) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101830706A (zh) * | 2010-05-28 | 2010-09-15 | 中国人民解放军国防科学技术大学 | 由PCS纤维连续制备Si-B-N-O纤维的方法 |
CN101787588B (zh) * | 2010-01-21 | 2011-12-14 | 中国人民解放军国防科学技术大学 | 一种由pcs纤维制备连续碳化硅纤维的方法 |
CN102392326A (zh) * | 2011-10-10 | 2012-03-28 | 中国人民解放军国防科学技术大学 | 轴向梯度的碳化硅纤维及其制备方法和装置 |
CN103556306A (zh) * | 2013-11-21 | 2014-02-05 | 江苏赛菲新材料有限公司 | 一种工业法制备连续聚碳硅烷纤维不熔化的生产方法 |
CN103614858A (zh) * | 2013-11-21 | 2014-03-05 | 苏州中宝复合材料有限公司 | 一种微米碳化硅纤维毡及其制备方法 |
CN104327274A (zh) * | 2014-11-24 | 2015-02-04 | 中国人民解放军国防科学技术大学 | 一种聚铝碳硅烷的合成方法 |
CN104327275A (zh) * | 2014-11-24 | 2015-02-04 | 中国人民解放军国防科学技术大学 | 一种含铝聚碳硅烷的合成方法 |
CN105384940A (zh) * | 2015-12-10 | 2016-03-09 | 中国人民解放军国防科学技术大学 | 一种纺丝级聚铝碳硅烷先驱体的合成方法 |
CN107226910A (zh) * | 2017-07-12 | 2017-10-03 | 东南大学 | 一种以8‑羟基喹啉铝为铝源制备聚铝碳硅烷先驱体的方法及其应用 |
CN107383376A (zh) * | 2017-07-12 | 2017-11-24 | 东南大学 | 一种以硬脂酸铝为铝源制备聚铝碳硅烷先驱体的方法及其应用 |
CN109825903A (zh) * | 2019-03-04 | 2019-05-31 | 中国科学院宁波材料技术与工程研究所 | 一种含铝碳化硅纤维及其制备方法 |
CN111733484A (zh) * | 2020-07-22 | 2020-10-02 | 中国科学院化学研究所 | 一种Al-Si复相氧化物连续陶瓷纤维及其制备方法 |
CN112142984A (zh) * | 2020-10-23 | 2020-12-29 | 浙江华茂航天科技股份有限公司 | 一种聚铝碳硅烷及其制备方法和应用 |
CN112962214A (zh) * | 2021-03-02 | 2021-06-15 | 中国人民解放军国防科技大学 | 一种高结晶近化学计量比SiC微纳纤维膜及其制备方法 |
CN113024260A (zh) * | 2021-03-22 | 2021-06-25 | 浙江理工大学 | 一种聚铝硅氮烷陶瓷先驱体的制备及熔融纺丝方法 |
CN113968743A (zh) * | 2020-07-22 | 2022-01-25 | 中国科学院化学研究所 | 一种Al-Si共聚氧化物陶瓷前驱体及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5945362A (en) * | 1996-10-02 | 1999-08-31 | Ube Industries, Ltd. | Silicon carbide fiber having excellent alkali durability |
CN1168859C (zh) * | 2002-11-18 | 2004-09-29 | 中国人民解放军国防科学技术大学 | 耐高温多晶碳化硅纤维的制备方法 |
JP3979311B2 (ja) * | 2003-03-13 | 2007-09-19 | 宇部興産株式会社 | 炭化ケイ素系セラミックス繊維及びその製造方法 |
-
2005
- 2005-06-29 CN CNB200510031778XA patent/CN1330805C/zh active Active
Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101787588B (zh) * | 2010-01-21 | 2011-12-14 | 中国人民解放军国防科学技术大学 | 一种由pcs纤维制备连续碳化硅纤维的方法 |
CN101830706A (zh) * | 2010-05-28 | 2010-09-15 | 中国人民解放军国防科学技术大学 | 由PCS纤维连续制备Si-B-N-O纤维的方法 |
CN102392326A (zh) * | 2011-10-10 | 2012-03-28 | 中国人民解放军国防科学技术大学 | 轴向梯度的碳化硅纤维及其制备方法和装置 |
CN102392326B (zh) * | 2011-10-10 | 2013-07-31 | 中国人民解放军国防科学技术大学 | 轴向梯度的碳化硅纤维及其制备方法和装置 |
CN103556306B (zh) * | 2013-11-21 | 2016-02-24 | 江苏赛菲新材料有限公司 | 一种工业法制备连续聚碳硅烷纤维不熔化的生产方法 |
CN103556306A (zh) * | 2013-11-21 | 2014-02-05 | 江苏赛菲新材料有限公司 | 一种工业法制备连续聚碳硅烷纤维不熔化的生产方法 |
CN103614858A (zh) * | 2013-11-21 | 2014-03-05 | 苏州中宝复合材料有限公司 | 一种微米碳化硅纤维毡及其制备方法 |
CN103614858B (zh) * | 2013-11-21 | 2016-04-20 | 苏州赛菲集团有限公司 | 一种微米碳化硅纤维毡及其制备方法 |
CN104327275B (zh) * | 2014-11-24 | 2016-09-21 | 中国人民解放军国防科学技术大学 | 一种含铝聚碳硅烷的合成方法 |
CN104327275A (zh) * | 2014-11-24 | 2015-02-04 | 中国人民解放军国防科学技术大学 | 一种含铝聚碳硅烷的合成方法 |
CN104327274B (zh) * | 2014-11-24 | 2016-09-21 | 中国人民解放军国防科学技术大学 | 一种聚铝碳硅烷的合成方法 |
CN104327274A (zh) * | 2014-11-24 | 2015-02-04 | 中国人民解放军国防科学技术大学 | 一种聚铝碳硅烷的合成方法 |
CN105384940B (zh) * | 2015-12-10 | 2018-02-23 | 中国人民解放军国防科学技术大学 | 一种纺丝级聚铝碳硅烷先驱体的合成方法 |
CN105384940A (zh) * | 2015-12-10 | 2016-03-09 | 中国人民解放军国防科学技术大学 | 一种纺丝级聚铝碳硅烷先驱体的合成方法 |
CN107383376B (zh) * | 2017-07-12 | 2020-04-24 | 东南大学 | 一种以硬脂酸铝为铝源制备聚铝碳硅烷先驱体的方法及其应用 |
CN107383376A (zh) * | 2017-07-12 | 2017-11-24 | 东南大学 | 一种以硬脂酸铝为铝源制备聚铝碳硅烷先驱体的方法及其应用 |
CN107226910A (zh) * | 2017-07-12 | 2017-10-03 | 东南大学 | 一种以8‑羟基喹啉铝为铝源制备聚铝碳硅烷先驱体的方法及其应用 |
CN107226910B (zh) * | 2017-07-12 | 2020-08-11 | 东南大学 | 一种以8-羟基喹啉铝为铝源制备聚铝碳硅烷先驱体的方法及其应用 |
CN109825903A (zh) * | 2019-03-04 | 2019-05-31 | 中国科学院宁波材料技术与工程研究所 | 一种含铝碳化硅纤维及其制备方法 |
CN109825903B (zh) * | 2019-03-04 | 2021-08-06 | 中国科学院宁波材料技术与工程研究所 | 一种含铝碳化硅纤维及其制备方法 |
CN111733484A (zh) * | 2020-07-22 | 2020-10-02 | 中国科学院化学研究所 | 一种Al-Si复相氧化物连续陶瓷纤维及其制备方法 |
CN113968743A (zh) * | 2020-07-22 | 2022-01-25 | 中国科学院化学研究所 | 一种Al-Si共聚氧化物陶瓷前驱体及其制备方法 |
CN113968743B (zh) * | 2020-07-22 | 2022-07-12 | 中国科学院化学研究所 | 一种Al-Si共聚氧化物陶瓷前驱体及其制备方法 |
CN112142984A (zh) * | 2020-10-23 | 2020-12-29 | 浙江华茂航天科技股份有限公司 | 一种聚铝碳硅烷及其制备方法和应用 |
CN112962214A (zh) * | 2021-03-02 | 2021-06-15 | 中国人民解放军国防科技大学 | 一种高结晶近化学计量比SiC微纳纤维膜及其制备方法 |
CN113024260A (zh) * | 2021-03-22 | 2021-06-25 | 浙江理工大学 | 一种聚铝硅氮烷陶瓷先驱体的制备及熔融纺丝方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1330805C (zh) | 2007-08-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1715466A (zh) | 含铝连续碳化硅纤维的制备方法 | |
Flores et al. | Ceramic fibers based on SiC and SiCN systems: current research, development, and commercial status | |
CN107419364B (zh) | 一种高耐温性的高结晶近化学计量比连续SiC纤维的制备方法 | |
Miele et al. | Recent developments in Polymer‐Derived ceramic fibers (PDCFs): Preparation, properties and applications–A review | |
US4604367A (en) | Method for the preparation of an inorganic fiber containing silicon, carbon, boron and nitrogen | |
CN104529462B (zh) | 一种由高软化点聚碳硅烷制备碳化硅纤维的方法 | |
CN1168859C (zh) | 耐高温多晶碳化硅纤维的制备方法 | |
CN105384940B (zh) | 一种纺丝级聚铝碳硅烷先驱体的合成方法 | |
CN110629324A (zh) | 一种含硼碳化硅纤维及其制备方法 | |
US7125514B2 (en) | Process for producing reinforcing SiC fiber for SiC composite material | |
CN106521710A (zh) | 一种含钛硼碳化硅基陶瓷纤维的制备方法 | |
US4832895A (en) | Boron-containing ceramics through the chemical conversian of borane-containing polymers | |
US20120237765A1 (en) | Stiochiometric silicon carbide fibers from thermo-chemically cured polysilazanes | |
EP2970020A2 (en) | Ceramic matrix composites and methods for producing ceramic matrix composites | |
CN106192078B (zh) | 一种采用空气不熔化进行低氧含量连续SiC纤维制备的方法 | |
CN107226910B (zh) | 一种以8-羟基喹啉铝为铝源制备聚铝碳硅烷先驱体的方法及其应用 | |
He et al. | Amorphous fine-diameter SiC-based fiber from a boron-modified polytitanocarbosilane precursor | |
US4810436A (en) | Process for the formation of boron-containing ceramics from organoboron preceramic polymers | |
Xie et al. | Synthesis and characterization of molybdenum‐modified polycarbosilane for SiC (Mo) ceramics | |
Yilmaz et al. | Silicon carbide fiber manufacturing: Cost and technology | |
CN109456065A (zh) | 一种SiC陶瓷纤维的制备方法 | |
Tang et al. | Preceramic polymer for Si B N C fiber via one‐step condensation of silane, BCl3, and silazane | |
CN109111574B (zh) | Si-Al-C-O纤维的制备方法 | |
US4931100A (en) | Boron-containing preceramic blend and fiber formed therefrom | |
JP6046266B2 (ja) | プレセラミック成形体を製造するための高分子ポリシラン及びその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PP01 | Preservation of patent right |
Effective date of registration: 20160912 Granted publication date: 20070808 |
|
RINS | Preservation of patent right or utility model and its discharge | ||
PD01 | Discharge of preservation of patent | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20170306 Granted publication date: 20070808 |
|
PP01 | Preservation of patent right | ||
PP01 | Preservation of patent right |
Effective date of registration: 20190320 Granted publication date: 20070808 |
|
PD01 | Discharge of preservation of patent | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20210320 Granted publication date: 20070808 |
|
PP01 | Preservation of patent right | ||
PP01 | Preservation of patent right |
Effective date of registration: 20220310 Granted publication date: 20070808 |