CN112055721A - 极性单体接枝聚丙烯树脂及其制备方法和应用 - Google Patents

极性单体接枝聚丙烯树脂及其制备方法和应用 Download PDF

Info

Publication number
CN112055721A
CN112055721A CN201980026153.4A CN201980026153A CN112055721A CN 112055721 A CN112055721 A CN 112055721A CN 201980026153 A CN201980026153 A CN 201980026153A CN 112055721 A CN112055721 A CN 112055721A
Authority
CN
China
Prior art keywords
polypropylene resin
hydroxide
polypropylene
grafted polypropylene
polar monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201980026153.4A
Other languages
English (en)
Inventor
乔金樑
王崧合
张晓红
戚桂村
宋志海
蔡传伦
王湘
赖金梅
李秉海
蒋海斌
茹越
张江茹
高建明
张红彬
韩朋
刘文璐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
Original Assignee
Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN201810389316.2A external-priority patent/CN110407962A/zh
Priority claimed from CN201810389343.XA external-priority patent/CN110407981A/zh
Application filed by Sinopec Beijing Research Institute of Chemical Industry, China Petroleum and Chemical Corp filed Critical Sinopec Beijing Research Institute of Chemical Industry
Publication of CN112055721A publication Critical patent/CN112055721A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/126—Microwaves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel

Abstract

本发明涉及聚丙烯接枝改性领域，并提供了极性单体接枝聚丙烯树脂及其制备方法和应用。根据本发明的接枝聚丙烯树脂通过将能够吸收微波从而使其在微波场中的温度升高至高于200℃的极性单体与固体聚丙烯树脂在不添加引发剂的情况下使用微波辐照进行接枝反应而制备。根据本发明获得了不含引发剂残留物并且与接枝前树脂相比分子量不显著下降的极性的接枝聚丙烯树脂。本发明的制备工艺简单，易操作，生产设备简单，成本低，易于工业化。

Description

PCT国内申请，说明书已公开。

Claims (33)

  1. PCT国内申请，权利要求书已公开。
CN201980026153.4A 2018-04-27 2019-04-26 极性单体接枝聚丙烯树脂及其制备方法和应用 Pending CN112055721A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN201810389316.2A CN110407962A (zh) 2018-04-27 2018-04-27 一种有机酸盐接枝聚丙烯树脂及其制备方法和应用
CN201810389343.XA CN110407981A (zh) 2018-04-27 2018-04-27 一种有机酸接枝聚丙烯树脂及其制备方法和应用
CN2018103893162 2018-04-27
CN201810389343X 2018-04-27
PCT/CN2019/084622 WO2019206288A1 (zh) 2018-04-27 2019-04-26 极性单体接枝聚丙烯树脂及其制备方法和应用

Publications (1)

Publication Number Publication Date
CN112055721A true CN112055721A (zh) 2020-12-08

Family

ID=68294389

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980026153.4A Pending CN112055721A (zh) 2018-04-27 2019-04-26 极性单体接枝聚丙烯树脂及其制备方法和应用

Country Status (8)

Country Link
US (1) US11926687B2 (zh)
EP (1) EP3786202B1 (zh)
JP (1) JP7447015B2 (zh)
CN (1) CN112055721A (zh)
BR (1) BR112020021939A2 (zh)
CA (1) CA3098221A1 (zh)
SG (1) SG11202010438RA (zh)
WO (1) WO2019206288A1 (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112830997A (zh) * 2020-12-31 2021-05-25 石家庄联合石化有限公司 一种接枝改性聚丙烯的制备方法
CN113185654A (zh) * 2021-05-11 2021-07-30 泰兴盛嘉树脂有限公司 一种哑光羟基丙烯酸树脂的制备方法
CN114752110A (zh) * 2022-04-21 2022-07-15 浙江沪天胶带有限公司 一种新型增塑剂的制备方法及其在制备pvc软管中的用途

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111116623B (zh) * 2019-12-18 2021-04-27 武汉华星光电半导体显示技术有限公司 一种热活化延迟荧光绿光高分子材料及其制备方法
US11882757B2 (en) 2019-12-18 2024-01-23 Wuhan China Star Optoelectronics Semiconductor Display Technology Co., Ltd. Thermally activated delayed fluorescence green polymer material and preparation method thereof
CN112158838B (zh) * 2020-10-25 2022-05-17 福州大学 一种氮氧共掺杂分级多孔碳材料的制备方法
CN112743945B (zh) * 2020-12-30 2022-05-06 中国科学院长春应用化学研究所 一种基于双连续结构的多层电磁屏蔽复合材料及其制备方法、应用
CN112694567A (zh) * 2020-12-31 2021-04-23 宁波能之光新材料科技股份有限公司 一种微波辅助聚丙烯接枝的方法
CN113484271B (zh) * 2021-07-06 2023-07-04 绍兴文理学院 一种接枝蚕丝接枝率的定量分析方法
CN113698723B (zh) * 2021-09-30 2024-03-08 国网黑龙江省电力有限公司电力科学研究院 一种用于环保型电缆的聚丙烯基热塑型半导电屏蔽料及制备方法
CN114103348B (zh) * 2021-11-22 2023-03-14 四川大学 多层复合bope电容膜及其制备方法
CN114380951B (zh) * 2021-12-28 2023-09-26 金发科技股份有限公司 一种极性组分接枝聚丙烯材料及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101580558A (zh) * 2008-05-13 2009-11-18 住友橡胶工业株式会社 改性天然橡胶、用于制备改性天然橡胶的方法、橡胶组合物以及轮胎
CN103102455A (zh) * 2011-11-10 2013-05-15 中国石油化工股份有限公司 一种聚烯烃接枝方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1821299A (en) * 1929-05-08 1931-09-01 Charles E Ferreira Reclining seat
JPS5247500B2 (zh) * 1972-09-05 1977-12-02
SU608813A1 (ru) 1977-01-11 1978-05-30 Московский Ордена Ленина И Ордена Трудового Красного Знамени Государственный Университет Имени М.В.Лононосова Способ получени привитых сополимеров
JPS5681323A (en) * 1979-12-07 1981-07-03 Toyo Ink Mfg Co Ltd Production of polyolefin type resin
JP2732477B2 (ja) * 1988-12-26 1998-03-30 三井化学株式会社 変性プロピレン系重合体
DE4022570A1 (de) 1990-07-16 1992-01-23 Basf Ag Gepfropfte, vernetzte und vernetzbare propylencopolymerisate
DE4308591A1 (de) * 1993-03-18 1994-09-22 Basf Ag Gepfropfte Propylencopolymerisate
JPH07278327A (ja) * 1994-04-07 1995-10-24 Tonen Chem Corp 高分子基材のグラフト化処理方法
AT403377B (de) 1994-09-26 1998-01-26 Danubia Petrochem Polymere Verfahren zur pfropfung von polyolefinen
US5612097A (en) * 1995-06-02 1997-03-18 The University Of Western Ontario, In Trust For Surface Science Western Plasma assisted grafting of maleic anhydride to polyolefins
US6228948B1 (en) 1998-01-16 2001-05-08 E. I. Du Pont De Nemours And Company High melt flow, highly-grafted polypropylene
CN1133669C (zh) 2000-08-30 2004-01-07 华南理工大学 聚烯烃与三单体固相接枝共聚物的制备方法及其应用
CN1208363C (zh) 2003-06-12 2005-06-29 中国科学院长春应用化学研究所 功能化聚烯烃树脂的制备方法
CN1704436A (zh) 2004-05-31 2005-12-07 华东理工大学 一种聚烯烃连续固相接枝生产方法和装置
CN1300201C (zh) * 2005-03-15 2007-02-14 华南理工大学 聚烯烃与乙烯基单体接枝共聚物的合成方法
CN100497463C (zh) * 2006-03-24 2009-06-10 中国科学院长春应用化学研究所 一种功能化聚丙烯材料的制备方法
ATE534675T1 (de) * 2007-04-27 2011-12-15 Basf Se Verfahren zur herstellung von en-addukten mittels mikrowellenstrahlung
RU2430116C1 (ru) 2010-01-29 2011-09-27 Закрытое Акционерное Общество "Сибур Холдинг" Способ полимеризации и сополимеризации олефиновых олигомеров
JP2012125556A (ja) * 2010-11-25 2012-07-05 Dic Corp ヒト免疫不全ウイルス除去或いは不活性化用高分子基材
CN102924661B (zh) 2012-11-15 2015-05-27 黄山贝诺科技有限公司 一种马来酸酐接枝聚丙烯材料
JP6514445B2 (ja) * 2013-06-06 2019-05-15 三井化学株式会社 変性オレフィン系重合体の製造方法
JP2016003332A (ja) * 2014-06-19 2016-01-12 ダイハツ工業株式会社 ポリプロピレン
CN104804143B (zh) 2015-05-14 2017-10-31 华东理工大学 一种马来酸酐接枝聚丙烯的制备方法
CN111848873B (zh) * 2019-04-26 2023-08-15 中国石油化工股份有限公司 一种功能单体接枝聚丙烯及其制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101580558A (zh) * 2008-05-13 2009-11-18 住友橡胶工业株式会社 改性天然橡胶、用于制备改性天然橡胶的方法、橡胶组合物以及轮胎
CN103102455A (zh) * 2011-11-10 2013-05-15 中国石油化工股份有限公司 一种聚烯烃接枝方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
SONGHE WANG ET.AL.: "《Polymer Solid-Phase Grafting at Temperature Higher than the Polymer Melting Point through Selective Heating》", vol. 52, pages 3222 - 3230 *
陈宋辉等: "《聚丙烯微波辐照固相接枝改性研究》", 《化学与生物工程》, vol. 23, no. 10, pages 25 - 27 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112830997A (zh) * 2020-12-31 2021-05-25 石家庄联合石化有限公司 一种接枝改性聚丙烯的制备方法
CN112830997B (zh) * 2020-12-31 2022-08-09 石家庄联合石化有限公司 一种接枝改性聚丙烯的制备方法
CN113185654A (zh) * 2021-05-11 2021-07-30 泰兴盛嘉树脂有限公司 一种哑光羟基丙烯酸树脂的制备方法
CN114752110A (zh) * 2022-04-21 2022-07-15 浙江沪天胶带有限公司 一种新型增塑剂的制备方法及其在制备pvc软管中的用途

Also Published As

Publication number Publication date
EP3786202A4 (en) 2022-03-30
US11926687B2 (en) 2024-03-12
US20210246248A1 (en) 2021-08-12
EP3786202A1 (en) 2021-03-03
EP3786202B1 (en) 2024-03-13
SG11202010438RA (en) 2020-11-27
CA3098221A1 (en) 2019-10-31
BR112020021939A2 (pt) 2021-03-02
WO2019206288A1 (zh) 2019-10-31
JP2021522388A (ja) 2021-08-30
JP7447015B2 (ja) 2024-03-11

Similar Documents

Publication Publication Date Title
CN112055721A (zh) 极性单体接枝聚丙烯树脂及其制备方法和应用
CN111848873B (zh) 一种功能单体接枝聚丙烯及其制备方法
CN108912272B (zh) 一种接枝改性聚丙烯的制备方法及由其制得的接枝改性聚丙烯
CN110407981A (zh) 一种有机酸接枝聚丙烯树脂及其制备方法和应用
KR910004490B1 (ko) 그라프트화 전구체 및 그 제조방법
KR20220056214A (ko) 무용제형 접착 촉진 사슬연장제 및 이의 제조 방법과 응용
WO2023045268A1 (zh) 无单体残留、高活性增粘扩链剂的制备方法及其应用
CN111607187B (zh) 一种改性abs材料及其制备方法
CN112694567A (zh) 一种微波辅助聚丙烯接枝的方法
DE102006041511A1 (de) Verfahren zur Herstellung von modifizierten PTFE-Pfropfcopolymer-Materialien durch Gasphasenpfropfung
US4939209A (en) Unsaturated copolymer resin composite
RU2801281C2 (ru) Полипропиленовая смола с привитым полярным мономером, способ ее получения и ее применение
CN110407962A (zh) 一种有机酸盐接枝聚丙烯树脂及其制备方法和应用
EP0575040B1 (en) Segmented copolymers
WO2014045303A2 (en) Disentangled ultra high molecular weight polyethylene graft co-polymers and a process for preparation thereof
JP4705474B2 (ja) 変性オレフィン系重合体の製造方法
CN111378260A (zh) 一种改性聚乳酸及其制备方法
CN109553724A (zh) 一种高熔体强度聚丙烯材料及其制备方法
CN104292478B (zh) 一种热可逆交联聚苯乙烯的一步熔融生产方法
CN113121740B (zh) 一种用于制备高白度abs树脂的聚丁二烯胶乳及其制备方法和用途
RU2020138669A (ru) Полипропиленовая смола с привитым полярным мономером, способ ее получения и ее применение
JPH0873540A (ja) 変性樹脂の製造方法
AU617343B2 (en) Pvc overpolymer
CA2635952A1 (en) Solid state modification of propylene polymers
KR20240038800A (ko) 가요성 폴리프로필렌 개질 절연재료, 이의 제조방법 및 응용

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination