JP6915816B2 - 害虫防除剤 - Google Patents
害虫防除剤 Download PDFInfo
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- JP6915816B2 JP6915816B2 JP2020026453A JP2020026453A JP6915816B2 JP 6915816 B2 JP6915816 B2 JP 6915816B2 JP 2020026453 A JP2020026453 A JP 2020026453A JP 2020026453 A JP2020026453 A JP 2020026453A JP 6915816 B2 JP6915816 B2 JP 6915816B2
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- pest
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- 241000607479 Yersinia pestis Species 0.000 title claims description 136
- NLOLSXYRJFEOTA-UPHRSURJSA-N (z)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C/C(F)(F)F NLOLSXYRJFEOTA-UPHRSURJSA-N 0.000 claims description 44
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 claims description 35
- 238000001816 cooling Methods 0.000 claims description 34
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims description 9
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 claims description 7
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 50
- 239000003795 chemical substances by application Substances 0.000 description 43
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- 238000012360 testing method Methods 0.000 description 24
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- 239000000126 substance Substances 0.000 description 15
- 241001674044 Blattodea Species 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000003915 liquefied petroleum gas Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 8
- 241000255925 Diptera Species 0.000 description 7
- 230000000749 insecticidal effect Effects 0.000 description 7
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- 238000009834 vaporization Methods 0.000 description 6
- 230000008016 vaporization Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
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- 239000004615 ingredient Substances 0.000 description 4
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- 241000257303 Hymenoptera Species 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
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- 238000009408 flooring Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
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- 239000002904 solvent Substances 0.000 description 3
- RIQRGMUSBYGDBL-UHFFFAOYSA-N 1,1,1,2,2,3,4,5,5,5-decafluoropentane Chemical compound FC(F)(F)C(F)C(F)C(F)(F)C(F)(F)F RIQRGMUSBYGDBL-UHFFFAOYSA-N 0.000 description 2
- DFUYAWQUODQGFF-UHFFFAOYSA-N 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound CCOC(F)(F)C(F)(F)C(F)(F)C(F)(F)F DFUYAWQUODQGFF-UHFFFAOYSA-N 0.000 description 2
- JYZFTXWDXGDNJZ-UHFFFAOYSA-N 1-fluorobut-2-ene Chemical compound CC=CCF JYZFTXWDXGDNJZ-UHFFFAOYSA-N 0.000 description 2
- DJXNLVJQMJNEMN-UHFFFAOYSA-N 2-[difluoro(methoxy)methyl]-1,1,1,2,3,3,3-heptafluoropropane Chemical compound COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F DJXNLVJQMJNEMN-UHFFFAOYSA-N 0.000 description 2
- 241000238657 Blattella germanica Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
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- 241001674048 Phthiraptera Species 0.000 description 2
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- 230000001771 impaired effect Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- 230000035699 permeability Effects 0.000 description 2
- OKIYQFLILPKULA-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane Chemical compound COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F OKIYQFLILPKULA-UHFFFAOYSA-N 0.000 description 1
- SQEGLLMNIBLLNQ-UHFFFAOYSA-N 1-ethoxy-1,1,2,3,3,3-hexafluoro-2-(trifluoromethyl)propane Chemical compound CCOC(F)(F)C(F)(C(F)(F)F)C(F)(F)F SQEGLLMNIBLLNQ-UHFFFAOYSA-N 0.000 description 1
- FNUBKINEQIEODM-UHFFFAOYSA-N 3,3,4,4,5,5,5-heptafluoropentanal Chemical compound FC(F)(F)C(F)(F)C(F)(F)CC=O FNUBKINEQIEODM-UHFFFAOYSA-N 0.000 description 1
- 241000239223 Arachnida Species 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 206010003497 Asphyxia Diseases 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 244000304337 Cuminum cyminum Species 0.000 description 1
- 235000007129 Cuminum cyminum Nutrition 0.000 description 1
- 208000012661 Dyskinesia Diseases 0.000 description 1
- 206010049976 Impatience Diseases 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 241000320508 Pentatomidae Species 0.000 description 1
- 241001510010 Periplaneta fuliginosa Species 0.000 description 1
- 241001374765 Pristomyrmex Species 0.000 description 1
- 241001299872 Pteropus rodricensis Species 0.000 description 1
- 241000257185 Sarcophagidae Species 0.000 description 1
- 241000736892 Thujopsis dolabrata Species 0.000 description 1
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- 150000001298 alcohols Chemical class 0.000 description 1
- -1 alicyclic hydrocarbons Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000010627 cedar oil Substances 0.000 description 1
- 239000010628 chamomile oil Substances 0.000 description 1
- 235000019480 chamomile oil Nutrition 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 239000010630 cinnamon oil Substances 0.000 description 1
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- 239000001941 cymbopogon citratus dc and cymbopogon flexuosus oil Substances 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
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- 150000002222 fluorine compounds Chemical class 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000010648 geranium oil Substances 0.000 description 1
- 235000019717 geranium oil Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000008433 psychological processes and functions Effects 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Description
試験例1は、表1に示すように、比較例1と、実施例1〜7の効力の差を得るための試験である。
試験例2は、表2に示すように、様々な害虫に対する比較例1と実施例2の効力の差を得るための試験である。
試験例3は、噴射剤をLPGとし、かつ、冷却用代替フロンを含まない実施例8の効力を確認するための試験である。
試験例4は、cis-1,1,1,4,4,4-ヘキサフルオロ-2-ブテンとHFO−1234zeとを含んでおり、LPG及びジメチルエーテルは含んでいない実施例9の効力を確認するための試験である。
1a 容器本体
1b ヘッドキャップ
1c ノズル
Claims (1)
- 害虫に付着させる害虫防除剤において、
害虫防除の有効成分として、
cis-1,1,1,4,4,4-ヘキサフルオロ-2-ブテンと、
1,1-ジフルオロエタン、1,1,1,2-テトラフルオロエタン、2,3,3,3-テトラフルオロプロペン、1,3,3,3-テトラフルオロプロペンから選択される冷却用代替フロンであるハイドロフルオロカーボンおよび/またはハイドロフルオロオレフィンとを含むことを特徴とする害虫防除剤。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2020026453A JP6915816B2 (ja) | 2016-01-14 | 2020-02-19 | 害虫防除剤 |
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Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016005417A JP6713776B2 (ja) | 2016-01-14 | 2016-01-14 | 害虫防除剤 |
JP2020026453A JP6915816B2 (ja) | 2016-01-14 | 2020-02-19 | 害虫防除剤 |
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JP2016005417A Division JP6713776B2 (ja) | 2016-01-14 | 2016-01-14 | 害虫防除剤 |
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JP2020073611A JP2020073611A (ja) | 2020-05-14 |
JP6915816B2 true JP6915816B2 (ja) | 2021-08-04 |
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JP2020026453A Active JP6915816B2 (ja) | 2016-01-14 | 2020-02-19 | 害虫防除剤 |
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JP (1) | JP6915816B2 (ja) |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5586157B2 (ja) * | 2008-02-25 | 2014-09-10 | フマキラー株式会社 | 害虫駆除用エアゾール |
WO2010035701A1 (ja) * | 2008-09-24 | 2010-04-01 | セントラル硝子株式会社 | エアゾール組成物 |
US8846754B2 (en) * | 2009-12-16 | 2014-09-30 | Honeywell International Inc. | Azeotrope-like compositions of cis-1,1,1,4,4,4-hexafluoro-2-butene |
US20110144216A1 (en) * | 2009-12-16 | 2011-06-16 | Honeywell International Inc. | Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene |
JP5778458B2 (ja) * | 2011-04-05 | 2015-09-16 | 株式会社ダイゾー | エアゾール製品 |
JP5788582B2 (ja) * | 2013-12-05 | 2015-09-30 | アース製薬株式会社 | エアゾール |
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