CN1134463C - 乙烯的均聚物和共聚物 - Google Patents

乙烯的均聚物和共聚物 Download PDF

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Publication number
CN1134463C
CN1134463C CNB99803648XA CN99803648A CN1134463C CN 1134463 C CN1134463 C CN 1134463C CN B99803648X A CNB99803648X A CN B99803648XA CN 99803648 A CN99803648 A CN 99803648A CN 1134463 C CN1134463 C CN 1134463C
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China
Prior art keywords
multipolymer
protection
value
ethene
butadiene
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Expired - Lifetime
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CNB99803648XA
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English (en)
Chinese (zh)
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CN1292802A (zh
Inventor
I���Dz�
C·K·蔡
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Ineos Sales UK Ltd
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BP Chemicals Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Artificial Filaments (AREA)
  • Polymerisation Methods In General (AREA)
CNB99803648XA 1998-01-07 1999-01-05 乙烯的均聚物和共聚物 Expired - Lifetime CN1134463C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9800245.4A GB9800245D0 (en) 1998-01-07 1998-01-07 Novel polymers
GB9800245.4 1998-01-07

Publications (2)

Publication Number Publication Date
CN1292802A CN1292802A (zh) 2001-04-25
CN1134463C true CN1134463C (zh) 2004-01-14

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CNB99803648XA Expired - Lifetime CN1134463C (zh) 1998-01-07 1999-01-05 乙烯的均聚物和共聚物

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US (2) US6518385B1 (enExample)
EP (2) EP1045868B1 (enExample)
JP (2) JP2002500249A (enExample)
KR (1) KR100645271B1 (enExample)
CN (1) CN1134463C (enExample)
AR (1) AR014252A1 (enExample)
AT (1) ATE269873T1 (enExample)
AU (1) AU760130B2 (enExample)
BR (1) BR9906811A (enExample)
CA (1) CA2316165C (enExample)
CO (1) CO4830472A1 (enExample)
CZ (1) CZ302705B6 (enExample)
DE (1) DE69918263T2 (enExample)
DK (1) DK1045868T3 (enExample)
DZ (1) DZ2704A1 (enExample)
EG (1) EG22389A (enExample)
ES (2) ES2486842T3 (enExample)
GB (1) GB9800245D0 (enExample)
HU (1) HU224167B1 (enExample)
MY (1) MY122063A (enExample)
NO (1) NO20003488L (enExample)
PL (1) PL198209B1 (enExample)
PT (1) PT1045868E (enExample)
RU (1) RU2223283C2 (enExample)
SA (1) SA99191234B1 (enExample)
SK (1) SK10132000A3 (enExample)
TR (1) TR200001955T2 (enExample)
TW (1) TW557303B (enExample)
UA (1) UA66375C2 (enExample)
WO (1) WO1999035174A1 (enExample)
ZA (1) ZA9811886B (enExample)

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GB9800245D0 (en) * 1998-01-07 1998-03-04 Bp Chem Int Ltd Novel polymers
GB9918668D0 (en) * 1999-08-06 1999-10-13 Bp Chem Int Ltd Polymerisation catalysts
JP3798694B2 (ja) * 1999-12-01 2006-07-19 エクソンモービル・ケミカル・パテンツ・インク 触媒化合物、それらを含む触媒系及びそれらの重合法への使用
EP1108749A1 (en) * 1999-12-13 2001-06-20 Fina Research S.A. Medium density polyethylene compositions for film applications
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
KR100377287B1 (ko) * 2000-05-29 2003-03-26 삼성종합화학주식회사 에틸렌 중합 방법
CA2427239A1 (en) * 2000-10-04 2002-04-11 Grant B. Jacobsen Supported catalyst compositions
US7132486B2 (en) 2000-10-06 2006-11-07 Univation Technologies, Llc Linear low density polyethylenes with high melt strength and high melt index ratio
US6734265B1 (en) 2000-10-06 2004-05-11 Univation Technologies, Llc. Linear low density polyethylenes with high melt strength and high melt index ratio
US6884747B2 (en) * 2000-10-06 2005-04-26 Univation Technologies, Llc Linear low density polyethylenes with high melt strength and high melt index ratio
JP4903357B2 (ja) * 2003-03-28 2012-03-28 住友化学株式会社 エチレン重合体
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
ATE534676T1 (de) * 2004-11-02 2011-12-15 Dow Global Technologies Llc Verfahren zur herstellung von polyethylenzusammensetzungen mit niedriger dichte und damit hergestellte polymere
JP5546730B2 (ja) * 2005-02-09 2014-07-09 イネオス ユーロープ リミテッド コポリマーおよびそのフィルム
EP1845110A1 (en) * 2006-04-13 2007-10-17 Total Petrochemicals Research Feluy Chromium-based catalysts
JP2009533513A (ja) * 2006-04-13 2009-09-17 トータル・ペトロケミカルズ・リサーチ・フエリユイ 低密度および中密度の分岐ポリエチレン
GB0610668D0 (en) * 2006-05-30 2006-07-12 Nova Chem Int Sa Supported antistatic polymerization catalysts
EP1935909A1 (en) * 2006-12-21 2008-06-25 Ineos Europe Limited Copolymers and films thereof
WO2008140280A2 (en) * 2007-05-16 2008-11-20 Lg Chem, Ltd. Long chain-branched ethylene-alpha olefin copolymer
WO2009069821A1 (ja) * 2007-11-30 2009-06-04 Sumitomo Chemical Company, Limited エチレン－α－オレフィン共重合体および成形体
JP5392015B2 (ja) * 2008-11-11 2014-01-22 住友化学株式会社 エチレン−α−オレフィン共重合体及び成形体
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
JP2010276128A (ja) * 2009-05-29 2010-12-09 Sumitomo Chemical Co Ltd チューブ
DE112010002188T5 (de) * 2009-05-29 2012-08-30 Sumitomo Chemical Company, Ltd. Ethylen-α-Olefin-Copolymer und Formgegenstand
EP2348057A1 (en) 2010-01-21 2011-07-27 INEOS Manufacturing Belgium NV Novel polymers
CN103087240B (zh) * 2011-10-31 2015-07-22 中国石油化工股份有限公司 一种制备乙烯聚合物的方法
US9096700B2 (en) 2012-12-10 2015-08-04 Exxonmobil Chemical Patents Inc. Polymerization process for production of polymer
US9266977B2 (en) 2012-12-21 2016-02-23 Exxonmobil Chemical Patents Inc. Bridged metallocene compounds, catalyst systems and processes for polymerization therewith
WO2014099307A1 (en) * 2012-12-21 2014-06-26 Exxonmobil Chemical Patents Inc. Branched polyethylene with improved processing and high tear films made therefrom
KR101924198B1 (ko) 2015-12-23 2018-11-30 주식회사 엘지화학 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체
EP4428166A3 (en) * 2015-12-31 2024-12-11 Hanwha Chemical Corporation Hybrid supported metallocene catalyst, method for preparing olefin polymer by using same, and olefin polymer having improved melt strength
US11091571B2 (en) 2016-12-05 2021-08-17 Lg Chem, Ltd. Hybrid supported catalyst
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties

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FR2532649B1 (fr) * 1982-09-07 1986-08-29 Bp Chimie Sa Copolymerisation d'ethylene et d'hexene-1 en lit fluidise
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DE69412576T3 (de) * 1993-12-21 2002-05-29 Univation Technologies,Llc Herstellung von Polyolefinen mit lankettiger Verzweigung nach einem Gasphaseverfahren
EP0676421B1 (en) * 1994-04-07 2006-02-15 Innovene Europe Limited Polymerisation process and polyolefins obtained thereby
US5527929A (en) * 1994-08-02 1996-06-18 The Dow Chemical Company Zwitterionic biscyclopentadienyl complexes
DE69521434T2 (de) * 1994-09-07 2001-10-04 The Dow Chemical Co., Midland Elastisches lineares polyethylenniedriger dichte
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UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
GB9800245D0 (en) * 1998-01-07 1998-03-04 Bp Chem Int Ltd Novel polymers

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JP2002500249A (ja) 2002-01-08
CA2316165C (en) 2008-12-30
PL198209B1 (pl) 2008-06-30
EP1443062A3 (en) 2004-10-20
AU760130B2 (en) 2003-05-08
KR100645271B1 (ko) 2006-11-13
CO4830472A1 (es) 1999-08-30
NO20003488L (no) 2000-09-07
ES2224598T3 (es) 2005-03-01
EP1045868A1 (en) 2000-10-25
MY122063A (en) 2006-03-31
SA99191234B1 (ar) 2006-11-14
KR20010033966A (ko) 2001-04-25
PL341677A1 (en) 2001-04-23
DZ2704A1 (fr) 2003-09-01
US20030139551A1 (en) 2003-07-24
HU224167B1 (hu) 2005-06-28
ES2486842T3 (es) 2014-08-19
CN1292802A (zh) 2001-04-25
DE69918263T2 (de) 2005-07-21
JP5804485B2 (ja) 2015-11-04
CZ302705B6 (cs) 2011-09-14
UA66375C2 (uk) 2004-05-17
SK10132000A3 (sk) 2001-07-10
EP1443062B1 (en) 2014-05-07
NO20003488D0 (no) 2000-07-06
ATE269873T1 (de) 2004-07-15
US6518385B1 (en) 2003-02-11
ZA9811886B (en) 2000-06-28
HUP0100366A3 (en) 2002-03-28
EP1443062A2 (en) 2004-08-04
PT1045868E (pt) 2004-10-29
CZ20002454A3 (cs) 2001-04-11
GB9800245D0 (en) 1998-03-04
EG22389A (en) 2003-01-29
RU2223283C2 (ru) 2004-02-10
AU2064099A (en) 1999-07-26
TR200001955T2 (tr) 2000-11-21
TW557303B (en) 2003-10-11
BR9906811A (pt) 2000-10-10
EP1045868B1 (en) 2004-06-23
HUP0100366A2 (hu) 2001-06-28
CA2316165A1 (en) 1999-07-15
DK1045868T3 (da) 2004-10-25
DE69918263D1 (de) 2004-07-29
JP2010047776A (ja) 2010-03-04
AR014252A1 (es) 2001-02-07
WO1999035174A1 (en) 1999-07-15

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