CN105859515A - 顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途 - Google Patents

顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途 Download PDF

Info

Publication number
CN105859515A
CN105859515A CN201610096274.4A CN201610096274A CN105859515A CN 105859515 A CN105859515 A CN 105859515A CN 201610096274 A CN201610096274 A CN 201610096274A CN 105859515 A CN105859515 A CN 105859515A
Authority
CN
China
Prior art keywords
hfo
weight
1336mzzm
hfc
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610096274.4A
Other languages
English (en)
Chinese (zh)
Inventor
R.赫尔斯
G.J.兹豪斯基
B.霍夫曼
D.威廉斯
G.克诺佩克
R.G.理查
R.巴苏
R.R.辛赫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell International Inc
Original Assignee
Honeywell International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=44143648&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN105859515(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Honeywell International Inc filed Critical Honeywell International Inc
Publication of CN105859515A publication Critical patent/CN105859515A/zh
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N29/00Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
    • A01N29/02Acyclic compounds or compounds containing halogen attached to an aliphatic side-chain of a cycloaliphatic ring system
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof
    • A23L27/11Natural spices, flavouring agents or condiments; Extracts thereof obtained by solvent extraction
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/20Synthetic spices, flavouring agents or condiments
    • A23L27/202Aliphatic compounds
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/0057Polyhaloalkanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/14Manufacture of cellular products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/127Mixtures of organic and inorganic blowing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00Fireproofing materials
    • C09K21/06Organic materials
    • C09K21/08Organic materials containing halogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/30Materials not provided for elsewhere for aerosols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/04Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/04Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M131/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen
    • C10M131/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen and halogen only
    • C10M131/04Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen and halogen only aliphatic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/008Lubricant compositions compatible with refrigerants
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/02Recovery or refining of essential oils from raw materials
    • C11B9/025Recovery by solvent extraction
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/24Organic compounds containing halogen
    • C11D3/245Organic compounds containing halogen containing fluorine
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/24Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/263Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/264Aldehydes; Ketones; Acetals or ketals
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D7/5018Halogenated solvents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/16Unsaturated hydrocarbons
    • C08J2203/162Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/18Binary blends of expanding agents
    • C08J2203/182Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/18Binary blends of expanding agents
    • C08J2203/184Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • C08J2375/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/11Ethers
    • C09K2205/112Halogenated ethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/12Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/12Hydrocarbons
    • C09K2205/122Halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/22All components of a mixture being fluoro compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/30Refrigerators lubricants or compressors lubricants

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Emergency Medicine (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Detergent Compositions (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201610096274.4A 2009-12-16 2010-12-16 顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途 Pending CN105859515A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US28703309P 2009-12-16 2009-12-16
US61/287033 2009-12-16
US12/968506 2010-12-15
US12/968,506 US20110144216A1 (en) 2009-12-16 2010-12-15 Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
CN201080063844.0A CN102741204B (zh) 2009-12-16 2010-12-16 顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201080063844.0A Division CN102741204B (zh) 2009-12-16 2010-12-16 顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途

Publications (1)

Publication Number Publication Date
CN105859515A true CN105859515A (zh) 2016-08-17

Family

ID=44143648

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201610096274.4A Pending CN105859515A (zh) 2009-12-16 2010-12-16 顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途
CN201080063844.0A Active CN102741204B (zh) 2009-12-16 2010-12-16 顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201080063844.0A Active CN102741204B (zh) 2009-12-16 2010-12-16 顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途

Country Status (8)

Country Link
US (3) US20110144216A1 (enExample)
EP (2) EP2513023B1 (enExample)
JP (4) JP2013514450A (enExample)
CN (2) CN105859515A (enExample)
DK (1) DK2513023T3 (enExample)
ES (1) ES2761933T3 (enExample)
PL (1) PL2513023T3 (enExample)
WO (1) WO2011084553A2 (enExample)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108285775A (zh) * 2017-01-09 2018-07-17 浙江省化工研究院有限公司 一种含1,1,1,4,4,4-六氟-2-丁烯的组合物
CN109689753A (zh) * 2016-09-23 2019-04-26 科慕埃弗西有限公司 具有z-1,1,1,4,4,4-六氟-2-丁烯的新型泡沫
CN110831672A (zh) * 2017-05-08 2020-02-21 霍尼韦尔国际公司 灭火组合物、系统和方法
CN112204060A (zh) * 2018-05-29 2021-01-08 欧文斯科宁知识产权资产有限公司 用于隔热泡沫的发泡剂组合物
CN112204124A (zh) * 2018-05-28 2021-01-08 科慕·三井氟产品株式会社 非共沸清洁组合物
CN112585235A (zh) * 2018-08-23 2021-03-30 科慕埃弗西有限公司 Z-1,1,1,4,4,4-六氟丁-2-烯的共沸和类共沸组合物
CN113667455A (zh) * 2021-05-24 2021-11-19 浙江大学 一种含反式-1,1,1,4,4,4-六氟-2-丁烯的混合制冷剂及其应用
CN113789155A (zh) * 2021-09-16 2021-12-14 珠海格力电器股份有限公司 一种混合制冷剂和空调系统
CN114026160A (zh) * 2019-06-24 2022-02-08 科慕埃弗西有限公司 用于热塑性聚合物的发泡剂共混物
CN114555752A (zh) * 2019-10-10 2022-05-27 科慕埃弗西有限公司 包含新戊烷和HFO-1336mzz的异构体的共沸和类共沸组合物

Families Citing this family (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8463441B2 (en) 2002-12-09 2013-06-11 Hudson Technologies, Inc. Method and apparatus for optimizing refrigeration systems
ES2926707T3 (es) * 2008-05-07 2022-10-27 Chemours Co Fc Llc Composiciones
US8672646B2 (en) * 2008-06-16 2014-03-18 Mitsubishi Electric Corporation Scroll compressor
AU2010210806B2 (en) * 2009-02-03 2015-10-01 The Chemours Company Fc, Llc. Foam-forming compositions containing mixtures of cis-1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,3,3-pentafluoropropane and their uses in the preparation of polyisocyanate-based foams
CN102459498B (zh) 2009-06-03 2016-08-24 纳幕尔杜邦公司 含有顺式-1,1,1,4,4,4-六氟-2-丁烯的冷却器设备及其制冷方法
FR2948679B1 (fr) * 2009-07-28 2011-08-19 Arkema France Procede de transfert de chaleur
US8821749B2 (en) * 2010-04-26 2014-09-02 E I Du Pont De Nemours And Company Azeotrope-like compositions of E-1,1,1,4,4,4-hexafluoro-2-butene and 1-chloro-3,3,3-trifluoropropene
US20110269860A1 (en) * 2010-04-28 2011-11-03 E.I. Du Pont De Nemours And Company Foam expansion agent compositions containing hydrohaloolefin butene and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
US9145480B2 (en) * 2010-10-28 2015-09-29 Honeywell International Inc. Mixtures containing 1,1,1,3,3,3-hexafluorobutene and 1-chloro-3,3,3-trifluoropropene
ES2936125T3 (es) * 2010-11-25 2023-03-14 Arkema France Uso de composiciones de cloro-trifluoropropeno y hexafluorobuteno
FR2968009B1 (fr) 2010-11-25 2012-11-16 Arkema France Fluides frigorigenes contenant du (e)-1,1,1,4,4,4-hexafluorobut-2-ene
FR2968310B1 (fr) 2010-12-03 2012-12-07 Arkema France Compositions a base de 1,1,1,4,4,4-hexafluorobut-2-ene et de 3,3,4,4,4-pentafluorobut-1-ene
TWI573971B (zh) * 2011-01-31 2017-03-11 杜邦股份有限公司 使用包含z-1,1,1,4,4,4-六氟-2-丁烯之工作流體製熱
WO2012106565A2 (en) * 2011-02-04 2012-08-09 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions involving certain haloolefins and uses thereof
FR2977256B1 (fr) 2011-07-01 2013-06-21 Arkema France Compositions de 2,4,4,4-tetrafluorobut-1-ene et de cis-1,1,1,4,4,4-hexafluorobut-2-ene
ES2989330T3 (es) * 2011-08-19 2024-11-26 Chemours Co Fc Llc Proceso de ciclos de Rankine orgánicos para generar energía mecánica a partir de calor
US20130104575A1 (en) * 2011-11-02 2013-05-02 E I Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally z-1,1,1,4,4,4-hexafluoro-2-butene in high temperature heat pumps
US9003797B2 (en) * 2011-11-02 2015-04-14 E L Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally Z-1,1,1,4,4,4-hexafluoro-2-butene in power cycles
US20130104573A1 (en) * 2011-11-02 2013-05-02 E I Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally z-1,1,1,4,4,4-hexafluoro-2-butene in chillers
US9102580B2 (en) 2011-11-10 2015-08-11 The Chemours Company Fc, Llc Catalytic fluorination process of making hydrohaloalkane
AU2012346370B2 (en) * 2011-12-02 2016-07-14 The Chemours Company Fc, Llc. Foam expansion agent compositions containing Z-1,1,1,4,4,4-hexafluoro-2-butene and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
CN103998562A (zh) * 2011-12-21 2014-08-20 纳幕尔杜邦公司 E-1,1,1,4,4,5,5,5-八氟-2-戊烯和任选的1,1,1,2,3-五氟丙烷在冷却器中的用途
EP2814580A1 (en) * 2012-02-17 2014-12-24 E. I. Du Pont de Nemours and Company Azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene and e-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
FR2989084B1 (fr) 2012-04-04 2015-04-10 Arkema France Compositions a base de 2,3,3,4,4,4-hexafluorobut-1-ene
CN102675579A (zh) * 2012-05-07 2012-09-19 南京宝新聚氨酯有限公司 一种聚氨酯反应组合物及采用该组合物制备的硬质泡沫的方法
US20150191576A1 (en) * 2012-08-01 2015-07-09 E I Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of e-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene and z-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
WO2014028697A1 (en) 2012-08-15 2014-02-20 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of 2,3,3,4,4,4-hexafluoro-1-butene and 1,1,1,2,3,3-hexafluoropropane and uses thereof
WO2014030654A1 (ja) * 2012-08-21 2014-02-27 東ソー株式会社 ポリウレタンフォーム製造用の原料配合組成物及びポリウレタンフォーム又はイソシアヌレート変性ポリウレタンフォームの製造方法
US10023681B2 (en) 2012-10-24 2018-07-17 Evonik Degussa Gmbh Delay action catalyst for improving the stability of polyurethane systems having halogen containing blowing agents
SG10201703513WA (en) 2012-10-30 2017-06-29 Air Liquide Fluorocarbon molecules for high aspect ratio oxide etch
US9879164B2 (en) 2013-01-25 2018-01-30 Trane International Inc. Refrigerant additives and compositions
GB2510911A (en) * 2013-02-19 2014-08-20 Mexichem Amanco Holding Sa Heat transfer compositions
CN106414573B (zh) * 2014-01-24 2020-03-17 旭化成建材株式会社 酚醛树脂发泡体及其制造方法
US20150210818A1 (en) * 2014-01-27 2015-07-30 E I Du Pont De Nemours And Company Cryogenic insulation foam
CN106415152A (zh) * 2014-03-17 2017-02-15 三菱电机株式会社 热泵装置
CN103965836B (zh) * 2014-04-02 2017-04-19 浙江大学 一种用于汽车空调的环保型制冷剂及其制备方法
JP6391998B2 (ja) * 2014-06-09 2018-09-19 株式会社カネカ 発泡剤
DE102014220985A1 (de) * 2014-07-03 2016-01-07 Siemens Aktiengesellschaft Vorrichtung und Verfahren zur Verwendung von 1,1,1,4,4,4-Hexafluor-2-Buten als gasförmiges, elektrisch isolierendes und/oder Lichtbogen-löschendes Medium
US20160009886A1 (en) * 2014-07-10 2016-01-14 Owens Corning Intellectual Capital, Llc Methods of manufacturing extruded polystyrene foams using carbon dioxide as a major blowing agent
US10188887B2 (en) * 2014-08-12 2019-01-29 The Chemours Company Fc, Llc Azeotropic and azeotrope-like compositions of HFO-E-1,3,4,4,4-PENTAFLUORO-3-trifluoromethyl-1-butene and uses thereof
US9650596B2 (en) * 2014-08-27 2017-05-16 Illinois Tool Works Inc. Non-flammable ternary cleaning compositions
CN104263323B (zh) * 2014-09-09 2017-06-06 西安交通大学 一种替代hcfc‑22的混合制冷剂及其制备方法和应用
ES2998907T3 (en) 2014-09-26 2025-02-24 Daikin Ind Ltd Haloolefin-based composition
ES2936064T3 (es) 2014-09-26 2023-03-14 Daikin Ind Ltd Composición basada en haloolefina y uso de la misma
CN112920777A (zh) * 2015-02-06 2021-06-08 科慕埃弗西有限公司 包含e-1,1,1,4,4,4-六氟-2-丁烯的组合物及其用途
EP3253844B1 (en) * 2015-02-06 2022-06-22 The Chemours Company FC, LLC Compositions comprising z-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
JP6735766B2 (ja) * 2015-03-02 2020-08-05 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー Z−1−クロロ−3,3,3−トリフルオロプロペンの共沸及び共沸様組成物
US10400149B2 (en) * 2015-04-27 2019-09-03 Trane International Inc. Improving glide in refrigerant blends and/or azeotopic blends, alternatives to R123 refrigerant, and refrigerant compositions, methods, and systems thereof
FR3040525B1 (fr) * 2015-08-28 2017-08-11 Arkema France Utilisation d'hexafluorobutenes pour l'isolation ou l'extinction d'arcs electriques
JP6599749B2 (ja) * 2015-12-14 2019-10-30 三井・ケマーズ フロロプロダクツ株式会社 共沸混合物様組成物
JP6915816B2 (ja) * 2016-01-14 2021-08-04 フマキラー株式会社 害虫防除剤
JP6713776B2 (ja) * 2016-01-14 2020-06-24 フマキラー株式会社 害虫防除剤
EP3405516B1 (en) 2016-01-22 2022-03-02 The Chemours Company FC, LLC Foaming of a reaction product of a polyisocyanate and an active hydrogen-containing compound
JP7038668B2 (ja) * 2016-05-06 2022-03-18 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー スチレンポリマーの発泡
US10612825B2 (en) 2016-05-10 2020-04-07 Trane International Inc. Lubricant blends to reduce refrigerant solubility
CH712780B1 (de) 2016-07-20 2020-03-13 Brugg Rohr Ag Holding Thermisch gedämmte Mediumrohre mit HFO-haltigem Zellgas.
US20180022884A1 (en) * 2016-07-25 2018-01-25 Honeywell International Inc. Polyester polyol compositions containing hfo-1336mzzm (z)
CA2963751A1 (en) * 2017-02-13 2018-08-13 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
JPWO2018159430A1 (ja) * 2017-03-01 2019-12-19 パナソニックIpマネジメント株式会社 断熱体、断熱箱体、断熱扉及び冷凍冷蔵庫
MX2019010052A (es) 2017-03-20 2020-02-05 Chemours Co Fc Llc Composiciones y usos de trans-1,1,1,4,4,4-hexafluoro-2-buteno.
US10920181B2 (en) 2017-05-03 2021-02-16 Illinois Tool Works Inc. Aerosol cleaning composition
US11083921B2 (en) * 2017-05-08 2021-08-10 Honeywell International Inc. Fire extinguishing compositions, systems and methods
HUE059728T2 (hu) * 2017-05-10 2022-12-28 Chemours Co Fc Llc Z-HFO-1336MZZ hajtóanyag-keverékek polisztirolt tartalmazó termoplasztikus polimerek habosítására
JP2020521009A (ja) * 2017-05-19 2020-07-16 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー 発泡体膨張剤として有用なフッ素化化合物
WO2018218102A1 (en) * 2017-05-26 2018-11-29 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene and cyclopentane
JP2017201022A (ja) * 2017-05-30 2017-11-09 アルケマ フランス クロロトリフルオロプロペンとヘキサフルオロブテンとの組成物
AT17135U3 (de) * 2017-07-11 2021-09-15 Brugg Rohr Ag Holding Thermisch gedämmte Mediumrohre mit HFO-haltigem Zellgas
TW201920334A (zh) * 2017-09-19 2019-06-01 美商霍尼韋爾國際公司 形成多元醇預混物和可發泡組合物的方法和由其形成的泡沫
US20200362088A1 (en) * 2017-11-17 2020-11-19 Covestro Deutschland Ag Polyurethane foam composite panel
US20200399515A1 (en) * 2017-11-27 2020-12-24 The Chemours Company Fc, Llc Aerosol compositions
US10407602B2 (en) * 2017-11-30 2019-09-10 Trane International Inc. Low global warming potential refrigerants in liquid chillers
CN108129631A (zh) * 2017-12-28 2018-06-08 青岛海尔股份有限公司 聚氨酯硬质泡沫塑料及其制备方法
FR3079359B1 (fr) 2018-03-22 2020-10-09 Arkema France Utilisation du 1-chloro-2,3,3,3-tetrafluoropropene pour l'isolation ou l'extinction d'arcs electriques
MX2020011135A (es) * 2018-05-04 2020-11-11 Chemours Co Fc Llc Espumas con rendimiento de aislamiento mejorado.
US20220002582A1 (en) * 2018-09-25 2022-01-06 Sekisui Chemical Co., Ltd. Mixed liquid agent, polyurethane composition, polyurethane foam, spray can, and mixing system
KR102122945B1 (ko) * 2018-10-11 2020-06-15 한국과학기술원 초월임계 이산화탄소 발전 시스템
US11155737B2 (en) * 2018-11-21 2021-10-26 Honeywell International Inc. Nonflammable refrigerants having low GWP, and systems for and methods of providing refrigeration
CN109762199B (zh) * 2018-12-18 2022-04-01 浙江巨化新材料研究院有限公司 用于热固性泡沫的聚合物发泡剂和热固性泡沫的制备方法
JP7550781B2 (ja) * 2019-03-04 2024-09-13 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー R-1225ye(E)、HFO-1234yfYF、R-32、R-125、及びCO2を含む熱伝達組成物
CA3137465A1 (en) * 2019-05-29 2020-12-03 The Chemours Company Fc, Llc Blowing agent blends for thermoplastic polymers
JP7535380B2 (ja) * 2020-02-05 2024-08-16 株式会社ダイゾー エアゾール組成物
BR112022026388A2 (pt) 2020-06-25 2023-01-17 Basf Se Processo para produzir espumas de poliisocianurato e espuma rígida de poliisocianurato
US11655328B2 (en) 2020-09-02 2023-05-23 Ventrex Systems, LLC Dimensionally stable closed-cell and rigid foams produced with methylal blowing agent
WO2022261267A1 (en) 2021-06-09 2022-12-15 The Chemours Company Fc, Llc Compositions comprising e-hfo-1336mzz and methyl formate and their use as expansion agents for thermoplastic foam
WO2023023086A1 (en) * 2021-08-16 2023-02-23 Honeywell International Inc. Foamable thermoplastic compositions, thermoplastic foams and methods of making same
JP7674229B2 (ja) * 2021-12-09 2025-05-09 株式会社ジェイエスピー ポリスチレン系樹脂押出発泡板の製造方法
US12391814B2 (en) * 2021-12-27 2025-08-19 Icp Construction, Inc. Open cell polyurethane flame-retardant foams
CN114507508B (zh) * 2022-03-15 2023-03-21 浙江大学 一种热泵混合工质的应用
EP4600239A1 (en) * 2022-10-04 2025-08-13 Daikin Industries, Ltd. Fluorine-containing ether compound and method for producing same
WO2025096186A1 (en) 2023-10-30 2025-05-08 The Chemours Company Fc, Llc Low-gwp blowing agent blends and uses thereof
WO2025096370A2 (en) * 2023-10-30 2025-05-08 The Chemours Company Fc, Llc Compositions comprising 1,3,3,3-tetrafluoropropene, methods of making same, and uses thereof
WO2025096368A2 (en) * 2023-10-30 2025-05-08 The Chemours Company Fc, Llc Compositions comprising 1,3,3,3-tetrafluoropropene, methods of making same, and uses thereof
JP2025184352A (ja) * 2024-06-07 2025-12-18 三井・ケマーズ フロロプロダクツ株式会社 洗浄剤組成物及び洗浄方法

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2210796A1 (en) * 1996-07-26 1998-01-26 Bernd Guettes Production of rigid polyurethane foams
CN1263247A (zh) * 1998-12-30 2000-08-16 普拉塞尔技术有限公司 用多组分致冷剂流体致冷进行低温尤其深冷分离的方法
US20040256594A1 (en) * 2002-10-25 2004-12-23 Honeywell International, Inc. Compositions containing fluorine substituted olefins
US20070108403A1 (en) * 2005-11-01 2007-05-17 Sievert Allen C Compositions comprising fluoroolefins and uses thereof
WO2007100886A2 (en) * 2006-02-28 2007-09-07 E. I. Du Pont De Nemours And Company Azeotropic compositions comprising fluorinated compounds for cleaning applications
WO2008121776A1 (en) * 2007-03-29 2008-10-09 Arkema Inc. Hydrofluoropropene blowing agents for thermoplastics
WO2008134061A2 (en) * 2007-04-27 2008-11-06 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene
WO2009032983A1 (en) * 2007-09-06 2009-03-12 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of e-1,1,1,4,4,5,5,5-octafluoro-2-pentene
WO2009048807A2 (en) * 2007-10-12 2009-04-16 Honeywell International Inc. Amine catalysts for polyurethane foams
WO2009048826A2 (en) * 2007-10-12 2009-04-16 Honeywell International Inc. Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents
CN101546415A (zh) * 2008-03-11 2009-09-30 霍尼韦尔国际公司 用于在签发保险时减轻风险的方法和系统
CN101575263A (zh) * 2008-04-24 2009-11-11 霍尼韦尔国际公司 由3-氯-1,1,1,3-四氟丙烷脱氟化氢制备1-氯-3,3,3-四氟丙烯的方法
WO2009140231A2 (en) * 2008-05-12 2009-11-19 Arkema Inc. Compositions of hydrochlorofluoroolefins
WO2010062888A2 (en) * 2008-11-26 2010-06-03 E. I. Du Pont De Nemours And Company Absorption cycle system having dual absorption circuits

Family Cites Families (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE536296A (enExample) * 1954-03-22
BE538608A (enExample) * 1954-06-10
US2846458A (en) * 1956-05-23 1958-08-05 Dow Corning Organosiloxane ethers
DE3725213A1 (de) * 1987-07-30 1989-02-09 Bayer Ag Herstellung von polyfluorbutenen
JPH05179043A (ja) * 1991-11-18 1993-07-20 Daikin Ind Ltd フルオロブテンからなる発泡剤およびプラスチック発泡体の製造方法
DE4237617A1 (de) * 1992-11-06 1994-05-11 Bayer Ag Verwendung von substituierten Benzimidazolen
DE4237597A1 (de) * 1992-11-06 1994-05-11 Bayer Ag Substituierte Benzimidazole
WO1994012454A1 (fr) * 1992-11-20 1994-06-09 Daikin Industries, Ltd. Procede de production de 1,1,1,4,4,4-hexafluoro-2-butene et de 1,1,1,4,4,4-hexafluorobutane
JP3304468B2 (ja) * 1993-01-29 2002-07-22 ダイキン工業株式会社 1,1,1,4,4,4−ヘキサフルオロ−2−ブテン類及び1,1,1,4,4,4−ヘキサフルオロブタンの製造方法
US5539008A (en) * 1993-12-29 1996-07-23 Minnesota Mining And Manufacturing Company Foamable composition containing unsaturated perfluorochemical blowing agent
US5900342A (en) * 1996-04-26 1999-05-04 Eastman Kodak Company Photoconductive element having an outermost layer of a fluorinated diamond-like carbon and method of making the same
JP2001507207A (ja) * 1996-05-01 2001-06-05 イマアーレクス・フアーマシユーチカル・コーポレーシヨン 化合物を細胞に送達する方法
US6120751A (en) * 1997-03-21 2000-09-19 Imarx Pharmaceutical Corp. Charged lipids and uses for the same
US5849445A (en) * 1998-02-13 1998-12-15 Eastman Kodak Company Multilayer photoconductive elements having low dark decay
US5849443A (en) * 1998-02-13 1998-12-15 Eastman Kodak Company Method of making multilayer electrophotographic elements
US6589355B1 (en) * 1999-10-29 2003-07-08 Alliedsignal Inc. Cleaning processes using hydrofluorocarbon and/or hydrochlorofluorocarbon compounds
FR2806077B1 (fr) * 2000-03-07 2004-01-30 Solvay Procede pour l'obtention d'un hydrofluoroalcane epure, hydrofluoroalcane epure, utilisation de l'hydrofluoroalcane et methode d'analyse d'un hydrofluoroalcane
US7077960B2 (en) * 2000-03-07 2006-07-18 Solvay (Societe Anonyme) Method for obtaining a purified hydrofluoroalkane, purified hydrofluoroalkane, use of same and method for analysing same
US6516837B2 (en) * 2000-09-27 2003-02-11 Honeywell International Inc. Method of introducing refrigerants into refrigeration systems
KR100868512B1 (ko) * 2002-05-24 2008-11-12 마쓰모토유시세이야쿠 가부시키가이샤 열팽창성 마이크로 캡슐 및 그 이용
US9796848B2 (en) * 2002-10-25 2017-10-24 Honeywell International Inc. Foaming agents and compositions containing fluorine substituted olefins and methods of foaming
US7161049B2 (en) * 2002-12-13 2007-01-09 E. I. Du Pont De Nemours And Company Process for purifying hydrofluoropropanes
BR0317477A (pt) * 2002-12-17 2005-11-16 Honeywell Int Inc Método para limpeza de um artigo contendo contaminantes, composição solvente zeotrópica, composição para aplicação por aspersão, e método para limpeza de um artigo contendo contaminantes
CA2510860C (en) * 2002-12-20 2012-10-09 Exxonmobil Chemical Patents Inc. Polymerization process utilizing hydrofluorocarbons as diluents
US7425601B2 (en) * 2002-12-20 2008-09-16 Exxonmobil Chemical Patents Inc. Polymers with new sequence distributions
WO2004058827A1 (en) * 2002-12-20 2004-07-15 Exxonmobil Chemical Patents Inc. Polymerization processes
EP1572763B1 (en) * 2002-12-20 2010-05-26 ExxonMobil Chemical Patents Inc. Polymers with new sequence distributions
JP4604524B2 (ja) * 2004-03-16 2011-01-05 味の素株式会社 変異型アルドラーゼ、並びにこれを用いた光学活性ihog及び光学活性モナティンの製造方法
WO2005090271A2 (en) * 2004-03-17 2005-09-29 Solvay (Societe Anonyme) Method for the analysis of 1,1,1,2-tetrafluoroethane
US9102579B2 (en) * 2004-04-29 2015-08-11 Honeywell International Inc. Method for producing fluorinated organic compounds
US8084653B2 (en) * 2004-04-29 2011-12-27 Honeywell International, Inc. Method for producing fluorinated organic compounds
JP5134952B2 (ja) * 2004-06-23 2013-01-30 エクソンモービル・ケミカル・パテンツ・インク 抽出蒸留を用いたプロセス
US7428816B2 (en) * 2004-07-16 2008-09-30 Honeywell International Inc. Working fluids for thermal energy conversion of waste heat from fuel cells using Rankine cycle systems
US7897823B2 (en) * 2004-10-29 2011-03-01 E. I. Du Pont De Nemours And Company Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
US7429557B2 (en) * 2005-01-27 2008-09-30 Mainstream Engineering Corporation Replacement solvents having improved properties and methods of using the same
US20060179852A1 (en) * 2005-02-16 2006-08-17 Honeywell International Inc. Compositions and methods for cleaning vapor compression systems
JP2008531975A (ja) * 2005-03-04 2008-08-14 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー エンジン排ガス駆動タービンを動力源とする冷凍/空気調節装置
US20060243945A1 (en) * 2005-03-04 2006-11-02 Minor Barbara H Compositions comprising a fluoroolefin
US20060245944A1 (en) * 2005-03-21 2006-11-02 Leck Thomas J Cooling apparatus powered by a ratioed gear drive assembly
US8420706B2 (en) * 2005-06-24 2013-04-16 Honeywell International Inc. Foaming agents, foamable compositions, foams and articles containing halogen substituted olefins, and methods of making same
TW201533108A (zh) * 2005-06-24 2015-09-01 Honeywell Int Inc 含有經氟取代之烯烴之發泡劑及組合物,及發泡方法
US20070100010A1 (en) * 2005-11-01 2007-05-03 Creazzo Joseph A Blowing agents for forming foam comprising unsaturated fluorocarbons
EP3564349A1 (en) * 2005-11-01 2019-11-06 The Chemours Company FC, LLC Solvent compositions comprising unsaturated fluorinated hydrocarbons
WO2007053697A2 (en) * 2005-11-01 2007-05-10 E. I. Du Pont De Nemours And Company Compositions comprising fluoroolefins and uses thereof
US7759532B2 (en) * 2006-01-13 2010-07-20 E.I. Du Pont De Nemours And Company Refrigerant additive compositions containing perfluoropolyethers
US8148450B2 (en) * 2006-06-23 2012-04-03 Exxonmobil Chemical Patents Inc. Process to produce a hydrocarbon rubber cement utilizing a hydrofluorocarbon diluent
US7629397B2 (en) * 2006-06-23 2009-12-08 Exxonmobil Chemical Patents Inc. Phase separation process utilizing a hydrofluorocarbon
US20080000647A1 (en) * 2006-07-03 2008-01-03 Honeywell International Inc. Non-Ferrous Metal Cover Gases
US20080003127A1 (en) * 2006-07-03 2008-01-03 Honeywell International Inc. Non-Ferrous Metal Cover Gases
US7803975B2 (en) * 2006-07-13 2010-09-28 E.I. Du Pont De Nemours And Company Process for separating a fluoroolefin from HF by liquid-liquid extraction
WO2008033570A2 (en) * 2006-09-15 2008-03-20 E. I. Du Pont De Nemours And Company Method of detecting leaks of fluoroolefin compositions and sensors used therefor
AR062864A1 (es) * 2006-09-15 2008-12-10 Du Pont Metodo para determinar los componentes de una composicion de fluoroolefina, metodo para recargar un sistema de fluido en respuesta a ello, y sensores que se utilizan con dicho fin
US20080191163A1 (en) * 2007-02-09 2008-08-14 Mocella Michael T Laser-Assisted Etching Using Gas Compositions Comprising Unsaturated Fluorocarbons
JP2008239864A (ja) * 2007-03-28 2008-10-09 National Institute Of Advanced Industrial & Technology 発泡剤組成物、発泡体用組成物および発泡体の製造方法
US8618339B2 (en) * 2007-04-26 2013-12-31 E I Du Pont De Nemours And Company High selectivity process to make dihydrofluoroalkenes
CN110951463B (zh) * 2007-06-12 2021-06-11 科慕埃弗西有限公司 E-1,1,1,4,4,4-六氟-2-丁烯的共沸和类共沸组合物
US7795482B2 (en) * 2007-07-03 2010-09-14 E. I. Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
JP2010534254A (ja) * 2007-07-20 2010-11-04 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 組成物、およびポリイソシアネートベースの発泡体の製造におけるトランス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡成形用組成物の使用
JP2010534253A (ja) * 2007-07-20 2010-11-04 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー シス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡成形用組成物、およびポリイソシアネートベースの発泡体の製造における組成物の使用
US7795480B2 (en) * 2007-07-25 2010-09-14 Honeywell International Inc. Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf)
ES2559315T3 (es) * 2007-12-19 2016-02-11 E. I. Du Pont De Nemours And Company Composiciones formadoras de espuma que contienen una mezcla azeotrópica o similar a un azeótropo que contiene z-1,1,1,4,4,4-hexafluoro-2-buteno y formiato de metilo y sus usos en la preparación de espumas basadas en poliisocianato
US20090204444A1 (en) * 2008-02-08 2009-08-13 Honeywell International Inc. Method and system for mitigating risk in issuing wind only insurance
EP2285930B1 (en) * 2008-06-20 2016-01-27 E. I. du Pont de Nemours and Company Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene
US20100154419A1 (en) * 2008-12-19 2010-06-24 E. I. Du Pont De Nemours And Company Absorption power cycle system
US8680037B2 (en) * 2009-06-02 2014-03-25 E I Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of Z-1,1,1,4,4,4-hexafluoro-2-butene and ethanol
US20110147638A1 (en) * 2009-06-26 2011-06-23 E.I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene, trans-1,2-dichloroethylene, and cyclopentane
ES2582406T3 (es) * 2009-09-16 2016-09-12 The Chemours Company Fc, Llc Aparato que comprende cis-1,1,1,4,4,4-hexafluoro-2-buteno y trans-1,2-dicloroetileno y procedimientos para producir enfriamiento en él
EP2480222B1 (en) * 2009-09-25 2020-09-09 Arkema Inc. Method of making a low density polylactic acid foam with improved dimensional stability
US20110269860A1 (en) * 2010-04-28 2011-11-03 E.I. Du Pont De Nemours And Company Foam expansion agent compositions containing hydrohaloolefin butene and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2210796A1 (en) * 1996-07-26 1998-01-26 Bernd Guettes Production of rigid polyurethane foams
CN1263247A (zh) * 1998-12-30 2000-08-16 普拉塞尔技术有限公司 用多组分致冷剂流体致冷进行低温尤其深冷分离的方法
US20040256594A1 (en) * 2002-10-25 2004-12-23 Honeywell International, Inc. Compositions containing fluorine substituted olefins
US20070108403A1 (en) * 2005-11-01 2007-05-17 Sievert Allen C Compositions comprising fluoroolefins and uses thereof
WO2007100886A2 (en) * 2006-02-28 2007-09-07 E. I. Du Pont De Nemours And Company Azeotropic compositions comprising fluorinated compounds for cleaning applications
WO2008121776A1 (en) * 2007-03-29 2008-10-09 Arkema Inc. Hydrofluoropropene blowing agents for thermoplastics
WO2008134061A2 (en) * 2007-04-27 2008-11-06 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene
WO2009032983A1 (en) * 2007-09-06 2009-03-12 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of e-1,1,1,4,4,5,5,5-octafluoro-2-pentene
WO2009048807A2 (en) * 2007-10-12 2009-04-16 Honeywell International Inc. Amine catalysts for polyurethane foams
WO2009048826A2 (en) * 2007-10-12 2009-04-16 Honeywell International Inc. Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents
CN101546415A (zh) * 2008-03-11 2009-09-30 霍尼韦尔国际公司 用于在签发保险时减轻风险的方法和系统
CN101575263A (zh) * 2008-04-24 2009-11-11 霍尼韦尔国际公司 由3-氯-1,1,1,3-四氟丙烷脱氟化氢制备1-氯-3,3,3-四氟丙烯的方法
WO2009140231A2 (en) * 2008-05-12 2009-11-19 Arkema Inc. Compositions of hydrochlorofluoroolefins
WO2010062888A2 (en) * 2008-11-26 2010-06-03 E. I. Du Pont De Nemours And Company Absorption cycle system having dual absorption circuits

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109689753A (zh) * 2016-09-23 2019-04-26 科慕埃弗西有限公司 具有z-1,1,1,4,4,4-六氟-2-丁烯的新型泡沫
CN109689753B (zh) * 2016-09-23 2022-06-21 科慕埃弗西有限公司 具有z-1,1,1,4,4,4-六氟丁烯的泡沫
CN108285775B (zh) * 2017-01-09 2020-10-16 浙江省化工研究院有限公司 一种含1,1,1,4,4,4-六氟-2-丁烯的组合物
CN108285775A (zh) * 2017-01-09 2018-07-17 浙江省化工研究院有限公司 一种含1,1,1,4,4,4-六氟-2-丁烯的组合物
CN110831672A (zh) * 2017-05-08 2020-02-21 霍尼韦尔国际公司 灭火组合物、系统和方法
CN114558269A (zh) * 2017-05-08 2022-05-31 霍尼韦尔国际公司 灭火组合物、系统和方法
CN114558269B (zh) * 2017-05-08 2024-04-05 霍尼韦尔国际公司 灭火组合物、系统和方法
CN110831672B (zh) * 2017-05-08 2022-04-05 霍尼韦尔国际公司 灭火组合物、系统和方法
CN112204124B (zh) * 2018-05-28 2022-04-08 科慕·三井氟产品株式会社 非共沸清洁组合物
CN112204124A (zh) * 2018-05-28 2021-01-08 科慕·三井氟产品株式会社 非共沸清洁组合物
CN112204060A (zh) * 2018-05-29 2021-01-08 欧文斯科宁知识产权资产有限公司 用于隔热泡沫的发泡剂组合物
CN112585235A (zh) * 2018-08-23 2021-03-30 科慕埃弗西有限公司 Z-1,1,1,4,4,4-六氟丁-2-烯的共沸和类共沸组合物
CN114026160A (zh) * 2019-06-24 2022-02-08 科慕埃弗西有限公司 用于热塑性聚合物的发泡剂共混物
CN114555752A (zh) * 2019-10-10 2022-05-27 科慕埃弗西有限公司 包含新戊烷和HFO-1336mzz的异构体的共沸和类共沸组合物
CN113667455A (zh) * 2021-05-24 2021-11-19 浙江大学 一种含反式-1,1,1,4,4,4-六氟-2-丁烯的混合制冷剂及其应用
CN113789155A (zh) * 2021-09-16 2021-12-14 珠海格力电器股份有限公司 一种混合制冷剂和空调系统

Also Published As

Publication number Publication date
EP3342840A3 (en) 2018-11-14
EP2513023A4 (en) 2014-06-18
EP2513023B1 (en) 2019-11-13
ES2761933T3 (es) 2020-05-21
JP2017141457A (ja) 2017-08-17
PL2513023T3 (pl) 2020-05-18
US20200017740A1 (en) 2020-01-16
WO2011084553A2 (en) 2011-07-14
US20110144216A1 (en) 2011-06-16
EP3342840A2 (en) 2018-07-04
JP2013514450A (ja) 2013-04-25
DK2513023T3 (da) 2020-01-13
EP2513023A2 (en) 2012-10-24
US20170009116A1 (en) 2017-01-12
CN102741204A (zh) 2012-10-17
CN102741204B (zh) 2016-03-23
JP2019031671A (ja) 2019-02-28
WO2011084553A3 (en) 2011-10-13
JP2016074912A (ja) 2016-05-12

Similar Documents

Publication Publication Date Title
CN102741204B (zh) 顺式-1,1,1,4,4,4-六氟-2-丁烯的组合物和用途
JP7702987B2 (ja) Z-1-クロロ-2,3,3,3-テトラフルオロプロパ-1-エンの組成物及び使用
US11986692B2 (en) Compositions and uses of trans-1,1,1,4,4,4-hexafluoro-2-butene
CN102741203B (zh) 顺式-1,1,1,4,4,4-六氟-2-丁烯的类共沸物组合物
CN102782077B (zh) 氟丙烯化合物和使用其的组合物和方法
JP2015187279A (ja) フッ素置換オレフィンを含有する組成物

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160817

WD01 Invention patent application deemed withdrawn after publication