CN100387385C - 金刚石膜被覆工具 - Google Patents
金刚石膜被覆工具 Download PDFInfo
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- CN100387385C CN100387385C CNB2003801104120A CN200380110412A CN100387385C CN 100387385 C CN100387385 C CN 100387385C CN B2003801104120 A CNB2003801104120 A CN B2003801104120A CN 200380110412 A CN200380110412 A CN 200380110412A CN 100387385 C CN100387385 C CN 100387385C
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- Prior art keywords
- diamond film
- diamond
- base material
- coated tool
- phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910003460 diamond Inorganic materials 0.000 title claims abstract description 370
- 239000010432 diamond Substances 0.000 title claims abstract description 370
- 238000000034 method Methods 0.000 title abstract description 35
- 230000008569 process Effects 0.000 title description 7
- 239000000758 substrate Substances 0.000 claims abstract description 40
- 230000003746 surface roughness Effects 0.000 claims abstract description 37
- 239000011195 cermet Substances 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims description 122
- 239000002245 particle Substances 0.000 claims description 80
- 229910045601 alloy Inorganic materials 0.000 claims description 51
- 239000000956 alloy Substances 0.000 claims description 51
- 229910001573 adamantine Inorganic materials 0.000 claims description 46
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 claims description 45
- 229910052739 hydrogen Inorganic materials 0.000 claims description 34
- 239000001257 hydrogen Substances 0.000 claims description 34
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 22
- 230000005415 magnetization Effects 0.000 claims description 19
- 229920006395 saturated elastomer Polymers 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 238000001069 Raman spectroscopy Methods 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 7
- 238000002441 X-ray diffraction Methods 0.000 claims description 6
- 238000010183 spectrum analysis Methods 0.000 claims description 6
- 244000050510 Cunninghamia lanceolata Species 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 abstract description 59
- 238000005255 carburizing Methods 0.000 abstract description 21
- 239000011248 coating agent Substances 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 7
- 239000012071 phase Substances 0.000 description 45
- 238000003754 machining Methods 0.000 description 29
- 230000015572 biosynthetic process Effects 0.000 description 19
- 238000004519 manufacturing process Methods 0.000 description 19
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 238000002425 crystallisation Methods 0.000 description 16
- 230000008025 crystallization Effects 0.000 description 16
- 238000004050 hot filament vapor deposition Methods 0.000 description 16
- 238000001000 micrograph Methods 0.000 description 14
- 238000012545 processing Methods 0.000 description 14
- 238000005452 bending Methods 0.000 description 12
- 239000002173 cutting fluid Substances 0.000 description 12
- 238000000227 grinding Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- 239000011435 rock Substances 0.000 description 10
- 239000000523 sample Substances 0.000 description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000010306 acid treatment Methods 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 238000005530 etching Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 229910000551 Silumin Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 235000013495 cobalt Nutrition 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- -1 iron group metals Chemical class 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 239000011164 primary particle Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 229910000861 Mg alloy Inorganic materials 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000001020 plasma etching Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004215 Carbon black (E152) Chemical class 0.000 description 1
- 240000007762 Ficus drupacea Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000001237 Raman spectrum Methods 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005307 ferromagnetism Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 229930195733 hydrocarbon Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000004446 light reflex Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
- B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
- C23C16/27—Diamond only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
- B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
- B23B27/18—Cutting tools of which the bits or tips or cutting inserts are of special material with cutting bits or tips or cutting inserts rigidly mounted, e.g. by brazing
- B23B27/20—Cutting tools of which the bits or tips or cutting inserts are of special material with cutting bits or tips or cutting inserts rigidly mounted, e.g. by brazing with diamond bits or cutting inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23G—THREAD CUTTING; WORKING OF SCREWS, BOLT HEADS, OR NUTS, IN CONJUNCTION THEREWITH
- B23G5/00—Thread-cutting tools; Die-heads
- B23G5/02—Thread-cutting tools; Die-heads without means for adjustment
- B23G5/06—Taps
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0209—Pretreatment of the material to be coated by heating
- C23C16/0218—Pretreatment of the material to be coated by heating in a reactive atmosphere
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23G—THREAD CUTTING; WORKING OF SCREWS, BOLT HEADS, OR NUTS, IN CONJUNCTION THEREWITH
- B23G2200/00—Details of threading tools
- B23G2200/26—Coatings of tools
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23G—THREAD CUTTING; WORKING OF SCREWS, BOLT HEADS, OR NUTS, IN CONJUNCTION THEREWITH
- B23G2225/00—Materials of threading tools, workpieces or other structural elements
- B23G2225/08—Cermets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23G—THREAD CUTTING; WORKING OF SCREWS, BOLT HEADS, OR NUTS, IN CONJUNCTION THEREWITH
- B23G2225/00—Materials of threading tools, workpieces or other structural elements
- B23G2225/16—Diamond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23G—THREAD CUTTING; WORKING OF SCREWS, BOLT HEADS, OR NUTS, IN CONJUNCTION THEREWITH
- B23G2225/00—Materials of threading tools, workpieces or other structural elements
- B23G2225/28—Hard metal, i.e. cemented carbides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Chemical Vapour Deposition (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
Description
试验品No. | 膜平均粗糙度Ra(μm) | 起伏h(nm) | 加工表面粗糙度Rmax(μm) | 寿命 |
1(比较例) | 0.005 | 30 | 7.85 | 3000m以上 |
2(本发明) | 0.01 | 50 | 3.21 | 3000m以上 |
3(本发明) | 0.07 | 300 | 1.71 | 3000m以上 |
4(本发明) | 0.18 | 900 | 3.51 | 3000m以上 |
5(比较例) | 0.28 | 1200 | 8.20 | 3000m以上 |
6(比较例) | 0.35 | 1500 | 11.55 | 3000m以上 |
试验品No. | 膜平均粗糙度Ra(μm) | RMS(nm) | 起伏h(nm) | 加工表面粗糙度Rmax(μm) | 寿命 |
7(本发明) | 0.01 | 10 | 61 | 3.13 | 3000m以上 |
8(本发明) | 0.01 | 15 | 62 | 2.80 | 3000m以上 |
9(本发明) | 0.13 | 100 | 540 | 1.80 | 3000m以上 |
10(本发明) | 0.18 | 200 | 892 | 2.95 | 3000m以上 |
11(本发明) | 0.19 | 300 | 897 | 3.45 | 3000m以上 |
试验品No. | 氢含量(at%) | 起伏h(nm) | RMS(nm) | 加工表面粗糙度Rmax(μm) | 加工3000m后的状态 |
12(本发明) | 0.2 | 683 | 99 | 3.8 | 一处发生崩刃 |
13(本发明) | 1.0 | 670 | 88 | 2.5 | 没有问题 |
14(本发明) | 5.0 | 674 | 95 | 2.8 | 没有问题 |
15(本发明) | 6.0 | 665 | 85 | 3.3 | 膜有若干磨损 |
试验品No. | 结合相少的部分的厚度(μm) | 起伏h(nm) | RMS(nm) | 寿命 |
16(本发明) | 0 | 550 | 120 | 500个孔以上 |
17(本发明) | 10 | 535 | 97 | 500个孔以上 |
18(本发明) | 20 | 562 | 128 | 500个孔以上 |
19(本发明) | 30 | 544 | 118 | 500个孔以上(一处有崩刃) |
20(本发明) | 40 | 540 | 114 | 500个孔以上(三处有崩刃) |
试验品No. | 起伏(nm) | 颗粒直径(μm) | 氢含量(at%) | RMS(nm) | 切削阻力(N) | 脱落数量(个) | 熔敷厚度(μm) |
21(本发明) | 680 | 0.5~0.8 | 0.2 | 97 | 6 | 1 | 0 |
22(本发明) | 670 | 0.5~0.8 | 1.5 | 95 | 6 | 0 | 0 |
23(本发明) | 690 | 0.5~0.8 | 1.5 | 101 | 6 | 0 | 0 |
24(比较例) | 无 | 0.5~0.8 | 0 | 120 | 9 | 3 | 0 |
25(比较例) | 无 | 10~12 | 0 | 396 | 10 | 4 | 1 |
26(比较例) | 无 | 10~12 | 0 | 405 | 16 | 8 | 5 |
Claims (16)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003283835 | 2003-07-31 | ||
JP283835/2003 | 2003-07-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1819885A CN1819885A (zh) | 2006-08-16 |
CN100387385C true CN100387385C (zh) | 2008-05-14 |
Family
ID=34113820
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003801104120A Expired - Fee Related CN100387385C (zh) | 2003-07-31 | 2003-11-12 | 金刚石膜被覆工具 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7883775B2 (zh) |
EP (1) | EP1649955B1 (zh) |
JP (1) | JP4420901B2 (zh) |
KR (1) | KR101065572B1 (zh) |
CN (1) | CN100387385C (zh) |
AU (1) | AU2003280758A1 (zh) |
HK (1) | HK1091435A1 (zh) |
MY (1) | MY138872A (zh) |
TW (1) | TWI268192B (zh) |
WO (1) | WO2005011902A1 (zh) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006088315A (ja) * | 2004-08-24 | 2006-04-06 | Shapton Kk | 砥石修正器、砥石の製造方法および砥石修正器、砥石 |
JP4825490B2 (ja) * | 2004-10-14 | 2011-11-30 | 住友電気工業株式会社 | ダイヤモンド膜被覆部材の製造方法 |
GB2434771B (en) * | 2006-02-02 | 2011-11-30 | Bencere Ltd | A Cutting Insert |
US8404313B1 (en) * | 2006-03-22 | 2013-03-26 | University Of South Florida | Synthesis of nanocrystalline diamond fibers |
EP1944110B1 (de) * | 2007-01-15 | 2012-11-07 | Fraisa Holding AG | Verfahren zur Behandlung und Bearbeitung von Werkzeugen zur spanabhebenden Bearbeitung von Werkstücken |
GB0700984D0 (en) | 2007-01-18 | 2007-02-28 | Element Six Ltd | Polycrystalline diamond elements having convex surfaces |
JP2010524710A (ja) * | 2007-04-27 | 2010-07-22 | デグテック エルティーディー | コーティングされた超硬合金切削工具とその製造のための前処理及びコーティング方法 |
US20090214826A1 (en) * | 2008-01-04 | 2009-08-27 | Charles West | Controlling diamond film surfaces |
FR2930423B1 (fr) * | 2008-04-25 | 2010-05-07 | Gerard Scortecci | Dispositif pour la regeneration osseuse |
JP5488873B2 (ja) * | 2009-07-13 | 2014-05-14 | 三菱マテリアル株式会社 | 耐欠損性と耐摩耗性にすぐれたダイヤモンド被覆工具 |
US8715789B2 (en) * | 2009-12-18 | 2014-05-06 | Sub-One Technology, Inc. | Chemical vapor deposition for an interior of a hollow article with high aspect ratio |
JP5459504B2 (ja) * | 2010-07-16 | 2014-04-02 | 三菱マテリアル株式会社 | ダイヤモンド被覆切削工具 |
GB2482151A (en) * | 2010-07-21 | 2012-01-25 | Element Six Production Pty Ltd | Method of making a superhard construction |
JP5553013B2 (ja) * | 2010-11-25 | 2014-07-16 | 三菱マテリアル株式会社 | 硬質難削材の高速高送り切削加工で硬質被覆層がすぐれた耐剥離性とすぐれた耐チッピング性を発揮する表面被覆切削工具 |
US20120251256A1 (en) * | 2011-04-04 | 2012-10-04 | GM Global Technology Operations LLC | Cutting tool for control of surface roughness |
JP5966564B2 (ja) * | 2011-06-08 | 2016-08-10 | 三星ダイヤモンド工業株式会社 | スクライビングホイール及びスクライブ方法 |
CN103765330B (zh) * | 2011-07-21 | 2019-01-29 | 斯沃奇集团研究和开发有限公司 | 功能性微机械组件 |
JP5915346B2 (ja) * | 2012-04-13 | 2016-05-11 | 三星ダイヤモンド工業株式会社 | スクライビングホイール |
JP2013233793A (ja) * | 2012-04-13 | 2013-11-21 | Mitsuboshi Diamond Industrial Co Ltd | スクライビングホイール及びその製造方法 |
JP5536143B2 (ja) * | 2012-06-07 | 2014-07-02 | ユニオンツール株式会社 | 切削工具用ダイヤモンド皮膜 |
JP6040698B2 (ja) * | 2012-10-17 | 2016-12-07 | 三菱マテリアル株式会社 | ダイヤモンド被覆超硬合金製ドリル |
TWI490064B (zh) * | 2012-12-11 | 2015-07-01 | Nat Univ Tsing Hua | 微型鑽頭及其製備方法 |
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- 2003-11-12 US US10/566,633 patent/US7883775B2/en active Active
- 2003-11-12 KR KR1020067001999A patent/KR101065572B1/ko active IP Right Grant
- 2003-11-12 AU AU2003280758A patent/AU2003280758A1/en not_active Abandoned
- 2003-11-12 EP EP03772725.2A patent/EP1649955B1/en not_active Expired - Lifetime
- 2003-11-12 CN CNB2003801104120A patent/CN100387385C/zh not_active Expired - Fee Related
- 2003-11-13 TW TW092131808A patent/TWI268192B/zh not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
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JPWO2005011902A1 (ja) | 2006-09-14 |
CN1819885A (zh) | 2006-08-16 |
TWI268192B (en) | 2006-12-11 |
US7883775B2 (en) | 2011-02-08 |
MY138872A (en) | 2009-08-28 |
EP1649955B1 (en) | 2013-08-14 |
AU2003280758A1 (en) | 2005-02-15 |
KR20060109868A (ko) | 2006-10-23 |
EP1649955A4 (en) | 2009-10-21 |
JP4420901B2 (ja) | 2010-02-24 |
TW200503873A (en) | 2005-02-01 |
EP1649955A1 (en) | 2006-04-26 |
KR101065572B1 (ko) | 2011-09-19 |
HK1091435A1 (en) | 2007-01-19 |
US20060216515A1 (en) | 2006-09-28 |
WO2005011902A1 (ja) | 2005-02-10 |
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