CA2738771C - Nanocomposite thermoelectric conversion material, thermoelectric conversion element including the same, and method of producing nanocomposite thermoelectric conversion material - Google Patents
Nanocomposite thermoelectric conversion material, thermoelectric conversion element including the same, and method of producing nanocomposite thermoelectric conversion material Download PDFInfo
- Publication number
- CA2738771C CA2738771C CA2738771A CA2738771A CA2738771C CA 2738771 C CA2738771 C CA 2738771C CA 2738771 A CA2738771 A CA 2738771A CA 2738771 A CA2738771 A CA 2738771A CA 2738771 C CA2738771 C CA 2738771C
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- Prior art keywords
- thermoelectric conversion
- dispersed
- conversion material
- nanocomposite
- source
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- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title claims abstract description 599
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 299
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 149
- 238000000034 method Methods 0.000 title claims description 44
- 239000011159 matrix material Substances 0.000 claims abstract description 95
- 239000002105 nanoparticle Substances 0.000 claims abstract description 69
- 239000003638 chemical reducing agent Substances 0.000 claims description 69
- 150000003839 salts Chemical class 0.000 claims description 65
- 239000000203 mixture Substances 0.000 claims description 54
- 239000002904 solvent Substances 0.000 claims description 52
- 239000002002 slurry Substances 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 230000015572 biosynthetic process Effects 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 18
- 239000007791 liquid phase Substances 0.000 claims description 18
- 238000003786 synthesis reaction Methods 0.000 claims description 18
- 239000013078 crystal Substances 0.000 claims description 15
- 239000000956 alloy Substances 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 14
- 239000011246 composite particle Substances 0.000 claims description 14
- 239000002178 crystalline material Substances 0.000 claims description 12
- 230000001376 precipitating effect Effects 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 11
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 239000004020 conductor Substances 0.000 claims description 2
- 239000011810 insulating material Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 description 73
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 56
- 229910052787 antimony Inorganic materials 0.000 description 42
- 230000000052 comparative effect Effects 0.000 description 37
- 239000002245 particle Substances 0.000 description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 30
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 28
- 229910052797 bismuth Inorganic materials 0.000 description 26
- 229910052759 nickel Inorganic materials 0.000 description 26
- 239000000843 powder Substances 0.000 description 22
- 239000006087 Silane Coupling Agent Substances 0.000 description 14
- 229910052714 tellurium Inorganic materials 0.000 description 13
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 12
- 238000006722 reduction reaction Methods 0.000 description 12
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 11
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 11
- 230000009467 reduction Effects 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 238000005245 sintering Methods 0.000 description 9
- 239000012279 sodium borohydride Substances 0.000 description 9
- 229910000033 sodium borohydride Inorganic materials 0.000 description 9
- 238000003917 TEM image Methods 0.000 description 8
- 150000001805 chlorine compounds Chemical class 0.000 description 8
- 239000000470 constituent Substances 0.000 description 8
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- 239000012071 phase Substances 0.000 description 8
- 229910052718 tin Inorganic materials 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
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- 229910018985 CoSb3 Inorganic materials 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 6
- 238000002490 spark plasma sintering Methods 0.000 description 6
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000004065 semiconductor Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- JQGGAELIYHNDQS-UHFFFAOYSA-N Nic 12 Natural products CC(C=CC(=O)C)c1ccc2C3C4OC4C5(O)CC=CC(=O)C5(C)C3CCc2c1 JQGGAELIYHNDQS-UHFFFAOYSA-N 0.000 description 4
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- GFHNAMRJFCEERV-UHFFFAOYSA-L cobalt chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Co+2] GFHNAMRJFCEERV-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052732 germanium Inorganic materials 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- LAIZPRYFQUWUBN-UHFFFAOYSA-L nickel chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Ni+2] LAIZPRYFQUWUBN-UHFFFAOYSA-L 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052711 selenium Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- -1 V203 Inorganic materials 0.000 description 3
- 239000003708 ampul Substances 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- 150000003842 bromide salts Chemical class 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 150000004673 fluoride salts Chemical class 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 238000010335 hydrothermal treatment Methods 0.000 description 3
- 229910052745 lead Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 229910002899 Bi2Te3 Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910002665 PbTe Inorganic materials 0.000 description 2
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 229910007372 Zn4Sb3 Inorganic materials 0.000 description 2
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 239000002070 nanowire Substances 0.000 description 2
- LIYKJALVRPGQTR-UHFFFAOYSA-M oxostibanylium;chloride Chemical compound [Cl-].[Sb+]=O LIYKJALVRPGQTR-UHFFFAOYSA-M 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- OCGWQDWYSQAFTO-UHFFFAOYSA-N tellanylidenelead Chemical compound [Pb]=[Te] OCGWQDWYSQAFTO-UHFFFAOYSA-N 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- ZPQAUEDTKNBRNG-UHFFFAOYSA-N 2-methylprop-2-enoylsilicon Chemical compound CC(=C)C([Si])=O ZPQAUEDTKNBRNG-UHFFFAOYSA-N 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000012448 Lithium borohydride Substances 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000005678 Seebeck effect Effects 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- NOKSMMGULAYSTD-UHFFFAOYSA-N [SiH4].N=C=O Chemical compound [SiH4].N=C=O NOKSMMGULAYSTD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000002173 high-resolution transmission electron microscopy Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- IYMSIPPWHNIMGE-UHFFFAOYSA-N silylurea Chemical compound NC(=O)N[SiH3] IYMSIPPWHNIMGE-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000992 sputter etching Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B19/00—Selenium; Tellurium; Compounds thereof
- C01B19/007—Tellurides or selenides of metals
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/01—Manufacture or treatment
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/80—Constructional details
- H10N10/85—Thermoelectric active materials
- H10N10/851—Thermoelectric active materials comprising inorganic compositions
- H10N10/852—Thermoelectric active materials comprising inorganic compositions comprising tellurium, selenium or sulfur
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/80—Constructional details
- H10N10/85—Thermoelectric active materials
- H10N10/857—Thermoelectric active materials comprising compositions changing continuously or discontinuously inside the material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008-264247 | 2008-10-10 | ||
| JP2008264247 | 2008-10-10 | ||
| JP2009-179393 | 2009-07-31 | ||
| JP2009179393A JP4715953B2 (ja) | 2008-10-10 | 2009-07-31 | ナノコンポジット熱電変換材料、それを用いた熱電変換素子およびナノコンポジット熱電変換材料の製造方法 |
| PCT/IB2009/007244 WO2010041146A2 (en) | 2008-10-10 | 2009-10-09 | Nanocomposite thermoelectric conversion material, thermoelectric conversion element including the same, and method of producing nanocomposite thermoelectric conversion material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2738771A1 CA2738771A1 (en) | 2010-04-15 |
| CA2738771C true CA2738771C (en) | 2014-08-05 |
Family
ID=41855721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2738771A Expired - Fee Related CA2738771C (en) | 2008-10-10 | 2009-10-09 | Nanocomposite thermoelectric conversion material, thermoelectric conversion element including the same, and method of producing nanocomposite thermoelectric conversion material |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8628691B2 (enExample) |
| EP (1) | EP2331457B1 (enExample) |
| JP (1) | JP4715953B2 (enExample) |
| CN (1) | CN102177091B (enExample) |
| CA (1) | CA2738771C (enExample) |
| WO (1) | WO2010041146A2 (enExample) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9755128B2 (en) | 2008-10-10 | 2017-09-05 | Toyota Motor Engineering & Manufacturing North America, Inc. | Method of producing thermoelectric material |
| US9978924B2 (en) * | 2009-10-09 | 2018-05-22 | Toyota Jidosha Kabushiki Kaisha | Method of producing thermoelectric material |
| KR20110018102A (ko) * | 2009-08-17 | 2011-02-23 | 삼성전자주식회사 | 복합체형 열전재료 및 이를 포함하는 열전소자와 열전 모듈 |
| JP5418146B2 (ja) | 2009-10-26 | 2014-02-19 | トヨタ自動車株式会社 | ナノコンポジット熱電変換材料およびその製造方法 |
| JP5024393B2 (ja) | 2010-01-18 | 2012-09-12 | トヨタ自動車株式会社 | ナノコンポジット熱電変換材料およびその製造方法 |
| JP5206768B2 (ja) * | 2010-11-08 | 2013-06-12 | トヨタ自動車株式会社 | ナノコンポジット熱電変換材料、その製造方法および熱電変換素子 |
| US8957299B2 (en) * | 2011-01-24 | 2015-02-17 | Samsung Electronics Co., Ltd. | Thermoelectric material including nano-inclusions, thermoelectric module and thermoelectric apparatus including the same |
| US10811160B2 (en) * | 2011-05-27 | 2020-10-20 | Toyota Motor Engineering & Manufacturing North America, Inc. | Method of producing thermoelectric material |
| US8419980B2 (en) * | 2011-04-26 | 2013-04-16 | Toyota Motor Engineering And Manufacturing North America | Ternary thermoelectric material containing nanoparticles and process for producing the same |
| US9847470B2 (en) * | 2011-04-26 | 2017-12-19 | Toyota Motor Engineering & Manufacturing North America, Inc. | Method of producing thermoelectric material |
| US10672966B2 (en) | 2011-05-27 | 2020-06-02 | Toyota Motor Engineering & Manufacturing North America, Inc. | Method of producing thermoelectric material |
| CN102856486B (zh) * | 2011-06-28 | 2015-05-13 | 苏州大学 | 纳米复合热电材料的制备方法 |
| JP5853483B2 (ja) | 2011-08-12 | 2016-02-09 | トヨタ自動車株式会社 | ナノコンポジット熱電変換材料 |
| US8641917B2 (en) * | 2011-12-01 | 2014-02-04 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ternary thermoelectric material containing nanoparticles and process for producing the same |
| US8834736B2 (en) * | 2011-12-01 | 2014-09-16 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ternary thermoelectric material containing nanoparticles and process for producing the same |
| US8840799B2 (en) * | 2011-12-01 | 2014-09-23 | Toyota Motor Engineering & Manufacturing North America, Inc. | Binary thermoelectric material containing nanoparticles and process for producing the same |
| KR102001062B1 (ko) | 2012-01-16 | 2019-10-01 | 삼성전자주식회사 | 나노복합체형 열전재료, 이를 포함하는 열전모듈과 열전장치 |
| DE102012000763A1 (de) * | 2012-01-18 | 2013-07-18 | Emitec Gesellschaft Für Emissionstechnologie Mbh | Halbleiterelement und Verfahren zur Herstellung eines rohrförmigen thermoelektrischen Moduls |
| JP6054606B2 (ja) * | 2012-01-26 | 2016-12-27 | トヨタ自動車株式会社 | 熱電半導体 |
| JP2013219116A (ja) * | 2012-04-05 | 2013-10-24 | Toyota Motor Corp | ナノコンポジット熱電変換材料 |
| JP6150493B2 (ja) * | 2012-10-30 | 2017-06-21 | 重行 鶴見 | 熱電変換素子 |
| WO2014189769A1 (en) * | 2013-05-21 | 2014-11-27 | The Regents Of The University Of California | Metals-semiconductor nanowire composites |
| JP5714660B2 (ja) * | 2013-07-11 | 2015-05-07 | トヨタ自動車株式会社 | ナノコンポジット熱電変換材料の製造方法 |
| DE102013108791B3 (de) * | 2013-08-14 | 2014-12-11 | O-Flexx Technologies Gmbh | Verfahren zum Abscheiden von thermoelektrischem Material |
| JP2015056491A (ja) * | 2013-09-11 | 2015-03-23 | トヨタ自動車株式会社 | ナノコンポジット熱電変換材料及びその製造方法 |
| JP6110421B2 (ja) * | 2014-03-28 | 2017-04-05 | トヨタ自動車株式会社 | フォノン散乱材、ナノコンポジット熱電材料及びその製造方法 |
| JP6158755B2 (ja) * | 2014-06-06 | 2017-07-05 | トヨタ自動車株式会社 | 熱電変換材料及びその製造方法 |
| EP2959989B1 (en) * | 2014-06-23 | 2017-08-02 | Belenos Clean Power Holding AG | Sb nanocrystals or Sb-alloy nanocrystals for fast charge/discharge Li- and Na-ion battery anodes |
| JP6333209B2 (ja) * | 2015-04-15 | 2018-05-30 | トヨタ自動車株式会社 | ナノコンポジット熱電変換材料及びその製造方法 |
| US10944037B2 (en) * | 2015-06-30 | 2021-03-09 | Sumitomo Electric Industries, Ltd. | Thermoelectric material, thermoelectric element, optical sensor, and method for manufacturing thermoelectric material |
| JP6603518B2 (ja) * | 2015-09-04 | 2019-11-06 | 株式会社日立製作所 | 熱電変換材料および熱電変換モジュール |
| JP6655918B2 (ja) * | 2015-09-10 | 2020-03-04 | 学校法人中部大学 | 熱電材料 |
| JP6453748B2 (ja) * | 2015-12-09 | 2019-01-16 | トヨタ自動車株式会社 | 熱電変換材料 |
| KR102391282B1 (ko) * | 2017-02-01 | 2022-04-28 | 엘지이노텍 주식회사 | 열전 소결체 및 열전소자 |
| JP6923182B2 (ja) * | 2017-03-14 | 2021-08-18 | 国立研究開発法人産業技術総合研究所 | 熱電変換材料およびその製造方法、熱電発電モジュール、並びにペルチェ冷却器 |
| KR102074172B1 (ko) * | 2018-03-30 | 2020-02-06 | 경북대학교 산학협력단 | 원형 공진기, 이를 포함하는 광 변환기 및 광학 소자 |
| JP7363059B2 (ja) * | 2019-03-12 | 2023-10-18 | 株式会社プロテリアル | 熱電変換材料の製造方法 |
| JP7279697B2 (ja) * | 2020-09-25 | 2023-05-23 | トヨタ自動車株式会社 | 情報処理装置、情報処理方法、及び情報処理プログラム |
| KR102603769B1 (ko) * | 2021-10-26 | 2023-11-17 | 국민대학교산학협력단 | 유기-무기 복합 열전체 및 이를 구비하는 열전 발전기 |
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| JP3502724B2 (ja) * | 1996-07-16 | 2004-03-02 | 本田技研工業株式会社 | 熱電材料 |
| JPH11298052A (ja) | 1998-04-09 | 1999-10-29 | Toshiba Corp | 熱電素子、熱電材料及び熱電材料の製造方法 |
| JP3949848B2 (ja) | 1998-06-30 | 2007-07-25 | 松下電器産業株式会社 | スカッテルダイト系熱電材料の製造方法 |
| JP2000261047A (ja) | 1999-03-05 | 2000-09-22 | Ngk Insulators Ltd | 熱電変換用半導体材料およびその製造方法 |
| JP2001076452A (ja) | 1999-07-01 | 2001-03-23 | Fujitsu Ltd | ヘッドサスペンションおよびディスク装置 |
| JP4166927B2 (ja) | 2000-07-03 | 2008-10-15 | 三洋電機株式会社 | 熱電材料の製造方法、熱電材料及び熱電材料製造装置 |
| JP3559962B2 (ja) * | 2000-09-04 | 2004-09-02 | 日本航空電子工業株式会社 | 熱電変換材料及びその製造方法 |
| JP3925932B2 (ja) | 2004-01-08 | 2007-06-06 | 株式会社 東北テクノアーチ | 有機修飾金属酸化物ナノ粒子の製造法 |
| US7465871B2 (en) * | 2004-10-29 | 2008-12-16 | Massachusetts Institute Of Technology | Nanocomposites with high thermoelectric figures of merit |
| US7309830B2 (en) * | 2005-05-03 | 2007-12-18 | Toyota Motor Engineering & Manufacturing North America, Inc. | Nanostructured bulk thermoelectric material |
| JP4830383B2 (ja) * | 2005-07-19 | 2011-12-07 | 大日本印刷株式会社 | コアシェル型ナノ粒子および熱電変換材料 |
| CN101356659A (zh) * | 2005-12-07 | 2009-01-28 | 丰田自动车株式会社 | 热电转换材料及其制造方法 |
| US8044292B2 (en) * | 2006-10-13 | 2011-10-25 | Toyota Motor Engineering & Manufacturing North America, Inc. | Homogeneous thermoelectric nanocomposite using core-shell nanoparticles |
| JP4900061B2 (ja) | 2007-06-06 | 2012-03-21 | トヨタ自動車株式会社 | 熱電変換素子及びその製造方法 |
| JP2009147145A (ja) * | 2007-12-14 | 2009-07-02 | Toyota Motor Corp | 熱電変換素子 |
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2009
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- 2009-10-09 US US13/122,575 patent/US8628691B2/en not_active Expired - Fee Related
- 2009-10-09 CA CA2738771A patent/CA2738771C/en not_active Expired - Fee Related
- 2009-10-09 WO PCT/IB2009/007244 patent/WO2010041146A2/en not_active Ceased
- 2009-10-09 EP EP09764027.0A patent/EP2331457B1/en not_active Not-in-force
- 2009-10-09 CN CN2009801398117A patent/CN102177091B/zh not_active Expired - Fee Related
Also Published As
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|---|---|
| JP4715953B2 (ja) | 2011-07-06 |
| CA2738771A1 (en) | 2010-04-15 |
| CN102177091A (zh) | 2011-09-07 |
| EP2331457B1 (en) | 2015-08-26 |
| WO2010041146A2 (en) | 2010-04-15 |
| EP2331457A2 (en) | 2011-06-15 |
| US20110198541A1 (en) | 2011-08-18 |
| JP2010114419A (ja) | 2010-05-20 |
| US8628691B2 (en) | 2014-01-14 |
| CN102177091B (zh) | 2013-11-20 |
| WO2010041146A3 (en) | 2010-12-02 |
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