CN1175272A - 含有改性碳产品的水性油墨和涂料 - Google Patents
含有改性碳产品的水性油墨和涂料 Download PDFInfo
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Abstract
介绍了一种包括改性碳产品的水性油墨组合物,该改性碳产品含有连有至少一个有机基团的碳,该有机基团被一个离子或可离子化的基团所取代。也介绍了一种涂料组合物,该涂料组合物包括水、粘合剂和具有至少一个连到该碳上的改性碳产品,其中该有机基团被一个离子或可离子化的基团取代。
Description
本发明是美国专利系列申请08/356,660和08/356,653的继续申请部分,这两篇专利是在1994年12月15日提交的,其公开内容这里引为参考。
本发明涉及含有改性碳产品的水性油墨和涂料。
目前使用的油墨有许多种类。这些种类包括印刷油墨、紫外线固化油墨、圆珠笔油墨、印油或打印油墨。从本质上来讲,油墨可有四类主要材料组成。它们是着色剂、连接料或清漆、添加剂和溶剂。
更详细地,包括颜料、调色剂和染料的着色剂,提供了与底物相对比的颜色。连接料或清漆在印刷操作中作着色剂的载体。添加剂影响适印性、膜的性能、干燥速率和最终使用性能。最后,溶剂除了参与形成连接料外,还用来减少油墨的粘度,并用来调整干燥的容易程度和树脂的性能。通常,根据所想要的配方,把选自这四类的各组分称重、混合和研磨(即分散)(一起或分别研磨)。
目前,主要的黑颜料是炭黑,如炉法炭黑,它可以干粉状、挤水色浆(flushed paste)或液体浓缩状用作着色剂。挤水色浆和液体浓缩物形式是更经济的,因为它们需要最少的分散作用。一般,着色剂的形式影响其色调、耐久性、松密度(bulk)、不透明性、光泽度、流变学、最终用途和印刷质量。
通常,可通过活版印刷、平版印刷、苯胺印刷、凹版印刷、丝网印刷、镂花版、复印和静电印刷来涂布油墨。因此油墨可用在如报纸、印刷品、商业广告、折叠卡通、书籍、瓦楞盒、纸袋、包装纸、标签、金属容器、塑料容器、塑料膜、箔、薄层、食品中的插入物、卫生巾、纺织品等用途中。McGraw-Hill的“科学和技术百科全书”(Encyclopedia of Science andTechnology),第7卷,第159-164页,提供了其他可用油墨种类和其用途的细节,所有这些内容这里引为参考。
即使使用可市购的油墨,仍需要提供更易于制备的油墨。
涂料用于许多种类表面的装饰、防护和功能性处理。这些表面包括:线圈、金属、器具、家俱、硬纸板、木材和胶合板、船舶、维护、汽车、罐头和纸板。一些涂料,如那些海底管道上的涂料,是用于保护性的目的。其他一些涂料,如汽车外用涂料,既具有装饰性功能又具有保护性功能。另外还有涂料提供船甲板和汽车底座上的摩擦控制。一些涂料防止船底弄脏,另外一些保护罐头里的食品和饮料。硅片、印刷电路板、信号传输的波导纤维上的涂料、录像磁带和计算机磁盘上的磁性涂料是涂料中的一些所谓的高科技应用。
每年制备出成千上万种涂料。一般来说,它们由一种或多种粘合剂(如树脂或粘合剂)、至少一种溶剂、一种或多种颜料和任选的几种添加剂组成。大多数涂料制备成液状体且以液体状应用,当涂布到底物上后转化成“固体”膜。
颜料和涂料提供了不透明度和颜色。颜料内含物控制最终膜的光泽度,并可对其机械性能有很重要的影响。一些颜料甚至防止腐蚀。另外,颜料影响向其粘度并提高该涂料的涂布性。一个决定颜料性能的重要变量是颜料的粒径和粒径分布。把颜料制备方法设计成能提供最佳综合考虑了该颜料粒子的粒径和粒径分布的方法。在涂料的制备中,希望以得到一个稳定的分散体的这样一种方式分散该颜料,其中大多数颜料粒子,如果不是全部的话,被分散成颜料制造商设计成产品的单个粒子。颜料的分散包括润湿、分离和稳定。
有三类漆料:其中粘合剂可溶于水的漆料、在其中胶态分散的漆料以及在其中乳化形成胶乳的漆料。表面涂料组合物通常是多少有点粘的液体,它具有三种基本组份:成膜物质或称为粘合剂的物质混合物、一种颜料或多种颜料的混合物以及挥发性液体。粘合剂和挥发性液体的组合物称为漆料,该漆料可以一种溶液或细粘合剂粒子在非溶剂中的分散体。颜料是磨碎的、不溶的、分散在涂料漆料中的固体粒子,并在最终膜中分散在整个粘合剂中。表面活性剂被用作颜料分散剂。水性涂料的组份和制备进一步讨论在“聚合物、科学和工程的精选百科全书”(Concised Encyclopedia of Polymer,Scienceand Engineering),第160-171页(1990),其内容这里引为参考。
仍需要一种既可在水性油墨又可在涂料中更易制备的水性涂料。溶剂是(或含有)水。
因此,本发明涉及含有水和改性碳产品的水性油墨组合物或水性涂料组合物,该改性碳产品含有连有有机基团的碳。该有机基团被一个离子或一个可离子化的基团所取代。这里所用的碳,能与重氮盐反应形成上述改性的碳产品。该碳可以是结晶形的或无定形的。其例子包括,但不局限于:石墨、炭黑、玻璃碳、活性炭、活性碳以及它们的混合物。上述碳的磨碎形式是优选的。
该有机基团包括a)至少一个芳基,和b)至少一个离子基团、至少一个可离子化的基团、或一个离子基团和一个可离子化的基团的混合物。该具有芳基的有机基团通过该芳基直接连到该碳上。
另外,该改性碳产品的有机基团包括a)至少一个C1-C12取代或未取代的烷基,和b)至少一个离子基团、至少一个可离子化的基团或一个离子基团和一个可离子化的基团的混合物。
本发明的水性油墨和涂料提供了所希望的分散稳定性、印刷质量和图像光密度。
下面的说明书介绍了本发明其他特征和优点。通过该说明或通过实施所述的本发明,将更清楚或更领会这些功能。通过在下面说明书和所附权利要求书中具体指出的方法、产品和组合物,将认识和实现这些目的和其他优点。
这里所用的碳,能与重氮盐反应以形成上述改性的碳产品。该碳可以是结晶或无定形的。其例子包括、但不局限于:石墨、炭黑、玻璃碳、活性炭、活性炭黑和它们的混合物。优选是上述碳的磨碎形式。
本发明涉及含有水性连接料和改性碳产品的水性油墨和涂料组合物。与常规碳颜料相反,用于本发明油墨或涂料中的改性碳产品不难分散在水性连接料中。该改性的碳产品未必需要常规的研磨过程,也未必需要得到可用的油墨或涂料所需要的分散剂。优选该改性的碳产品仅需要低的剪切搅拌或混合,就把颜料很容易地分散在水中。
该碳产品的制备如下:在液体反应介质中把上述定义的碳与重氮盐反应,来把至少一个有机基团连到该碳的表面上。优选的反应介质包括水、含水的任何介质和含醇的任何介质。水是最优选的介质。这些改性的碳产品(其中该碳是炭黑)和其各种制备方法介绍在1994年12月15日提交的题为“炭黑与重氮盐的反应、生成的炭黑产品及其用途”(“Reaction of Carbon MaterialsWith Diazonium Salts,Resultant Carbon Black Products and Their Uses”)的美国专利申请系列号08/356,660以及与该申请同时提交的其接续部分申请中,这两个申请本文引为参考。这些改性碳产品(其中该碳不是炭黑)和其各种制备方法介绍在1994年12月15日提交的题为“碳材料与重氮盐的反应和生成的碳产品”(“Reaction of Carbon Materials With Diazonium Salts,Resultant CarbonBlack Products”)的专利申请系列号08/356,653中,该申请本文也引为参考。
为了制备上述的改性碳产品,该重氮盐仅需要足够稳定来与碳反应就行。因此,该反应可用一些在其他情况下认为是不稳定并易于分解的重氮盐来进行。一些分解过程可与该碳和重氮盐之间的反应竞争,并可减少连接到该碳上的有机基团的总数。另外,该反应可在较高的温度下进行,这时许多重氮盐易于分解。较高的温度也可有利地增加该重氮盐在反应介质中的溶解性并提高在其该方法中的加工性。然而,由于其他的分解过程,较高的温度可导致一些重氮盐的损失。
当碳作为稀的、易于搅拌的水性浆料存在时,或在用来炭黑造粒的适量水存在时,该炭黑可与重氮盐反应。如果需要,可用常规的造粒工艺形成炭黑粒料。其他的碳可类似地与重氮盐反应。另外,当把用碳而不是炭黑的改性碳产品用于水性油墨和涂料中时,优选在与重氮盐反应之前,应该先将碳研磨成细小的粒径,来避免在该油墨中形成不希望要的沉淀。可连到该碳上的有机基团是用作为官能团的离子或可离子化基团取代的有机基团。可离子化基团是一个在使用介质中能形成离子基的基团。该离子基可以是阴离子基或阳离子基,且该可离子化的基团可以形成一个阴离子或阳离子。
形成阴离子的可离子化的官能团包括:例如,酸基或酸基的盐。因此,该有机基团包括从有机酸衍生的基团。优选当它含有一个形成阴离子的可离子化的基团时,这样的一个有机基团具有a)一个芳基,或一个C1-C12取代或未取代的烷基和b)至少一个pKa小于11的酸基,或至少一个pKa小于11的酸基的盐,或至少一个pKa小于11的酸基和至少一个pKa小于11的酸基的盐的混合物。该酸基的pKa是指整个有机基团的pKa,而不只是该酸基取代基的。更优选,该pKa小于10,且最优选小于9。优选该有机基团的芳族基或烷基直接连到该碳上。该芳族基可进一步被取代或未取代,如用烷基。该C1-C12烷基可以是支化或未支化的,并优选是乙基。更优选,该有机基团是苯基或萘基,且该酸基是磺酸基、亚磺酸基、膦酸基或羧酸基。其例子包括-COOH、-SO3H、-PO3H2、-SO2NH2、-SO2NHCOR以及它们的盐。如-COONa、-COOK、-COO-NR4 +、-SO3Na、-HPO3Na、-SO3 -NR4 +和PO3Na2,其中R是烷基或苯基。特别优选的可离子化的取代基是-COOH和-SO3H以及它们的钠盐和钾盐。
更优选,该有机基团是取代或未取代的磺基苯基或其盐;取代或未取代的(多磺基)苯基或其盐;取代或未取代的磺基萘基或其盐;取代或未取代的(多磺基)萘基或其盐。一种优选的取代的磺基苯基是羟基磺基苯基或其盐。
具体的具有形成阴离子的可离子化的官能团的有机基团是:对-磺苯基、4-羟基-3-磺苯基和2-磺乙基。
胺代表形成阳离子基团的可离子化的官能团的例子且可连到与上述形成阴离子的可离子化的基团相同的有机基团上。例如,胺在酸性介质中可质子化形成铵基。优选,具有胺基取代基的有机基团的pKb小于5。季铵基(-NR3 +)和季磷鎓基(-PR3 +)也代表阳离子基团的例子且可连到与上述形成阴离子的可离子化的基团相同的有机基团上。优选,该有机基团含有一个如苯基或萘基的芳基和一个季铵基或一个季磷鎓基。该芳基优选直接连到碳上。季环状胺、甚至季芳香胺,也可用作该有机基团。因此,N-取代的吡啶鎓化合物,如N-甲基-吡啶基,可用在此处。有机基团的例子包括,但不局限于:(C5H4N)C2H5 +、C6H4(NC5H5)+、C6H4COCH2N(CH3)3 +、C6H4COCH2(NC5H5)+、(C5H4N)CH3 +和C6C4CH2N(CH3)3 +。
连有用离子或可离子化的基团取代的有机基团的改性碳产品的一个优点是:相对于相应的未处理碳,该改性的碳产品具有提高的水分散性。通常,改性的碳产品的水分散性随着连接到碳(具有可离子化基团)上的有机基团的数目的增加而增加,或随着连接到指定有机基团上的可离子化的基团的数目的增加而增加。因此,增加连到该改性碳产品上的可离子化基团的数目应提高其水分散性,并允许把水分散性控制在一个所希望的水平上。应注意:通过酸化水性漆料,也可提高含有胺作为连接到该碳上的有机基团的改性碳产品的水分散性。
由于该碳产品的水分散性在某种程度上取决于电荷的稳定性,所以优选该水性介质的离子强度小于0.1摩尔浓度。更优选,该离子强度小于0.01摩尔浓度。本发明的改性的碳产品优选不含有副产物或盐。
当制备本发明的水分散的改性的碳产品时,优选在该反应介质中离子化该离子或可离子化的基团。该生成的产品分散液或浆料可照原状使用或使用前加以稀释。另外,该改性的碳产品可用常规炭黑所用的工艺进行干燥。这些工艺包括,但不局限于:在烘箱或旋转炉中干燥。然而,过度干燥可引起水分散性程度的损失。在上述改性的碳产品在水性连结料中不如所希望的那样容易分散时,可用常规的已知工艺如磨碎或研磨来分散该改性的碳产品。
本发明的改性炭黑产品特别适用于水性油墨配方。因此,本发明提供了含有水和本发明的改性碳产品的改进油墨组合物。可把其他已知的水性油墨添加剂加到该水性油墨配方中。
一般来说,油墨包括四个基本组份:(1)着色剂或颜料,(2)在印刷时起着载体作用的连接料或清漆,(3)提高适印性、干燥性等的添加剂,和(4)调节粘度、干燥性和与其他油墨组份相容性的溶剂。对油墨的性能、制备和用途的一般性研究,参见“印刷手册”(The Printing Manual),第五版,Leach等人编(Chapman & Hall,1993)。各种水性油墨组合物也公开在,例如,美国专利2,833,736、3,607,813、4,104,833、4,308,061、4,770,706和5,026,755中,所有这些专利引入本文作为参考。
可用标准工艺把本发明的改性碳产品作为预分散体或固体加到水性油墨配方中。使用本发明的水可分散的改性碳产品具有显著的优点,并由于减少或消除了常规炭黑通常所使用的研磨步骤而节约了成本。
苯胺油墨代表一组油墨组合物。苯胺油墨通常包括着色剂、粘合剂和溶剂。本发明的改性碳产品可用于苯胺油墨着色剂。实施例3示出了本发明的改性碳产品在水性苯胺油墨组合物中的应用。
本发明的改性碳产品可用于水性新闻油墨。例如,水性新闻油墨组合物可包括水、本发明的改性碳产品、树脂和常规添加剂(如防泡添加剂或表面活性剂)。
本发明的改性碳产品也可用于水性涂料组合物,如油漆或涂饰剂。因此,本发明的一个实施方案是一种含有水、树脂和本发明的改性碳产品的改进水性涂料组合物。其他已知的常规涂料添加剂可加到该水溶性涂料组合物中。参见,例如,“科学和技术的McGraw-Hill百科全书”(McGraw-HillEncyclopedia of Science & Technology),第五版,(McGraw-Hill,1982),这里引为参考。也可参见美国专利5,051,464、5,319,044、5,204,404、5,051,464、4,692,481、5,356,973、5,314,945、5,266,406和5,266,361,所有这些专利这里引为参考。
可用标准工艺,把作为预分散体或固体的本发明改性碳产品加到水性涂料配方中。使用水可分散的改性碳产品使用本发明的水可分散的改性碳产品具有显著的优点,并由于减少或消除了常规炭黑通常所使用的研磨步骤而节约了成本。下面一些实施例介绍本发明的改性碳产品在水性汽车顶层配方中的应用。
当使用上述碳产品时,可用最少的组份和加工步骤,制备含有水性连接料和作为颜料的稳定分散的碳产品的水性油墨或涂料。这样的油墨或涂料可用于各种用途。优选,在本发明的水性油墨和涂料中,该改性碳产品的存在是小于或等于油墨或涂料重量的20%。使用含有未改性的碳和本发明的改性碳产品的混合物的水性油墨或涂料配方也在本发明的范围内。可把下面所讨论的那些常规添加剂加到该分散液中来进一步提高该水性油墨或涂料的性能。
实施例分析方法
根据ASTM D-4820,得到用于表面积测定的BET氮气表面积。根据ASTM D-2414得到DBPA(邻苯二甲酸正二丁酯)数据。
如下测定挥发物含量。炭黑样品在125℃下干燥至恒重。把45ml于燥炭黑样品置于一已在950℃下干燥过的加盖的50ml坩埚中,并在隔焰炉中950℃下加热7分钟。挥发物含量表示为炭黑样品失重的百分数。
在下面的各个实施例中用下述方法来测定本发明炭黑产品和未处理炭黑的水性残余物。用45g水振动炭黑产品(5g)5分钟。将该生成的悬浮液倾倒通过一个筛子,并用水洗涤直到洗液呈无色。除了另外说明,使用325目筛子。干燥该筛子后,测定该筛子上残余物的重量,并表示为试验中所用的炭黑的百分数。
实施例1
在销式造粒机中用预制的重氮盐制备炭黑产品
该实施例介绍制备本发明炭黑产品的另外一种方法。向销式造粒机中加入400g表面积为80m2/g、DBPA为85ml/100g的飞扬性炭黑(fluffy carbonblack)。从27.1g磺胺酸的钠盐、10.32g亚硝酸钠、29.0g浓HCl和293.5g水制得氢氧化4-磺苯基重氮内盐的冷悬浮液,并把该悬浮液加到造粒机中。造粒2分钟后,取出样品并在115℃干燥至恒重。与未处理炭黑的残余物为81%相比较,该产品有0.1%325目残余物。用乙醇进行Soxhlet萃取过夜,得到含有1.1%硫的炭黑产品,与未处理炭黑含有0.8%硫相比较。这表明:27%的对-C6H4SO3 -基团连到该炭黑产品上。因此,该炭黑产品有0.09mmol/g相连的对-C6H4SO3 -基团。
实施例2
用现场制备的重氮盐制备炭黑产品
该实施例介绍制备本发明炭黑产品的另外一种方法。使用表面积为560m2/g、DBPA为90ml/100g和挥发物含量为9.5%的飞扬性炭黑。把50g飞扬性炭黑加到溶于420g水中的8.83g磺胺酸的溶液中。把该生成的悬浮液冷却到30℃,并加入4.6g浓亚硝酸。在搅拌下逐渐加入含有3.51g亚硝酸钠的水溶液,现场形成氢氧化4-磺苯基重氮内盐,该内盐与飞扬性炭黑反应。与未处理炭黑有6%残余物相比较,该生成的产品有0.1%325目残余物。该炭黑产品用乙醇进行Soxhlet萃取过夜后会有1.97%硫,与未处理飞扬性炭黑有0.24%硫相比较。这相当于53%的对-C6H4SO3 -基团连到该炭黑产品上。因此,该炭黑产品有0.54mmol/g相连的对-C6H4SO3 -基团。
实施例3
炭黑产品在水性油墨的制备中的应用
该实施例介绍在水性油墨配方中使用本发明的炭黑产品的优点。如下制备油墨组合物A:把3.13份实施例1的炭黑产品加到一种连接料中,并在油漆摇动器中振动该组合物10分钟,该连接料是通过混合2.92份JONCRYL61LV树脂、0.21份异丙醇、0.31份ARROWFLEX脱泡剂,7.29份JONCRYL89树脂和6.98份水而制备的。下表示出了635目残余物的量。
JONCRYL是由WI.Racine的SC Johnson Polymer生产和销售的树脂的注册商标。ARROWFLEX是由NY,New York的Witco制造和销售的脱泡剂的注册商标。
油墨组合物B的制备如下:研磨120份实施例1所用的炭黑产品,112份JONCRYL 61LV树脂、8份异丙醇、4份ARROWFLEX脱泡剂、156份水和400g研磨介质的混合物。为了检查研磨程度,定期取样到组合物C中,该组合物C含有15.0份炭黑产品、140份JONCRYL61LV树脂、1.0份异丙醇、1.7份ARROWFLEX脱泡剂、35.1份Joncryl 89和33.4份水。
油墨组合物D的制备如下:研磨120份实施例1用的未处理炭黑、112份JONCRYL 61LV树脂、8份异丙醇、4份ARROWFLEX脱泡剂、156份水和400g研磨介质。为了检查研磨程度,定期取样到组合物E中,该组合物E含有15.0份炭黑产品、140份JONCRYL 61LV树脂、1.0份异丙醇、1.7份ARROWFLEX脱泡剂、35.1份JONCRYL89树脂和33.4份水。
在下表中示出了作为研磨时间的函数的油墨组合物A、C和E中的残余物,并清楚地表明:本发明的炭黑产品比相应的那些水性油墨中的未处理炭黑更易分散。
分散时间 | 油墨A635目残余物,% | 油墨C635目残余物,% | 油墨E635目残余物,% |
10分钟振动 | 2.6 | - | - |
20分钟球磨 | - | 0.3 | - |
40分钟球磨 | - | 0.2 | - |
1小时球磨 | - | 0.02 | 约100 |
2小时球磨 | - | - | 10.8 |
3小时球磨 | - | - | 5.8 |
4小时球磨 | - | - | 0.9 |
10小时球磨 | - | - | 0.5 |
14小时球磨 | - | - | 0.3 |
15小时球磨 | - | - | 1.0 |
16小时球磨 | - | - | 1.0 |
实施例4
炭黑产品在水性涂料的制备中的应用
该实施例表明本发明的炭黑产品可用于水性涂料的制备。通过搅拌10分钟,把实施例2的炭黑产品(10g)分散在90g水中。如下制备涂料组合物A:把4.3g这种分散液搅拌入下面这种混合物中,该混合物含有7.53g CARGILL17-7240丙烯酸树脂、0.80g二甲基乙醇胺(DMEA)、19.57g水、0.37gSURFYNOL CT 136表面活性剂、1.32g CARGILL 23-2347三聚氰胺树脂、0.53g乙二醇单丁基醚和0.075g BYK-306表面活性剂。CARGILL 17-7240丙烯酸酯树脂和CARGILL 23-2347三聚氰胺可购自MN,Minneapolis,Cargill Inc.。SURFYNOL CT 136是PA,Allentown的气体产品和化学品公司(Air Products and Chemicals,Inc.)生产和销售的表面活性剂的注册商标。BYK-306是Wallingford的BYK-Chemie USA制造和销售的表面活性剂的注册商标。
如下制备研磨料:在一种混合物中研磨表面积为560m2/g、DBPA为80ml/100g、挥发物含量为9%的氧化炭黑产品(15g)直到平均粒径为0.18微米,该混合物含有74.6g CARGIL 17-7240丙烯酸树脂、9.53g DMEA、236.5g水和16.35g CT-136表面活性剂。对比涂料组合物B的制备为:把这种研磨料24.4g与下面这种混合物混合,该混合物含有17.51g CARGILL 17-7240丙烯酸树脂、1.74g DMEA、50.56g水、3.97g CARGILL23-2347三聚氰胺树脂、1.59g乙二醇单丁醚和0.23g BYK-306表面活性剂。
把涂有组合物A和B的光亮lenetla纸在350°F下干燥10分钟。涂布透明的涂层,并把样品再次干燥。涂有组合物A的纸的亨特L、a、b值分别为1.0、0.01和0.03,与涂有对比组合物B的纸的各值分别为1.1、0.01和-0.06相比较。
实施例5
炭黑产品的制备和其在水性涂料中的应用
该实施例介绍本发明炭黑产品的制备和该炭黑产品在水性涂料中的应用。把CTAB表面积为350m2/g、DBPA为120ml/100g的炭黑(200g)加到42.4g磺胺酸在2800g水中的搅拌溶液中。把二氧化氮(25.5g)溶于100g冷水中,并加到该炭黑产品的悬浮液中。放出气泡。现场生成氢氧化4-磺苯基重氮内盐,该内盐与炭黑反应。搅拌1小时后,把另外5gNO2直接加到该炭黑的分散体中。把该分散体搅拌另外15分钟,并放置过液。在烘箱中130℃下干燥该分散体来回收该生成的炭黑产品。
把10g炭黑产品搅拌在90g水中,来制备该炭黑产品的分散体。如下制备涂料组合物C:把4.3g这种分散体搅拌入一种混合物中,该混合物含有7.53g CARGILL 17-7240丙烯酸树脂、0.80g DMEA、19.57g水、0.37gSURFYNOL CT 136表面活性剂、1.32g CARGILL 23-2347三聚氰胺树脂、0.53g乙二醇单丁醚和0.075g BYK-306表面活性剂。
如下制备研磨料:(在超微磨碎机中)在一种混合物中研磨表面积为560m2/g、DBPA为91ml/100g、挥发物含量为9.5%的氧化炭黑产品(15g)24小时,该混合物含有74.6g CARGILL 17-7240丙烯酸树脂、9.53g DMEA、236.5g水和16.35g SURFYNOL CT-136表面活性剂。如下制备对比涂料组合物D:把这种研磨料24.4g与一种混合物混合,该混合物含有17.51gCARGILL 17-7240丙烯酸树脂、1.74g DMEA、50.56g 水、3.97gCARGILL23-2347三聚氰胺树脂、1.59g乙二醇单丁醚和0.23g BYK-306表面活性剂。
把涂有组合物A和B的光亮lenetta纸在350°F下干燥10分钟。涂布透明涂层,并再次干燥这些样品。涂有组合物C的纸的亨特L、a和b值分别为1.0、0.01和0.03,与涂有对比组合物D的纸的各值分别为1.1、0.01和-0.06相比较。
Claims (16)
1.一种含有水和改性碳产品的水性油墨组合物,该改性碳产品具有至少一个连到该碳上的有机基团,其中该有机基团用一个离子或可离子化的基团取代。
2.权利要求1的水性油墨组合物,其中该离子或可离子化的基团是磺酸基或其盐、亚磺酸基或其盐、羧酸基或其盐、膦酸基或其盐、或季铵基。
3.权利要求1的水性油墨组合物,其中该有机基团是取代或未取代的磺苯基或其盐,或该有机基团是取代的或未取代的(多磺基)苯基或其盐。
4.权利要求1的水性油墨组合物,其中该有机基团是取代或未取代的磺萘基或其盐,或该有机基团是取代的或未取代的(多磺基)萘基或其盐。
5.权利要求3的水性油墨组合物,其中该有机基团是取代或未取代的对-磺苯基或其盐。
6.权利要求5的水性油墨组合物,其中该有机基团是对-C6H4SO3Na。
7.权利要求1的水性油墨组合物,其中所说的碳是炭黑、石墨、玻璃碳、磨碎的碳、活性碳、活性炭、或它们的混合物。
8.权利要求7的水性油墨组合物,其中所说的碳是炭黑。
9.一种含有水、粘合剂和改性碳产品的水性涂料组合物,该改性碳产品具有至少一个连到碳上的有机基团,其中该有机基团被一个离子或可离子化的基团所取代。
10.权利要求9的水性涂料组合物,其中该离子或可离子化的基团是磺酸基或其盐、亚磺酸基或其盐、羧酸基或其盐、膦酸基或其盐、或季铵基。
11.权利要求9的水性涂料组合物,其中该有机基团是取代或未取代的磺苯基或其盐,或该有机基团是取代的或未取代的(多磺基)苯基或其盐。
12.权利要求9的水性涂料组合物,其中该机基团是取代或未取代的磺萘基或其盐,或该有机基团是取代的或未取代的(多磺基)萘基或其盐。
13.权利要求11的水性涂料组合物,其中该有机基团是取代或未取代的对-磺苯基或其盐。
14.权利要求13的水性涂料组合物,其中该有机基是对-C6H4SO3Na。
15.权利要求9的水性涂料组合物,其中所说的碳是炭黑、石墨、玻璃碳、磨碎的碳、活性碳、活性炭、或它们的混合物。
16.权利要求15的水性涂料组合物,其中所说的碳是炭黑。
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US08/356,653 US5554739A (en) | 1994-12-15 | 1994-12-15 | Process for preparing carbon materials with diazonium salts and resultant carbon products |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102604442A (zh) * | 2005-05-17 | 2012-07-25 | 卡伯特公司 | 炭黑和包含它的聚合物 |
CN106967334A (zh) * | 2015-12-28 | 2017-07-21 | 佳能株式会社 | 墨、墨盒和喷墨记录方法 |
Families Citing this family (204)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6852156B2 (en) | 2000-06-05 | 2005-02-08 | E.I. Du Pont De Nemours And Company | Self-dispersing pigment and process of making and use of same |
US6008272A (en) * | 1995-05-22 | 1999-12-28 | Cabot Corporation | Elastomeric compounds incorporating silicon-treated carbon blacks |
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US5747562A (en) | 1996-06-14 | 1998-05-05 | Cabot Corporation | Ink and coating compositions containing silicon-treated carbon black |
WO1997047699A1 (en) * | 1996-06-14 | 1997-12-18 | Cabot Corporation | Modified colored pigments and ink jet inks containing them |
CA2266887A1 (en) * | 1996-09-25 | 1998-04-02 | Cabot Corporation | Pre-coupled silicon-treated carbon blacks |
EP0931113A1 (en) | 1996-09-25 | 1999-07-28 | Cabot Corporation | Silica coated carbon blacks |
DE69719283T2 (de) * | 1996-10-24 | 2003-08-28 | Seiko Epson Corp., Tokio/Tokyo | Tintenzusammensetzung zur Tintenstrahlaufzeichnung und Tintensatz |
US5749952A (en) * | 1996-10-31 | 1998-05-12 | Hewlett-Packard Company | Preparation of microemulsion and micellar color inks from modified water-soluble color chromaphores for thermal ink-jet printing |
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US6399029B1 (en) | 1997-03-24 | 2002-06-04 | Cabot Corporation | Chemical processing using a dual feeder system, a sample port assembly, and a fluid flow control system |
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JP3745130B2 (ja) | 1997-10-30 | 2006-02-15 | キヤノン株式会社 | 画像記録方法 |
US6368239B1 (en) | 1998-06-03 | 2002-04-09 | Cabot Corporation | Methods of making a particle having an attached stable free radical |
JP2001521972A (ja) | 1997-10-31 | 2001-11-13 | キャボット コーポレイション | 結合した安定型フリーラジカルを持つ粒子、重合変性粒子、及びその製造方法 |
US6068688A (en) * | 1997-11-12 | 2000-05-30 | Cabot Corporation | Particle having an attached stable free radical and methods of making the same |
US6387500B1 (en) | 1997-11-06 | 2002-05-14 | Cabot Corporation | Multi-layered coatings and coated paper and paperboards |
US6472471B2 (en) | 1997-12-16 | 2002-10-29 | Cabot Corporation | Polymeric products containing modified carbon products and methods of making and using the same |
JP3862441B2 (ja) | 1998-03-20 | 2006-12-27 | キヤノン株式会社 | インクジェット記録用インク、インクセット、インクカートリッジ、記録ユニット、画像記録装置、画像記録方法、カラー画像の形成方法および画像の光学濃度向上方法 |
DE69901944T3 (de) * | 1998-04-03 | 2009-05-14 | Cabot Corp., Boston | Modifizierte pigmente mit verbesserten dispergierenden eigenschaften |
US6103380A (en) | 1998-06-03 | 2000-08-15 | Cabot Corporation | Particle having an attached halide group and methods of making the same |
US6221141B1 (en) | 1998-06-23 | 2001-04-24 | Canon Kabushiki Kaisha | Ink, ink-jet recording process, recording unit, ink cartridge and ink-jet recording apparatus |
US6150433A (en) | 1998-07-31 | 2000-11-21 | Hewlett-Packard Company | Ink-jet ink compositions containing modified macromolecular chromophores with covalently attached polymers |
US6979488B2 (en) | 1998-08-10 | 2005-12-27 | Eastman Kodak Company | Receiver having hydrophilic receiving surface |
JP3435371B2 (ja) | 1998-09-14 | 2003-08-11 | 株式会社日本触媒 | カーボンブラックグラフトポリマーおよびその用途 |
US6277183B1 (en) | 1998-10-08 | 2001-08-21 | Cabot Corporation | Ink compositions containing metal oxides |
US6458458B1 (en) * | 1998-10-13 | 2002-10-01 | Cabot Corporation | Polymer coated carbon products and other pigments and methods of making same by aqueous media polymerizations or solvent coating methods |
US6261347B1 (en) | 1998-10-30 | 2001-07-17 | Ncr Corporation | Scented jet ink and printed articles therefrom |
US6218067B1 (en) | 1998-11-06 | 2001-04-17 | Cabot Corporation | Toners containing chargeable modified pigments |
US6210473B1 (en) | 1998-11-09 | 2001-04-03 | Xerox Corporation | Ink composition and processes thereof |
JP2000190480A (ja) | 1998-12-25 | 2000-07-11 | Canon Inc | インクプリント方法およびインクプリント装置 |
CA2626296C (en) | 1999-01-20 | 2011-12-13 | Cabot Corporation | Polymer foams comprising chemically modified carbonaceous filler |
EP2316874A1 (en) | 1999-01-20 | 2011-05-04 | Cabot Corporation | Aggregates having attached polymer groups and polymer foams |
US6177485B1 (en) | 1999-02-17 | 2001-01-23 | Hewlett-Packard Company | Polymers derived from unsaturated surfactants for use in ink-jet inks |
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US6221143B1 (en) | 1999-03-12 | 2001-04-24 | Cabot Corporation | Cationic pigments and aqueous compositions containing same |
US6572692B1 (en) * | 1999-03-15 | 2003-06-03 | Canon Kabushiki Kaisha | Ink, method for improving intermittent dischargeability of ink-jet recording apparatus, method for recording image, recording unit, ink cartridge, ink set, and image recording apparatus |
JP4428758B2 (ja) * | 1999-06-25 | 2010-03-10 | キヤノン株式会社 | インクジェットプリント装置およびその方法 |
US6221138B1 (en) | 1999-06-30 | 2001-04-24 | Ncr Corporation | Jet ink with a magneto-rheological fluid |
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JP4851040B2 (ja) | 1999-10-28 | 2012-01-11 | キャボット コーポレイション | インクジェット用インク、インク、および着色顔料を含有するその他の組成物 |
KR100532912B1 (ko) * | 1999-11-24 | 2005-12-02 | 제일모직주식회사 | 수용액 중에서의 분산성이 우수한 카본블랙의 제조방법 및이를 이용한 잉크젯 잉크 조성물 |
EP1244906A1 (en) | 1999-12-30 | 2002-10-02 | Cabot Corporation | Sensors with improved properties |
AU2001229740A1 (en) | 2000-01-25 | 2001-08-07 | Cabot Corporation | Polymers containing modified pigments and methods of preparing the same |
US6479571B1 (en) | 2000-01-25 | 2002-11-12 | Cabot Corporation | Elastomeric compositions containing polymer coated carbon products and other pigments |
ITPC20000006A1 (it) * | 2000-02-03 | 2000-05-03 | Grafiche Rekord Srl | Metodo per incollare etichette di plastica su contenitori idrorepellenti a mezzo di impianti per colle ad acqua. |
DE60113901T2 (de) * | 2000-03-10 | 2006-06-22 | Canon K.K. | Tintenstrahldruckverfahren |
US6533859B2 (en) * | 2000-05-26 | 2003-03-18 | Flexsys America L.P. | Surface treated carbon black having improved dispersability in rubber and compositions of rubber therefrom having improved processability, rheological and dynamic mechanical properties |
US6494569B2 (en) * | 2000-06-21 | 2002-12-17 | Canon Kabushiki Kaisha | Ink-jet printing method |
AU2001273085A1 (en) | 2000-07-06 | 2002-01-21 | Cabot Corporation | Modified pigment products, dispersions thereof, and compositions comprising the same |
US6468337B1 (en) | 2000-07-19 | 2002-10-22 | Xerox Corporation | Ink compositions with amine-functionalized pigments |
US6500401B2 (en) | 2000-07-20 | 2002-12-31 | Cabot Corporation | Carbon foams and methods of making the same |
US6706105B2 (en) | 2000-09-29 | 2004-03-16 | Canon Kabushiki Kaisha | Aqueous ink, ink-jet recording method, recording unit, ink cartridge, ink set, and ink-jet recording apparatus |
US6822781B1 (en) | 2000-10-24 | 2004-11-23 | Cabot Corporation | Gyricon displays containing modified particles |
EP1355998B1 (en) * | 2001-02-02 | 2006-04-05 | Cabot Corporation | Ink compositions comprising salts with polyvalent ions |
US20030022055A1 (en) * | 2001-04-11 | 2003-01-30 | Jameel Menashi | Fuel cells and other products containing modified carbon products |
US7541308B2 (en) | 2001-04-11 | 2009-06-02 | Cabot Corporation | Fuel cells and other products containing modified carbon products |
US6645287B2 (en) | 2001-04-27 | 2003-11-11 | Cabot Corporation | Coating compositions comprising high t-area carbon products |
US6602335B2 (en) | 2001-05-08 | 2003-08-05 | Hewlett-Packard Development Company, L.P. | Pigment solubilization via treatment with strong base and substitution |
JP4188091B2 (ja) * | 2001-05-15 | 2008-11-26 | イー インク コーポレイション | 電気泳動粒子 |
TW525063B (en) * | 2001-09-03 | 2003-03-21 | Via Tech Inc | General accelerated graphic port interface system and the operation method thereof |
US6908961B2 (en) | 2001-12-07 | 2005-06-21 | Cabot Corporation | Elastomer composites, elastomer blends and methods |
US7176248B2 (en) * | 2002-01-16 | 2007-02-13 | E. I. Du Pont De Nemours And Company | Smear resistant inkjet inks |
US20030151028A1 (en) * | 2002-02-14 | 2003-08-14 | Lawrence Daniel P. | Conductive flexographic and gravure ink |
DE60329482D1 (de) * | 2002-03-27 | 2009-11-12 | Cabot Corp | Verfahren zur anbindung einer oder mehrerer organischer gruppen an ein teilchen |
US7173078B2 (en) | 2002-04-12 | 2007-02-06 | Cabot Corporation | Process for preparing modified pigments |
WO2003100884A2 (en) | 2002-05-23 | 2003-12-04 | Columbian Chemicals Company | Sulfonated conducting polymer-grafted carbon material for fuel cell applications |
WO2003100883A2 (en) * | 2002-05-23 | 2003-12-04 | Columbian Chemicals Company | Conducting polymer-grafted carbon material for fuel cell applications |
US7390441B2 (en) * | 2002-05-23 | 2008-06-24 | Columbian Chemicals Company | Sulfonated conducting polymer-grafted carbon material for fuel cell applications |
US7459103B2 (en) | 2002-05-23 | 2008-12-02 | Columbian Chemicals Company | Conducting polymer-grafted carbon material for fuel cell applications |
US7195834B2 (en) * | 2002-05-23 | 2007-03-27 | Columbian Chemicals Company | Metallized conducting polymer-grafted carbon material and method for making |
US7241334B2 (en) * | 2002-05-23 | 2007-07-10 | Columbian Chemicals Company | Sulfonated carbonaceous materials |
US6899754B2 (en) * | 2002-06-06 | 2005-05-31 | E. I. Du Pont De Nemours And Company | Inkjet inks with increased optical density |
US7045002B2 (en) * | 2002-11-15 | 2006-05-16 | E. I. Du Pont De Nemours And Company | Interactive ink set for inkjet printing |
US6863719B2 (en) * | 2002-12-30 | 2005-03-08 | Lexmark International, Inc. | Ink jet ink with improved reliability |
US20040201658A1 (en) * | 2003-01-16 | 2004-10-14 | Christian Jackson | Inkjet ink set and method of using same |
KR101059025B1 (ko) * | 2003-01-17 | 2011-08-23 | 캐보트 코포레이션 | 착색 안료 수분산액의 제조 방법 및 잉크젯 잉크 조성물 |
US6936097B2 (en) * | 2003-04-16 | 2005-08-30 | Cabot Corporation | Modified organic colorants and dispersions, and methods for their preparation |
US6942724B2 (en) * | 2003-04-16 | 2005-09-13 | Cabot Corporation | Modified organic colorants and dispersions, and methods for their preparation |
JP4508703B2 (ja) | 2003-04-24 | 2010-07-21 | キヤノン株式会社 | インクジェット用インク及びこれを用いたインクジェット記録方法 |
US20050020730A1 (en) * | 2003-05-19 | 2005-01-27 | Valentini Jose E. | Inkjet ink |
US20050039631A1 (en) * | 2003-05-23 | 2005-02-24 | Best Kevin J. | Pigmented inkjet ink set |
US20050090599A1 (en) * | 2003-06-06 | 2005-04-28 | Spinelli Harry J. | Aqueous ionically stabilized dispersions |
US20050032930A1 (en) * | 2003-07-02 | 2005-02-10 | Christian Jackson | Inkjet ink |
US7001936B2 (en) * | 2003-07-16 | 2006-02-21 | Lexmark International, Inc. | Pigmented inkjet ink |
US20050070629A1 (en) * | 2003-08-06 | 2005-03-31 | Roberts C. Chad | Inkjet ink |
WO2005026272A1 (en) * | 2003-09-08 | 2005-03-24 | E.I. Dupont De Nemours And Company | Inkjet ink, ink set and method of printing |
US7192472B2 (en) * | 2003-09-18 | 2007-03-20 | E. I. Du Pont De Nemours And Company | Inkjet ink composition |
US7495042B2 (en) * | 2003-10-28 | 2009-02-24 | Cabot Corporation | Non-aqueous coating compositions |
US7897658B2 (en) * | 2003-10-28 | 2011-03-01 | Cabot Corporation | Aqueous coating compositions |
JP4791369B2 (ja) * | 2003-11-12 | 2011-10-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | インクジェット・インク、インクセットおよび印刷の方法 |
EP1697258A4 (en) * | 2003-11-26 | 2010-03-10 | Cabot Corp | PARTICULATE ABSORBENT MATERIALS AND PROCESSES FOR PRODUCING THE SAME |
US20050215663A1 (en) * | 2004-01-21 | 2005-09-29 | Berge Charles T | Inkjet inks containing crosslinked polyurethanes |
KR100891337B1 (ko) * | 2004-03-15 | 2009-04-01 | 캐보트 코포레이션 | 연료전지 및 유사 장치에 이용되는 변성 탄소 산물, 및 관련 방법 |
US20050256225A1 (en) * | 2004-05-11 | 2005-11-17 | Viola Michael S | Aqueous inkjet ink compositions comprising comb-branched copolymers |
US7351278B2 (en) * | 2004-06-09 | 2008-04-01 | E.I. Du Pont De Nemours And Company | Additive for high optical density inkjet ink |
DE102004029074A1 (de) * | 2004-06-16 | 2005-12-29 | Degussa Ag | Lackformulierung zur Verbesserung der Oberflächeneigenschaften |
US7347892B2 (en) * | 2004-08-13 | 2008-03-25 | Xerox Corporation | Phase change inks containing modified pigment particles |
US20060038901A1 (en) * | 2004-08-17 | 2006-02-23 | Pictureflow, Llc. | System and method for recording dynamic range of a photograph's luminance |
WO2006023792A1 (en) * | 2004-08-18 | 2006-03-02 | E.I. Dupont De Nemours And Company | Inkjet ink with long latency |
US20060068987A1 (en) * | 2004-09-24 | 2006-03-30 | Srinivas Bollepalli | Carbon supported catalyst having reduced water retention |
KR101341262B1 (ko) * | 2004-10-15 | 2013-12-13 | 캐보트 코포레이션 | 높은 저항률 조성물 |
EP1833932B1 (en) * | 2004-12-17 | 2012-01-18 | Cabot Corporation | Method of preparing oxidized modified pigments and inkjet ink compositions comprising the same |
DE102005009321A1 (de) * | 2005-03-01 | 2006-09-07 | Degussa Ag | Suspension |
US7537650B2 (en) | 2005-03-30 | 2009-05-26 | Eastman Kodak Company | Aqueous ink of colored ink and colorless ink containing anionic polymer |
DE102005037336A1 (de) * | 2005-08-04 | 2007-02-08 | Degussa Ag | Kohlenstoffmaterial |
US7479179B2 (en) | 2005-08-05 | 2009-01-20 | Eastman Kodak Company | Pigment inks having excellent image and storage properties |
EP1937763A2 (en) * | 2005-08-08 | 2008-07-02 | Cabot Corporation | Polymeric compositions containing nanotubes |
US20070043144A1 (en) * | 2005-08-18 | 2007-02-22 | Eastman Kodak Company | Pigment ink jet ink composition |
US7655708B2 (en) * | 2005-08-18 | 2010-02-02 | Eastman Kodak Company | Polymeric black pigment dispersions and ink jet ink compositions |
CN101291996B (zh) * | 2005-08-31 | 2012-10-03 | 卡伯特公司 | 制备改性颜料的方法 |
JP5001292B2 (ja) | 2005-10-31 | 2012-08-15 | キャボット コーポレイション | 変性着色剤及び変性着色剤を含むインクジェットインキ組成物 |
KR100665757B1 (ko) * | 2005-11-09 | 2007-01-09 | 제일모직주식회사 | 벤젠화합물로 표면처리된 카본블랙 및 이를 이용한 블랙 매트릭스용 카본블랙 분산액 조성물 |
US7749957B2 (en) | 2006-04-06 | 2010-07-06 | E.I. Du Pont De Nemours And Company | Clay-binding peptides and methods of use |
US8728223B2 (en) | 2006-05-16 | 2014-05-20 | Cabot Corporation | Low viscosity, high particulate loading dispersions |
US8585816B2 (en) * | 2006-05-16 | 2013-11-19 | Cabot Corporation | Low viscosity, high particulate loading dispersions |
US7554815B2 (en) * | 2006-05-31 | 2009-06-30 | Hewlett-Packard Development Company, L.P. | Resilient clip for circuit board |
US7732509B2 (en) * | 2006-08-24 | 2010-06-08 | Eastman Kodak Company | Polymeric colorant-based ink compositions |
CN101528865B (zh) * | 2006-08-28 | 2013-01-30 | 卡伯特公司 | 具有脂族多元酸基团的改性着色剂 |
US8163075B2 (en) | 2006-10-31 | 2012-04-24 | Sensient Colors Llc | Inks comprising modified pigments and methods for making and using the same |
US20080249217A1 (en) * | 2007-02-27 | 2008-10-09 | Sze-Ming Lee | Inkjet ink compositions comprising multiple modified pigments |
US7771523B2 (en) * | 2007-04-20 | 2010-08-10 | E.I. Du Pont De Nemours And Company | Ink jet ink |
US7799121B2 (en) * | 2007-04-20 | 2010-09-21 | E.I. Du Pont De Nemours And Company | Inkjet ink |
US20090020035A1 (en) * | 2007-04-20 | 2009-01-22 | Christian Jackson | Inkjet ink |
US8133311B2 (en) * | 2007-04-30 | 2012-03-13 | Cabot Corporation | Pigment dipsersions comprising functionalized non-polymeric dispersants |
JP5706159B2 (ja) | 2007-08-23 | 2015-04-22 | センシエント カラーズ エルエルシー | 自己分散型顔料ならびにその製造方法および使用 |
DE102007060307A1 (de) * | 2007-12-12 | 2009-06-18 | Evonik Degussa Gmbh | Verfahren zur Nachbehandlung von Ruß |
JP2011509318A (ja) * | 2007-12-18 | 2011-03-24 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ブリード制御剤を含む水性インクジェットインク |
DE102008005005A1 (de) | 2008-01-17 | 2009-07-23 | Evonik Degussa Gmbh | Kohlenstoff-Aerogele, Verfahren zu deren Herstellung und deren Verwendung |
US8562122B2 (en) * | 2008-01-25 | 2013-10-22 | E I Du Pont De Nemours And Company | Ink jet inks having improved corrosion resistance for use in ink jet print heads comprising nickel or nickel alloys |
US20090192261A1 (en) * | 2008-01-25 | 2009-07-30 | Waifong Liew Anton | Ink jet inks having improved corrosion resistance |
US7819962B2 (en) * | 2008-03-17 | 2010-10-26 | Cabot Corporation | Modified pigments having reduced phosphate release, and dispersions and inkjet ink compositions therefrom |
US8556402B2 (en) * | 2008-05-22 | 2013-10-15 | E I Du Pont De Nemours And Company | Fixer inks for use with ink jet inks |
US20100081740A1 (en) * | 2008-09-29 | 2010-04-01 | Christian Jackson | Aqueous inkjet ink comprising self-dispersing pigment |
DE102008044116A1 (de) * | 2008-11-27 | 2010-06-02 | Evonik Degussa Gmbh | Pigmentgranulat, Verfahren zu dessen Herstellung und Verwendung |
EP2385973B1 (en) | 2009-01-09 | 2017-01-04 | Cabot Corporation | Modified pigment containing inkjet ink compositions having a reduced conductivity increase |
US8398762B2 (en) | 2009-03-24 | 2013-03-19 | E I Du Pont De Nemours And Company | Pigmented inkjet ink comprising a bleed control agent |
BRPI1014677A2 (pt) | 2009-03-30 | 2016-04-12 | Du Pont | sistemas baseados em peptídeos para distribuição de agentes cosméticos |
WO2010114638A1 (en) | 2009-03-30 | 2010-10-07 | E. I. Du Pont De Nemours And Company | Peptide-based tooth whitening reagents |
WO2010118187A2 (en) | 2009-04-07 | 2010-10-14 | Sensient Colors Inc. | Self-dispersing particles and methods for making and using the same |
US8419176B2 (en) | 2009-05-29 | 2013-04-16 | Eastman Kodak Company | Aqueous compositions with improved silicon corrosion characteristics |
JP5589564B2 (ja) * | 2009-06-30 | 2014-09-17 | 住友化学株式会社 | 加硫ゴム及びその製造方法 |
EP2497137B1 (en) | 2009-11-02 | 2019-07-24 | Cabot Corporation | Lead-acid batteries and pastes therefor |
HUE046044T2 (hu) | 2009-11-02 | 2020-01-28 | Cabot Corp | Nagy fajlagos felületû és kis szerkezetû kormok, energiatárolási alkalmazásra |
US8398191B2 (en) | 2009-11-24 | 2013-03-19 | Eastman Kodak Company | Continuous inkjet printer aquous ink composition |
US20110123714A1 (en) | 2009-11-24 | 2011-05-26 | Hwei-Ling Yau | Continuous inkjet printer aquous ink composition |
WO2011082961A2 (de) * | 2009-12-14 | 2011-07-14 | Basf Se | Verfahren zur herstellung von metallisierten oberflächen, metallisierte oberfläche und ihre verwendung |
DE102010002244A1 (de) * | 2010-02-23 | 2011-08-25 | Evonik Carbon Black GmbH, 63457 | Ruß, Verfahren zu seiner Herstellung und seine Verwendung |
US9434201B2 (en) | 2010-05-17 | 2016-09-06 | Eastman Kodak Company | Inkjet recording medium and methods therefor |
WO2011150301A1 (en) | 2010-05-27 | 2011-12-01 | E. I. Du Pont De Nemours And Company | Fixer inks for use with ink jet inks |
US8434857B2 (en) | 2010-08-31 | 2013-05-07 | Eastman Kodak Company | Recirculating fluid printing system and method |
US8430492B2 (en) | 2010-08-31 | 2013-04-30 | Eastman Kodak Company | Inkjet printing fluid |
CZ2013147A3 (cs) * | 2010-09-03 | 2013-10-23 | Cabot Corporation | Modifikovaná plniva a elastomerní kompozity s jejich obsahem |
US20120156375A1 (en) | 2010-12-20 | 2012-06-21 | Brust Thomas B | Inkjet ink composition with jetting aid |
US8465578B2 (en) | 2011-03-31 | 2013-06-18 | Eastman Kodak Company | Inkjet printing ink set |
WO2012149324A1 (en) | 2011-04-29 | 2012-11-01 | Eastman Kodak Company | Recirculating inkjet printing fluid, system and method |
US8759419B2 (en) | 2011-08-30 | 2014-06-24 | Brother Kogyo Kabushiki Kaisha | Water-based ink for ink-jet recording and cartridge |
US8741048B2 (en) | 2011-08-30 | 2014-06-03 | Brother Kogyo Kabushiki Kaisha | Water-based ink for ink-jet recording and ink cartridge |
US8764161B2 (en) | 2011-08-31 | 2014-07-01 | Eastman Kodak Company | Printing fluids including a humectant |
US20130189499A1 (en) | 2012-01-24 | 2013-07-25 | Thomas Nelson Blanton | Antibacterial and antifungal protection for ink jet image |
US20130186301A1 (en) | 2012-01-24 | 2013-07-25 | Thomas Nelson Blanton | Ink having antibacterial and antifungal protection |
US8801166B2 (en) | 2011-09-29 | 2014-08-12 | Brother Kogyo Kabushiki Kaisha | Water-based ink for ink-jet recording, ink cartridge, and ink-jet recording apparatus |
US10640630B2 (en) * | 2012-03-02 | 2020-05-05 | Cabot Corporation | Elastomeric composites containing modified fillers and functionalized elastomers |
US9175150B2 (en) * | 2012-03-02 | 2015-11-03 | Cabot Corporation | Modified carbon blacks having low PAH amounts and elastomers containing the same |
US9067448B2 (en) | 2012-05-02 | 2015-06-30 | Eastman Kodak Company | Pre-treatment composition for inkjet printing |
WO2014012002A2 (en) | 2012-07-13 | 2014-01-16 | Cabot Corporation | High structure carbon blacks |
US20140120339A1 (en) | 2012-10-31 | 2014-05-01 | Cabot Corporation | Porous carbon monoliths templated by pickering emulsions |
DE112014001173T5 (de) | 2013-03-05 | 2015-11-12 | Cabot Corporation | Wässrige Pigmentdispersionen |
DE112014001322T5 (de) | 2013-03-12 | 2016-01-14 | Cabot Corporation | Wässrige Dispersionen, die nanokristalline Cellulose umfassen, undZusammensetzungen für den kommerziellen Tintenstrahldruck |
BR112015022726A2 (pt) | 2013-03-14 | 2017-07-18 | Cabot Corp | materiais poliméricos de núcleo-casca |
US9206325B2 (en) | 2014-03-15 | 2015-12-08 | Brother Kogyo Kabushiki Kaisha | Water-based ink for ink-jet recording, water-based ink set for ink-jet recording, and treatment agent |
CN104910692B (zh) | 2014-03-15 | 2019-12-31 | 兄弟工业株式会社 | 喷墨记录用水性油墨、墨盒、喷墨记录用水性油墨组、处理剂及盒 |
JP6300084B2 (ja) | 2014-03-31 | 2018-03-28 | ブラザー工業株式会社 | インクジェット記録用水性インク及びインクカートリッジ |
US9523011B2 (en) | 2014-06-23 | 2016-12-20 | Eastman Kodak Company | Recirculating inkjet printing fluid |
US9920209B2 (en) | 2014-10-14 | 2018-03-20 | Cabot Corporation | Aqueous inkjet ink compositions |
EP3294813B1 (en) | 2015-05-15 | 2024-06-12 | Cabot Corporation | Amphoteric polymers and use in inkjet ink compositions |
CN107851799B (zh) | 2015-05-27 | 2021-06-01 | 魁北克电力公司 | 保护电极材料以防潮的方法 |
JP6808410B2 (ja) | 2015-10-20 | 2021-01-06 | キヤノン株式会社 | 水性インク、インクカートリッジ、及びインクジェット記録方法 |
US10106696B2 (en) | 2015-11-18 | 2018-10-23 | Cabot Corporation | Inkjet ink compositions |
KR101748872B1 (ko) * | 2016-03-14 | 2017-06-19 | 한남대학교 산학협력단 | 높은 열안정성을 갖는 카본블랙 분산체 및 그 제조방법 |
NL2032660B1 (en) | 2016-10-31 | 2023-02-24 | Cabot Corp | Polymers for inkjet ink compositions |
WO2018140367A1 (en) | 2017-01-27 | 2018-08-02 | Cabot Corporation | Supercapacitors containing carbon black particles cleaned with an acid |
US10927261B2 (en) | 2017-05-03 | 2021-02-23 | Cabot Corporation | Carbon black and rubber compounds incorporating same |
WO2019051021A1 (en) | 2017-09-07 | 2019-03-14 | Cabot Corporation | INK COMPOSITIONS FOR INKJET PRINTING |
EP3694935A4 (en) * | 2018-04-16 | 2020-09-02 | Hewlett-Packard Development Company, L.P. | FLUID SETS |
DE112020002674T5 (de) | 2019-06-05 | 2022-06-02 | Beyond Lotus Llc | Verfahren zum Herstellen eines Verbundwerkstoffs mit Elastomer und Füllmaterial |
US20240026094A1 (en) | 2020-12-09 | 2024-01-25 | Beyond Lotus Llc | Methods of preparing a composite comprising never-dried natural rubber and filler |
WO2022125677A1 (en) | 2020-12-09 | 2022-06-16 | Beyond Lotus Llc | Method of preparing a compound having elastomer and filler |
ES2965335A2 (es) | 2021-07-20 | 2024-04-12 | Beyond Lotus Llc | Compuestos elastoméricos almacenados |
Family Cites Families (140)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2121535A (en) * | 1934-09-22 | 1938-06-21 | Cabot Godfrey L Inc | Granular product and method of preparing the same |
US2156591A (en) * | 1936-06-29 | 1939-05-02 | Sealco By Products Company | Manufacture of carburized silica |
US2502254A (en) * | 1945-12-07 | 1950-03-28 | Ici Ltd | Manufacture of pigments |
US2514236A (en) * | 1948-03-12 | 1950-07-04 | Ici Ltd | Manufacture of pigments |
DE957755C (de) * | 1949-06-08 | 1957-01-17 | W. R. Grace a Co., New York, N. Y. (V. St. A.) | Verfahren zur Herstellung eines als Mattierungsmittel für Lacke od. dgl. geeigneten Kieselsäuregels |
US2793100A (en) * | 1952-10-16 | 1957-05-21 | Degussa | Process of modifying carbon black |
US2833736A (en) * | 1953-07-20 | 1958-05-06 | Western Union Telegraph Co | Aqueous graphite-polyvinyl alcohol ink composition |
US3011902A (en) * | 1954-05-27 | 1961-12-05 | Cabot Corp | Process of manufacturing carbon black pellets for inks |
US2867540A (en) * | 1955-12-30 | 1959-01-06 | Monsanto Chemicals | Modified carbon black product and process |
GB862018A (en) | 1957-01-16 | 1961-03-01 | Etude Des Ind Du Petrole Au Po | Water-dispersible carbon black and production thereof |
FR1164786A (fr) | 1957-01-16 | 1958-10-14 | Etude Des Ind Du Petrole Au Po | Noir de carbone soluble dans l'eau et sa préparation |
US3043708A (en) * | 1958-07-22 | 1962-07-10 | Dunlop Rubber Co | Modified carbon black |
GB910309A (en) * | 1958-07-22 | 1962-11-14 | Dunlop Rubber Co | Rubber compositions |
FR1215895A (fr) | 1958-11-21 | 1960-04-21 | Etude Des Ind Du Petrole Au Po | Noir de carbone modifié, sa préparation et ses applications |
FR1224131A (fr) | 1959-01-16 | 1960-06-22 | Etude Des Ind Du Petrole Au Po | Noirs de carbone solubles modifiés, leur préparation et leurs applications |
US3335020A (en) * | 1964-03-02 | 1967-08-08 | Huber Corp J M | Modified carbon blacks |
US3674670A (en) * | 1964-12-04 | 1972-07-04 | Ppg Industries Inc | Coating method |
US3479300A (en) * | 1965-10-22 | 1969-11-18 | Cabot Corp | Carbonaceous products |
GB1191872A (en) | 1966-08-18 | 1970-05-13 | Japan Gas Chemical Co | Process for Preparing a Carbon Black-Synthetic Resin Composition |
UST860001I4 (en) * | 1966-12-22 | 1969-03-18 | Defensive publication | |
US3528840A (en) * | 1967-11-15 | 1970-09-15 | Huber Corp J M | Sulfonated carbon black |
US3607813A (en) * | 1969-09-05 | 1971-09-21 | Union Carbide Corp | Printing ink compositions |
US3686111A (en) * | 1970-06-22 | 1972-08-22 | Ppg Industries Inc | Non-aqueous polymeric pseudo-dispersion |
US3876603A (en) * | 1970-06-22 | 1975-04-08 | Ppg Industries Inc | Method of encapsulating pigments in organic dispersions of polymers |
US4014844A (en) * | 1970-06-26 | 1977-03-29 | Agence Nationale De Valorisation De La Recherche (Anvar) | Process for grafting polymers on carbon black through free radical mechanism |
US3846141A (en) * | 1970-12-07 | 1974-11-05 | Dick Co Ab | Jet printing ink composition |
GB1506464A (en) * | 1974-05-29 | 1978-04-05 | Degussa | Aqueous carbon black preparation |
US4003751A (en) * | 1974-09-05 | 1977-01-18 | Union Carbide Corporation | Coating and ink compositions |
JPS51137506A (en) * | 1975-05-22 | 1976-11-27 | Konishiroku Photo Ind | Composition of ink for ink jet recording |
US4014833A (en) * | 1975-11-28 | 1977-03-29 | Owens-Illinois, Inc. | Aqueous printing ink with polyethylene oxide |
US4061830A (en) * | 1975-12-23 | 1977-12-06 | Ppg Industries, Inc. | Selective solar energy receiver and method for its production |
US4204871A (en) * | 1978-04-04 | 1980-05-27 | Sun Chemical Corporation | Printing inks containing nucleated organic pigments |
US4204876A (en) * | 1978-07-17 | 1980-05-27 | M. Hamburger & Sons, Inc. | Cement coloring composition and method of producing same |
SU834062A1 (ru) * | 1979-10-17 | 1981-05-30 | Киевский Филиал По Специальным Видампечати Всесоюзного Научно-Исследова-Тельского Института Комплексных Проб-Лем Полиграфии | Краска дл глубокой или флексогра-фСКОй пЕчАТи |
JPS5682859A (en) * | 1979-12-11 | 1981-07-06 | Sakura Color Prod Corp | Ink composition |
US4290072A (en) * | 1980-01-28 | 1981-09-15 | American Can Company | Opaque jet ink printing method and composition |
JPS56128362A (en) | 1980-03-05 | 1981-10-07 | Toho Beslon Co | Production of carbon fiber |
US4293394A (en) * | 1980-03-31 | 1981-10-06 | Ppg Industries, Inc. | Electrolytically producing chlorine using a solid polymer electrolyte-cathode unit |
DE3115532A1 (de) * | 1980-04-17 | 1982-01-28 | Canon K.K., Tokyo | Tintenstrahl-aufzeichnungsverfahren und aufzeichnungstinte fuer die aufzeichnung auf einem bildempfangsmaterial |
US4478905A (en) * | 1980-04-21 | 1984-10-23 | Ppg Industries, Inc. | Spandrel product with silicate coating |
US4476270A (en) * | 1980-06-06 | 1984-10-09 | E. I. Du Pont De Nemours And Company | Process for making high solids acrylic dispersion lacquer |
US4328041A (en) * | 1980-06-09 | 1982-05-04 | Milliken Research Corporation | Comminuted inorganic materials |
DE3039527C2 (de) | 1980-10-20 | 1984-02-02 | Chemische Werke Brockhues AG, 6229 Walluf | Färbemittel für zementhaltige Gegenstände |
ATE33660T1 (de) * | 1982-07-09 | 1988-05-15 | Battelle Memorial Institute | Stabile waessrige niederviskose dispersion von gepfropftem russ. |
DE3228723A1 (de) * | 1982-07-31 | 1984-02-02 | Basf Farben + Fasern Ag, 2000 Hamburg | Lagerstabile, hitzehaertbare stoffmischungen aus polyisocyanat und mit isocyanatgruppen reaktionsfaehigen verbindungen, verfahren zu deren herstellung und verwendung |
WO1984000768A1 (en) * | 1982-08-09 | 1984-03-01 | Ford Werke Ag | Glycidyl-hydroxy-acrylic high solids coating compositions |
DE3276818D1 (en) * | 1982-08-09 | 1987-08-27 | Ford Motor Co | High solids coating compositions |
US4451597A (en) * | 1982-11-15 | 1984-05-29 | E. I. Du Pont De Nemours And Company | High solids color coat containing alcohol soluble cellulose acetate butyrate |
US4442256A (en) * | 1982-12-16 | 1984-04-10 | E. I. Du Pont De Nemours And Company | Additive for alkyd resin coating compositions |
US4605596A (en) * | 1982-12-20 | 1986-08-12 | E. I. Du Pont De Nemours And Company | Additive for coating compositions |
DE3311513A1 (de) * | 1983-03-30 | 1984-10-04 | Basf Farben + Fasern Ag, 2000 Hamburg | Hitzehaertbare ueberzugsmittel und ihre verwendung |
US4503174A (en) * | 1983-09-06 | 1985-03-05 | E. I. Du Pont De Nemours And Company | Low temperature curing coating composition |
US4680204A (en) * | 1983-09-06 | 1987-07-14 | Ppg Industries, Inc. | Color plus clear coating system utilizing inorganic microparticles |
US4525521A (en) * | 1983-10-14 | 1985-06-25 | E. I. Du Pont De Nemours And Company | Coating composition of an acrylic polymer having amino ester groups and a glycidyl acrylic polymer |
US4556427A (en) * | 1983-12-12 | 1985-12-03 | Union Camp Corporation | Use of humates in printing inks |
US4503175A (en) * | 1983-12-19 | 1985-03-05 | E. I. Du Pont De Nemours And Company | Acrylic polyurethane coating composition |
US4555535A (en) * | 1984-03-07 | 1985-11-26 | E. I. Du Pont De Nemours And Company | Acrylic polyurethane coating composition |
US4620993A (en) * | 1984-03-30 | 1986-11-04 | Ppg Industries, Inc. | Color plus clear coating system utilizing organo-modified clay in combination with organic polymer microparticles |
US4620994A (en) * | 1984-03-30 | 1986-11-04 | Ppg Industries, Inc. | Color plus clear coating system utilizing organo-modified clay |
FR2564489B1 (fr) | 1984-05-18 | 1986-10-10 | Onera (Off Nat Aerospatiale) | Procede electrochimique de traitement de surface de fibres de carbone, fibre traitee par ce procede et materiau composite comportant de telles fibres |
US4665128A (en) * | 1984-09-17 | 1987-05-12 | E. I. Du Pont De Nemours And Company | Flexible coating compositions |
US4719132A (en) * | 1984-09-21 | 1988-01-12 | Ppg Industries, Inc. | Process for the preparation of multi-layered coatings and coated articles derived therefrom |
US4692481A (en) * | 1984-09-27 | 1987-09-08 | E. I. Du Pont De Nemours And Company | Process for matching color of paint to a colored surface |
US4741780A (en) * | 1985-02-11 | 1988-05-03 | Atkinson George K | Treatment of titanium dioxide and other pigments to improve dispersibility |
US5026755A (en) * | 1985-03-13 | 1991-06-25 | Sun Chemical Corporation | Water-based printing ink prepared from polyamide/acrylic graft copolymers |
US5008335A (en) * | 1985-08-07 | 1991-04-16 | Ppg Industries, Inc. | Powder coating compositions of polyepoxides, acrylic copolymers and aliphatic or polyester dibasic acids |
US4650718A (en) * | 1985-08-19 | 1987-03-17 | Ppg Industries, Inc. | Color plus clear coatings employing polyepoxides and polyacid curing agents |
US4681811A (en) * | 1985-08-19 | 1987-07-21 | Ppg Industries, Inc. | Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat |
US4883838A (en) * | 1985-09-30 | 1989-11-28 | Basf Lacke & Farben Ag | Soluble acrylate copolymer containing carboxyl groups, processes for its preparation and coating agents based on the acrylate copolymer |
DE3545618A1 (de) * | 1985-12-21 | 1987-06-25 | Basf Lacke & Farben | Wasserverduennbares ueberzugsmittel zur herstellung der basisschicht eines mehrschichtueberzuges |
US4659770A (en) * | 1986-02-03 | 1987-04-21 | E.I. Du Pont De Nemours And Company | Coating composition of an amine polymer and a blocked polyisocyanate |
US4764430A (en) * | 1986-03-07 | 1988-08-16 | Ppg Industries, Inc. | Crosslinkable compositions containing polyepoxides and polyacid curing agents |
US4727100A (en) * | 1986-08-15 | 1988-02-23 | E. I. Du Pont De Nemours And Company | Coating composition containing a reactive urethane component an acrylic fatty acid drying oil resin and a metallic alkylate |
DE3629470A1 (de) * | 1986-08-29 | 1988-03-10 | Basf Lacke & Farben | Carboxylgruppen und tertiaere aminogruppen enthaltendes polykondensations- und/oder additionsprodukt, ueberzugsmittel auf der basis desselben sowie deren verwendung |
US5319044A (en) | 1986-09-10 | 1994-06-07 | Basf Lacke + Farben Ag | Branched polymer containing silyl groups, a process for the preparation thereof, coating agents based on the polymer, and the use thereof |
DE3636726C1 (de) * | 1986-10-29 | 1988-03-17 | Pelikan Ag | Waessrige Schreibfluessigkeiten sowie ein Verfahren zu deren Herstellung |
US4752532A (en) * | 1986-10-31 | 1988-06-21 | E. I. Du Pont De Nemours And Company | Polyester primer composition |
FR2607528B1 (fr) | 1986-12-02 | 1989-03-17 | Onera (Off Nat Aerospatiale) | Procede electrochimique de traitement de surface de carbone; carbone, notamment fibres de carbone, traite par ce procede et materiau composite comportant de telles fibres |
US4880857A (en) * | 1986-12-17 | 1989-11-14 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Carbon black-graft polymer, method for production thereof, and use thereof |
JPH068366B2 (ja) * | 1987-04-23 | 1994-02-02 | 株式会社ブリヂストン | タイヤ用ゴム組成物 |
US4808656A (en) * | 1987-05-04 | 1989-02-28 | Ppg Industries, Inc. | High solids coating compositions |
US4840674A (en) * | 1987-06-01 | 1989-06-20 | Xerox Corporation | Ink compositions |
US4789400A (en) * | 1987-07-10 | 1988-12-06 | Xerox Corporation | Waterfast ink jet compositions and process |
US4927868A (en) * | 1987-08-19 | 1990-05-22 | Ppg Industries, Inc. | High solids coating compositions containing a polyepoxide and a copolymer of an alpha-olefin and an olefinically unsaturated monoanhydride |
US4798746A (en) * | 1987-08-24 | 1989-01-17 | Ppg Industries, Inc. | Basecoat/clearcoat method of coating utilizing an anhydride additive in the thermoplastic polymer-containing basecoat for improved repairability |
US4798745A (en) * | 1987-08-24 | 1989-01-17 | Ppg Industries, Inc. | Non-yellowing coating composition based on a hydroxy component and an anhydride component and utilization in a process of coating |
US4853037A (en) * | 1987-10-30 | 1989-08-01 | Hewlett-Packard Company | Low glycol inks for plain paper printing |
ZA891937B (en) * | 1988-04-04 | 1990-11-28 | Ppg Industries Inc | Pigment grinding vehicles containing quaternary ammonium and ternary sulfonium groups |
US4975474A (en) * | 1988-06-27 | 1990-12-04 | E. I. Du Pont De Nemours And Company | Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and a self-stabilized dispersion resin |
US4908397A (en) * | 1988-06-27 | 1990-03-13 | E. I. Du Pont De Nemours And Company | Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and a self-stabilized dispersion resin |
US5093391A (en) * | 1988-06-27 | 1992-03-03 | E. I. Du Pont De Nemours And Company | Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and an acid functional component |
US5017435A (en) * | 1988-06-27 | 1991-05-21 | E. I. Du Pont De Nemours And Company | Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and a monomeric or oligomeric anhydride component |
DE3834738A1 (de) | 1988-10-12 | 1990-04-19 | Basf Lacke & Farben | Verfahren zur herstellung eines mehrschichtigen ueberzuges, waessrige beschichtungszusammensetzungen, wasserverduennbare polyacrylatharze und verfahren zur herstellung von wasserverduennbaren polyacrylatharzen |
DE69008705T2 (de) | 1989-01-07 | 1994-11-24 | Canon Kk | Aufzeichnungsflüssigkeit und Verfahren zur Tintenstrahl-Aufzeichnung mit dieser Flüssigkeit. |
US5204404A (en) | 1989-03-21 | 1993-04-20 | E. I. Du Pont De Nemours And Company | Waterbased acrylic silane and polyurethane containing coating composition |
US5066733A (en) * | 1989-04-03 | 1991-11-19 | Ppg Industries, Inc. | Chip resistant coatings and methods of application |
US5242751A (en) | 1989-04-27 | 1993-09-07 | Ppg Industries, Inc. | Paint composites |
EP0410152B1 (en) * | 1989-07-24 | 1994-02-23 | Sumitomo Chemical Company Limited | Rubber composition having excellent dynamic properties |
DE3924618A1 (de) | 1989-07-26 | 1991-01-31 | Basf Lacke & Farben | Ueberzugsmittel auf der basis von carboxylgruppenhaltigen polymeren und epoxidgruppenhaltigen vernetzern, verfahren zur herstellung des ueberzugsmittels sowie seine verwendung |
US5051464A (en) * | 1989-09-01 | 1991-09-24 | E. I. Du Pont De Nemours And Company | Waterborne acrylourethane pigment dispersant polymer |
JP2889326B2 (ja) * | 1989-09-14 | 1999-05-10 | 昭和キャボット株式会社 | カーボンブラック及びゴム組成物 |
US5168106A (en) * | 1989-09-14 | 1992-12-01 | Cabot Corporation | Carbon blacks |
US5064719A (en) * | 1989-09-26 | 1991-11-12 | E. I. Du Pont De Nemours And Company | Coating composition of acrylic polymers containing reactive groups and an epoxy organosilane |
ES2049885T3 (es) * | 1989-10-19 | 1994-05-01 | Canon Kk | Tinta y metodo para impresion por chorros de tinta, cartucho de tinta, dispositivo para chorros de tinta y aparato para la impresion por chorros de tinta que utiliza los mismos. |
EP0425439B1 (de) * | 1989-10-26 | 1995-08-02 | Ciba-Geigy Ag | Wässerige Drucktinten für den Tintenstrahldruck |
US5076843A (en) * | 1989-10-27 | 1991-12-31 | Lexmark, International, Inc. | Nonaqueous thermaljet ink compositions |
US5266406A (en) | 1989-11-08 | 1993-11-30 | E. I. Du Pont De Nemours And Company | Waterbased methylol (meth)acrylamide acrylic polymer and an acrylic hydrosol coating composition |
EP0454872B1 (en) * | 1989-11-21 | 1995-06-28 | Seiko Epson Corporation | Ink for use in ink jet recording |
DE59004417D1 (de) * | 1989-12-11 | 1994-03-10 | Ciba Geigy | Verfahren zum Färben von Leder. |
US5122552A (en) * | 1989-12-12 | 1992-06-16 | E. I. Du Pont De Nemours And Company | Coating composition of polyesterurethane and multifunctional epoxy compound |
JP2664287B2 (ja) | 1990-01-08 | 1997-10-15 | キャボット コーポレイション | 優れたトレッド摩耗/ヒステリシス性能を付与するカーボンブラック及びカーボンブラックの製造方法 |
US5200164A (en) | 1990-04-04 | 1993-04-06 | Cabot Corporation | Easily dispersible carbon blacks |
US5182355A (en) * | 1990-04-05 | 1993-01-26 | Ppg Industries, Inc. | Polyurethane polyanhydride oligomers and method of preparation |
DE4021126C2 (de) | 1990-07-03 | 1998-01-29 | Basf Lacke & Farben | Lacke und Verwendung der Lacke zur Lackierung von Automobilkarosserien |
DE4023537A1 (de) * | 1990-07-25 | 1992-01-30 | Degussa | Mit organosiliciumverbindungen chemisch modifizierte russe, verfahren zu deren herstellung und deren verwendung |
US5281261A (en) | 1990-08-31 | 1994-01-25 | Xerox Corporation | Ink compositions containing modified pigment particles |
US5100470A (en) * | 1990-10-25 | 1992-03-31 | Hewlett-Packard Company | Waterfast ink formulations for thermal ink-jet using organic amines |
DE4038000A1 (de) * | 1990-11-29 | 1992-06-04 | Bayer Ag | Kautschukvulkanisate mit verbessertem hysterese-verhalten |
US5314945A (en) | 1990-12-03 | 1994-05-24 | E. I. Du Pont De Nemours And Company | Waterbased coating compositions of methylol(meth)acrylamide acrylic polymer, polyurethane and melamine crosslinking agent |
US5290848A (en) | 1990-12-18 | 1994-03-01 | E. I. Du Pont De Nemours And Company | Coating composition of a glycidyl acrylic polymer, an aminoester acrylic polymer and a polyester or a polyesterurethane |
US5221581A (en) | 1990-12-18 | 1993-06-22 | E. I. Du Pont De Nemours And Company | Coating composition of a glycidyl acrylic polymer, an aminoester acrylic polymer and a polyester or a polyesterurethane |
FR2672307B1 (fr) * | 1991-02-01 | 1993-06-04 | Centre Nat Rech Scient | Procede de modification de la surface de materiaux carbones par reduction electrochimique de sels de diazonium, notamment de fibres de carbone pour materiaux composites, materiaux carbones ainsi modifies. |
US5206295A (en) | 1991-02-25 | 1993-04-27 | E. I. Du Pont De Nemours And Company | Coating composition comprising an anhydride-containing polymer and a structured epoxy-containing polymer |
US5286286A (en) | 1991-05-16 | 1994-02-15 | Xerox Corporation | Colorless fast-drying ink compositions for printing concealed images detectable by fluorescence |
US5141556A (en) * | 1991-06-13 | 1992-08-25 | E. I. Du Pont De Nemours And Company | Penetrants for aqueous ink jet inks |
US5114477A (en) * | 1991-09-03 | 1992-05-19 | Xerox Corporation | Liquid ink compositions |
US5314953A (en) | 1991-10-21 | 1994-05-24 | E. I. Du Pont De Nemours And Company | Clear coating composition for clear coat/color coat finish |
US5229452A (en) | 1991-11-13 | 1993-07-20 | Cabot Corporation | Carbon blacks |
US5173111A (en) * | 1991-11-18 | 1992-12-22 | Sun Chemical Corporation | Abrasion resistant printing inks |
US5236992A (en) | 1991-11-18 | 1993-08-17 | Cabot Corporation | Carbon blacks and their use in rubber applications |
US5232974A (en) | 1991-11-25 | 1993-08-03 | Cabot Corporation | Low rolling resistance/high treadwear resistance carbon blacks |
US5310778A (en) | 1992-08-25 | 1994-05-10 | E. I. Du Pont De Nemours And Company | Process for preparing ink jet inks having improved properties |
US5356973A (en) | 1992-08-31 | 1994-10-18 | Ppg Industries, Inc. | Aqueous based coating compositions having improved metallic pigment orientation |
US5324790A (en) | 1992-09-29 | 1994-06-28 | E. I. Du Pont De Nemours And Company | Esterification of carboxylate containing polymers |
US5334650A (en) | 1992-09-29 | 1994-08-02 | Basf Corporation | Polyurethane coating composition derived from long-chain aliphatic polyol |
US5272189A (en) | 1992-10-19 | 1993-12-21 | Ppg Industries, Inc. | Reduced yellowing electrodepositable coating composition |
US5352289A (en) | 1992-12-18 | 1994-10-04 | Cabot Corporation | Low ash carbon blacks |
US5302197A (en) | 1992-12-30 | 1994-04-12 | E. I. Du Pont De Nemours And Company | Ink jet inks |
US5401313A (en) | 1993-02-10 | 1995-03-28 | Harcros Pigments, Inc. | Surface modified particles and method of making the same |
US5366828A (en) | 1993-11-08 | 1994-11-22 | Struthers Ralph C | Metal alloy laded carbon aerogel hydrogen hydride battery |
-
1995
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102604442A (zh) * | 2005-05-17 | 2012-07-25 | 卡伯特公司 | 炭黑和包含它的聚合物 |
CN102604442B (zh) * | 2005-05-17 | 2015-04-08 | 卡伯特公司 | 炭黑和包含它的聚合物 |
CN106967334A (zh) * | 2015-12-28 | 2017-07-21 | 佳能株式会社 | 墨、墨盒和喷墨记录方法 |
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