CA2688051C - A catalytic cracking catalyst and the preparation and use thereof - Google Patents

A catalytic cracking catalyst and the preparation and use thereof Download PDF

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Publication number
CA2688051C
CA2688051C CA2688051A CA2688051A CA2688051C CA 2688051 C CA2688051 C CA 2688051C CA 2688051 A CA2688051 A CA 2688051A CA 2688051 A CA2688051 A CA 2688051A CA 2688051 C CA2688051 C CA 2688051C
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Prior art keywords
catalyst
pores
alumina
substrate
zeolite
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CA2688051A
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English (en)
French (fr)
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CA2688051A1 (en
Inventor
Jun Long
Yujian Liu
Huiping Tian
Liuzhou Zhao
Yuxia Zhu
Zhenyu Chen
Yun Xu
Jing Fan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Research Institute of Petroleum Processing
China Petroleum and Chemical Corp
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Sinopec Research Institute of Petroleum Processing
China Petroleum and Chemical Corp
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Publication of CA2688051A1 publication Critical patent/CA2688051A1/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057—Zeolite Beta

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA2688051A 2007-06-27 2008-06-27 A catalytic cracking catalyst and the preparation and use thereof Active CA2688051C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN200710118011.X 2007-06-27
CN200710118011XA CN101332433B (zh) 2007-06-27 2007-06-27 一种催化裂化催化剂及其制备和应用方法
PCT/CN2008/001241 WO2009000164A1 (fr) 2007-06-27 2008-06-27 Catalyseur de craquage catalytique, sa préparation et son utilisation

Publications (2)

Publication Number Publication Date
CA2688051A1 CA2688051A1 (en) 2008-12-31
CA2688051C true CA2688051C (en) 2016-04-05

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CA2688051A Active CA2688051C (en) 2007-06-27 2008-06-27 A catalytic cracking catalyst and the preparation and use thereof

Country Status (11)

Country Link
US (1) US9486795B2 (enExample)
EP (1) EP2161077B1 (enExample)
JP (1) JP5587185B2 (enExample)
KR (1) KR101138779B1 (enExample)
CN (1) CN101332433B (enExample)
BR (1) BRPI0813225B1 (enExample)
CA (1) CA2688051C (enExample)
ES (1) ES2937658T3 (enExample)
RU (1) RU2471553C2 (enExample)
TW (1) TWI454316B (enExample)
WO (1) WO2009000164A1 (enExample)

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JP5973457B2 (ja) * 2010-11-16 2016-08-23 ロディア オペレーションズＲｈｏｄｉａ Ｏｐｅｒａｔｉｏｎｓ アルミナ触媒担体
RU2472586C1 (ru) * 2011-08-26 2013-01-20 Открытое акционерное общество "Газпромнефть-Омский НПЗ" Микросферический катализатор для снижения содержания серы в бензине крекинга и способ его приготовления
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CN105478162B (zh) * 2014-10-11 2019-05-17 中国石油化工股份有限公司 减少生焦多产低碳烯烃的催化剂
JP6564875B2 (ja) * 2015-11-11 2019-08-21 日揮触媒化成株式会社 低級オレフィン製造用流動接触分解触媒用添加物およびその製造方法
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CN109133976B (zh) * 2018-08-28 2020-10-16 东北大学 一种多孔氧化铝制备方法
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WO2020044859A1 (ja) * 2018-08-29 2020-03-05 日揮触媒化成株式会社 炭化水素油用流動接触分解触媒
CN111744483B (zh) * 2019-03-28 2021-09-07 中国石油化工股份有限公司 一种氧化铝、其制备方法及应用
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CN112108171B (zh) * 2019-06-21 2023-05-26 中国石油天然气股份有限公司 一种抗重金属催化裂化催化剂的制备方法
CN112108172B (zh) * 2019-06-21 2023-05-26 中国石油天然气股份有限公司 一种高抗磨损的催化裂化催化剂的制备方法
CN112108176B (zh) * 2019-06-21 2023-06-30 中国石油天然气股份有限公司 一种降低催化裂化汽油硫含量催化剂的制备方法
CN112108190B (zh) * 2019-06-21 2023-06-30 中国石油天然气股份有限公司 一种高活性载体材料的制备方法
CN112108173B (zh) * 2019-06-21 2023-06-30 中国石油天然气股份有限公司 一种降低柴油收率的催化剂制备方法
CN112108174B (zh) * 2019-06-21 2023-05-26 中国石油天然气股份有限公司 一种高选择性的催化裂化催化剂的制备方法
CN113797962B (zh) * 2020-06-17 2023-01-13 中国石油化工股份有限公司 一种催化裂化助剂及其制备方法和应用
US11142703B1 (en) * 2020-08-05 2021-10-12 Saudi Arabian Oil Company Fluid catalytic cracking with catalyst system containing modified beta zeolite additive
CN113134348B (zh) * 2021-04-23 2023-05-05 中国石油化工股份有限公司 一种接触剂的应用以及改性接触剂及其制备方法与应用
CN115888799B (zh) * 2021-09-30 2024-09-24 中国石油化工股份有限公司 抗金属污染催化剂其制备和应用

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TWI379711B (en) 2004-11-05 2012-12-21 Grace W R & Co Catalyst for light olefins and lpg in fluidized catalytic cracking units
CN100443170C (zh) 2005-09-01 2008-12-17 中国石油天然气股份有限公司 乙苯脱氢制苯乙烯催化剂及其制备方法

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RU2471553C2 (ru) 2013-01-10
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CA2688051A1 (en) 2008-12-31
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US9486795B2 (en) 2016-11-08
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WO2009000164A1 (fr) 2008-12-31
CN101332433B (zh) 2011-07-20
JP5587185B2 (ja) 2014-09-10
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