CN103788259B - 一种分子量窄分布聚丙烯 - Google Patents

一种分子量窄分布聚丙烯 Download PDF

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Publication number
CN103788259B
CN103788259B CN201210425066.6A CN201210425066A CN103788259B CN 103788259 B CN103788259 B CN 103788259B CN 201210425066 A CN201210425066 A CN 201210425066A CN 103788259 B CN103788259 B CN 103788259B
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Prior art keywords
polypropylene
propylene
compound
preparation methods
formula
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CN201210425066.6A
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English (en)
Chinese (zh)
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CN103788259A (zh
Inventor
王良诗
于鲁强
张师军
乔金樑
郭梅芳
杨芝超
殷建军
黄红红
侯莉萍
盛建昉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
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Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
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Application filed by Sinopec Beijing Research Institute of Chemical Industry, China Petroleum and Chemical Corp filed Critical Sinopec Beijing Research Institute of Chemical Industry
Priority to CN201210425066.6A priority Critical patent/CN103788259B/zh
Priority to DE102013221844.3A priority patent/DE102013221844A1/de
Priority to ZA2013/08088A priority patent/ZA201308088B/en
Priority to TW102139087A priority patent/TWI626251B/zh
Priority to BE2013/0730A priority patent/BE1022317B1/fr
Priority to IT001794A priority patent/ITMI20131794A1/it
Priority to NL2011695A priority patent/NL2011695C2/en
Priority to KR1020130130246A priority patent/KR101761843B1/ko
Priority to JP2013225693A priority patent/JP6209056B2/ja
Priority to US14/067,278 priority patent/US10301405B2/en
Priority to BR102013027916A priority patent/BR102013027916B1/pt
Publication of CN103788259A publication Critical patent/CN103788259A/zh
Publication of CN103788259B publication Critical patent/CN103788259B/zh
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06Catalyst characterized by its size
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201210425066.6A 2012-10-30 2012-10-30 一种分子量窄分布聚丙烯 Active CN103788259B (zh)

Priority Applications (11)

Application Number Priority Date Filing Date Title
CN201210425066.6A CN103788259B (zh) 2012-10-30 2012-10-30 一种分子量窄分布聚丙烯
DE102013221844.3A DE102013221844A1 (de) 2012-10-30 2013-10-28 Polypropylen mit enger Molekulargewichtsverteilung und Verfahren zu dessen Herstellung
NL2011695A NL2011695C2 (en) 2012-10-30 2013-10-29 Polypropylene with narrow molecular weight distribution and process for preparation thereof.
TW102139087A TWI626251B (zh) 2012-10-30 2013-10-29 一種分子量窄分佈聚丙烯及其製備方法
BE2013/0730A BE1022317B1 (fr) 2012-10-30 2013-10-29 Polypropylene ayant une distribution de poids moleculaire etroite et son procede de preparation
IT001794A ITMI20131794A1 (it) 2012-10-30 2013-10-29 Polipropilene con distribuzione ristretta del peso molecolare e processo per la preparazione dello stesso
ZA2013/08088A ZA201308088B (en) 2012-10-30 2013-10-29 Polypropylene with narrow molecular weight distribution and process for preparation thereof
US14/067,278 US10301405B2 (en) 2012-10-30 2013-10-30 Polypropylene with narrow molecular weight distribution range and processes for preparation thereof
JP2013225693A JP6209056B2 (ja) 2012-10-30 2013-10-30 狭分子量分布ポリプロピレンおよびその調製方法
KR1020130130246A KR101761843B1 (ko) 2012-10-30 2013-10-30 분자량 분포가 좁은 폴리프로필렌, 및 이의 제조 방법
BR102013027916A BR102013027916B1 (pt) 2012-10-30 2013-10-30 polipropileno, processo para preparar polipropileno e uso do polipropileno

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210425066.6A CN103788259B (zh) 2012-10-30 2012-10-30 一种分子量窄分布聚丙烯

Publications (2)

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CN103788259A CN103788259A (zh) 2014-05-14
CN103788259B true CN103788259B (zh) 2017-05-31

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US (1) US10301405B2 (enExample)
JP (1) JP6209056B2 (enExample)
KR (1) KR101761843B1 (enExample)
CN (1) CN103788259B (enExample)
BE (1) BE1022317B1 (enExample)
BR (1) BR102013027916B1 (enExample)
DE (1) DE102013221844A1 (enExample)
IT (1) ITMI20131794A1 (enExample)
NL (1) NL2011695C2 (enExample)
TW (1) TWI626251B (enExample)
ZA (1) ZA201308088B (enExample)

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CN107075207B (zh) 2014-11-19 2018-07-27 博里利斯股份公司 基于丙烯均聚物的注射成型制品
CN106632761B (zh) * 2015-07-16 2019-06-28 中国石油化工股份有限公司 一种窄分子量分布聚丙烯及其制备方法
BR112018002018B1 (pt) 2015-08-04 2022-05-17 Basell Poliolefine Italia S.R.L. Componente catalisador pré-polimerizado, sistema de catalisador e processo em fase gasosa para polimerização de olefinas
WO2017178046A1 (en) * 2016-04-13 2017-10-19 Borealis Ag Injection molded article based on propylene homopolymer
CN107629155B (zh) * 2016-07-18 2020-06-09 中国石油化工股份有限公司 一种聚丙烯及其制备方法和应用
JP7044710B2 (ja) * 2016-10-03 2022-03-30 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分、オレフィン類重合用固体触媒成分の製造方法、オレフィン類重合用触媒、オレフィン類重合体の製造方法、プロピレン系共重合体の製造方法およびプロピレン系共重合体
KR102412129B1 (ko) * 2017-12-13 2022-06-22 주식회사 엘지화학 호모 폴리프로필렌의 제조방법
CN110016097B (zh) * 2018-01-10 2021-12-31 中国石油化工股份有限公司 一种低溶出物、低熔点、窄分子量分布、热氧稳定的乙丙无规共聚物及其制备方法和应用
CN109734997A (zh) * 2018-12-18 2019-05-10 东华能源(宁波)新材料有限公司 一种采用氢调和降解法制备聚丙烯材料的方法
CA3132862A1 (en) * 2019-03-15 2020-09-24 W.R. Grace & Co.-Conn. Catalyst system for producing olefin polymers with no fines
CN110183559B (zh) * 2019-04-04 2021-07-23 东华能源(宁波)新材料有限公司 一种高流动性纺粘非织造布用聚丙烯树脂的生产方法
KR102886189B1 (ko) * 2019-06-20 2025-11-14 주식회사 엘지화학 폴리프로필렌 및 그의 제조방법
WO2021105373A1 (en) * 2019-11-29 2021-06-03 Thai Polyethylene Co., Ltd. Catalyst composition for the polymerization of olefins
CN114149524B (zh) * 2020-09-05 2023-07-21 中国石油化工股份有限公司 用于烯烃聚合的催化剂载体及其制备方法与应用和催化剂及其应用
CN114437264B (zh) * 2020-10-20 2024-03-26 中国石油化工股份有限公司 一种低voc低气味聚丙烯树脂及其制备方法和应用
TWI762127B (zh) 2020-12-29 2022-04-21 臺灣塑膠工業股份有限公司 聚丙烯與其製作方法及熔噴纖維布
KR102539409B1 (ko) * 2021-01-25 2023-06-05 에쓰대시오일 주식회사 자일렌 용해도가 향상된 호모 폴리프로필렌 수지 조성물 및 그 제조방법
US20250326923A1 (en) * 2021-04-30 2025-10-23 Borealis Ag Polymer composition comprising polypropylene and hydrocarbon resin
KR102750347B1 (ko) * 2022-01-26 2025-01-03 고려대학교 산학협력단 강성과 연신성이 뛰어난 호모 폴리프로필렌 수지 조성물 및 이의 제조 방법
CN119306864B (zh) * 2024-12-19 2025-03-28 安徽省众望科希盟科技有限公司 聚四氟乙烯及其制备方法、膨化聚四氟乙烯及其应用

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CN1097770A (zh) * 1993-04-29 1995-01-25 黑蒙特股份公司 具有高熔融流动速率值和窄分子量分布的结晶丙烯聚合物
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CN1147523A (zh) * 1995-06-02 1997-04-16 智索公司 高立构规整性聚丙烯

Also Published As

Publication number Publication date
NL2011695A (en) 2014-05-01
US10301405B2 (en) 2019-05-28
US20140121339A1 (en) 2014-05-01
BE1022317B1 (fr) 2016-03-15
KR20140056092A (ko) 2014-05-09
BR102013027916B1 (pt) 2020-05-19
ITMI20131794A1 (it) 2014-05-01
JP2014145072A (ja) 2014-08-14
NL2011695C2 (en) 2015-04-01
TWI626251B (zh) 2018-06-11
KR101761843B1 (ko) 2017-08-04
TW201425346A (zh) 2014-07-01
CN103788259A (zh) 2014-05-14
BR102013027916A2 (pt) 2014-10-21
JP6209056B2 (ja) 2017-10-04
ZA201308088B (en) 2014-07-30
DE102013221844A1 (de) 2014-04-30

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