CN105705647B - 从1，3-丙二醇制造丙烯酸、丙烯腈和1，4-丁二醇的方法 - Google Patents

从1，3-丙二醇制造丙烯酸、丙烯腈和1，4-丁二醇的方法 Download PDF

Info

Publication number
CN105705647B
CN105705647B CN201480048789.6A CN201480048789A CN105705647B CN 105705647 B CN105705647 B CN 105705647B CN 201480048789 A CN201480048789 A CN 201480048789A CN 105705647 B CN105705647 B CN 105705647B
Authority
CN
China
Prior art keywords
propanediol
bio
acrylic acid
pat
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201480048789.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN105705647A (zh
Inventor
V·格纳纳德斯坎
R·辛格
R·达萨里
M·阿尔杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PTT Global Chemical PCL
Original Assignee
Myriant Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Myriant Corp filed Critical Myriant Corp
Publication of CN105705647A publication Critical patent/CN105705647A/zh
Application granted granted Critical
Publication of CN105705647B publication Critical patent/CN105705647B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/27—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with oxides of nitrogen or nitrogen-containing mineral acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/20—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic unsaturated carbon skeleton
    • C07C211/21—Monoamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
    • C07C255/07—Mononitriles
    • C07C255/08—Acrylonitrile; Methacrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/44—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon double or triple bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
    • C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
    • C07C33/03—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond in beta-position, e.g. allyl alcohol, methallyl alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
CN201480048789.6A 2013-09-03 2014-09-03 从1，3-丙二醇制造丙烯酸、丙烯腈和1，4-丁二醇的方法 Active CN105705647B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361873328P 2013-09-03 2013-09-03
US61/873,328 2013-09-03
PCT/US2014/053933 WO2015034948A1 (en) 2013-09-03 2014-09-03 A process for manufacturing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol

Publications (2)

Publication Number Publication Date
CN105705647A CN105705647A (zh) 2016-06-22
CN105705647B true CN105705647B (zh) 2020-03-27

Family

ID=52628900

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480048789.6A Active CN105705647B (zh) 2013-09-03 2014-09-03 从1，3-丙二醇制造丙烯酸、丙烯腈和1，4-丁二醇的方法

Country Status (7)

Country Link
US (1) US10035749B2 (cg-RX-API-DMAC7.html)
EP (1) EP3041942B1 (cg-RX-API-DMAC7.html)
JP (1) JP2016534131A (cg-RX-API-DMAC7.html)
KR (1) KR102266181B1 (cg-RX-API-DMAC7.html)
CN (1) CN105705647B (cg-RX-API-DMAC7.html)
CA (1) CA2922120C (cg-RX-API-DMAC7.html)
WO (1) WO2015034948A1 (cg-RX-API-DMAC7.html)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107771191B (zh) 2015-06-17 2020-08-28 科莱恩国际有限公司 作为水泥浆中的降失水剂的水溶性或水溶胀性聚合物
EP3984992B1 (en) 2016-06-20 2025-09-17 Clariant International Ltd Compound comprising certain level of bio-based carbon
BR112019006051A2 (pt) * 2016-09-27 2019-06-25 Shell Int Research processo para produção de álcool alílico
EP3551681A1 (en) 2016-12-12 2019-10-16 Clariant International Ltd Polymer comprising certain level of bio-based carbon
EP3551163B1 (en) 2016-12-12 2021-02-17 Clariant International Ltd Use of bio-based polymer in a cosmetic, dermatological or pharmaceutical composition
US20200009041A1 (en) 2016-12-12 2020-01-09 Clariant International Ltd. Polymer Comprising Certain Level Of Bio-Based Carbon
EP3551680A1 (en) 2016-12-12 2019-10-16 Clariant International Ltd Polymer comprising certain level of bio-based carbon
US11339241B2 (en) 2016-12-15 2022-05-24 Clariant International Ltd. Water-soluble and/or water-swellable hybrid polymer
ES3032643T3 (en) 2016-12-15 2025-07-22 Clariant Int Ltd Water-soluble and/or water-swellable hybrid polymer
WO2018108663A1 (en) 2016-12-15 2018-06-21 Clariant International Ltd Water-soluble and/or water-swellable hybrid polymer
WO2018108664A1 (en) 2016-12-15 2018-06-21 Clariant International Ltd Water-soluble and/or water-swellable hybrid polymer
CN110346465A (zh) * 2019-06-12 2019-10-18 南京市产品质量监督检验院 一种气相色谱法测定胶粘剂中丙烯腈含量的方法
KR20220063219A (ko) * 2019-09-18 2022-05-17 롬 앤드 하스 캄파니 고수율 및 저순도로의 알릴 알코올로부터의 아크롤레인 또는 아크릴산의 생성
WO2021209535A1 (en) 2020-04-15 2021-10-21 Lego A/S Toy building bricks made of recycled abs material
JP2022021338A (ja) * 2020-07-21 2022-02-02 Ｄｉｃグラフィックス株式会社 リキッド印刷インキ、印刷物、及びラミネート積層体
JP7574410B2 (ja) * 2021-03-31 2024-10-28 積水化成品工業株式会社 樹脂微粒子、塗膜軟質化剤、塗料用艶消し剤、硬化性樹脂用応力緩和剤、光拡散剤、光拡散性樹脂組成物及び樹脂組成物
CN116060031B (zh) * 2021-11-04 2025-03-25 中国石油化工股份有限公司 一种丙烯氨氧化制丙烯腈催化剂及其制备方法和应用
WO2024077181A1 (en) 2022-10-06 2024-04-11 Microbyre, Inc. Methods of producing reuterin and propenoic acid using an isolated strain of lactobacillus reuteri
CN120737005B (zh) * 2025-08-26 2025-11-28 湖北晶星科技股份有限公司 一种邻氯苯腈的合成工艺

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4051181A (en) * 1975-08-11 1977-09-27 National Distillers And Chemical Corporation Oxidation of allyl alcohol to acrylic acid
CN101248033A (zh) * 2005-04-25 2008-08-20 阿肯马法国公司 用丙三醇生产丙烯酸的方法
CN101405247A (zh) * 2006-03-22 2009-04-08 利安德化学技术有限公司 生产烯醇的方法
CN102272316A (zh) * 2008-11-07 2011-12-07 代谢探索者公司 蔗糖作为底物用于发酵产生1,2-丙二醇的用途

Family Cites Families (91)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US78000A (en) 1868-05-19 Rufus spaulding merrill
JPS5129124B1 (cg-RX-API-DMAC7.html) 1971-04-27 1976-08-24
US3869527A (en) 1971-08-17 1975-03-04 Leo Ab Secondary phosphate esters
GB1424513A (en) 1972-06-13 1976-02-11 Ciba Geigy Ag Organic phosphates
US3907859A (en) 1972-10-25 1975-09-23 Standard Oil Co Ohio Coproduction of acrylonitrile and acrylic acid
US3886096A (en) 1973-01-02 1975-05-27 Monsanto Co Oxidation and ammoxidation catalyst
US3893951A (en) 1973-02-22 1975-07-08 Standard Oil Co Catalysts for oxidation reactions
JPS5246208B2 (cg-RX-API-DMAC7.html) 1973-03-22 1977-11-22
US3993680A (en) 1973-09-04 1976-11-23 The Standard Oil Company (Ohio) Ammoxidation using chromium-containing catalysts
US4018712A (en) 1973-12-27 1977-04-19 Monsanto Company Oxidation/ammoxidation catalyst
US3983161A (en) 1974-12-09 1976-09-28 Monsanto Company Oxidation of unsaturated amines
US3940429A (en) 1974-12-09 1976-02-24 Monsanto Company Oxidation of unsaturated amines
FR2294167A1 (fr) * 1974-12-09 1976-07-09 Monsanto Co Procede d'oxydation d'amines insaturees pour former des nitriles insatures et nouveaux produits ainsi obtenus
US4036881A (en) 1975-06-02 1977-07-19 Texaco Development Corporation Preparation of polyalkylene polyamines
US4339355A (en) 1975-10-09 1982-07-13 Union Carbide Corporation Catalytic oxide of molybdenum, vanadium, niobium and optional 4th metal
US4144398A (en) 1977-07-07 1979-03-13 National Distillers And Chemical Corporation Process for the preparation of acrolein and acrylic acid
JPS5849532B2 (ja) * 1977-12-15 1983-11-05 株式会社クラレ ブタンジオ−ル類の製造方法
IT1160321B (it) * 1978-12-12 1987-03-11 Euteco Spa Catalizzatori per l'ossidazione di acroleina ad acido acrilico
US4405498A (en) 1979-12-17 1983-09-20 Monsanto Company Oxidation and ammoxidation catalysts
US4417074A (en) 1981-10-22 1983-11-22 Air Products And Chemicals, Inc. Allylamines from allyl alcohol
JPS5910537A (ja) 1982-07-07 1984-01-20 Daicel Chem Ind Ltd ブタンジオ−ルの取得法
EP0107638B1 (en) * 1982-09-30 1988-05-11 Monsanto Company Catalysts for the oxidation and ammoxidation of alcohols
JPS606630A (ja) 1983-06-24 1985-01-14 Kuraray Co Ltd アリルアルコ−ルの連続ヒドロホルミル化方法
US4590311A (en) 1983-12-29 1986-05-20 Shell Oil Company Process for the preparation of 1,4-butanediol
US4529808A (en) 1984-02-02 1985-07-16 Texaco Inc. Bi-solvent system for the hydroformylation of allyl alcohol using a rhodium catalyst
JPS63137755A (ja) 1986-11-28 1988-06-09 Nippon Shokubai Kagaku Kogyo Co Ltd 触媒の再活性化法
JPH0759535B2 (ja) * 1987-12-11 1995-06-28 昭和電工株式会社 アリル型アミンの製造法
US5254467A (en) 1988-09-01 1993-10-19 Henkel Kommanditgesellschaft Auf Aktien Fermentive production of 1,3-propanediol
EP0373230B1 (en) 1988-12-12 1993-02-17 Unilever N.V. Process for the microbiological preparation of 1,3-propane-diol from glycerol
DE4238493C1 (de) 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
US5426250A (en) 1993-01-11 1995-06-20 Darien Chemical Corporation Process for preparing 1,4-butanediol
US5290743A (en) 1993-03-22 1994-03-01 Arco Chemical Technology L.P. Process for regenerating a deactivated rhodium hydroformylation catalyst system
US5693832A (en) 1994-06-27 1997-12-02 Showa Denko K.K Hydroformylation of allyl alcohol
US6428767B1 (en) 1995-05-12 2002-08-06 E. I. Du Pont De Nemours And Company Method for identifying the source of carbon in 1,3-propanediol
US5686276A (en) 1995-05-12 1997-11-11 E. I. Du Pont De Nemours And Company Bioconversion of a fermentable carbon source to 1,3-propanediol by a single microorganism
US5633362A (en) 1995-05-12 1997-05-27 E. I. Du Pont De Nemours And Company Production of 1,3-propanediol from glycerol by recombinant bacteria expressing recombinant diol dehydratase
US5639916A (en) * 1995-11-29 1997-06-17 Air Products And Chemicals, Inc. Amination of allylic alcohols
CA2269088C (en) 1996-11-13 2009-07-28 E.I. Du Pont De Nemours And Company Method for the production of 1,3-propanediol by recombinant organisms
US5981810A (en) 1997-06-16 1999-11-09 Mitsubishi Chemical Corporation Process for preparing 1,4-butanediol
US7074608B1 (en) 1998-05-12 2006-07-11 E. I. Du Pont De Nemours And Company Method for the production of 1,3-propanediol by recombinant organisms comprising genes for coenzyme B12 synthesis
US6127584A (en) 1999-04-14 2000-10-03 Arco Chemical Technology, L.P. Butanediol production
DE60029971T2 (de) 1999-08-18 2007-05-16 E.I. Dupont De Nemours And Co., Wilmington Verfahren zur biologischen herstellung von 1,3-propandiol
US6361983B1 (en) 1999-09-30 2002-03-26 E. I. Du Pont De Nemours And Company Process for the isolation of 1,3-propanediol from fermentation broth
US6225509B1 (en) 2000-01-06 2001-05-01 Arco Chemical Technology, L.P. Allyl alcohol hydroformylation
US6479716B2 (en) 2000-03-29 2002-11-12 Archer-Daniels-Midland Company Method of recovering 1,3-propanediol from fermentation broth
US6426437B1 (en) 2000-12-13 2002-07-30 Arco Chemical Technology, L.P. Hydroformylation process
CN1165623C (zh) * 2001-12-05 2004-09-08 大连理工大学 两步微生物发酵生产1，3-丙二醇的方法
JP3800205B2 (ja) * 2002-09-09 2006-07-26 チッソ株式会社 不飽和アルコール製造用触媒と不飽和アルコール製造方法
BR0314498A (pt) 2002-10-04 2005-08-16 Du Pont Linhagens de e. coli e método para a bioprodução de 1,3-propanodiol
DE602004028359D1 (de) * 2003-05-06 2010-09-09 Du Pont Reinigung von biologisch produziertem 1,3-propandiol
DE10351269A1 (de) 2003-10-31 2005-06-02 Basf Ag Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation von Propen zu Acrylsäure
JP4771437B2 (ja) 2004-08-27 2011-09-14 ライス ユニバーシティー 増加したコハク酸産生を有する変異Ｅ．ｃｏｌｉ株
US6969780B1 (en) 2004-12-20 2005-11-29 Lyondell Chemical Technology, L.P. Production of butanediol
FR2884818B1 (fr) 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
MY154509A (en) 2006-08-09 2015-06-30 Univ Florida Re-engineering bacteria for ethanol production
US7271295B1 (en) 2006-10-13 2007-09-18 Lyondell Chemical Technology, L.P. Hydroformylation process
JP5095203B2 (ja) * 2006-12-27 2012-12-12 株式会社日本触媒 グリセリンからのアリルアルコールおよびアクリル酸の製造方法
JP5551448B2 (ja) 2007-03-16 2014-07-16 ジェノマティカ・インコーポレイテッド １，４−ブタンジオールおよびその前駆体の生合成のための組成物および方法
ES2389582T3 (es) 2007-03-20 2012-10-29 University Of Florida Research Foundation, Inc. Materiales y métodos para la producción eficaz de succinato y malato
US7279606B1 (en) * 2007-04-02 2007-10-09 Lyondell Chemical Technology, L.P. Hydroformylation process
WO2009015508A1 (en) 2007-07-27 2009-02-05 Fu-Biau Hsu Fabric used as a burner cover
DE102007035489A1 (de) 2007-07-28 2009-01-29 GM Global Technology Operations, Inc., Detroit Kraftfahrzeug mit nach vorne gewölbter Stirnwand
US7947483B2 (en) 2007-08-10 2011-05-24 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
WO2010079500A2 (en) * 2008-02-28 2010-07-15 Reliance Life Sciences Pvt. Ltd Aerobic production of 1,3-propanediol from crude glycerol from biodiesel process.
WO2009127889A1 (en) 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
AU2009291825B2 (en) 2008-09-10 2016-05-05 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol
BRPI1009992A2 (pt) 2009-04-02 2020-08-18 University Of Florida Research Foundation, Inc. células bacterianas
AU2010256428B2 (en) 2009-06-04 2016-02-11 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol and related methods
KR20120038433A (ko) 2009-06-04 2012-04-23 게노마티카 인코포레이티드 발효액 성분들의 분리 방법
CA2773694A1 (en) 2009-09-09 2011-03-17 Genomatica, Inc. Microorganisms and methods for the co-production of isopropanol with primary alcohols, diols and acids
JPWO2011033649A1 (ja) 2009-09-18 2013-02-07 公立大学法人高知工科大学 複数のセンシング領域を有する分布型光ファイバーセンサー装置
AU2010349739B2 (en) 2009-11-18 2014-10-16 Ptt Global Chemical Public Company Limited Metabolic evolution of Escherchia coli strains that produce organic acids
WO2011063157A2 (en) 2009-11-18 2011-05-26 Myriant Technologies Llc Organic acid production in microorganisms by combined reductive and oxidative tricarboxylic acid cycle pathways
US9017976B2 (en) 2009-11-18 2015-04-28 Myriant Corporation Engineering microbes for efficient production of chemicals
WO2011066076A1 (en) 2009-11-25 2011-06-03 Genomatica, Inc. Microorganisms and methods for the coproduction of 1,4-butanediol and gamma-butyrolactone
WO2011082378A2 (en) 2009-12-31 2011-07-07 Myriant Technologies Llc Purification of succinic acid from the fermentation broth containing ammonium succinate
BR112012026539A2 (pt) 2010-04-16 2015-09-22 Myriant Corp "produção de ácidos orgãnicos a partir de hidrolisado rico em xilose por fermentação bacteriana"
WO2012015770A2 (en) 2010-07-30 2012-02-02 Cook Medical Technologies Llc Coaxial incisional full-core biopsy needle
CA2807102C (en) 2010-07-31 2018-08-21 Myriant Corporation Improved fermentation process for the production of organic acids
US8818718B2 (en) 2010-08-02 2014-08-26 Qualcomm Incorporated PND repositioning detector for better navigation accuracy in a car
WO2012033845A2 (en) 2010-09-07 2012-03-15 Myriant Corporation Catalytic dehydration of lactic acid and lactic acid esters
US8129170B1 (en) 2010-12-06 2012-03-06 E.I. Du Pont De Nemours And Company Recombinant bacteria having the ability to metabolize sucrose
ES2686301T3 (es) 2010-12-13 2018-10-17 Myriant Corporation Método de producción de ácido succínico y otros productos químicos utilizando una materia prima que contiene sacarosa
KR20140083970A (ko) 2011-07-22 2014-07-04 미리안트 코포레이션 유기산으로의 글리세롤의 발효
CN102433940B (zh) 2011-08-31 2013-09-25 青岛科瑞新型环保材料有限公司 外墙高效节能防火保温板的制备方法
JP2013070675A (ja) * 2011-09-28 2013-04-22 Daicel Corp アルキルジオールを産生する組換え菌の培養方法
CN103890186A (zh) 2011-10-05 2014-06-25 宝洁公司 通过高丝氨酸生产丙烯酸酯和其它产品的微生物和方法
CA2866003A1 (en) 2012-03-07 2013-09-12 Myriant Corporation Preparation of alpha, beta-unsaturated carboxylic acids and esters thereof
TWI586643B (zh) 2012-05-29 2017-06-11 利安德化學科技有限公司 烯丙醇之氫甲醯化的速率及選擇性上的改良
US8742180B1 (en) 2012-11-13 2014-06-03 Lyondell Chemical Technology, L.P. Process control with Raman spectroscopy
WO2014089412A1 (en) * 2012-12-07 2014-06-12 Evernu Technology Llc Catalytic conversion of bio-mass derivable aliphatic alcohols to valuable alkenes or oxygenates

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4051181A (en) * 1975-08-11 1977-09-27 National Distillers And Chemical Corporation Oxidation of allyl alcohol to acrylic acid
CN101248033A (zh) * 2005-04-25 2008-08-20 阿肯马法国公司 用丙三醇生产丙烯酸的方法
CN101405247A (zh) * 2006-03-22 2009-04-08 利安德化学技术有限公司 生产烯醇的方法
CN102272316A (zh) * 2008-11-07 2011-12-07 代谢探索者公司 蔗糖作为底物用于发酵产生1,2-丙二醇的用途

Also Published As

Publication number Publication date
KR20160071376A (ko) 2016-06-21
EP3041942A4 (en) 2017-04-26
CA2922120C (en) 2022-09-06
US10035749B2 (en) 2018-07-31
EP3041942A1 (en) 2016-07-13
JP2016534131A (ja) 2016-11-04
WO2015034948A1 (en) 2015-03-12
EP3041942B1 (en) 2020-07-01
KR102266181B1 (ko) 2021-06-17
CN105705647A (zh) 2016-06-22
US20160207865A1 (en) 2016-07-21
CA2922120A1 (en) 2015-03-12

Similar Documents

Publication Publication Date Title
CN105705647B (zh) 从1，3-丙二醇制造丙烯酸、丙烯腈和1，4-丁二醇的方法
Zhu et al. Bio-based 1, 4-butanediol and tetrahydrofuran synthesis: perspective
Della Pina et al. A green approach to chemical building blocks. The case of 3-hydroxypropanoic acid
Duan et al. Future prospect of the production of 1, 3-butadiene from butanediols
Fan et al. Selective catalysis of lactic acid to produce commodity chemicals
Bozell et al. Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited
EP2094857B1 (en) Method for making 2-butanol
EP3183241B1 (en) Catalyst and process for producing 2,5-furandicarboxylic acid from hydromethylfurfural in water
Ventura et al. Catalytic processes for biomass-derived platform molecules valorisation
Marchesan et al. A roadmap for renewable C2–C3 glycols production: a process engineering approach
US10189764B2 (en) Hydrogenation of oxygenated molecules from biomass refining
JP7416177B2 (ja) アルコールの製造方法
Ochoa-Gómez et al. Production of sorbitol from biomass
Binczarski et al. Biologically synthesized crude calcium lactate as a substrate for propylene glycol production
KR101177565B1 (ko) 고순도 부탄올 제조 공정
Bohmer et al. Valorisation of glycerol as renewable feedstock: comparison of the exploration of chemical transformation methods aided by high throughput experimentation
JP6486020B2 (ja) ２，３−ブタンジオールの製造方法
JP2015048336A (ja) ブタジエン及び／又は３−ブテン−２−オールの製造方法
CN102898278A (zh) 一种秸秆水解糖液制备小分子多元醇的方法
Ji et al. Bio‐Based Butanediols Production: The Contributions of Catalysis, Metabolic Engineering, and Synthetic Biology
CN103732754A (zh) 用于从生物质合成基于双官能烃的化合物的方法
EP3529228B1 (en) Process
Beccaria et al. The Pauper and the Prince: Glycerol in a view from biofuels and biorefineries
TW201307268A (zh) 純化乙醇粗產物之製程

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: Massachusetts, USA

Applicant after: PTTGC innovating American company

Address before: Massachusetts, USA

Applicant before: Myriant Corp.

CB02 Change of applicant information
TA01 Transfer of patent application right

Effective date of registration: 20200108

Address after: Bangkok Thailand

Applicant after: PTT Global Chemistry Public Limited

Address before: Massachusetts, USA

Applicant before: PTTGC innovating American company

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant