CN1162532C - 洗碟用柔性含蛋白酶的液体或凝胶洗涤组合物 - Google Patents
洗碟用柔性含蛋白酶的液体或凝胶洗涤组合物 Download PDFInfo
- Publication number
- CN1162532C CN1162532C CNB011030240A CN01103024A CN1162532C CN 1162532 C CN1162532 C CN 1162532C CN B011030240 A CNB011030240 A CN B011030240A CN 01103024 A CN01103024 A CN 01103024A CN 1162532 C CN1162532 C CN 1162532C
- Authority
- CN
- China
- Prior art keywords
- composition
- dish
- alkyl
- washing
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 143
- 108091005804 Peptidases Proteins 0.000 title claims abstract description 37
- 239000003599 detergent Substances 0.000 title claims abstract description 25
- 239000004365 Protease Substances 0.000 title claims abstract description 8
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 title claims abstract 4
- 239000007788 liquid Substances 0.000 title claims description 30
- 238000004851 dishwashing Methods 0.000 title claims description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 23
- -1 alkyl poly glucoside Chemical class 0.000 claims description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000013543 active substance Substances 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 102000004190 Enzymes Human genes 0.000 claims description 15
- 108090000790 Enzymes Proteins 0.000 claims description 15
- 150000001412 amines Chemical class 0.000 claims description 14
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 13
- 229930195729 fatty acid Natural products 0.000 claims description 13
- 239000000194 fatty acid Substances 0.000 claims description 13
- 239000006260 foam Substances 0.000 claims description 13
- 239000000047 product Substances 0.000 claims description 13
- 239000000344 soap Substances 0.000 claims description 13
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- 229910001424 calcium ion Inorganic materials 0.000 claims description 10
- 239000011777 magnesium Substances 0.000 claims description 10
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 7
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 7
- 230000001737 promoting effect Effects 0.000 claims description 7
- 239000007859 condensation product Substances 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 4
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 229930182478 glucoside Natural products 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 108010022999 Serine Proteases Proteins 0.000 claims description 2
- 102000012479 Serine Proteases Human genes 0.000 claims description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 150000003333 secondary alcohols Chemical class 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims 5
- 241000194108 Bacillus licheniformis Species 0.000 claims 2
- 244000063299 Bacillus subtilis Species 0.000 claims 1
- 235000014469 Bacillus subtilis Nutrition 0.000 claims 1
- 241000282326 Felis catus Species 0.000 claims 1
- 206010040880 Skin irritation Diseases 0.000 claims 1
- 239000006210 lotion Substances 0.000 claims 1
- 230000036556 skin irritation Effects 0.000 claims 1
- 231100000475 skin irritation Toxicity 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 28
- 150000002500 ions Chemical class 0.000 abstract description 15
- 102000035195 Peptidases Human genes 0.000 description 33
- 229910052799 carbon Inorganic materials 0.000 description 33
- 125000000217 alkyl group Chemical group 0.000 description 31
- 125000004432 carbon atom Chemical group C* 0.000 description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 16
- 239000002253 acid Substances 0.000 description 14
- 229910052739 hydrogen Inorganic materials 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 210000003491 skin Anatomy 0.000 description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 9
- 125000001931 aliphatic group Chemical group 0.000 description 9
- 150000001408 amides Chemical class 0.000 description 9
- 239000002585 base Substances 0.000 description 9
- 239000011575 calcium Substances 0.000 description 9
- 239000004744 fabric Substances 0.000 description 8
- 150000001336 alkenes Chemical class 0.000 description 7
- 239000000872 buffer Substances 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 6
- 235000011130 ammonium sulphate Nutrition 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000007046 ethoxylation reaction Methods 0.000 description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 5
- 235000013599 spices Nutrition 0.000 description 5
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 108010056079 Subtilisins Proteins 0.000 description 4
- 102000005158 Subtilisins Human genes 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 108010020132 microbial serine proteinases Proteins 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000009991 scouring Methods 0.000 description 4
- 239000003352 sequestering agent Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 230000003019 stabilising effect Effects 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 4
- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 3
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000005466 alkylenyl group Chemical group 0.000 description 3
- 125000001118 alkylidene group Chemical group 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 150000002632 lipids Chemical class 0.000 description 3
- 235000009973 maize Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 239000002516 radical scavenger Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical class CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 3
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- NCFXAHBHGZLSFB-UHFFFAOYSA-N 2-methyl-2-[methyl(propan-2-yl)amino]pentanoic acid Chemical compound CCCC(C)(C(O)=O)N(C)C(C)C NCFXAHBHGZLSFB-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 2
- CWXZKCWJDURNBS-UHFFFAOYSA-N C(CN)COS(=O)(=O)CC(CN)O Chemical compound C(CN)COS(=O)(=O)CC(CN)O CWXZKCWJDURNBS-UHFFFAOYSA-N 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 101710171243 Peroxidase 10 Proteins 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 101710180012 Protease 7 Proteins 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 229940047662 ammonium xylenesulfonate Drugs 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 229910052728 basic metal Inorganic materials 0.000 description 2
- 150000003818 basic metals Chemical class 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
- 125000003147 glycosyl group Chemical group 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000008101 lactose Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 108010003855 mesentericopeptidase Proteins 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- HESSGHHCXGBPAJ-UHFFFAOYSA-N n-[3,5,6-trihydroxy-1-oxo-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexan-2-yl]acetamide Chemical compound CC(=O)NC(C=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O HESSGHHCXGBPAJ-UHFFFAOYSA-N 0.000 description 2
- GSWAOPJLTADLTN-UHFFFAOYSA-N oxidanimine Chemical compound [O-][NH3+] GSWAOPJLTADLTN-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000006268 reductive amination reaction Methods 0.000 description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 2
- LJCJRRKKAKAKRV-UHFFFAOYSA-N (2-amino-2-methylpropyl) 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(N)COC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 LJCJRRKKAKAKRV-UHFFFAOYSA-N 0.000 description 1
- MPCAJMNYNOGXPB-KCDKBNATSA-N (2r,3r,4r,5s)-2-(hydroxymethyl)oxane-3,4,5-triol Chemical compound OC[C@H]1OC[C@H](O)[C@@H](O)[C@H]1O MPCAJMNYNOGXPB-KCDKBNATSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- FOUZISDNESEYLX-UHFFFAOYSA-N 2-(2-hydroxyethylazaniumyl)acetate Chemical compound OCCNCC(O)=O FOUZISDNESEYLX-UHFFFAOYSA-N 0.000 description 1
- VLDBEZDOSUKOBS-UHFFFAOYSA-O 2-(3-hydroxyphenyl)ethyl-trimethylazanium Chemical compound C[N+](C)(C)CCC1=CC=CC(O)=C1 VLDBEZDOSUKOBS-UHFFFAOYSA-O 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- RGICCULPCWNRAB-UHFFFAOYSA-N 2-[2-(2-hexoxyethoxy)ethoxy]ethanol Chemical compound CCCCCCOCCOCCOCCO RGICCULPCWNRAB-UHFFFAOYSA-N 0.000 description 1
- GBHSCKFAHCEEAZ-UHFFFAOYSA-N 2-[hydroxymethyl(methyl)amino]acetic acid Chemical compound OCN(C)CC(O)=O GBHSCKFAHCEEAZ-UHFFFAOYSA-N 0.000 description 1
- BDWTUWFDMGJTOD-UHFFFAOYSA-N 2-butylnonanoic acid Chemical compound CCCCCCCC(C(O)=O)CCCC BDWTUWFDMGJTOD-UHFFFAOYSA-N 0.000 description 1
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 1
- WCSAPKHLAQFSIW-UHFFFAOYSA-N 3-(dimethylamino)-2-hydroxypropane-1-sulfonic acid Chemical compound CN(C)CC(O)CS(O)(=O)=O WCSAPKHLAQFSIW-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 description 1
- XSBRVRMMKVWXQZ-UHFFFAOYSA-M CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1.CC(C([O-])=O)N(C)C Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1.CC(C([O-])=O)N(C)C XSBRVRMMKVWXQZ-UHFFFAOYSA-M 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241001459693 Dipterocarpus zeylanicus Species 0.000 description 1
- 108010083608 Durazym Proteins 0.000 description 1
- 239000004258 Ethoxyquin Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 238000007869 Guerbet synthesis reaction Methods 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 1
- FSVCELGFZIQNCK-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)glycine Chemical compound OCCN(CCO)CC(O)=O FSVCELGFZIQNCK-UHFFFAOYSA-N 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical class CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical class CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 1
- WKELIVWALJPJGV-UHFFFAOYSA-N OBO.OB(O)O Chemical compound OBO.OB(O)O WKELIVWALJPJGV-UHFFFAOYSA-N 0.000 description 1
- DNLZCSFXDLJUFK-UHFFFAOYSA-N OC(C(S(=O)(=O)O)(N)CC)(C)O Chemical class OC(C(S(=O)(=O)O)(N)CC)(C)O DNLZCSFXDLJUFK-UHFFFAOYSA-N 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 108090000787 Subtilisin Proteins 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 241000863032 Trieres Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 229910001413 alkali metal ion Chemical group 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-PQMKYFCFSA-N alpha-D-mannose Chemical compound OC[C@H]1O[C@H](O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-PQMKYFCFSA-N 0.000 description 1
- SRBFZHDQGSBBOR-LECHCGJUSA-N alpha-D-xylose Chemical compound O[C@@H]1CO[C@H](O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-LECHCGJUSA-N 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 239000007998 bicine buffer Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- GHXRKGHKMRZBJH-UHFFFAOYSA-N boric acid Chemical compound OB(O)O.OB(O)O GHXRKGHKMRZBJH-UHFFFAOYSA-N 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- RCPKXZJUDJSTTM-UHFFFAOYSA-L calcium;2,2,2-trifluoroacetate Chemical compound [Ca+2].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F RCPKXZJUDJSTTM-UHFFFAOYSA-L 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 229960002798 cetrimide Drugs 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- TUTWLYPCGCUWQI-UHFFFAOYSA-N decanamide Chemical compound CCCCCCCCCC(N)=O TUTWLYPCGCUWQI-UHFFFAOYSA-N 0.000 description 1
- KAOPHVRFVWFGRN-UHFFFAOYSA-M decyl(trimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCC[N+](C)(C)C KAOPHVRFVWFGRN-UHFFFAOYSA-M 0.000 description 1
- 230000002478 diastatic effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- MRXJLUSSMZAJGV-UHFFFAOYSA-N dimethylamino hexane-1-sulfonate Chemical compound CCCCCCS(=O)(=O)ON(C)C MRXJLUSSMZAJGV-UHFFFAOYSA-N 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical class [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- SDCJMBBHNJPYGW-UHFFFAOYSA-L disodium;hydrogen carbonate;chloride Chemical compound [Na+].[Na+].Cl.[O-]C([O-])=O SDCJMBBHNJPYGW-UHFFFAOYSA-L 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- VICYBMUVWHJEFT-UHFFFAOYSA-N dodecyltrimethylammonium ion Chemical compound CCCCCCCCCCCC[N+](C)(C)C VICYBMUVWHJEFT-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
- 229940093500 ethoxyquin Drugs 0.000 description 1
- 235000019285 ethoxyquin Nutrition 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 235000019534 high fructose corn syrup Nutrition 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical class CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 1
- 229940033355 lauric acid Drugs 0.000 description 1
- DJQJFMSHHYAZJD-UHFFFAOYSA-N lidofenin Chemical compound CC1=CC=CC(C)=C1NC(=O)CN(CC(O)=O)CC(O)=O DJQJFMSHHYAZJD-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical compound COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical compound CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- QEALYLRSRQDCRA-UHFFFAOYSA-N myristamide Chemical compound CCCCCCCCCCCCCC(N)=O QEALYLRSRQDCRA-UHFFFAOYSA-N 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229960003487 xylose Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/521—Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C11D2111/14—
Abstract
柔性洗涤剂组合物,包含洗涤表面活性剂和少量蛋白酶。该组合物具有优良的清洗功能。优选的实施中还可以添加泡沫助促剂。
Description
本发明是申请号为94193906.5的专利申请的分案申请。
技术领域
本发明涉及为用户较佳皮肤条件的液体或凝胶洗碟用洗涤组合物,它含有洗涤表面活性剂和少量蛋白酶。
发明背景
在本技术领域已很熟悉柔性洗碟用液体或凝胶洗涤组合物。常常使用一些表面活性剂来实现清洗剂的软性,例如使用高乙氧基化醇的硫酸盐的表面活性剂(参见如Rose和Thiele的美国专利3,743,233),和/或使用乙氧基羧酸烷酯的表面活性剂(参见日本专利申请48-60706和48-64102)。也有人提出甜菜碱(betaine)用来改善液体洗碟组合物的软性和泡沫。
同样,本技术领域也充斥各种含清洗酶的洗涤组合物(参见Francke等的美国专利3,799,897;Thiele等的3,634,266,Maeda等的3,707,505,Maguire,Jr等的4,162,987和Place的4,101,457。
现已发现向柔性的液体或凝胶洗碟用洗涤组合物中加入的蛋白酶即使它含有苛性的表面活性剂也可改善组合物的软性,同时也令人惊异地改善皮肤的干燥度。
发明概述
本发明涉及洗碟用柔性液体或凝胶洗涤组合物,按重量百分比它包括:
(a)约5%-99%的洗涤表面活性剂,此表面活性剂选自多羟基脂肪酸酰胺、非离子型脂肪烷基多葡糖苷;C8-22烷基硫酸盐;C9-15烷基苯磺酸盐;C8-22烷基醚硫酸盐;C8-22烯烃磺酸盐;C8-22烷烃硫酸盐;C8-22烷基甘油醚磺酸盐;脂肪酸酯基磺酸盐;三级醇硫酸盐;C12-16烷基乙氧基羧酸盐;C11-16特皂(Spcial Soaps);两性的洗涤表面活性剂;两性离子的洗涤表面活性剂;以及它们的混合物;和
(b)约0.001%-5%的活性蛋白酶;
所述的组合物的pH在约4-11之间。
此组合物的特别优选的实施方案还包括约1.0%-20%的肥皂泡辅剂和约0.01%-4%,优选约0.1%-4%的二价离子(即,镁和/或钙)。
发明的详细描述
本发明的柔性洗碟用液体或凝胶洗涤组合物含有两种基本组分:
(1)洗涤表面活性剂;和
(2)少量在洗涤组合物的pH值下有效的蛋白酶。
还可加入的任选组分,尤其是肥皂泡辅剂,可提供各种功能和美学特性。
本文所用的术语“洗碟用柔性洗涤组合物”(“light-duty dishwashing detergent composition”)是指专用于手工(即用手)洗碟的这种洗涤组合物。
洗涤表面活性剂
本发明的组合物含有约5%-99%,较好约10%-70%,最好约20%-60%的洗涤组合物。
在此类洗涤组合物中包括几种通用于液体或凝胶洗碟用洗涤剂的阴离子表面活性剂。与这些阴离子表面活性剂相结合的阳离子选自钙、钠、钾、镁、铵或链烷醇铵以及它们的混合物,较好地选自钠、铵、钙、和镁和/或它们的混合物。用于本发明的阴离子表面活性剂的例子有:
(1)烷基苯磺酸盐,其中烷基含有9-15个碳原子,优选11-14个碳原子,为直链或支链构型。特别优选的是含约12个碳原子的线性烷基苯磺酸盐。美国专利2,220,099和2,477,383详细描述了这些表面活性剂。
(2)硫酸盐化8-12个碳原子,优选12-16个碳原子,的醇得到的烷基硫酸盐。此烷基硫酸盐的化学式为ROSO3 -M+,其中R为C8-22的烷基和M为一价和/或二价阳离子。
(3)烷基部分为8-22个优选为12-16个碳原子的链烷烃磺酸盐。这些磺酸盐酯是以Hoechst Celanese以Hostapur SAS市售得到的。
(4)8-22个优选为12-16个碳原子的烯烃磺酸盐。美国专利3,332,880对这些适宜的烯烃磺酸盐有描述。
(5)从8-22个优选12-16个碳原子的醇乙氧基化得到的烷基醚磺酸盐含有少于30优选少于12摩尔的环氧乙烷。此烷基醚硫酸盐的化学式为RO(C2H4O)XSO3 -M+。
其中R是C8-22烷基,x为1-30,和M为一价或二价阳离子。
(6)烷基部分为8-22个优选12-16个碳原子的烷基甘油醚磺酸盐。
(7)脂肪酸酯磺酸盐,其化学式为:
R1-CH(SO3 -M+)CO2R2
其中R为C8-C18优选为C12-16的直链或支链烷基,和R2为C1-C6优选为主要为C1的直链或支链烷基,和M+为一价或二价阳离子。
(8)6-18个优选为8-16个碳原子的二级醇硫酸盐。
(9)下述通式的烷基乙氧基羧酸盐:
RO(CH2CH2O)XCH2COO-M+
其中R为C12-C16烷基,x为0-10,和以重量计乙氧基化物的含量,当x为0时是低于约20%,优选低于约15%和最优选低于约10%,和当x>7时,是低于约25%,优选低于约15%和最优选低于约10%,当平均R值为C13或更低时平均x约为2-4,和当平均R值>C13时平均x约为3-6,和M优选为碱金属、铵、一,二和三乙醇铵的阳离子,最优选为钠、钾、铵及其组合的阳离子。优选的烷基乙氧基羧酸盐为R是C12-C14烷基的。
(10)下述的一般结构是具有一些在本发明中使用的“特皂”(“Special Soaps)或其前体酸(aka C11-16烷基羰基化物)。
A.本发明所用的最优选一类皂包括化学式为R3CH(R4)COOM的C10-C16二级羧基物质,其中R3为CH3(CH2)X和R4为CH3(CH2)Y,其中y可以为零或1-6的整数,x为6-12的整数和x+y的和为6-12,优选为7-11和最优选为8-9。
B.本发明所用的另一类特皂包括这些羧基化合物其中羧基取代基是在烃环单元内,即式为R5-R6-COOM的二级皂(Secondary soaps),式中R5为C7-C10,优选为C8-C9的烷基或链烯基和R6为环状结构如苯、环戊烷、环己烷等。(注:R5相对于环上的羧基可以是邻、对或间位)。
C.还有另一类皂包括如下式的C10-C18的一级和二级羧基化合物:R7CH(R8)COOM,其中R7和R8的碳原子之和为8-16,R7为CH3-(CHR9)x和R8为H-(CHR9)y,其中,x和y为0-15范围内的整数和R9为H或C1-4线性或支链烷基。R9可以是一个单一(CHR9)X,Y内的H与C1-4线性或支链烷基的任意组合物; 但是这类皂的每个分子必须含有至少一个不是H的R9。这类分子可以用许多方法制备,例如支链烯烃醛化和氧化,支链烯烃的羟基羧基化,包括支链氧代醇的Guerbet反应产物的氧化。短链烯烃如丁烯、异丁烯、支链己烯、丙烯和戊烯的齐聚化可得到支链烯烃。
D.再另一类皂包括C10-C18三级羧基化合物,如式R10CR11(R12)COOM的新酸(neo-acids),式中R10、R11和R12碳原子的总和为8-16。R10、R11和R12为-CH3-(CHR13)X,其中x为0-13范围内的整数,R13是H或C1-4线性或支链烷基。注:R13可以是在一单个-(CHR13)X基团内H与C1-4线性或支链烷基部分的任意组合。这类分子是从例如经Koch反应使羧基加成到支链烯烃上来得到的。市售例子包括Exxon制造的新癸醇和Shell制造的VersaticTM酸。
在上述A,B,C和D的式中,M可以是任何合适的尤其是水溶性的反离子,如H,碱金属,碱土金属,铵,醇铵、二醇铵和三醇铵,C1-C5烷基取代的铵等。钠是最适宜的,二乙醇铵也是如此。
本发明使用的优选的二级皂是水溶性的,选自下列各酸的水溶性盐:
2-甲基-1-十一酸,2-乙基-1-癸酸,
2-丙基-1-壬酸,2-丁基-1-辛酸,
2-戊基-1-庚酸,2-甲基-1-十二酸,
2-乙基-1-十一酸,2-丙基-1-癸酸,
2-丁基-1-壬酸,2-戊基-1-辛酸,及其混合。
(11)
上述各项的混合物。
前述的阴离子表面活性剂都是可以市售得到的。应当指出,磺基琥珀酸二烷酯或脂肪酸酯磺酸酯在中性至弱碱性pH下均有好的功能,但在pH大于8.5多时的组合物中,它们在化学上是不稳定的。
在本组合物中使用的其它有用的表面活性剂是非离子型脂肪烷基多葡糖苷。这类表面活性剂含有直链或支链的C8-C15优选C12-C14烷基,和平均约1-5个葡糖单元,优选为1-2个葡糖单元。美国专利4,393,203和4,732,704描述了这类表面活性剂,此文献并入本发明作为参考。
本组合物也可含有多羟基脂肪酸胺表面活性剂,其结构式为:
其中,R1是H,C1-C4烃基,2-羟基乙基,2-羟基丙基,或其混合物,优选为C1-C4烷基,更优选为C1或C2烷基,最优选为C1烷基(即甲基);R2是C5-C31烃基,优选为直链C7-C19烷基或链烃基,更优选为直链C9-C17烷基或链烯基,最优选为C11-C17烷基或链烯基,或其混合物;Z为多羟基烃基,它有一线性烃链,链上直接与之相连至少3个羟基,或它们的烷氧基化衍生物(优选为乙氧基化或丙氧基化)。优选地Z是在还原性胺化反应中从还原糖类得到的;更优选Z是糖基(glycityl)。适宜的还原糖类包括葡糖、果糖、麦芽糖、乳糖、半乳糖、甘露糖和木糖。除了上面列出的单个糖类外,作为原材料,高葡萄糖玉米糖浆、高果糖玉米糖浆和高麦芽糖玉米糖浆也可以使用。这些玉米糖浆可以得到Z所需的糖类组分的混合物。应该理解,列出上述材料决不意味着本发明排除其它适宜的原料。Z最好选自:-CH2-(CHOH)n-CH2OH,-CH(CH2OH)-(CHOH)n-1-CH2OH,-CH2(CHOH)2(CHOR1)(CHOH)-CH2OH,其中n是包括端值的3-5的整数,和R1是H或环状或脂族的单糖,和它们的烷氧基化衍生物。最优选的Z是n为4的糖基,尤其是-CH2-(CHOH)4-CH2OH。
式I中,例如R1可以是N-甲基、N-乙基、N-丙基、N-异丙基、N-丁基、N-2-羟基乙基或N-2-羟基丙基。
R2-CO-N<,例如,可以是,椰子油酸酰胺(Cocamide),硬脂酰胺,油酸酰胺,月桂酰胺,肉豆蔻酰胺,癸酰胺,棕榈酸酰胺,脂油酸酰胺等。
Z可以是1-脱氧葡糖基,2-脱氧果糖基,1-脱氧麦芽糖基,1-脱氧乳糖基,1-脱氧半乳糖基,1-脱氧甘露糖基,1-脱氧麦芽糖-丙糖基(1-deoxymalto-triotityl),等。
制造多羟基脂肪酸酰胺的方法在本技术领域是已知的。通常它们是这样制造的:在还原胺化反应中使烷基胺与还原糖反应,生成相应的N-烷基多羟基胺,然后在一缩合/酰胺化步骤中使N-烷基多羟基胺与脂肪脂族酯(fatty aliphatic ester)或甘油三酯反应,生成N-烷基、N-多羟基脂肪酸酰胺产物。制备含多羟基脂肪酸酰胺的组合物的方法已公开,例如,以下专利文献:ThomasHedley & Go.,Ltd.,在1959年2月18日公开的美国专利说明书809,060;E.R.Wilson的在1960年12月20日发表的U.S.Patent 2,965,576,和Anthony M.Schwartz在1955年3月8日发表的U.S.Patent 2,703,798,Piggott的在1934年12月25日发表的U.S.Patent 1,985,424,Connor等在1993年2月23日发表的U.S.Patent 5,188,769和Connor等在1993年3月16日发表的U.S.Patent5,194,639。上述各文献均并入本发明作为参考。
两性离子表面活性剂包括:脂族季胺、膦和锍化合物的衍生物,其中脂族部分可以是直链或支链和其中一个脂族取代基含约8-24个碳原子和含有一个阴离子水溶性基团。特别优选的二性离子物质是在U.S.Patent 3,925,262(Laughlin等,1975年12月9日发表)和3,929,262(Laughlin等,1975年12月30日发表)中公开的磺酸和硫酸乙氧基化铵。它们也引入本发明作为参考。
两性的表面活性剂包括脂族或杂环的仲胺和叔胺,其中脂族部分可以是直链或支链和其中一个脂族取代基含约8-24个碳原子和至少一个脂族取代基含一个阴离子水溶性基团。
蛋白酶
本发明组合物含有约0.001-5%(重量)优选约0.003-4%,更优选约0.005-3%的活性蛋白酶。蛋白活性可用每仟克洗涤剂的Anson单位(A.U.)表示。对本发明组合物已发明可接受的水平为约0.01-150优选约0.05-80更优选约0.1-40A.U./千克。
蛋白酶可取自动物、蔬菜或微生物(优选)。更优选为取自细菌的丝氨酸蛋白酶。此酶的纯化或未纯化形式均可采用。由化学或基团改性的突变体产生的蛋白酶也包括在定义之内,就象结构上接近的酶变体一样。特别优选的是从
Bacillus,Bacillus
Subtilis和/或
Bacillus licheniformis得到的细菌丝氨酸蛋白酶。
适合的蛋白酶包括AlcalaseR,EsperaseR,DurazymR,SavinaseR(优选的);MaxataseR,MaxacalR(优选的)和MaxapemR 15(protein engineered Maxacal);PurafectR(优选的)和Subtilisin BPN和BPN′;它们都是可市售得到的。最优选的蛋白酶为改性的细菌丝氨酸蛋白酶,如1987年4月28日提交的欧洲专利申请87-303761.8中(尤其是P17,24和98)所描述的,在本文中称之为“蛋白酶B”,和如1986年10月29日发表的Venegas的欧洲专利申请199,404,此文献涉及一改性的细菌丝氨酸蛋白酶,本文中称之为“蛋白酶A”。优选的蛋白酶包括:SavinaseR,AlcalaseR,EsperaseR,MaxacalR,PurafectR,BPN′,蛋白酶A和蛋白酶B及其组合;更优选为AlcalaseR,SavinaseR,BPN′,蛋白酶B及其组合;最优选为蛋白酶B。
据信蛋白酶的主要功能是为洗涤组合物提供脱皮作用。蛋白酶除去了皮肤表面损坏(如干裂)的皮肤细胞,因而消除与此有关的粗糙感。蛋白酶除去原先对皮肤的损害效果,使皮肤鲜润、好看和有良好感觉。当蛋白酶与洗涤表面活性剂组合时,整体效果是促进了皮肤的健康,和与其它类似的不含此两个基本成分的洗涤组合物相比,使顾客更能感觉到软性或有更好的皮肤触感或外观,同时又能保持优良的清洗功能。
组合物的pH
在使用时即稀释和用于污碟时,本发明的洗碟组合物会受到食物污迹的酸性作用。如果组合物的pH大于7时其改进功能最有效,它应含有能保持组合物和稀释溶液在碱性pH的缓冲剂,即含量为约0.1-0.4%(重量)的组合物水溶液。此缓冲剂的pKa值应低于所需组合物pH值(如上述所确定的)约0.5-0.1pH单位。优选地,缓冲剂的pKa值应为约7-9.5。在这些条件下,缓冲剂使用最低量即可最有效地控制pH值。
缓冲剂本身可以就是活性洗涤剂,或是低分子量的有机或无机材料用于本组合物仅用来保持碱性pH。本发明组合物的优选缓冲剂是含氮材料。一些例子有氨基酸或低级醇胺如一、二和三乙醇胺。其它优选的含氮缓冲剂有:2-氨基-2-乙基-1,3-丙二醇,2-氨基-2-甲基-丙醇,2-氨基-2-甲基-1,3-丙二醇,三-(羟-甲基)氨基甲烷(a.k.a.tris)和谷氨酸二钠。优选的例子还有:N-甲基二乙醇胺,1,3-二氨基-2-丙醇,N,N′-四甲基-1,3二氨基-2-丙醇,N,N-二(2-羟乙基)甘氨酸(a,k,a,bicine),和N-三(羟甲基)甲基甘氨酸(a.k.a.fricine)。上述的任何混合物也是可以接受的。
本发明的组合物中存在的缓冲剂的含量为以组合物重量为基约0.1-15%,优选约1-10%和最优选约2-8%。
酯稳定体系
本发明组合物优选地还含有约0.001-10%较好约0.005-8%更好约0.01-6%(重量)的酶稳定体系。它们可以是与本发明的酶相适配的任何酶稳定体系。这样的稳定体系包括:钙离子,硼酸(boric acid),丙二醇,短链的羧酸,硼酸(boronic acid),多羟基化合物及其混合,例如下述文献所描述的:1981年4月14日发表的Hora等的美国专利4,261,868;1983年9月13日发表的Tai的4,404,115;Letton等的4,318,818,1981年1月6日发表的Guidert等的4,243,543;1984年7月31日发表的Boskamp的4,462,922;1985年7月30日发表的Boskamp的4,532,064;和1985年8月27日发表的Severson Jr.,的4,537,707。以上文献并入本发明作为参考。
另外,为防止许多给水中存在的氯漂白物对酶的侵害和去活,尤其是在碱性条件下,可以向本发明组合物中加入约0-10%,优选约0.01-6%的氯漂白清除剂。虽然水中氯的水平可能是小的,典型地为约0.5-1.75ppm,但在洗涤期间与酶接触的水的总体积中可得到的氯通常是大的;因此在使用中酶的稳定可能是有问题的。
适宜的氯清除剂阴离子是含铵阳离子的盐。它们选自:还原物质,如亚硫酸盐、亚硫酸氢盐、硫代亚硫酸盐、硫代硫酸盐,碘化物等;抗氧化剂,如氨基甲酸盐、抗坏血酸盐等;有机胺,如乙二胺四乙酸(EDTA)或它的碱金属盐和-乙醇胺(MEA),和它们的混合物。还可以使用的其它常规清除剂阴离子有如硫酸盐、硫酸氢盐、碳酸盐、碳酸氢盐、过碳酸盐、硝酸盐、氯化物、硼酸盐、过硼酸钠四水合物、过硼酸钠一水合物、过碳酸盐、磷酸盐、缩聚磷酸盐、乙酸盐、苯甲酸盐、柠檬酸盐、甲酸盐、乳酸盐、苹果酸盐、洒石酸盐、水杨酸盐等及其混合物,特定脱氧剂阴离子的优选铵盐或其它盐可以代替泡沫控制剂,也可以与泡沫控制剂同时加入。
虽然铵盐可以与洗涤组合物混合,但它们易于吸收水和/或放出氨气。因此最好以颗粒保护形式使用如U.S.Patent 4,652,392(Baginski等)中所描述的,此处引用此文献作为参考。
泡沫助促剂
非常希望的组合包括约1-20%优选约2-15%的泡沫助促剂,例如甜菜碱、环氧乙烷缩合物、脂肪酸酰胺、氧化胺半极性非离子剂、Sultaines、配位的甜菜碱阳(Complex betaines)和阴离子表面活性剂。
本发明组合物可以包含如下述通式所示的甜菜碱洗涤表面活性剂:
其中R是疏水基团,选自含10-22个碳原子、优选12-18个碳原子的烷基,含相同数目碳原子的烷芳基或芳烷基,带有处理成相当于连接2个碳原子的苯环,和由酰氨基或其它键隔开的相同结构;每个R1是1-3个碳原子的烷基;和R2是1-6个碳原子的亚烷基。
优选的甜菜碱的例子有:十二烷基二甲基甜菜碱,十六烷基二甲基甜菜碱,十二烷基酰氨基丙基二甲基甜菜碱,十四烷基二甲基甜菜碱,十四烷基酰氨基丙基二甲基甜菜碱和十二烷基二甲基己酸铵。
别的适宜的酰氨烷基甜菜碱在美国专利3,950,417;4,137,191;和4,375,421;和英国专利2,103,236中公开,它们都并入本发明作为参考。
应当理解,上述甜菜碱表面活性剂的烷基(和芳基)可以从天然或人工来源衍生而得,如它们可来自天然存在的脂肪酸,通过Ziegler或Oxo方法制备那样一类烯烃;或从经过裂化或未裂化的石油分离出的烯烃。
环氧乙烷缩合物广义地说是环氧乙烯基团(亲水性的)与疏水有机化合物缩合而得的化合物,它们可以是脂族或烷芳族化合物。与某个特定疏水基团缩合的亲水或聚氧乙烯基的长度易于调节,以得到在亲水和疏水性之间达到所需平衡的水溶性化合物。
适宜作泡沫稳定剂的这种环氧乙烷缩合物的例子有:脂族醇与环氧乙烷的缩合产物。脂族醇的烷基链可以为直链或支链,为具有泡沫稳定剂的最佳性能,一般含有8-18个优选含有8-14个碳原子,环氧乙烷含量为每摩尔醇约8-30摩尔、优选为约8-14摩尔环氧乙烷。
本发明使用的酰胺表面活性剂的例子包括具有8-18个碳原子酯酰部分的子脂肪酸的氨、一乙醇酰胺和二乙醇酰胺,可用下通式表示:
R1-CO-N(H)m-1(R2OH)3-m
其中R1是饱和或不饱和的具有7-21优选11-17个碳原子的脂族烃基;R2表示亚甲基或亚乙基;和m是1,2或3,优选为1。所述酰胺的具体例子有:一乙醇胺椰子脂肪酸酰胺和二乙醇胺十二烷基脂肪酸酰胺。该酰基部分可从天然存在的甘油酯,如椰子油,棕榈油、大豆油和动物脂油中衍生出来,也可以通过如石油氧化或一氧化碳经Fischer-Tropsch方法而氢化合成出来。优选的是C12-14脂肪酸的一乙醇酰胺和二乙醇酰胺。
氧化胺半极性非离子型表面活性剂包括下式所示的化合物及其混合物:
式中,R1为烷基、2-羟烷基、3-羟烷基或3-烷氧基-2-羟丙基,其中烷基和烷氧基分别含有8-18个碳原子,R2和R3每个为甲基、乙基、丙基、异丙基、2-羟乙基、2-羟丙基或3-羟丙基,和n为0-10。
特别优选的氧化胺如下式所示:
式中,R1是C12-16烷基,和R2和R3是甲基或乙基。上述环氧乙烷缩合物、酰胺和氧化胺在美国专利4,316,824(Pancheri)中有更充分描述,该文献并入本发明作为参考。
本发明使用的Sultaines是下式所示的化合物:(R(R1)2N+R2SO3 -。式中R为C6-C18烃基、优选为C10-C16烷基、更优选为C12-C13烷基,每个R1通常为C1-C3烷基、优选为甲基,和R2为C1-C6烃基,优选为C1-C3亚烷基,或优选为羟亚烷基。适合的Sultaines的例子有:C12-C14二甲基氨基-2-羟丙基磺酸盐,C12-14酰氨丙基氨基-2-羟丙基磺酸盐,C12-14二羟乙基氨基丙烷磺酸盐和C12-18二甲基氨基己烷磺酸盐。优选为C12-14酰氨丙基氨基-2-羟丙基磺酸盐(C12-14 amido propylammonio-2-hydroxypropyl sultaine)。
用于本发明的配位的甜菜碱如下式表示:
式中,R是7-22个碳原子的烃基,A是(C(O))基团,n是0或1,R1是氢或低级烷基,x是2或3,y是0-4的整数,Q是-R2COOM基团,其中R2是1-6个碳原子的亚烷基和M是氢或碱金属离子、碱土金属离子、铵离子和取代的铵离子,和B是氢或如Q所限定的基团。
此类化合物的例子是如下式所示的烷基两性多羧基甘氨酸盐(alkylamphopolycarboxy glycinate):
本发明组合物还可含有以下式所示的某些阳离子季铵盐表面活性剂:
[R1(OR2)y][R3(OR2)y]2R4N+X-
或含有下式所示的胺表面活性剂:
[R1(OR2)y][R3(OR2)y]R4N
上两式中,R1为烷基或烷基部分含6-16个碳原子烷苄基;每个R2各自选自:-CH2CH2-,-CH2CH(CH3)-,-CH2CH(CH2OH)-,-CH2CH2CH2-或其组合;每个R3选自:C1-C4烷基,C1-C4羟烷基,苄基和y不为零时是氢;R4与R3定义相同或是一烷基链,其中R1+R4的碳原子总数是8-16;每个y是0-10和y值总和为0-15;和X是任何相容的阴离子。
上述优选的化合物是烷基季铵表面活性剂,尤其是如上式所述当R4选自与R3相同的基团时的单一长链烷基表面活性剂。最优选的季铵表面活性剂是:氯化、溴化和甲基硫酸的C8-16烷基三甲基铵盐,C8-16烷基二(羟乙基)甲基铵盐,C8-16烷基羟乙基二甲基铵盐,C8-16烷氧基丙基三甲基铵盐,和C8-16烷氧基丙基二羟乙基甲基铵盐。上述化合物中,C10-14烷基三甲基铵盐是最优选的,如甲基硫酸癸烷基三甲基铵。氯化十二烷基三甲基铵、溴化十四烷基三甲基铵和氯化椰子酯基(coconut)三甲基铵和甲基硫酸盐。
本发明组合物中所使用的泡沫助促剂可含有上面所列的一种或多种泡沫助促剂。
钙或镁离子
钙和/或镁(二价)离子的存在会改进各种组合物对多油尘土的去污,即含有烷基乙氧基羧酸酯和/或多羟基脂肪酸酰胺。当该组合物用于含有一些二价离子的软水中时尤其如此,据信钙和/或镁离子增强表面活性剂在油/水界面的积聚,因而减小表面张力和改进油脂的去污。
本发明的含镁和/或钙离子的组合物表现出好的去除油脂功能、对皮肤的良好柔性和极佳的贮存稳定性。在组合物中具有活性的含量为0.1-4%优选为0.3-3.5%和更优选为0.5-1%(重量)。
最好镁或钙离子以下述形式加入到本发明组合物中:氢氧化物、氯化物、乙酸盐、甲酸盐、氧化物或硝酸盐。
在本发明组合物中钙或镁离子的量将取决于其中存在的表面活性剂的总量,包括烷基乙氧基羧酸酯和多羟基脂肪酸酰胺的量。当本发明组合物含钙离子时,钙离子对总阴离子表面活性剂的摩尔比为约0.25∶1-2∶1。
由于二价离子尤其是镁与氢氧根离子的不相容性,以碱性pH基体来配制这样的含二价离子的组合物可能是困难的。在二价离子和碱性pH与本发明的表面活性剂混合物相结合的情况下,实现油脂去污要比单独的碱性pH或二价离子的情况要好得多。另外,在贮存中由于氢氧化物沉淀的形成该组合物的稳定性会变差。因此,下面要讨论的螯合剂可能也是必要的。
其它任选的组分
除了前述基本成分之外,本发明组合物可含有其它常规成分,尤其是与洗碟组合物有关的成分。
该组合物还可含有不发泡和甚至可抑制发泡的非离子洗涤表面活性剂,其量为约0.01%-15%优选约1%-10%(重量)。适宜的非离子洗涤剂在以下美国专利中公开:U.S.Patent 4,321,164(Smith等,1982年3月23日);4,316,824(Pancheri,1982年2月23日)和3,929,678(Laughlin等,1975年12月30日)。
下面给出一些非限定的可用的非离子表面活性剂的例子:
1.烷基酚的聚环氧乙烷、聚环氧丙烷和聚环氧丁烷的缩合物。优选为聚环氧乙烷的缩合物。这些化合物包括烷基为6-12个碳原子直链或支链的烷基酚与环氧烷的缩合物。这类可市售得到的非离子表面活性剂有:IgepalTMCO-630(从GAF Corporation购得)和TritonTMX-45,X-114,X-100和X-102(均从Rohm & Haas Company购得)。
2.脂族醇与1-25摩尔环氧乙烷的缩合产物。脂族醇的烷基链可以为直链或支链、伯或仲和通常含8-22个碳原子。特别优选为10-20个碳原子的烷基醇与约2-10摩尔环氧乙烷/摩尔醇的缩合产物。
3.环氧丙烷与丙二醇缩合生成的疏水碱,与环氧乙烷的缩合产物。这些化合物的疏水部分优选为分子量约1500-1800和呈现水不溶性。
4.环氧丙烷与乙二胺反应所得产物,与环氧乙烷的缩合产物。
5.美国专利U.S.Pantent 4,565,647(LLenado,1986年1月21日)公开的烷基多糖,其疏水基团含有6-30、优选10-16个碳原子,和其多糖如多糖苷,亲水基团含有1.3-10、优选1.3-3、更优选1.3-2.7糖单元。美国专利4,373,203和4,732,704也描述了可采用的表面活性剂,它们也并入本发明作为参考。
其它常规任选组分包括遮光剂、抗氧化剂、杀菌剂、染料、香料、光学增白剂等,它们通常活性量为低于约5%。
为增强清洗效果,本发明组合物中可加入如脂肪酶和/或淀粉酶的任选酶组分。
也可以包含洗涤增洁剂(Detergency builders),其含量为0-约50%,优选为约2-30%和更优选为约5-15%。典型地在柔性液体或凝胶洗碟组合物中不包含洗涤增洁剂。但是,含镁或钙离子的某些组合物需要一些螯合剂存在,其量为低水平、优选0-10%,更优选为约0.5-3%,该螯合剂选自:N-二(羟乙基)甘氨酸/双(2-乙醇)甘氨酸,柠檬酸,N-(2-羟乙基)亚氨基二乙酸(HIDA),N-(2,3-二羟基-丙基)亚氨基二乙酸(GIDA),以及它们的碱金属盐。在本技术领域上述一些螯合剂也称作洗涤增洁剂。
本发明的组合物为了螯合和洗涤目的还可含有约0.001-15%的如下通式所示的某些烷基多乙氧基多羧酸盐表面活性剂:
式中,R是C6-C18烷基,X范围在1-24,R1和R2是选自:氢、甲酸根、琥珀酸根、羟基琥珀酸根,及其混合物,其中至少一个R1或R2是琥珀酸和/或羟基琥珀酸根。市售可以得到的烷基多乙氧基多羧酸盐的例子是POLY-TERGENT C,Olin Corporation Cheshire,CT.,它可用于本发明。
烷基多乙氧基多羧酸盐表面活性剂是基于它的亲水性进行选择。为得到最大螯合优点同时又不影响与二价离子有联系的清洗作用,或液体或凝胶洗碟清洗组合物的起泡,在该烷基多乙氧基多羧酸盐中羧基化和乙氧基化需要作出平衡。羧基数目决定螯合能力,如羧基化太强将导致太强的螯合体和妨碍二价离子的清洗作用。高度乙氧基化则是柔性和溶解度所要求的;但乙氧化太强也会影响泡沫。因此,希望该烷基多乙氧基多羧酸盐具有中度的乙氧基化和最小的羧基化。
其它需要的成分包括稀释剂和溶剂。稀释剂可以是无机盐,如硫酸钠、氯化钠,碳酸氢钠等,和溶剂包括水,低分子量醇,如乙醇、异丙醇等。在液体洗涤组合物中,通常含有0-约90%优选约20-70%更优选约40-60%的水,和0-约50%、优选约3-10%的促溶成分,包括乙醇或异丙醇,常规的水溶助长剂等。
方法
在本发明的方法方面,是使用有效量,通常约0.5-20毫升、优选约3-10毫升本发明的洗涤组合物与脏碟子(每次处理25支碟子)接触。
液体洗涤剂的实际用量是基于用户的判断,一般取决这样一些因素:如组合物的具体产品配方包括组合物中活性组分含量;待清洗脏碟的数目;碟子脏污的程度等。反过来,产品的具体配方也取决于许多因素,如对该组合物产品的打入市场(即美国、欧洲或日本等)。下面是本发明用于洗碟的典型方法的例子。这些例子只是为例示说明,但并不限制本发明。
在美国的典型应用,在一桶中加入约3-15毫升优选约5-10毫升液体洗涤组合物和约1000-10000毫升,更典型为约3000-5000毫升的水,该桶的体积为约5000-20000毫升,更典型为10000-15000毫升。该洗涤组合物中表面活性剂混合物的浓度为约21-44%,优选约25-40%(重量)。脏碟子浸没在装有洗涤组合物和水的桶中,使脏碟表面与布、海绵或类似物品接触而被清洗。在布、海绵或类似物脏碟表面接触之前可以先浸没在洗涤组合物与水的混合物中,虽然随每个使用和用户的不同实际操作时间有所不同,任通常布、海绵或类似物与脏碟表面接触约1-10秒钟。这接触最好也伴随同时进行的对碟子表面的擦洗。
在欧洲市场的典型应用,在一桶中加入约3-15毫升优选约3-10毫升液体洗涤组合物和约1000-10000毫升,更典型为约3000-5000毫升水,该桶的体积为约5000-20000毫升,更典型为10000-15000毫升。该洗涤组合物中表面活性剂混合物的浓度为约20%-50%,优选为约30-40%(重量)。脏碟子浸没在装有洗涤组合物和水的桶中,使脏碟表面与布、海绵或类似物接触而被清洗。在布、海绵或类似物与脏碟表面接触之前可以先浸没在洗涤组合物与水的混合物中,虽然随每次使用和用户的不同实际操作时间也会有所不同,但通常布、海绵或类似物与脏碟表面接触约1-10秒钟。这接触最好也同时伴随碟子表面的擦洗。
在拉丁美洲和日本市场的典型应用,在一槽中加入约1-50毫升,优选约2-10毫升洗涤组合物和约50-2000毫升、更典型为约100-1000毫升水,该槽体积为约500-5000毫升,更典型为约500-2000毫升。该洗涤组合物中表面活性剂混合物的浓度为约5-40%,优选为约10-30%(重量)。脏碟子通过其表面与布、海绵或类似物接触而被清洗。在布、海绵或类似物与脏碟表面接触之前可以先浸没在洗涤组合物与水的混合物中,虽然随每次使用和用户的不同实际操作时间也会有所不同,但通常布、海绵或类似物与脏碟表面接触约1-10秒钟。这接触最好同时伴随对碟子表面的擦洗。
另一种使用方法是将脏碟子浸泡在无液体洗涤剂的水浴中。一个吸收液体洗碟洗涤剂的装置,如海绵可直接放在单独量的未稀释的液体洗涤组合物中一般1-5秒钟。然后吸收装置和因之未稀释的液体洗涤组合物与每个要除去脏污的碟子表面接触。吸收装置典型地与每个碟子表面接触1-10秒钟,当然实际操作时间可能视污脏程度等因素而定。吸收装置与碟子表面的接触最好同时伴随擦洗。
除另有说明,本文所用的百分数、份数和比例均指重量。
为帮助理解,下面举例加以说明。
实例I
向一柔性洗碟液中加入其量为每仟克产物26 Anson单位的市售酶(一种蛋白酶得到组合物A,所述柔性洗碟液(组合物B)包含:13份C12-13烷基多乙氧化物(1)硫酸铵,14份C12-13烷基多乙氧基化物(12)硫酸铵和5份C12烷基二甲基氧化胺。
进行了120家的两周家用试验。一半使用含酶产品(组合物A)和另一半使用不含酶产品(组合物B)。然后请他们将试验品与自己原产品进行比较。在产品的软性、手的柔性及手的光滑性方面,组合物A明显地评级较高(>95%可信度)。
同样地,在手浸试验中,请受试者将他们的手浸泡在两种不同的产品溶液中,以星期一到星期四每天泡30分钟。然后由专家分级评价它们受试验手的状况,即评价总的健康情况和表皮脱落程度,同时也确定受试者在处理中的偏爱。所有结果都表明组合物A处理的皮肤比组合物B更湿润和更光滑,也更得到受试者的喜爱。
实例II
柔性液体洗碟洗涤剂的配方如下:
组合物
成分 C D E
%重量
C12-13烷基乙氧基
(1)硫酸铵 28.50 28.50 28.50
椰子氧化铵 2.61 2.61 2.61
甜菜碱/Tetronic704R 0.87/0.10 0.87/0.10 0.87/0.10
二甲苯磺酸铵 2.00 2.00 2.00
乙醇 4.00 4.00 4.00
柠檬酸铵 0.06 0.06 0.06
氯化镁 332 3.32 3.32
硫酸铵 0.08 0.08 0.08
过氧化氢 200ppm 200ppm 200ppm
香料 0.18 0.18 0.18
JR400聚合物 0.00 1.00 0.00
蛋白酶B 0.00 0.00 0.50
水和次要物 -----余量------
手浸试验中请受试者浸泡每支手在两种不同溶液中在四天内一天一次。与对照物(组合物C)和含阴离子聚合物的组合物D相比较,含蛋白酶的组合物E在软性方面有明显改进。
实例III
柔性液体洗碟洗涤剂的配方如下:
组合物
成分 F G H
%重量
C12-13烷基乙氧基
(1)硫酸铵 15.500 15.500 15.500
烷基乙氧基(平
均6.5)硫酸铵 11.900 11.900 11.900
氧化铵 5.000 5.000 5.000
二甲苯磺酸铵 4.000 4.000 4.000
乙醇 5.500 5.500 5.500
氯化钠 1.000 1.000 1.000
柠檬酸铵 0.100 0.100 0.100
香料 0.090 0.090 0.090
过氧化氢 0.165 0.165 0.165
蛋白酶B 0.000 0.050 0.150
水和次要物 -----余量------
手浸试验中请受试者浸泡它们的手,在四天内一天两次每次15分钟。与对照组合物F和含0.15%活性蛋白酶的组合物H相比,含较低量蛋白酶的组合物G的皮肤条件有明显改进。
实例IV
柔性液体洗涤剂的配方如下:
组合物
成分 I J K
%重量
C12-13烷基乙氧基
(1)硫酸钠 6.000 6.000 6.000
C12-13烷基乙氧基
(1-3)硫酸钠 13.200 13.200 13200
C12葡糖酰胺 6.000 6.000 6.000
椰子氧化胺 2.000 2.000 2.000
过氧化氢 0.006 0.006 0.006
乙醇 5.500 5.500 5.500
NeodolRC11Eg1 5.000 5.000 5.000
二亚乙基-五
-乙酸钠(40%) 0.030 0.030 0.030
香料 0.090 0.090 0.090
镁++(氯化物) 0.700 0.700 0.700
钙++(氯化物) 0.400 0.400 0.400
硫酸钠 0.060 0.060 0.060
蛋白酶B 0.000 0.050 0.010
水和次要物 -----余量------
10%的pH(制成时) 7.100 7.100 7.100
手浸试验者由18名受试者进行,将他们的手浸在试验产品中,在4天内一天一次每次30分钟。与对照物组合物I相比,两种含蛋白酶的组合物J和K的整个皮肤条件都得到明显改善。
实例V
浓缩的柔性液体洗碟洗涤剂的配方如下:
%重量
成分 L M N OI.
二亚乙基三胺-
五-乙酸盐 0.06 0.06 0.06 0.06
乙醇 9.15 9.15 9.15 9.15
氢氧化镁 2.18 2.18 2.18 2.18
蔗糖 1.50 1.50 1.50 1.50
烷基乙氧基
(1.0)硫酸盐 34.14 34.14 34.14 34.14
氢氧化钠 1.13 1.13 1.13 1.13
多羟基脂肪
酸酰胺 6.50 6.50 6.50 6.50
氧化胺 3.00 3.00 3.00 3.00
可可酰氨丙
基甜菜碱 2.00 2.00 2.00 2.00
香料 0.23 0.23 0.23 0.23
二甲苯磺酸钙 2.05 2.05 0.00 0.00
烷基二苯基氧化
物二磺酸盐 0.00 0.00 2.30 2.30
甲酸钙 0.53 0.53 1.14 1.14
蛋白酶B 0.05 0.08 0.05 0.08
水 …………余量………
注1DOWFAX 2A
当蛋白酶B用其它蛋白酶如MaxacalR,SavinaseR,和BPN代替时可得到本发明的其它组合物。
Claims (5)
1.一种在人工洗碟操作中浸泡手的方法,其结果是温和、手柔软和光滑,该方法包括:
1)由包含以下成分的有效量的人工洗碟液体或凝胶洗碟剂制备水性洗碟溶液,
(a)5-99%重量的洗涤表面活性剂,此表面活性剂选自多羟基脂肪酸酰胺;非离子型脂肪烷基多葡糖苷;C8-22烷基硫酸盐;C8-22烷基醚硫酸盐;C8-22烯烃磺酸盐;C8-22烷烃硫酸盐;C8-22烷基甘油醚磺酸盐;脂肪酸酯磺酸盐;二级醇硫酸盐;C11-16仲皂;及其混合物;和
(b)0.001-5%重量的活性蛋白酶,其量足以在人工洗碟过程中减少皮肤刺激;
(c)0-15%重量洗涤增洁剂,
(d)1-20%重量泡沫助促剂,选自环氧乙烷缩合物、脂肪酸酰胺、氧化胺、半极性非离子剂、甜菜碱、磺基甜菜碱、阳离子表面活性剂及其混合物,所述组合物的pH为4-11,和
(e)水和次要物加至100%;然后
2)将洗碟者的手浸渍在所述洗碟溶液中一段时间,足以有效地完成手洗操作,
其中洗碟者的手在所述洗碟溶液中浸泡至少15分钟。
2.权利要求1的浸泡手的方法,其中所述水性洗碟溶液通过将3-15ml所述液体洗碟剂组合物与1000-10000ml水混合而形成。
3.权利要求2的浸泡手的方法,其中所述用于形成水性洗液的液体洗碟剂组合物包含:
a)20-60%所述洗涤表面活性剂;
b)0.003-4%活性蛋白酶,选自得自枯草芽孢杆菌(Bacillus subtilis)或地衣芽孢杆菌(Bacilluslicheniformis)或其混合物的丝氨酸蛋白酶;
c)2-15%重量泡沫助促剂,选自甜菜碱、氧化胺半极性非离子剂、1-25mol的环氧乙烷与脂族醇的缩合产物及所述泡沫助促剂的混合物;及
d)其pH为6-10。
4.权利要求3所述的浸泡手的方法,其中用于形成所述水性洗涤溶液的液体洗碟剂组合物还包含0.01%-4%重量镁或钙离子或其混合物。
5.权利要求4所述的浸泡手的方法,其中用于形成所述水性洗涤溶液的液体洗碟剂组合物还包含0.001%-10%重量的酶稳定剂体系。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12133193A | 1993-09-14 | 1993-09-14 | |
US121,331 | 1993-09-14 | ||
US121331 | 1993-09-14 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94193906A Division CN1094515C (zh) | 1993-09-14 | 1994-08-30 | 洗碟用柔性含蛋白酶的液体或凝胶洗涤组合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1322804A CN1322804A (zh) | 2001-11-21 |
CN1162532C true CN1162532C (zh) | 2004-08-18 |
Family
ID=22395996
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011030240A Expired - Fee Related CN1162532C (zh) | 1993-09-14 | 1994-08-30 | 洗碟用柔性含蛋白酶的液体或凝胶洗涤组合物 |
CN94193906A Expired - Fee Related CN1094515C (zh) | 1993-09-14 | 1994-08-30 | 洗碟用柔性含蛋白酶的液体或凝胶洗涤组合物 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94193906A Expired - Fee Related CN1094515C (zh) | 1993-09-14 | 1994-08-30 | 洗碟用柔性含蛋白酶的液体或凝胶洗涤组合物 |
Country Status (23)
Country | Link |
---|---|
US (2) | US5599400A (zh) |
EP (1) | EP0719321B2 (zh) |
JP (1) | JP2904930B2 (zh) |
KR (1) | KR100351396B1 (zh) |
CN (2) | CN1162532C (zh) |
AT (1) | ATE178649T1 (zh) |
AU (1) | AU685844B2 (zh) |
BR (1) | BR9407498A (zh) |
CA (1) | CA2170024C (zh) |
CZ (1) | CZ76096A3 (zh) |
DE (1) | DE69417755T3 (zh) |
DK (1) | DK0719321T3 (zh) |
EG (1) | EG21117A (zh) |
ES (1) | ES2131703T5 (zh) |
FI (1) | FI961173A (zh) |
GR (1) | GR3030286T3 (zh) |
HU (1) | HU219172B (zh) |
NO (1) | NO961001L (zh) |
NZ (1) | NZ273214A (zh) |
PL (1) | PL180210B1 (zh) |
RU (1) | RU2142981C1 (zh) |
SK (1) | SK31996A3 (zh) |
WO (1) | WO1995007971A1 (zh) |
Families Citing this family (91)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2131703T5 (es) * | 1993-09-14 | 2009-06-24 | THE PROCTER & GAMBLE COMPANY | Composiciones detergentes para lavado de vajillas en forma liquida o gel, suaves, que contienen proteasa. |
US5883062A (en) * | 1993-09-14 | 1999-03-16 | The Procter & Gamble Company | Manual dishwashing compositions |
WO1995020028A1 (en) * | 1994-01-25 | 1995-07-27 | The Procter & Gamble Company | Low to moderate sudsing detergent compositions containing long chain amine oxide |
WO1995020025A1 (en) * | 1994-01-25 | 1995-07-27 | The Procter & Gamble Company | Low sudsing detergent compositions containing long chain amine oxide and branched alkyl carboxylates |
JPH09508166A (ja) * | 1994-01-25 | 1997-08-19 | ザ、プロクター、エンド、ギャンブル、カンパニー | 長鎖アミンオキシドを含有する高起泡性の軽質液状またはゲル状皿洗い洗剤組成物 |
CA2241884A1 (en) * | 1996-01-05 | 1997-07-17 | Kirsten Louise Mckillop | Light-duty liquid or gel dishwashing detergent compositions having beneficial skin conditioning, skin feel and rinsability aesthetics |
GB9613944D0 (en) * | 1996-07-03 | 1996-09-04 | Procter & Gamble | Cleansing compositions |
GB9613899D0 (en) * | 1996-07-03 | 1996-09-04 | Procter & Gamble | Cleansing compositions |
ES2213203T3 (es) * | 1997-01-23 | 2004-08-16 | THE PROCTER & GAMBLE COMPANY | Composiciones detergentes con estabilidad fisica a baja temperatura mejorada. |
US6723550B1 (en) * | 1997-07-15 | 2004-04-20 | Genencor International, Inc. | Proteases from gram-positive organisms |
CA2242651A1 (en) * | 1997-07-22 | 1999-01-22 | Calgon Corporation | Composition and method for cleaning surfaces |
US6194371B1 (en) | 1998-05-01 | 2001-02-27 | Ecolab Inc. | Stable alkaline emulsion cleaners |
EP0962520A1 (en) * | 1998-05-29 | 1999-12-08 | The Procter & Gamble Company | Liquid bleaching compositions |
US6017872A (en) * | 1998-06-08 | 2000-01-25 | Ecolab Inc. | Compositions and process for cleaning and finishing hard surfaces |
AU5459299A (en) * | 1998-08-20 | 2000-03-14 | Cognis Corporation | A surfactant blend based on alpha-olefin sulfonates and alkyl polyglycosides |
EP1135453A1 (en) * | 1998-12-02 | 2001-09-26 | Colgate-Palmolive Company | High foaming, grease cutting light duty liquid detergent |
GB9827033D0 (en) | 1998-12-10 | 1999-02-03 | Kemgas Limited | Lime treatment |
DE19858886C2 (de) | 1998-12-19 | 2002-10-31 | Cognis Deutschland Gmbh | Tensidgranulate |
US6387870B1 (en) * | 1999-03-29 | 2002-05-14 | Ecolab Inc. | Solid pot and pan detergent |
WO2001018165A1 (en) * | 1999-09-09 | 2001-03-15 | The Procter & Gamble Company | A detergent composition containing a protease |
US6554007B2 (en) | 1999-11-24 | 2003-04-29 | William S. Wise | Composition and method for cleaning and disinfecting a garbage disposal |
US6686324B2 (en) * | 1999-11-26 | 2004-02-03 | Virox Technologies, Inc. | Low-foaming hydrogen peroxide cleaning solution for organic soils |
US20030195707A1 (en) * | 2000-05-25 | 2003-10-16 | Schork Nicholas J | Methods of dna marker-based genetic analysis using estimated haplotype frequencies and uses thereof |
US20020077775A1 (en) * | 2000-05-25 | 2002-06-20 | Schork Nicholas J. | Methods of DNA marker-based genetic analysis using estimated haplotype frequencies and uses thereof |
EP1290130B1 (en) | 2000-06-15 | 2003-11-12 | Unilever N.V. | Concentrated liquid detergent composition |
US6774095B2 (en) * | 2001-05-24 | 2004-08-10 | Kao Corporation | Detergent composition |
US7285631B2 (en) * | 2001-08-10 | 2007-10-23 | Serono Genetics Institute S.A. | Human cDNAs and proteins and uses thereof |
ATE431844T1 (de) | 2002-02-11 | 2009-06-15 | Rhodia Chimie Sa | Waschmittel mit blockcopolymer |
AU2003245498B2 (en) | 2002-02-12 | 2008-04-03 | Diversey, Inc. | Enhanced activity hydrogen peroxide disinfectant |
US6926745B2 (en) | 2002-05-17 | 2005-08-09 | The Clorox Company | Hydroscopic polymer gel films for easier cleaning |
DE10231741A1 (de) * | 2002-07-13 | 2004-01-22 | Clariant Gmbh | Flüssige Neutralreinigungsmittel |
EP1955593B1 (en) * | 2002-11-15 | 2013-04-17 | Virox Technologies Inc. | Hydrogen Peroxide Disinfectant Containing Benzyl Alcohol |
US20080305182A1 (en) * | 2002-11-15 | 2008-12-11 | Ramirez Jose A | Hydrogen peroxide disinfectant containing a cyclic carboxylic acid and/or aromatic alcohol |
US20050020467A1 (en) * | 2003-07-22 | 2005-01-27 | Colgate-Palmolive Company | Gelled light duty liquid cleaning composition |
US20050049161A1 (en) * | 2003-08-28 | 2005-03-03 | Colgate-Palmolive Company | Liquid dish cleaning compositions |
US7033986B2 (en) * | 2003-08-28 | 2006-04-25 | Colgate-Palmolive Company | Liquid dish cleaning compositions comprising a mixture of alkyl benzene sulfonates and alkyl ether sulfates |
EP1771536A1 (en) * | 2004-07-23 | 2007-04-11 | The Procter and Gamble Company | Liquid detergent composition for improved low temperature grease cleaning and starch soil cleaning |
US7666963B2 (en) | 2005-07-21 | 2010-02-23 | Akzo Nobel N.V. | Hybrid copolymers |
US20080020961A1 (en) | 2006-07-21 | 2008-01-24 | Rodrigues Klin A | Low Molecular Weight Graft Copolymers |
NO20073834L (no) | 2006-07-21 | 2008-01-22 | Akzo Nobel Chemicals Int Bv | Sulfonerte podede kopolymerer |
US20100311633A1 (en) * | 2007-02-15 | 2010-12-09 | Ecolab Usa Inc. | Detergent composition for removing fish soil |
US8093200B2 (en) | 2007-02-15 | 2012-01-10 | Ecolab Usa Inc. | Fast dissolving solid detergent |
FR2913351B1 (fr) | 2007-03-08 | 2010-11-26 | Rhodia Recherches Et Tech | Utilisation d'une betaine a titre d'agent de reduction du drainage de la mousse |
ES2618291T3 (es) * | 2007-05-04 | 2017-06-21 | Ecolab Inc. | Composiciones que incluyen iones de dureza y gluconato y procedimientos que los emplean para reducir la corrosión y el grabado |
EP2216390B1 (en) * | 2009-02-02 | 2013-11-27 | The Procter and Gamble Company | Hand dishwashing method |
EP2216391A1 (en) * | 2009-02-02 | 2010-08-11 | The Procter & Gamble Company | Liquid hand dishwashing detergent composition |
EP2213715A1 (en) * | 2009-02-02 | 2010-08-04 | The Procter & Gamble Company | Liquid hand dishwashing detergent composition |
PL2391699T3 (pl) * | 2009-02-02 | 2014-11-28 | Procter & Gamble | Płynna kompozycja detergentu do ręcznego mycia naczyń |
EP2216392B1 (en) * | 2009-02-02 | 2013-11-13 | The Procter and Gamble Company | Liquid hand dishwashing detergent composition |
ES2461892T3 (es) * | 2009-02-02 | 2014-05-21 | The Procter & Gamble Company | Composición detergente líquida para lavado de vajillas a mano |
ES2488117T3 (es) * | 2009-02-02 | 2014-08-26 | The Procter & Gamble Company | Composición detergente líquida para lavado de vajillas a mano |
US9546274B2 (en) | 2009-05-26 | 2017-01-17 | The Armor All/Stp Products Company | Automotive protectant compositions with improved vertical cling |
WO2010138347A1 (en) | 2009-05-26 | 2010-12-02 | The Procter & Gamble Company | Aqueous liquid composition for pre-treating soiled dishware |
US20130137799A1 (en) | 2009-07-31 | 2013-05-30 | Akzo Nobel N.V. | Graft copolymers |
EP2412792A1 (en) * | 2010-07-29 | 2012-02-01 | The Procter & Gamble Company | Liquid detergent composition |
US8685171B2 (en) * | 2010-07-29 | 2014-04-01 | The Procter & Gamble Company | Liquid detergent composition |
JP2013542280A (ja) * | 2010-10-01 | 2013-11-21 | ロディア オペレーションズ | スポット形成防止効果及び/又は皮膜形成防止効果を有する洗剤組成物 |
US8974589B2 (en) | 2010-10-25 | 2015-03-10 | The Armor All/Stp Products Company | Silicone protectant compositions |
JP2014500356A (ja) | 2010-11-16 | 2014-01-09 | ダウ グローバル テクノロジーズ エルエルシー | 低voc、低臭気アルカノールアミンを含む硬質表面洗浄剤 |
JP2014511415A (ja) * | 2011-03-03 | 2014-05-15 | ザ プロクター アンド ギャンブル カンパニー | 食器洗浄方法 |
JP2014522896A (ja) * | 2011-07-12 | 2014-09-08 | クラリアント・インターナシヨナル・リミテツド | 液状洗濯洗剤の洗浄能力を高めるための、第二パラフィンスルホネートとアミラーゼとの組み合わせの使用 |
WO2013007367A1 (de) * | 2011-07-12 | 2013-01-17 | Clariant International Ltd. | Verwendung von sekundären paraffinsulfonaten zur erhöhung des reinigungsvermögens von enzymen |
US8853144B2 (en) | 2011-08-05 | 2014-10-07 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage |
US8636918B2 (en) | 2011-08-05 | 2014-01-28 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale |
US8841246B2 (en) | 2011-08-05 | 2014-09-23 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage |
US8679366B2 (en) | 2011-08-05 | 2014-03-25 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale |
WO2013064648A1 (en) | 2011-11-04 | 2013-05-10 | Akzo Nobel Chemicals International B.V. | Graft dendrite copolymers, and methods for producing the same |
CN103945828A (zh) | 2011-11-04 | 2014-07-23 | 阿克佐诺贝尔化学国际公司 | 混杂树枝状共聚物、其组合物及其制备方法 |
US8945314B2 (en) | 2012-07-30 | 2015-02-03 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
US9365805B2 (en) | 2014-05-15 | 2016-06-14 | Ecolab Usa Inc. | Bio-based pot and pan pre-soak |
MX2016014916A (es) * | 2014-05-21 | 2017-04-06 | Colgate Palmolive Co | Composicion liquida acuosa para lavado de platos. |
CN106635494A (zh) * | 2015-10-30 | 2017-05-10 | 深圳市芭格美生物科技有限公司 | 奶瓶生物酶清洗液及其制备方法和应用 |
CN106833946A (zh) * | 2015-12-04 | 2017-06-13 | 深圳市芭格美生物科技有限公司 | 餐具生物酶清洗液及其制备方法和应用 |
US11147268B2 (en) | 2015-12-10 | 2021-10-19 | The Clorox Company | Food contact surface sanitizing liquid |
CN105651015A (zh) * | 2016-03-04 | 2016-06-08 | 芜湖市金宇石化设备有限公司 | 一种车间螺旋式排气管的烘干工艺 |
US10806769B2 (en) | 2016-03-31 | 2020-10-20 | Gojo Industries, Inc. | Antimicrobial peptide stimulating cleansing composition |
WO2017173241A1 (en) | 2016-03-31 | 2017-10-05 | Gojo Industries, Inc. | Sanitizer composition with probiotic/prebiotic active ingredient |
CN105838508A (zh) * | 2016-05-11 | 2016-08-10 | 于文 | 浓缩高效加酶型机洗餐具洗涤剂及其制备方法 |
WO2017209708A1 (en) * | 2016-05-30 | 2017-12-07 | Hayat Kimya San. A. Ş. | A non-irritant hand dishwashing composition |
CA3043748A1 (en) | 2016-11-23 | 2018-05-31 | Gojo Industries, Inc. | Sanitizer composition with probiotic/prebiotic active ingredient |
WO2019027633A1 (en) * | 2017-07-31 | 2019-02-07 | Dow Global Technologies Llc | DETERGENT ADDITIVE |
US10450535B2 (en) | 2017-10-18 | 2019-10-22 | Virox Technologies Inc. | Shelf-stable hydrogen peroxide antimicrobial compositions |
JP6556318B2 (ja) | 2017-12-06 | 2019-08-07 | 花王株式会社 | 繊維製品用洗浄剤組成物 |
EP3802764A1 (en) * | 2018-06-07 | 2021-04-14 | Ecolab USA Inc. | Enzymatic pot and pan detergent |
CN109174754A (zh) * | 2018-08-20 | 2019-01-11 | 六安名家汇光电科技有限公司 | 一种led洗墙灯的灯壳的除尘方法 |
CN109652218A (zh) * | 2019-02-03 | 2019-04-19 | 南京林业大学 | 一种具有降解功能的蛋白类泡沫发生剂及其制备方法 |
JP2024514162A (ja) * | 2021-04-15 | 2024-03-28 | エコラボ ユーエスエー インコーポレイティド | 酵素床洗浄組成物 |
EP4341371A1 (en) | 2021-05-18 | 2024-03-27 | Nouryon Chemicals International B.V. | Polyester polyquats in cleaning applications |
EP4341317A1 (en) | 2021-05-20 | 2024-03-27 | Nouryon Chemicals International B.V. | Manufactured polymers having altered oligosaccharide or polysaccharide functionality or narrowed oligosaccharide distribution, processes for preparing them, compositions containing them, and methods of using them |
CN117940546A (zh) | 2021-06-30 | 2024-04-26 | 诺力昂化学品国际有限公司 | 螯合物-两性表面活性剂液体浓缩物及其在清洁应用中的用途 |
WO2024040007A1 (en) | 2022-08-15 | 2024-02-22 | Energizer Auto, Inc. | Surface treating formulation and method of making and using the same |
Family Cites Families (64)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE626011A (zh) * | ||||
US3553139A (en) * | 1966-04-25 | 1971-01-05 | Procter & Gamble | Enzyme containing detergent composition and a process for conglutination of enzymes and detergent composition |
US3627688A (en) * | 1968-11-12 | 1971-12-14 | Procter & Gamble | Stabilized aqueous enzyme containing compositions |
US3634266A (en) * | 1969-07-23 | 1972-01-11 | Procter & Gamble | Liquid detergent compositions containing amylolytic enzymes |
BE759360A (zh) * | 1969-11-25 | 1971-05-24 | Procter & Gamble Europ | |
US3707504A (en) * | 1969-12-19 | 1972-12-26 | Procter & Gamble | Detergent composition containing proteolytic enzyme elaborated by thermoactinomyces vulgaris atcc 15734 |
US3635828A (en) * | 1969-12-29 | 1972-01-18 | Procter & Gamble | Enzyme-containing detergent compositions |
JPS5014651B1 (zh) * | 1969-12-30 | 1975-05-29 | ||
NL7105204A (en) * | 1970-04-20 | 1971-10-22 | Stable enzymatic washing-up liquids | |
US3682842A (en) * | 1970-05-04 | 1972-08-08 | Irving Innerfield | Stabilized enzymic compositions containing protease and alpha amylase of bacterial origin and method of stabilizing such compositions |
US3755085A (en) * | 1970-09-30 | 1973-08-28 | Procter & Gamble | Prevention of enzyme deactivation by chlorine |
BE786277A (zh) * | 1971-07-16 | 1973-01-15 | Procter & Gamble Europ | |
US4169817A (en) * | 1971-12-23 | 1979-10-02 | Midwest Biochemical Corporation | Liquid cleaning composition containing stabilized enzymes |
US4072632A (en) * | 1972-04-06 | 1978-02-07 | Lever Brothers Company | Dishwashing compositions |
LU68355A1 (zh) * | 1973-09-04 | 1975-05-21 | ||
CA1062580A (en) * | 1974-11-15 | 1979-09-18 | The Procter And Gamble Company | Light-duty liquid detergent compositions having enhanced skin mildness properties |
US4133779A (en) * | 1975-01-06 | 1979-01-09 | The Procter & Gamble Company | Detergent composition containing semi-polar nonionic detergent and alkaline earth metal anionic detergent |
US4166048A (en) * | 1975-09-22 | 1979-08-28 | Kao Soap Co., Ltd. | High foaming detergent composition having low skin irritation properties |
US4101457A (en) * | 1975-11-28 | 1978-07-18 | The Procter & Gamble Company | Enzyme-containing automatic dishwashing composition |
DE2727463A1 (de) * | 1976-06-24 | 1978-01-05 | Procter & Gamble | Reinigungsmittel, das insbesondere zur verwendung in geschirrspuelmaschinen geeignet ist |
US4238345A (en) * | 1978-05-22 | 1980-12-09 | Economics Laboratory, Inc. | Stabilized liquid enzyme-containing detergent compositions |
US4318818A (en) * | 1979-11-09 | 1982-03-09 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
US4287082A (en) * | 1980-02-22 | 1981-09-01 | The Procter & Gamble Company | Homogeneous enzyme-containing liquid detergent compositions containing saturated acids |
US4305837A (en) * | 1980-10-30 | 1981-12-15 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
US4316842A (en) * | 1980-11-24 | 1982-02-23 | Eli Lilly And Company | Penicillin intermediates |
US4490285A (en) * | 1983-08-02 | 1984-12-25 | The Procter & Gamble Company | Heavy-duty liquid detergent composition |
GB8321924D0 (en) * | 1983-08-15 | 1983-09-14 | Unilever Plc | Enzymatic machine-dishwashing compositions |
GB8328075D0 (en) * | 1983-10-20 | 1983-11-23 | Unilever Plc | Dishwashing compositions |
US4681704A (en) * | 1984-03-19 | 1987-07-21 | The Procter & Gamble Company | Detergent composition containing semi-polar nonionic detergent alkaline earth metal anionic detergent and amino alkylbetaine detergent |
US4537706A (en) * | 1984-05-14 | 1985-08-27 | The Procter & Gamble Company | Liquid detergents containing boric acid to stabilize enzymes |
US4537707A (en) * | 1984-05-14 | 1985-08-27 | The Procter & Gamble Company | Liquid detergents containing boric acid and formate to stabilize enzymes |
US4904359A (en) * | 1985-10-31 | 1990-02-27 | The Procter & Gamble Company | Liquid detergent composition containing polymeric surfactant |
JPS62129397A (ja) † | 1985-11-29 | 1987-06-11 | ライオン株式会社 | 洗浄剤組成物 |
EG18543A (en) * | 1986-02-20 | 1993-07-30 | Albright & Wilson | Protected enzyme systems |
US5108457A (en) * | 1986-11-19 | 1992-04-28 | The Clorox Company | Enzymatic peracid bleaching system with modified enzyme |
US5156761A (en) * | 1988-07-20 | 1992-10-20 | Dorrit Aaslyng | Method of stabilizing an enzymatic liquid detergent composition |
US4882401A (en) * | 1988-09-28 | 1989-11-21 | Hercules Incorporated | Slow gel/cure systems based on dialkylzinc for dicyclopentadiene polymerization |
US4950417A (en) * | 1989-05-01 | 1990-08-21 | Miles Inc. | Detergent formulations containing alkaline lipase derived from Pseudomonas plantarii |
US5230823A (en) * | 1989-05-22 | 1993-07-27 | The Procter & Gamble Company | Light-duty liquid or gel dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant |
JPH078991B2 (ja) * | 1989-07-18 | 1995-02-01 | 花王株式会社 | 中性液体洗浄剤組成物 |
US5156773A (en) * | 1989-12-12 | 1992-10-20 | Novo Nordisk A/S | Stabilized enzymatic liquid detergent composition |
US5030378A (en) * | 1990-01-02 | 1991-07-09 | The Procter & Gamble Company | Liquid detergents containing anionic surfactant, builder and proteolytic enzyme |
US5221495A (en) * | 1990-04-13 | 1993-06-22 | Colgate-Palmolive Company | Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions |
BR9106919A (pt) * | 1990-09-28 | 1993-08-17 | Procter & Gamble | Tensoativos de polihidroxi amida de acido graxo para melhorar o desempenho de enzima |
GB9021217D0 (en) * | 1990-09-28 | 1990-11-14 | Procter & Gamble | Liquid detergent compositions |
CA2055048C (en) * | 1990-11-16 | 1996-05-14 | Kofi Ofosu-Asante | Alkaline light-duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant, magnesium ions, chelator and buffer |
ATE149561T1 (de) * | 1990-11-16 | 1997-03-15 | Procter & Gamble | Alkylethoxycarboxylattensid und calcium- oder magnesiumionen enthaltende milde geschirrspülwaschmittelzusammensetzung |
US5565146A (en) * | 1991-04-15 | 1996-10-15 | Cologate-Palmolive Co. | Light duty liquid detergent compositions |
US5298195A (en) * | 1992-03-09 | 1994-03-29 | Amway Corporation | Liquid dishwashing detergent |
US5223179A (en) * | 1992-03-26 | 1993-06-29 | The Procter & Gamble Company | Cleaning compositions with glycerol amides |
EP0591545B1 (en) * | 1992-03-30 | 1997-06-04 | Daikin Industries, Ltd. | Use of a composition as a mold release agent |
US5545354A (en) * | 1992-09-01 | 1996-08-13 | The Procter & Gamble Company | Liquid or gel dishwashing detergent containing a polyhydroxy fatty acid amide, calcium ions and an alkylpolyethoxypolycarboxylate |
DE69313298T2 (de) * | 1992-11-30 | 1998-03-26 | Procter & Gamble | Hochschäumende waschmittelzusammensetzungen mit speziell ausgewählten seifen |
CN1116432A (zh) * | 1993-01-12 | 1996-02-07 | 亨凯尔公司 | 洗碟用洗涤剂 |
CA2162021A1 (en) * | 1993-05-05 | 1994-11-10 | POUL NõRGAARD CHRISTENSEN | Cleaning gel |
AU7402194A (en) * | 1993-08-10 | 1995-02-28 | Procter & Gamble Company, The | Manual dishwashing composition comprising lipase enzymes and lime soap dispersant |
US5415814A (en) * | 1993-08-27 | 1995-05-16 | The Procter & Gamble Company | Concentrated liquid or gel light duty dishwashing detergent composition containing calcium xylene sulfonate |
US5489393A (en) * | 1993-09-09 | 1996-02-06 | The Procter & Gamble Company | High sudsing detergent with n-alkoxy polyhydroxy fatty acid amide and secondary carboxylate surfactants |
ES2131703T5 (es) * | 1993-09-14 | 2009-06-24 | THE PROCTER & GAMBLE COMPANY | Composiciones detergentes para lavado de vajillas en forma liquida o gel, suaves, que contienen proteasa. |
US5851973A (en) * | 1993-09-14 | 1998-12-22 | The Procter & Gamble Company | Manual dishwashing composition comprising amylase and lipase enzymes |
JPH09508122A (ja) * | 1994-01-25 | 1997-08-19 | ザ、プロクター、エンド、ギャンブル、カンパニー | ポリヒドロキシジアミンおよびそれらの洗剤組成物における使用 |
WO1995020025A1 (en) * | 1994-01-25 | 1995-07-27 | The Procter & Gamble Company | Low sudsing detergent compositions containing long chain amine oxide and branched alkyl carboxylates |
US5510052A (en) * | 1994-08-25 | 1996-04-23 | Colgate-Palmolive Co. | Enzymatic aqueous pretreatment composition for dishware |
US5503779A (en) * | 1995-03-20 | 1996-04-02 | Colgate Palmolive Company | High foaming light duty liquid detergent |
-
1994
- 1994-08-30 ES ES94926670T patent/ES2131703T5/es not_active Expired - Lifetime
- 1994-08-30 CN CNB011030240A patent/CN1162532C/zh not_active Expired - Fee Related
- 1994-08-30 JP JP7509225A patent/JP2904930B2/ja not_active Expired - Lifetime
- 1994-08-30 CZ CZ96760A patent/CZ76096A3/cs unknown
- 1994-08-30 DE DE69417755T patent/DE69417755T3/de not_active Expired - Lifetime
- 1994-08-30 RU RU96107895A patent/RU2142981C1/ru active
- 1994-08-30 BR BR9407498A patent/BR9407498A/pt not_active IP Right Cessation
- 1994-08-30 CN CN94193906A patent/CN1094515C/zh not_active Expired - Fee Related
- 1994-08-30 HU HU9600640A patent/HU219172B/hu not_active IP Right Cessation
- 1994-08-30 AU AU76438/94A patent/AU685844B2/en not_active Ceased
- 1994-08-30 KR KR1019960701305A patent/KR100351396B1/ko not_active IP Right Cessation
- 1994-08-30 AT AT94926670T patent/ATE178649T1/de not_active IP Right Cessation
- 1994-08-30 WO PCT/US1994/009923 patent/WO1995007971A1/en not_active Application Discontinuation
- 1994-08-30 DK DK94926670T patent/DK0719321T3/da active
- 1994-08-30 SK SK319-96A patent/SK31996A3/sk unknown
- 1994-08-30 NZ NZ273214A patent/NZ273214A/en unknown
- 1994-08-30 PL PL94313441A patent/PL180210B1/pl unknown
- 1994-08-30 EP EP94926670A patent/EP0719321B2/en not_active Expired - Lifetime
- 1994-08-30 CA CA002170024A patent/CA2170024C/en not_active Expired - Lifetime
- 1994-09-11 EG EG56794A patent/EG21117A/xx active
-
1995
- 1995-06-06 US US08/466,946 patent/US5599400A/en not_active Expired - Lifetime
-
1996
- 1996-03-12 NO NO961001A patent/NO961001L/no not_active Application Discontinuation
- 1996-03-13 FI FI961173A patent/FI961173A/fi unknown
-
1997
- 1997-02-03 US US08/792,742 patent/US5952278A/en not_active Expired - Lifetime
-
1999
- 1999-05-20 GR GR990401370T patent/GR3030286T3/el unknown
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1162532C (zh) | 洗碟用柔性含蛋白酶的液体或凝胶洗涤组合物 | |
CN1209161A (zh) | 具有皮肤有益调理作用、良好的皮肤感觉和漂洗美学效果的轻垢液体或凝胶状洗碗碟洗涤剂组合物 | |
CN1089989A (zh) | 含有多羟基脂肪酸酰胺、钙离子和一种烷基多乙氧基多羧酸盐的液体或凝胶洗碟机用洗涤剂 | |
US6274539B1 (en) | Light-duty liquid or gel dishwashing detergent compositions having controlled pH and desirable food soil removal, rheological and sudsing characteristics | |
CN1086843A (zh) | 含烷基两性羧酸和镁或钙离子的液体或胶状洗碟洗涤剂组合物 | |
CN1090887A (zh) | 含有特选皂的高泡洗涤剂组合物 | |
CN1062371A (zh) | 含有烷基乙氧基羧酸盐表面活性剂和钙或镁离子的轻垢型碟洗洗涤剂组合物 | |
CN1169674A (zh) | 包含赋予组合物以改进发泡性和增稠性的脂肪醇的温和型喷胶组合物 | |
CN1088251A (zh) | 含有烷基乙氧基羧酸盐、二价离子和烷基多乙氧基多羧酸盐的液体或凝胶餐具洗涤剂 | |
CN1345364A (zh) | 餐具洗涤剂组合物中的二醇和聚二醇 | |
CN1267323A (zh) | 具有理想的低温稳定性和理想的去油垢和起泡特性的轻垢型液体洗餐具洗涤剂组合物 | |
CN1222606C (zh) | 用于手洗织物的温和粒状衣物洗涤剂 | |
CN1262703A (zh) | 具有受控pH和理想的去食物污垢和起泡特征的轻垢型液体或凝胶洗餐具洗涤剂组合物 | |
CN1088974A (zh) | 含多羟基脂肪酸酰胺和某些元素的液体或凝胶体餐具洗涤剂组合物 | |
CN1030929C (zh) | 含有阴离子表面活性剂、多羟基脂肪酸酰胺和一种严格筛选出的泡沫增强剂的洗涤剂组合物 | |
CN1133609A (zh) | 包含脂解酶和蛋白酶的机洗餐具用组合物 | |
JPH09235588A (ja) | 液体洗浄組成物 | |
JP2002069487A (ja) | 液体洗浄剤組成物 | |
CN1135236A (zh) | 手洗餐具用组合物 | |
JPH06279795A (ja) | 粒状洗剤組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20040818 Termination date: 20120830 |