CA2832881A1 - Electrolyte non-aqueux, et dispositif d'accumulateur mettant en uvre celui-ci - Google Patents
Electrolyte non-aqueux, et dispositif d'accumulateur mettant en uvre celui-ci Download PDFInfo
- Publication number
- CA2832881A1 CA2832881A1 CA2832881A CA2832881A CA2832881A1 CA 2832881 A1 CA2832881 A1 CA 2832881A1 CA 2832881 A CA2832881 A CA 2832881A CA 2832881 A CA2832881 A CA 2832881A CA 2832881 A1 CA2832881 A1 CA 2832881A1
- Authority
- CA
- Canada
- Prior art keywords
- group
- carbon atoms
- acetate
- propynyl
- diethoxyphosphoryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000011255 nonaqueous electrolyte Substances 0.000 title abstract description 5
- 238000003860 storage Methods 0.000 title abstract description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 46
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 42
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 40
- 125000005843 halogen group Chemical group 0.000 claims abstract description 33
- 150000002903 organophosphorus compounds Chemical group 0.000 claims abstract description 28
- 125000005133 alkynyloxy group Chemical group 0.000 claims abstract description 27
- 125000004104 aryloxy group Chemical group 0.000 claims abstract description 22
- 125000000304 alkynyl group Chemical group 0.000 claims abstract description 15
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 9
- 125000003302 alkenyloxy group Chemical group 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 125000000000 cycloalkoxy group Chemical group 0.000 claims abstract description 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 180
- -1 2- (2- (diethoxyphosphoryl) acetoxy) ethyl methyl Chemical group 0.000 claims description 169
- 239000008151 electrolyte solution Substances 0.000 claims description 86
- 229910052744 lithium Inorganic materials 0.000 claims description 76
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 70
- 239000002904 solvent Substances 0.000 claims description 54
- 150000001875 compounds Chemical class 0.000 claims description 46
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims description 42
- 238000004146 energy storage Methods 0.000 claims description 31
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 29
- 150000003839 salts Chemical class 0.000 claims description 25
- 239000003792 electrolyte Substances 0.000 claims description 23
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 22
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 22
- 150000005676 cyclic carbonates Chemical class 0.000 claims description 19
- 125000004122 cyclic group Chemical group 0.000 claims description 17
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 15
- 239000007774 positive electrode material Substances 0.000 claims description 15
- 125000002947 alkylene group Chemical group 0.000 claims description 14
- 229910019142 PO4 Inorganic materials 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 13
- 235000021317 phosphate Nutrition 0.000 claims description 13
- 125000004419 alkynylene group Chemical group 0.000 claims description 11
- 239000007773 negative electrode material Substances 0.000 claims description 11
- 239000003575 carbonaceous material Substances 0.000 claims description 10
- 150000002825 nitriles Chemical class 0.000 claims description 9
- 229910001290 LiPF6 Inorganic materials 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- 239000003125 aqueous solvent Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- BYXGTJQWDSWRAG-UHFFFAOYSA-N prop-2-ynyl 2-diethoxyphosphorylacetate Chemical compound CCOP(=O)(OCC)CC(=O)OCC#C BYXGTJQWDSWRAG-UHFFFAOYSA-N 0.000 claims description 8
- BJWMSGRKJIOCNR-UHFFFAOYSA-N 4-ethenyl-1,3-dioxolan-2-one Chemical compound C=CC1COC(=O)O1 BJWMSGRKJIOCNR-UHFFFAOYSA-N 0.000 claims description 7
- 125000004438 haloalkoxy group Chemical group 0.000 claims description 7
- 125000001188 haloalkyl group Chemical group 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 6
- FSSPGSAQUIYDCN-UHFFFAOYSA-N 1,3-Propane sultone Chemical compound O=S1(=O)CCCO1 FSSPGSAQUIYDCN-UHFFFAOYSA-N 0.000 claims description 5
- 229910013131 LiN Inorganic materials 0.000 claims description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 5
- WQLCJLXSTLPQKJ-UHFFFAOYSA-N 2-methoxyethyl 2-diethoxyphosphorylacetate Chemical compound CCOP(=O)(OCC)CC(=O)OCCOC WQLCJLXSTLPQKJ-UHFFFAOYSA-N 0.000 claims description 4
- GNZAXMBWARXJMR-UHFFFAOYSA-N 2-o-(diethoxyphosphorylmethyl) 1-o-methyl oxalate Chemical compound CCOP(=O)(OCC)COC(=O)C(=O)OC GNZAXMBWARXJMR-UHFFFAOYSA-N 0.000 claims description 4
- AJGHXRXYVGIBCZ-UHFFFAOYSA-N [4-(trifluoromethyl)phenyl] 2-diethoxyphosphorylacetate Chemical compound CCOP(=O)(OCC)CC(=O)OC1=CC=C(C(F)(F)F)C=C1 AJGHXRXYVGIBCZ-UHFFFAOYSA-N 0.000 claims description 4
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 claims description 4
- WGVJYHMLXFOKSR-UHFFFAOYSA-N bis(dimethoxyphosphorylmethyl) oxalate Chemical compound COP(=O)(OC)COC(=O)C(=O)OCP(=O)(OC)OC WGVJYHMLXFOKSR-UHFFFAOYSA-N 0.000 claims description 4
- URWVQLWOBPHQCH-UHFFFAOYSA-N bis(prop-2-ynyl) oxalate Chemical compound C#CCOC(=O)C(=O)OCC#C URWVQLWOBPHQCH-UHFFFAOYSA-N 0.000 claims description 4
- VCWRFTAQTPXSDE-UHFFFAOYSA-N methyl 2-(2-oxo-1,3,2$l^{5}-dioxaphospholan-2-yl)acetate Chemical compound COC(=O)CP1(=O)OCCO1 VCWRFTAQTPXSDE-UHFFFAOYSA-N 0.000 claims description 4
- MHYFEEDKONKGEB-UHFFFAOYSA-N oxathiane 2,2-dioxide Chemical compound O=S1(=O)CCCCO1 MHYFEEDKONKGEB-UHFFFAOYSA-N 0.000 claims description 4
- VQKIWLNIHMMIDY-UHFFFAOYSA-N prop-2-ynyl 2-[ethoxy(ethyl)phosphoryl]acetate Chemical compound CCOP(=O)(CC)CC(=O)OCC#C VQKIWLNIHMMIDY-UHFFFAOYSA-N 0.000 claims description 4
- YVLDELCWFQPLPY-UHFFFAOYSA-N prop-2-ynyl 2-diethylphosphorylacetate Chemical compound CCP(=O)(CC)CC(=O)OCC#C YVLDELCWFQPLPY-UHFFFAOYSA-N 0.000 claims description 4
- KYYYJXMPEQXVJW-UHFFFAOYSA-N prop-2-ynyl 2-dimethoxyphosphorylacetate Chemical compound COP(=O)(OC)CC(=O)OCC#C KYYYJXMPEQXVJW-UHFFFAOYSA-N 0.000 claims description 4
- HGYGYVBJMDIPOP-UHFFFAOYSA-N prop-2-ynyl 2-diphenoxyphosphorylacetate Chemical compound C=1C=CC=CC=1OP(=O)(CC(=O)OCC#C)OC1=CC=CC=C1 HGYGYVBJMDIPOP-UHFFFAOYSA-N 0.000 claims description 4
- RIWMCTIKXDCICQ-UHFFFAOYSA-N prop-2-ynyl 3-diethoxyphosphorylpropanoate Chemical compound CCOP(=O)(OCC)CCC(=O)OCC#C RIWMCTIKXDCICQ-UHFFFAOYSA-N 0.000 claims description 4
- OWAHJGWVERXJMI-UHFFFAOYSA-N prop-2-ynyl methanesulfonate Chemical compound CS(=O)(=O)OCC#C OWAHJGWVERXJMI-UHFFFAOYSA-N 0.000 claims description 4
- WDXYVJKNSMILOQ-UHFFFAOYSA-N 1,3,2-dioxathiolane 2-oxide Chemical compound O=S1OCCO1 WDXYVJKNSMILOQ-UHFFFAOYSA-N 0.000 claims description 3
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 3
- VWEYDBUEGDKEHC-UHFFFAOYSA-N 3-methyloxathiolane 2,2-dioxide Chemical compound CC1CCOS1(=O)=O VWEYDBUEGDKEHC-UHFFFAOYSA-N 0.000 claims description 3
- IXDCVDJIUNKASO-UHFFFAOYSA-N 4-(methylsulfonylmethyl)-1,3,2-dioxathiolane 2-oxide Chemical compound CS(=O)(=O)CC1COS(=O)O1 IXDCVDJIUNKASO-UHFFFAOYSA-N 0.000 claims description 3
- RAEHYISCRHEVNT-UHFFFAOYSA-N 5-methyloxathiolane 2,2-dioxide Chemical compound CC1CCS(=O)(=O)O1 RAEHYISCRHEVNT-UHFFFAOYSA-N 0.000 claims description 3
- 229910000733 Li alloy Inorganic materials 0.000 claims description 3
- 229910013528 LiN(SO2 CF3)2 Inorganic materials 0.000 claims description 3
- INBQQOBOENPBBJ-UHFFFAOYSA-N [2-(trifluoromethyl)phenyl] 2-diethoxyphosphorylacetate Chemical compound CCOP(=O)(OCC)CC(=O)OC1=CC=CC=C1C(F)(F)F INBQQOBOENPBBJ-UHFFFAOYSA-N 0.000 claims description 3
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 3
- CZLPVLQKBGARAQ-UHFFFAOYSA-N bis(diethoxyphosphorylmethyl) oxalate Chemical compound CCOP(=O)(OCC)COC(=O)C(=O)OCP(=O)(OCC)OCC CZLPVLQKBGARAQ-UHFFFAOYSA-N 0.000 claims description 3
- WVSJSWSJDJHGNS-UHFFFAOYSA-N but-3-yn-2-yl 2-diethoxyphosphorylacetate Chemical compound CCOP(=O)(OCC)CC(=O)OC(C)C#C WVSJSWSJDJHGNS-UHFFFAOYSA-N 0.000 claims description 3
- ZTOMUSMDRMJOTH-UHFFFAOYSA-N glutaronitrile Chemical compound N#CCCCC#N ZTOMUSMDRMJOTH-UHFFFAOYSA-N 0.000 claims description 3
- LLEVMYXEJUDBTA-UHFFFAOYSA-N heptanedinitrile Chemical compound N#CCCCCCC#N LLEVMYXEJUDBTA-UHFFFAOYSA-N 0.000 claims description 3
- 239000001989 lithium alloy Substances 0.000 claims description 3
- IAHFWCOBPZCAEA-UHFFFAOYSA-N succinonitrile Chemical compound N#CCCC#N IAHFWCOBPZCAEA-UHFFFAOYSA-N 0.000 claims description 3
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 claims description 2
- LWLOKSXSAUHTJO-UHFFFAOYSA-N 4,5-dimethyl-1,3-dioxolan-2-one Chemical compound CC1OC(=O)OC1C LWLOKSXSAUHTJO-UHFFFAOYSA-N 0.000 claims description 2
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 claims description 2
- 229910006095 SO2F Inorganic materials 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- OBVPIEWBEVJXIF-UHFFFAOYSA-N 2-(2-diethoxyphosphorylacetyl)oxyethyl 2-diethoxyphosphorylacetate Chemical compound CCOP(=O)(OCC)CC(=O)OCCOC(=O)CP(=O)(OCC)OCC OBVPIEWBEVJXIF-UHFFFAOYSA-N 0.000 claims 1
- BBZJNBHYWMQDPF-UHFFFAOYSA-N 2-methylbut-3-yn-2-yl 2-diethoxyphosphorylacetate Chemical compound CCOP(=O)(OCC)CC(=O)OC(C)(C)C#C BBZJNBHYWMQDPF-UHFFFAOYSA-N 0.000 claims 1
- PWXXZRVGRZPUFN-UHFFFAOYSA-N 4-(2-diethoxyphosphorylacetyl)oxybut-2-ynyl 2-diethoxyphosphorylacetate Chemical compound CCOP(=O)(OCC)CC(=O)OCC#CCOC(=O)CP(=O)(OCC)OCC PWXXZRVGRZPUFN-UHFFFAOYSA-N 0.000 claims 1
- UGPGBZBAORCFNA-UHFFFAOYSA-N 4-methylsulfonyloxybut-2-ynyl methanesulfonate Chemical compound CS(=O)(=O)OCC#CCOS(C)(=O)=O UGPGBZBAORCFNA-UHFFFAOYSA-N 0.000 claims 1
- 229910008963 Li2PO3F Inorganic materials 0.000 claims 1
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- OZYDNCPMANHAFX-UHFFFAOYSA-N prop-2-ynyl 2-diethoxyphosphoryl-2-fluoroacetate Chemical compound CCOP(=O)(OCC)C(F)C(=O)OCC#C OZYDNCPMANHAFX-UHFFFAOYSA-N 0.000 claims 1
- 125000002521 alkyl halide group Chemical group 0.000 abstract 1
- 229910013916 LiPF6 + 0.05M Inorganic materials 0.000 description 40
- 238000000034 method Methods 0.000 description 38
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 37
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- 238000006243 chemical reaction Methods 0.000 description 35
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 34
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 28
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- 125000001424 substituent group Chemical group 0.000 description 14
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- 230000015572 biosynthetic process Effects 0.000 description 13
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 13
- 229910003002 lithium salt Inorganic materials 0.000 description 13
- 159000000002 lithium salts Chemical class 0.000 description 13
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- QRYYNNMBUMOQKO-UHFFFAOYSA-N dimethoxyphosphorylmethyl 2-methoxyethyl carbonate Chemical compound COCCOC(=O)OCP(=O)(OC)OC QRYYNNMBUMOQKO-UHFFFAOYSA-N 0.000 description 1
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- BSCHYGNXICZUFP-UHFFFAOYSA-N prop-2-ynyl 2-diphenylphosphorylpropanoate Chemical compound C=1C=CC=CC=1P(=O)(C(C(=O)OCC#C)C)C1=CC=CC=C1 BSCHYGNXICZUFP-UHFFFAOYSA-N 0.000 description 1
- GVTHGNJTJKXMOM-UHFFFAOYSA-N prop-2-ynyl 2-dipropoxyphosphorylacetate Chemical compound CCCOP(=O)(OCCC)CC(=O)OCC#C GVTHGNJTJKXMOM-UHFFFAOYSA-N 0.000 description 1
- BNBLWMNHYFUJJN-UHFFFAOYSA-N prop-2-ynyl 3-[ethoxy(ethyl)phosphoryl]propanoate Chemical compound CCOP(=O)(CC)CCC(=O)OCC#C BNBLWMNHYFUJJN-UHFFFAOYSA-N 0.000 description 1
- ZIZRBNVHQYMYFU-UHFFFAOYSA-N prop-2-ynyl 3-[methoxy(methyl)phosphoryl]propanoate Chemical compound COP(C)(=O)CCC(=O)OCC#C ZIZRBNVHQYMYFU-UHFFFAOYSA-N 0.000 description 1
- HEHTUZFSYBGIMJ-UHFFFAOYSA-N prop-2-ynyl 3-diethylphosphorylpropanoate Chemical compound CCP(=O)(CC)CCC(=O)OCC#C HEHTUZFSYBGIMJ-UHFFFAOYSA-N 0.000 description 1
- XGFYYKUIECRIFY-UHFFFAOYSA-N prop-2-ynyl 3-dimethylphosphorylpropanoate Chemical compound CP(C)(=O)CCC(=O)OCC#C XGFYYKUIECRIFY-UHFFFAOYSA-N 0.000 description 1
- UENJZWRWTZAJAG-UHFFFAOYSA-N prop-2-ynyl 3-diphenoxyphosphorylpropanoate Chemical compound C=1C=CC=CC=1OP(=O)(CCC(=O)OCC#C)OC1=CC=CC=C1 UENJZWRWTZAJAG-UHFFFAOYSA-N 0.000 description 1
- PIVMLFYMIPCZHR-UHFFFAOYSA-N prop-2-ynyl 4-[ethoxy(ethyl)phosphoryl]butanoate Chemical compound CCOP(=O)(CC)CCCC(=O)OCC#C PIVMLFYMIPCZHR-UHFFFAOYSA-N 0.000 description 1
- AVBOQWMRVRWRRJ-UHFFFAOYSA-N prop-2-ynyl 4-[methoxy(methyl)phosphoryl]butanoate Chemical compound COP(C)(=O)CCCC(=O)OCC#C AVBOQWMRVRWRRJ-UHFFFAOYSA-N 0.000 description 1
- RCBMOQABWRCZFP-UHFFFAOYSA-N prop-2-ynyl 4-diethoxyphosphorylbutanoate Chemical compound CCOP(=O)(OCC)CCCC(=O)OCC#C RCBMOQABWRCZFP-UHFFFAOYSA-N 0.000 description 1
- XSORTFKQJQSNBD-UHFFFAOYSA-N prop-2-ynyl 4-diethylphosphorylbutanoate Chemical compound CCP(=O)(CC)CCCC(=O)OCC#C XSORTFKQJQSNBD-UHFFFAOYSA-N 0.000 description 1
- CSJOMYHBPNMYBT-UHFFFAOYSA-N prop-2-ynyl 4-dimethoxyphosphorylbutanoate Chemical compound COP(=O)(OC)CCCC(=O)OCC#C CSJOMYHBPNMYBT-UHFFFAOYSA-N 0.000 description 1
- IPCYRCMUVJQAFG-UHFFFAOYSA-N prop-2-ynyl 4-dimethylphosphorylbutanoate Chemical compound CP(C)(=O)CCCC(=O)OCC#C IPCYRCMUVJQAFG-UHFFFAOYSA-N 0.000 description 1
- YFWCKFNXAHPWCB-UHFFFAOYSA-N prop-2-ynyl 4-diphenoxyphosphorylbutanoate Chemical compound C=1C=CC=CC=1OP(=O)(CCCC(=O)OCC#C)OC1=CC=CC=C1 YFWCKFNXAHPWCB-UHFFFAOYSA-N 0.000 description 1
- JIWGCXYEEVLDGV-UHFFFAOYSA-N prop-2-ynyl 4-diphenylphosphorylbutanoate Chemical compound C=1C=CC=CC=1P(=O)(CCCC(=O)OCC#C)C1=CC=CC=C1 JIWGCXYEEVLDGV-UHFFFAOYSA-N 0.000 description 1
- RIZZXCJMFIGMON-UHFFFAOYSA-N prop-2-ynyl acetate Chemical compound CC(=O)OCC#C RIZZXCJMFIGMON-UHFFFAOYSA-N 0.000 description 1
- KDIDLLIMHZHOHO-UHFFFAOYSA-N prop-2-ynyl formate Chemical compound O=COCC#C KDIDLLIMHZHOHO-UHFFFAOYSA-N 0.000 description 1
- SONPRQOOFBLJPG-UHFFFAOYSA-N propane-2,2-disulfonic acid Chemical compound OS(=O)(=O)C(C)(C)S(O)(=O)=O SONPRQOOFBLJPG-UHFFFAOYSA-N 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- QMKUYPGVVVLYSR-UHFFFAOYSA-N propyl 2,2-dimethylpropanoate Chemical compound CCCOC(=O)C(C)(C)C QMKUYPGVVVLYSR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical class FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(II) oxide Inorganic materials [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5304—Acyclic saturated phosphine oxides or thioxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
- C07F9/657181—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and, at least, one ring oxygen atom being part of a (thio)phosphonic acid derivative
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/64—Liquid electrolytes characterised by additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/60—Liquid electrolytes characterised by the solvent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Organic Chemistry (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011-088035 | 2011-04-12 | ||
JP2011088035 | 2011-04-12 | ||
JP2011-151848 | 2011-07-08 | ||
JP2011151848 | 2011-07-08 | ||
JP2011-227319 | 2011-10-14 | ||
JP2011227319 | 2011-10-14 | ||
PCT/JP2012/060073 WO2012141270A1 (fr) | 2011-04-12 | 2012-04-12 | Électrolyte non-aqueux, et dispositif d'accumulateur mettant en œuvre celui-ci |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2832881A1 true CA2832881A1 (fr) | 2012-10-18 |
Family
ID=47009434
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2832881A Abandoned CA2832881A1 (fr) | 2011-04-12 | 2012-04-12 | Electrolyte non-aqueux, et dispositif d'accumulateur mettant en uvre celui-ci |
Country Status (9)
Country | Link |
---|---|
US (1) | US9384906B2 (fr) |
EP (1) | EP2698859B1 (fr) |
JP (2) | JP6032200B2 (fr) |
KR (1) | KR20140022832A (fr) |
CN (1) | CN103460495B (fr) |
BR (1) | BR112013026067A2 (fr) |
CA (1) | CA2832881A1 (fr) |
RU (1) | RU2013145681A (fr) |
WO (1) | WO2012141270A1 (fr) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5776422B2 (ja) * | 2011-08-02 | 2015-09-09 | 三菱化学株式会社 | 非水系電解液及びそれを用いた非水系電解液電池 |
RU2013145681A (ru) * | 2011-04-12 | 2015-05-20 | Убе Индастриз, Лтд. | Неводный раствор электролита и устройство хранения энергии, использующее данный раствор |
CN103959547B (zh) * | 2011-09-29 | 2016-10-26 | 日立麦克赛尔株式会社 | 锂二次电池 |
JP6137177B2 (ja) * | 2012-05-08 | 2017-05-31 | 宇部興産株式会社 | 非水電解液、それを用いた蓄電デバイス、及びジハロリン酸エステル化合物 |
KR20150039751A (ko) * | 2012-07-31 | 2015-04-13 | 우베 고산 가부시키가이샤 | 비수 전해액 및 그것을 이용한 축전 디바이스 |
WO2014030684A1 (fr) * | 2012-08-24 | 2014-02-27 | 宇部興産株式会社 | Solution d'électrolyte non aqueux et dispositif de stockage d'électricité utilisant celle-ci |
JP5913611B2 (ja) * | 2012-10-03 | 2016-04-27 | 日立マクセル株式会社 | 密閉型電池及びその製造方法 |
EP2797155B1 (fr) | 2013-02-20 | 2017-04-05 | Lg Chem, Ltd. | Électrolyte non aqueux et batterie rechargeable au lithium comprenant ce dernier |
TWI636603B (zh) * | 2013-02-20 | 2018-09-21 | Lg化學股份有限公司 | 用於鋰二次電池之電解質液添加劑及含有該添加劑之非水性液態電解質液池及鋰二次電池 |
JP6189644B2 (ja) * | 2013-05-30 | 2017-08-30 | トヨタ自動車株式会社 | 非水電解液二次電池の製造方法 |
JP6221632B2 (ja) * | 2013-10-29 | 2017-11-01 | 三菱ケミカル株式会社 | 非水系電解液及びそれを用いた非水系電解液電池 |
JP6191395B2 (ja) * | 2013-10-29 | 2017-09-06 | 三菱ケミカル株式会社 | 非水系電解液及びそれを用いた非水系電解液電池 |
CN105830271B (zh) * | 2013-12-19 | 2018-11-16 | 宇部兴产株式会社 | 非水电解液、使用了其的蓄电装置及其中使用的膦酰基甲酸化合物 |
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-
2012
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- 2012-04-12 WO PCT/JP2012/060073 patent/WO2012141270A1/fr active Application Filing
- 2012-04-12 CN CN201280017927.5A patent/CN103460495B/zh active Active
- 2012-04-12 CA CA2832881A patent/CA2832881A1/fr not_active Abandoned
- 2012-04-12 US US14/111,015 patent/US9384906B2/en active Active
- 2012-04-12 EP EP12771624.9A patent/EP2698859B1/fr active Active
- 2012-04-12 KR KR1020137026552A patent/KR20140022832A/ko not_active Application Discontinuation
- 2012-04-12 BR BR112013026067A patent/BR112013026067A2/pt not_active IP Right Cessation
- 2012-04-12 JP JP2013509970A patent/JP6032200B2/ja active Active
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CN103460495B (zh) | 2016-01-27 |
RU2013145681A (ru) | 2015-05-20 |
KR20140022832A (ko) | 2014-02-25 |
EP2698859A1 (fr) | 2014-02-19 |
US20140030610A1 (en) | 2014-01-30 |
WO2012141270A1 (fr) | 2012-10-18 |
US9384906B2 (en) | 2016-07-05 |
EP2698859A4 (fr) | 2014-10-08 |
JP2013145749A (ja) | 2013-07-25 |
EP2698859B1 (fr) | 2016-07-27 |
JPWO2012141270A1 (ja) | 2014-07-28 |
JP5354118B2 (ja) | 2013-11-27 |
BR112013026067A2 (pt) | 2019-09-24 |
CN103460495A (zh) | 2013-12-18 |
JP6032200B2 (ja) | 2016-11-24 |
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