CN1246127A - 含乙烯基的大分子单体的制备 - Google Patents

含乙烯基的大分子单体的制备 Download PDF

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CN1246127A
CN1246127A CN98802127A CN98802127A CN1246127A CN 1246127 A CN1246127 A CN 1246127A CN 98802127 A CN98802127 A CN 98802127A CN 98802127 A CN98802127 A CN 98802127A CN 1246127 A CN1246127 A CN 1246127A
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ethylene
vinyl
reactor
transition metal
catalyst
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Chinese (zh)
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E·J·马克尔
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
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  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN98802127A 1997-02-07 1998-02-06 含乙烯基的大分子单体的制备 Pending CN1246127A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3732397P 1997-02-07 1997-02-07
US60/037,323 1997-02-07

Publications (1)

Publication Number Publication Date
CN1246127A true CN1246127A (zh) 2000-03-01

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CN98802127A Pending CN1246127A (zh) 1997-02-07 1998-02-06 含乙烯基的大分子单体的制备

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US (2) US6444773B1 (https=)
EP (1) EP0958309B2 (https=)
JP (1) JP2001511214A (https=)
KR (1) KR100503523B1 (https=)
CN (1) CN1246127A (https=)
BR (1) BR9806952A (https=)
CA (1) CA2276214A1 (https=)
DE (1) DE69836415T3 (https=)
ES (1) ES2277381T5 (https=)
WO (1) WO1998034965A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
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CN103443139A (zh) * 2011-03-25 2013-12-11 埃克森美孚化学专利公司 乙烯基封端的高级烯烃聚合物及其生产方法
CN104428326A (zh) * 2012-09-27 2015-03-18 埃克森美孚化学专利公司 乙烯基封端聚合物及其制造方法
CN111788238A (zh) * 2017-11-07 2020-10-16 诺瓦化学品(国际)股份有限公司 乙烯互聚物产品和膜

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2666708T3 (es) 1998-11-02 2018-05-07 Dow Global Technologies Llc Interpolímeros reo-fluidificantes de etileno/alfa-olefina y su preparación
US6372847B1 (en) 2000-05-10 2002-04-16 Exxon Mobil Chemical Patents, Inc. Polyolefin compositions having improved low temperature toughness
US6995229B2 (en) * 2000-07-26 2006-02-07 Mitsui Chemicals, Inc. Polymer and process for producing the same
EP1264848B1 (en) * 2000-07-26 2006-06-21 Mitsui Chemicals, Inc. Novel ethylene copolymer and uses thereof
EP1270603B1 (en) * 2001-06-20 2014-04-09 Mitsui Chemicals, Inc. Olefin polymerization catalyst, process for polymerizing olefins
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7678866B2 (en) * 2003-04-28 2010-03-16 Tosoh Corporation Polyethylene composition and process for producing same
US7928164B2 (en) * 2005-06-22 2011-04-19 Exxonmobil Chemical Patents Inc. Homogeneous polymer blend and process of making the same
US9745461B2 (en) 2005-06-22 2017-08-29 Exxonmobil Chemical Patents Inc. Vulcanized polymer blends
US7951872B2 (en) 2005-06-22 2011-05-31 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blend with continuous elastomeric phase and process of making the same
US8022142B2 (en) * 2008-12-15 2011-09-20 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
US9644092B2 (en) 2005-06-22 2017-05-09 Exxonmobil Chemical Patents Inc. Heterogeneous in-situ polymer blend
US20060293462A1 (en) * 2005-06-22 2006-12-28 Sunny Jacob Heterogeneous polymer blend and process of making the same
CN101970514B (zh) * 2008-03-13 2013-11-20 陶氏环球技术有限责任公司 乙烯与另一聚合物组合的长链支化(lcb)、嵌段或互联共聚物
US8283419B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Olefin functionalization by metathesis reaction
US8399725B2 (en) 2008-06-20 2013-03-19 Exxonmobil Chemical Patents Inc. Functionalized high vinyl terminated propylene based oligomers
EP2288630B1 (en) * 2008-06-20 2013-05-08 ExxonMobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8372930B2 (en) 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8283428B2 (en) * 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Polymacromonomer and process for production thereof
US8802797B2 (en) 2008-06-20 2014-08-12 Exxonmobil Chemical Patents Inc. Vinyl-terminated macromonomer oligomerization
US8093335B2 (en) * 2008-12-15 2012-01-10 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin in-reactor blends and molded articles therefrom
US8106127B2 (en) * 2008-12-15 2012-01-31 Exxonmobil Chemical Patents Inc. Heterogeneous in-reactor polymer blends
US8318648B2 (en) * 2009-12-15 2012-11-27 Exxonmobil Research And Engineering Company Polyether-containing lubricant base stocks and process for making
US8907034B2 (en) 2010-09-30 2014-12-09 Dow Global Technologies Llc Comb architecture olefin block copolymers
US8455597B2 (en) 2011-03-25 2013-06-04 Exxonmobil Chemical Patents Inc. Catalysts and methods of use thereof to produce vinyl terminated polymers
US8501894B2 (en) 2011-03-25 2013-08-06 Exxonmobil Chemical Patents Inc. Hydrosilyation of vinyl macromers with metallocenes
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
US8940839B2 (en) 2011-03-25 2015-01-27 Exxonmobil Chemical Patents Inc. Diblock copolymers prepared by cross metathesis
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US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8318998B2 (en) 2011-03-25 2012-11-27 Exxonmobil Chemical Patents Inc. Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers
US8426659B2 (en) 2011-03-25 2013-04-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
US8669330B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Olefin triblock polymers via ring-opening metathesis polymerization
US8841397B2 (en) 2011-03-25 2014-09-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8669326B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Amine functionalized polyolefin and methods for preparation thereof
US8604148B2 (en) 2011-11-29 2013-12-10 Exxonmobil Chemical Patents Inc. Functionalization of vinyl terminated polymers by ring opening cross metathesis
US8796376B2 (en) 2012-03-26 2014-08-05 Exxonmobil Chemical Patents Inc. Functionalized polymers and oligomers
US9045568B2 (en) 2012-08-03 2015-06-02 Exxonmobil Chemical Patents Inc. Vinyl terminated polyethylene with long chain branching
US9365661B2 (en) 2012-08-03 2016-06-14 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified salan catalyst compounds
US9382349B2 (en) * 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
US9376512B2 (en) * 2012-09-24 2016-06-28 Exxonmobil Chemical Patents Inc. Production of vinyl terminated polyethylene
US9120879B2 (en) * 2012-11-02 2015-09-01 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
US9422385B2 (en) 2013-01-30 2016-08-23 Exxonmobil Chemical Patents Inc. Polyethylene copolymers with vinyl terminated macromonomers as comonomers
US9540465B2 (en) 2013-11-19 2017-01-10 Chevron Phillips Chemical Company Lp Boron-bridged metallocene catalyst systems and polymers produced therefrom
WO2015088819A1 (en) 2013-12-13 2015-06-18 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
US9321856B2 (en) 2013-12-19 2016-04-26 Exxonmobil Chemical Patents Inc. Process to produce functionalized polymer
KR101792171B1 (ko) 2014-12-08 2017-10-31 주식회사 엘지화학 우수한 용융 강도를 갖는 올레핀계 중합체 및 이를 포함하는 필름
CN108047568B (zh) 2014-12-09 2020-06-09 三井化学株式会社 成型体和丙烯系树脂组合物
US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
US20190135960A1 (en) * 2017-11-07 2019-05-09 Nova Chemicals (International) S.A. Process to manufacture ethylene interpolymer products
US11377560B2 (en) 2018-12-18 2022-07-05 ExxonMobil Technology and Engineering Company Modified asphalts and methods for producing the same
SG11202107067RA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Organometallic chain transfer agents
SG11202107051UA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same
WO2020140067A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
KR102880619B1 (ko) 2018-12-28 2025-11-04 다우 글로벌 테크놀로지스 엘엘씨 텔레켈릭 폴리올레핀을 포함하는 경화성 조성물
EP3902809A1 (en) 2018-12-28 2021-11-03 Dow Global Technologies LLC Curable compositions comprising unsaturated polyolefins
JP2022183105A (ja) * 2021-05-26 2022-12-08 日本ポリエチレン株式会社 オレフィン重合用触媒、及び、エチレン系重合体の製造方法

Family Cites Families (96)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3350723A (en) 1965-04-27 1967-11-07 Arthur M Dyer Water volume control for water closet
US3989768A (en) 1971-02-22 1976-11-02 Cpc International Inc. Chemically joined phase separated thermoplastic graft copolymers
BE793639A (fr) 1972-01-03 1973-07-03 Xerox Corp Revelateur electrostatographique
JPS52141888A (en) 1976-05-21 1977-11-26 Nippon I P Rubber Kk Ethyleneepropylene copolymers rubber
US4335225A (en) 1978-06-20 1982-06-15 E. I. Du Pont De Nemours And Company Elastomeric polypropylene
DE3127133A1 (de) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3688258T3 (de) 1985-01-31 2001-02-22 Montell North America Inc., Wilmington Polypropylen mit freier Langkettenverzweigung, Verfahren zur Herstellung und Verwendung davon.
DE3508887A1 (de) 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4665208A (en) 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
IL80888A (en) * 1985-12-12 1991-12-12 Exxon Chemical Patents Inc Olefin polymerization catalysts,their preparation and use thereof
US4752597A (en) * 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
ATE177759T1 (de) 1986-09-24 1999-04-15 Mitsui Chemicals Inc Verfahren zur olefinpolymerisation
JPH0780933B2 (ja) 1986-11-20 1995-08-30 三井石油化学工業株式会社 オレフインの重合方法
JP2618384B2 (ja) * 1986-12-27 1997-06-11 三井石油化学工業株式会社 オレフイン重合用固体触媒およびその製法
US4921825A (en) 1986-12-30 1990-05-01 Mitsui Petrochemical Industries, Ltd. Solid catalyst for olefin polymerization and processes for its production
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5391629A (en) 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
JPH0742301B2 (ja) 1987-02-14 1995-05-10 三井石油化学工業株式会社 微粒子状アルミノオキサン、その製法およびその用途
DE8703096U1 (de) 1987-02-27 1987-08-20 Söffner, Georg, 8000 München Behältnis zur Aufnahme von mindestens einem Kondom
US4769910A (en) 1987-03-30 1988-09-13 Northern Telecom Limited Cutting tool for cylindrical articles
JP2538588B2 (ja) 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
US5206199A (en) 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
US5155080A (en) 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US4892851A (en) 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
EP0354893B2 (en) 1988-08-05 2002-03-13 Fina Technology, Inc. Process for producing large symmetrical polymer particles
US5091352A (en) 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
EP0366411A3 (en) 1988-10-28 1991-04-24 Exxon Chemical Patents Inc. Graft polymers of ethylene-propylene-diene monomer polymers with propylene, means of preparation, and use of polypropylene compositions
US4999403A (en) 1988-10-28 1991-03-12 Exxon Chemical Patents Inc. Graft polymers of functionalized ethylene-alpha-olefin copolymer with polypropylene, methods of preparation, and use in polypropylene compositions
US4908463A (en) 1988-12-05 1990-03-13 Ethyl Corporation Aluminoxane process
US5047485A (en) 1989-02-21 1991-09-10 Himont Incorporated Process for making a propylene polymer with free-end long chain branching and use thereof
US5103031A (en) 1989-02-21 1992-04-07 Ethyl Corporation Falling film aluminoxane process
DE3907964A1 (de) 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
US4968827A (en) 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US4924018A (en) 1989-06-26 1990-05-08 Ethyl Corporation Alkylaluminoxane process
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
DK0426637T4 (da) 1989-10-30 2002-01-14 Fina Technology Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner
US5087809A (en) 1990-11-26 1992-02-11 Eastman Kodak Company Spectrally selective dithering and color filter mask for increased image sensor blue sensitivity
ATE186918T1 (de) 1990-01-02 1999-12-15 Exxon Chemical Patents Inc Ionische metallocenkatalysatoren auf träger für olefinpolymerisation
GB2241244B (en) 1990-02-22 1994-07-06 James C W Chien Thermoplastic elastomers
CA2057892C (en) 1990-04-09 1995-08-08 Tetsunosuke Shiomura Propylene copolymer
AU7875791A (en) 1990-05-07 1991-11-27 Exxon Chemical Patents Inc. Unsaturated alpha-olefin copolymers and method for preparation thereof
RU2118203C1 (ru) 1990-06-22 1998-08-27 Экксон Кэмикал Пейтентс Инк. Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
EP0500944B1 (en) 1990-07-24 1998-10-07 Mitsui Chemicals, Inc. Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
JP3076619B2 (ja) 1991-05-14 2000-08-14 三井化学株式会社 ブロック共重合体の製造方法
DE4120009A1 (de) 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5235081A (en) 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
US5157137A (en) 1991-07-26 1992-10-20 Ethyl Corporation Method of making gel free alkylaluminoxane solutions
US5308815A (en) 1991-07-26 1994-05-03 Ethyl Corporation Heterogeneous methylaluminoxane catalyst system
TW300901B (https=) 1991-08-26 1997-03-21 Hoechst Ag
DE4130299A1 (de) 1991-09-12 1993-03-18 Basf Ag Verfahren zur herstellung von polypropylen unter hochdruck
ATE286918T1 (de) 1991-10-15 2005-01-15 Basell Polyolefine Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
ES2109473T3 (es) 1991-12-13 1998-01-16 Exxon Chemical Patents Inc Copolimeros de etileno/alfa-olefinas superiores.
EP0631589A1 (en) 1992-03-16 1995-01-04 Exxon Chemical Patents Inc. IONIC CATALYST FOR THE PRODUCTION OF POLY-$g(a)-OLEFINS OF CONTROLLED TACTICITY
US5329032A (en) 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5310794A (en) 1992-03-31 1994-05-10 Himont Incorporated Theromoplastic blends containing graft copolymers of polyacrylates as impact modifiers
ES2126647T3 (es) 1992-04-20 1999-04-01 Exxon Chemical Patents Inc Copolimeros de etileno/olefinas ramificadas.
EP0578838A1 (en) 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
EP0572034A2 (en) 1992-05-29 1993-12-01 Idemitsu Kosan Company Limited Ethylenic copolymer and ethylenic copolymer composition
EP0574597B2 (en) 1992-06-13 2002-06-26 Basell Polyolefine GmbH Process for the preparation of bridged, chiral metallocene catalysts of the bisindenyl type
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
JPH07509752A (ja) 1992-08-05 1995-10-26 エクソン・ケミカル・パテンツ・インク オレフィン重合用の担持されたイオン遷移金属触媒
US5248801A (en) 1992-08-27 1993-09-28 Ethyl Corporation Preparation of methylaluminoxanes
KR950703595A (ko) 1992-09-29 1995-09-20 벤셔 카펜헤르 장쇄 분지된 중합체 및 그의 제조방법(long chain branched polymers and a process to make long chain branched polymers)
DE69312306T2 (de) 1992-10-02 1997-11-13 Dow Chemical Co Aufträger homogener komplexkatalysator für olefinpolymerisation
DE69333470T2 (de) 1992-10-28 2004-08-19 Idemitsu Kosan Co. Ltd. Olefincopolymere und verfahren zu ihrer herstellung
US5939346A (en) 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
WO1994019381A1 (fr) * 1993-02-22 1994-09-01 Idemitsu Kosan Co., Ltd. Copolymere d'ethylene, composition de resine thermoplastique le contenant et procede de production de ce copolymere
US5414027A (en) 1993-07-15 1995-05-09 Himont Incorporated High melt strength, propylene polymer, process for making it, and use thereof
WO1995011931A1 (en) 1993-10-26 1995-05-04 Idemitsu Kosan Co., Ltd. Branched ethylene macromonomer and polymer produced therefrom
US5594080A (en) 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
US5539056A (en) 1995-01-31 1996-07-23 Exxon Chemical Patents Inc. Thermoplastic elastomers
CA2223258A1 (en) 1995-07-06 1997-01-23 Exxon Chemical Patents, Inc. Method for producing prepolymerized, supported metallocene catalyst systems
US6084030A (en) 1995-08-04 2000-07-04 Dsm Copolymer, Inc. Branched polymers with polyolefin arms
DE69632678T2 (de) 1995-09-11 2005-06-09 Mitsui Chemicals, Inc. Harzzusammensetzung und deren verwendung
EP0855413B1 (en) 1997-01-23 2002-01-02 JSR Corporation Ethylene copolymer rubber composition
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103443139A (zh) * 2011-03-25 2013-12-11 埃克森美孚化学专利公司 乙烯基封端的高级烯烃聚合物及其生产方法
CN103443139B (zh) * 2011-03-25 2016-10-12 埃克森美孚化学专利公司 乙烯基封端的高级烯烃聚合物及其生产方法
CN104428326A (zh) * 2012-09-27 2015-03-18 埃克森美孚化学专利公司 乙烯基封端聚合物及其制造方法
CN111788238A (zh) * 2017-11-07 2020-10-16 诺瓦化学品(国际)股份有限公司 乙烯互聚物产品和膜
CN111788238B (zh) * 2017-11-07 2023-01-24 诺瓦化学品(国际)股份有限公司 乙烯互聚物产品和膜

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