CN102906059B - 用于由c4提余液流产生叔-丁基苯酚的方法 - Google Patents

用于由c4提余液流产生叔-丁基苯酚的方法 Download PDF

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Publication number
CN102906059B
CN102906059B CN201080054733.3A CN201080054733A CN102906059B CN 102906059 B CN102906059 B CN 102906059B CN 201080054733 A CN201080054733 A CN 201080054733A CN 102906059 B CN102906059 B CN 102906059B
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China
Prior art keywords
tert
phenol
reaction
butylphenol
butylene
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Expired - Fee Related
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CN201080054733.3A
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English (en)
Chinese (zh)
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CN102906059A (zh
Inventor
罗杰·J·德索萨
斯科特·D·史密斯
基尔蒂瓦桑·纳贾拉简
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SI Group Inc
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SI Group Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
    • C07C37/88—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/06—Alkylated phenols

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201080054733.3A 2009-12-04 2010-12-03 用于由c4提余液流产生叔-丁基苯酚的方法 Expired - Fee Related CN102906059B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US26682809P 2009-12-04 2009-12-04
US61/266,828 2009-12-04
PCT/US2010/058866 WO2011069052A2 (en) 2009-12-04 2010-12-03 Process for producing a t-butyl phenol from a c4 raffinate stream

Publications (2)

Publication Number Publication Date
CN102906059A CN102906059A (zh) 2013-01-30
CN102906059B true CN102906059B (zh) 2015-09-23

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CN201080054733.3A Expired - Fee Related CN102906059B (zh) 2009-12-04 2010-12-03 用于由c4提余液流产生叔-丁基苯酚的方法

Country Status (14)

Country Link
US (1) US8937201B2 (enExample)
EP (2) EP2521706A2 (enExample)
JP (2) JP5851415B2 (enExample)
KR (1) KR101822607B1 (enExample)
CN (1) CN102906059B (enExample)
BR (1) BR112012013419C8 (enExample)
ES (1) ES2647102T3 (enExample)
PL (1) PL2657217T3 (enExample)
PT (1) PT2657217T (enExample)
RU (1) RU2606130C2 (enExample)
SA (1) SA110310888B1 (enExample)
SG (1) SG181078A1 (enExample)
TW (2) TWI624450B (enExample)
WO (1) WO2011069052A2 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9932436B2 (en) 2013-10-17 2018-04-03 Si Group, Inc. Modified alkylphenol-aldehyde resins stabilized by a salicylic acid
WO2015057879A1 (en) 2013-10-17 2015-04-23 Si Group, Inc. In-situ alkylphenol-aldehyde resins
WO2015094571A1 (en) * 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Phenol composition
US9434668B1 (en) 2015-04-09 2016-09-06 Council Of Scientific And Industrial Research Process for the production of tertiary butyl phenols
CN108026010A (zh) * 2015-09-11 2018-05-11 巴斯夫欧洲公司 用于酚的烷基化的方法
CN106975517A (zh) * 2017-05-16 2017-07-25 同济大学 一种绿色高效合成2,4‑二叔丁基苯酚的多相催化剂
CN113636916B (zh) * 2021-09-17 2023-08-29 陕西万汇能聚科技有限公司 一种合成2,4,6-三叔丁基苯酚的方法

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US2430190A (en) * 1943-08-30 1947-11-04 Universal Oil Prod Co Alkylation of phenols
GB655124A (en) 1948-06-16 1951-07-11 Standard Oil Dev Co Improvements in or relating to the preparation of poly-tert-butyl phenol or cresols
US3670030A (en) * 1970-02-20 1972-06-13 Universal Oil Prod Co Alkylation of phenolic compound
US3751509A (en) * 1972-07-17 1973-08-07 A Liakumovich Process for isolating isobutylene from butane-butylene fraction
SU783297A1 (ru) * 1976-08-11 1980-11-30 Стерлитамакский опытно-промышленный нефтехимический завод Способ получени 2,6-ди-третбутилфенола
US4166191A (en) 1976-09-20 1979-08-28 Hitachi Chemical Company, Ltd. Process for producing highly pure p-tertiary-butyl phenol
DE2745589C3 (de) * 1977-10-11 1980-03-27 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von p-Alkylphenolen
JPS6052688B2 (ja) 1977-11-18 1985-11-20 三井化学株式会社 フエノ−ルのアルキル化方法
US4260833A (en) 1979-11-30 1981-04-07 Uop Inc. Preparation of alkylphenols
JPS6052732B2 (ja) 1980-12-05 1985-11-21 三井化学株式会社 ２，６−ジ−ｔ−ブチルフエノ−ルの製造方法
JPS5852234A (ja) * 1981-09-21 1983-03-28 Yotsukaichi Gosei Kk パラタ−シヤリプチルフエノ−ルの製造法
JPS61200934A (ja) * 1985-03-02 1986-09-05 Maruzen Sekiyu Kagaku Kk ｔｅｒｔ―ブチルフエノール類の製造方法
US4631349A (en) * 1985-06-25 1986-12-23 Ethyl Corporation Heterogeneous catalyst process
JPH07108870B2 (ja) 1986-12-23 1995-11-22 三井石油化学工業株式会社 ２，４−ジ−ｔ−ブチルフエノ−ルの製造方法
US4731492A (en) * 1987-03-04 1988-03-15 Ethyl Corporation Phenol alkylation process
DE3941472C1 (enExample) * 1989-12-15 1991-02-21 Huels Ag, 4370 Marl, De
CS276820B6 (cs) * 1990-05-28 1992-08-12 Slovenska Technicke Univerzita Sposob alkylácie a/alebo arylalkylácie fenolu a/alebo jeho derivátov
DE4139056A1 (de) * 1991-11-28 1993-06-03 Huels Chemische Werke Ag Verfahren zur herstellung von ortho-substituierten alkylphenolen und katalysator hierfuer
JPH05294865A (ja) * 1992-04-15 1993-11-09 Dainippon Ink & Chem Inc ２，４−ジ（ｔ−ブチル）フェノールの製法
BR9202890A (pt) 1992-07-22 1994-02-01 Rhodia Aperfeicoamento em processo para obtencao de terciobutilfenois
ES2190228T5 (es) * 1998-09-03 2007-10-16 Crompton Corporation Purificacion de 2,4,6-tri-(ter.-butil)fenol por cristalizacion-fusion.
RU2164509C1 (ru) * 1999-08-06 2001-03-27 ООО "Синтезхим Бис" Способ получения 2,6-ди-трет-бутил-фенола
JP2002241334A (ja) * 2001-02-15 2002-08-28 Sumitomo Chem Co Ltd ｔｅｒｔ−ブチルフェノール類の製造方法
CN1844071A (zh) * 2006-03-24 2006-10-11 北京极易化工有限公司 一种高转化率高选择性的苯酚邻位烷基化方法
CN1935763A (zh) * 2006-10-20 2007-03-28 上海金海雅宝精细化工有限公司 一种2.4－二叔丁基苯酚烷化液的制备方法
CN101092331A (zh) * 2007-07-06 2007-12-26 宁波金海雅宝化工有限公司 一种固定床合成烷基酚的方法

Also Published As

Publication number Publication date
TWI624450B (zh) 2018-05-21
KR20120125234A (ko) 2012-11-14
WO2011069052A2 (en) 2011-06-09
JP5851415B2 (ja) 2016-02-03
JP2013512925A (ja) 2013-04-18
SG181078A1 (en) 2012-07-30
ES2647102T3 (es) 2017-12-19
EP2657217B1 (en) 2017-09-06
RU2606130C2 (ru) 2017-01-10
BR112012013419C8 (pt) 2019-09-03
CN102906059A (zh) 2013-01-30
SA110310888B1 (ar) 2014-06-18
JP2015221838A (ja) 2015-12-10
EP2657217A2 (en) 2013-10-30
BR112012013419B8 (pt) 2019-08-20
RU2012127805A (ru) 2014-01-10
TW201136882A (en) 2011-11-01
KR101822607B1 (ko) 2018-01-26
BR112012013419A2 (pt) 2017-03-21
EP2657217A3 (en) 2014-04-02
BR112012013419B1 (pt) 2018-10-09
PL2657217T3 (pl) 2018-01-31
US8937201B2 (en) 2015-01-20
TW201700445A (zh) 2017-01-01
US20130150629A1 (en) 2013-06-13
TWI570102B (zh) 2017-02-11
WO2011069052A3 (en) 2011-11-17
EP2521706A2 (en) 2012-11-14
PT2657217T (pt) 2017-11-02

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