BRPI0813225B1 - catalisador de craqueamento catalítico, seu processo de preparação e processo de craqueamento catalítico - Google Patents
catalisador de craqueamento catalítico, seu processo de preparação e processo de craqueamento catalítico Download PDFInfo
- Publication number
- BRPI0813225B1 BRPI0813225B1 BRPI0813225-9A BRPI0813225A BRPI0813225B1 BR PI0813225 B1 BRPI0813225 B1 BR PI0813225B1 BR PI0813225 A BRPI0813225 A BR PI0813225A BR PI0813225 B1 BRPI0813225 B1 BR PI0813225B1
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- weight
- alumina
- fact
- zeolite
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 166
- 238000000034 method Methods 0.000 title claims description 35
- 238000004523 catalytic cracking Methods 0.000 title claims description 32
- 230000008569 process Effects 0.000 title claims description 29
- 238000002360 preparation method Methods 0.000 title claims description 26
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 97
- 239000010457 zeolite Substances 0.000 claims description 92
- 229910021536 Zeolite Inorganic materials 0.000 claims description 86
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 86
- 239000011148 porous material Substances 0.000 claims description 75
- 239000000203 mixture Substances 0.000 claims description 58
- 239000002002 slurry Substances 0.000 claims description 56
- 239000000758 substrate Substances 0.000 claims description 52
- 239000002808 molecular sieve Substances 0.000 claims description 34
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 34
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 27
- 229910052782 aluminium Inorganic materials 0.000 claims description 23
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 23
- 239000003921 oil Substances 0.000 claims description 22
- 239000002243 precursor Substances 0.000 claims description 22
- 239000004927 clay Substances 0.000 claims description 20
- 239000004606 Fillers/Extenders Substances 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 238000009826 distribution Methods 0.000 claims description 13
- 229910001507 metal halide Inorganic materials 0.000 claims description 12
- 150000005309 metal halides Chemical class 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 238000001694 spray drying Methods 0.000 claims description 6
- 229910001648 diaspore Inorganic materials 0.000 claims description 5
- 229910001679 gibbsite Inorganic materials 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 238000004438 BET method Methods 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000003795 desorption Methods 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 40
- 239000000047 product Substances 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 239000000377 silicon dioxide Substances 0.000 description 17
- 239000007787 solid Substances 0.000 description 17
- 238000005336 cracking Methods 0.000 description 14
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 12
- 150000001336 alkenes Chemical class 0.000 description 12
- 229910052698 phosphorus Inorganic materials 0.000 description 12
- 239000011574 phosphorus Substances 0.000 description 12
- -1 ethylene, propylene Chemical group 0.000 description 10
- 229910052809 inorganic oxide Inorganic materials 0.000 description 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 10
- 230000002431 foraging effect Effects 0.000 description 9
- 239000000295 fuel oil Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 229910001415 sodium ion Inorganic materials 0.000 description 9
- 239000007921 spray Substances 0.000 description 9
- 238000005299 abrasion Methods 0.000 description 7
- 239000003208 petroleum Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
- 238000007233 catalytic pyrolysis Methods 0.000 description 5
- 239000000571 coke Substances 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 5
- 229910052939 potassium sulfate Inorganic materials 0.000 description 5
- 235000011151 potassium sulphates Nutrition 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 4
- 229910052906 cristobalite Inorganic materials 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000011268 mixed slurry Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 229910052682 stishovite Inorganic materials 0.000 description 4
- 229910052905 tridymite Inorganic materials 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 229910010165 TiCu Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000001282 iso-butane Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052761 rare earth metal Inorganic materials 0.000 description 3
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- 239000001120 potassium sulphate Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001432959 Chernes Species 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910001195 gallium oxide Inorganic materials 0.000 description 1
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 102200118166 rs16951438 Human genes 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7057—Zeolite Beta
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710118011.X | 2007-06-27 | ||
| CN200710118011XA CN101332433B (zh) | 2007-06-27 | 2007-06-27 | 一种催化裂化催化剂及其制备和应用方法 |
| PCT/CN2008/001241 WO2009000164A1 (fr) | 2007-06-27 | 2008-06-27 | Catalyseur de craquage catalytique, sa préparation et son utilisation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0813225A2 BRPI0813225A2 (pt) | 2014-12-23 |
| BRPI0813225B1 true BRPI0813225B1 (pt) | 2018-01-16 |
Family
ID=40185184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0813225-9A BRPI0813225B1 (pt) | 2007-06-27 | 2008-06-27 | catalisador de craqueamento catalítico, seu processo de preparação e processo de craqueamento catalítico |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9486795B2 (enExample) |
| EP (1) | EP2161077B1 (enExample) |
| JP (1) | JP5587185B2 (enExample) |
| KR (1) | KR101138779B1 (enExample) |
| CN (1) | CN101332433B (enExample) |
| BR (1) | BRPI0813225B1 (enExample) |
| CA (1) | CA2688051C (enExample) |
| ES (1) | ES2937658T3 (enExample) |
| RU (1) | RU2471553C2 (enExample) |
| TW (1) | TWI454316B (enExample) |
| WO (1) | WO2009000164A1 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5973457B2 (ja) * | 2010-11-16 | 2016-08-23 | ロディア オペレーションズＲｈｏｄｉａ Ｏｐｅｒａｔｉｏｎｓ | アルミナ触媒担体 |
| RU2472586C1 (ru) * | 2011-08-26 | 2013-01-20 | Открытое акционерное общество "Газпромнефть-Омский НПЗ" | Микросферический катализатор для снижения содержания серы в бензине крекинга и способ его приготовления |
| US9434658B2 (en) * | 2013-03-06 | 2016-09-06 | Ut-Battelle, Llc | Catalytic conversion of alcohols to hydrocarbons with low benzene content |
| CN104549449B (zh) * | 2013-10-28 | 2017-02-15 | 中国石油化工股份有限公司 | 耐磨损的催化裂解流化床催化剂及其制备方法 |
| CN105478162B (zh) * | 2014-10-11 | 2019-05-17 | 中国石油化工股份有限公司 | 减少生焦多产低碳烯烃的催化剂 |
| JP6564875B2 (ja) * | 2015-11-11 | 2019-08-21 | 日揮触媒化成株式会社 | 低級オレフィン製造用流動接触分解触媒用添加物およびその製造方法 |
| CA3087960A1 (en) | 2018-01-12 | 2019-07-18 | Albemarle Corporation | Fcc catalyst with enhanced mesoporosity, its preparation and use |
| CN109133976B (zh) * | 2018-08-28 | 2020-10-16 | 东北大学 | 一种多孔氧化铝制备方法 |
| US11731114B2 (en) | 2018-08-29 | 2023-08-22 | Jgc Catalysts And Chemicals Ltd. | Fluid catalytic cracking catalyst for hydrocarbon oil |
| JP7123864B2 (ja) * | 2019-02-28 | 2022-08-23 | 日揮触媒化成株式会社 | 炭化水素油用流動接触分解触媒 |
| WO2020044859A1 (ja) * | 2018-08-29 | 2020-03-05 | 日揮触媒化成株式会社 | 炭化水素油用流動接触分解触媒 |
| CN111744483B (zh) * | 2019-03-28 | 2021-09-07 | 中国石油化工股份有限公司 | 一种氧化铝、其制备方法及应用 |
| CN112110456B (zh) * | 2019-06-21 | 2023-07-25 | 中国石油天然气股份有限公司 | 一种原位晶化NaY分子筛的制备方法 |
| CN112108171B (zh) * | 2019-06-21 | 2023-05-26 | 中国石油天然气股份有限公司 | 一种抗重金属催化裂化催化剂的制备方法 |
| CN112108172B (zh) * | 2019-06-21 | 2023-05-26 | 中国石油天然气股份有限公司 | 一种高抗磨损的催化裂化催化剂的制备方法 |
| CN112108176B (zh) * | 2019-06-21 | 2023-06-30 | 中国石油天然气股份有限公司 | 一种降低催化裂化汽油硫含量催化剂的制备方法 |
| CN112108190B (zh) * | 2019-06-21 | 2023-06-30 | 中国石油天然气股份有限公司 | 一种高活性载体材料的制备方法 |
| CN112108173B (zh) * | 2019-06-21 | 2023-06-30 | 中国石油天然气股份有限公司 | 一种降低柴油收率的催化剂制备方法 |
| CN112108174B (zh) * | 2019-06-21 | 2023-05-26 | 中国石油天然气股份有限公司 | 一种高选择性的催化裂化催化剂的制备方法 |
| CN113797962B (zh) * | 2020-06-17 | 2023-01-13 | 中国石油化工股份有限公司 | 一种催化裂化助剂及其制备方法和应用 |
| US11142703B1 (en) * | 2020-08-05 | 2021-10-12 | Saudi Arabian Oil Company | Fluid catalytic cracking with catalyst system containing modified beta zeolite additive |
| CN113134348B (zh) * | 2021-04-23 | 2023-05-05 | 中国石油化工股份有限公司 | 一种接触剂的应用以及改性接触剂及其制备方法与应用 |
| CN115888799B (zh) * | 2021-09-30 | 2024-09-24 | 中国石油化工股份有限公司 | 抗金属污染催化剂其制备和应用 |
Family Cites Families (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4945364B1 (enExample) | 1966-11-10 | 1974-12-04 | ||
| US3647682A (en) | 1968-10-23 | 1972-03-07 | Union Carbide Corp | Olefin production by the catalytic treatment of hydrocarbons |
| US3839485A (en) | 1969-12-23 | 1974-10-01 | Haldor Topsoe As | Catalytic steam cracking of hydrocarbons and catalysts therefor |
| GB1306087A (enExample) | 1969-12-23 | 1973-02-07 | ||
| US3696053A (en) * | 1970-03-18 | 1972-10-03 | Pechiney Saint Gobain | Porous silica containing foreign ions and method for preparation for same |
| US3867279A (en) * | 1972-07-20 | 1975-02-18 | Union Oil Co | Hydrocarbon cracking with catalytic phosphate-silica-aluminosilicate compositions of improved crushing strength |
| US4003825A (en) * | 1974-03-14 | 1977-01-18 | Mobil Oil Corporation | Synthetic amorphous silicas of predetermined pore distribution, method of producing same and process of using same |
| US4198319A (en) | 1977-02-16 | 1980-04-15 | Filtrol Corporation | Method of producing zeolitic catalysts with silica alumina matrix |
| US4326993A (en) * | 1979-12-17 | 1982-04-27 | Mobil Oil Corporation | Novel cracking catalysts and catalyst supports |
| DD152356A1 (de) | 1980-08-01 | 1981-11-25 | Siegrid Hauser | Verfahren zur herstellung von olefinen durch katalytische kohlenwasserstoffspaltung |
| JPS59196745A (ja) | 1983-03-31 | 1984-11-08 | Res Assoc Residual Oil Process<Rarop> | 鉄含有ゼオライト組成物 |
| DE3317725A1 (de) * | 1983-05-16 | 1984-11-22 | Süd-Chemie AG, 8000 München | Katalysator fuer die methanolsynthese |
| JPS60222428A (ja) | 1984-04-19 | 1985-11-07 | Res Assoc Util Of Light Oil | 炭化水素の接触転化法 |
| DD225135A1 (de) | 1984-06-25 | 1985-07-24 | Adw Ddr | Verfahren zur thermokatalytischen spaltung von kohlenwasserstoffen |
| SU1214726A1 (ru) | 1984-11-01 | 1986-02-28 | Институт неорганической и физической химии АН АзССР | Способ получени низкомолекул рных олефинов |
| FR2582665B1 (fr) | 1985-06-04 | 1988-08-05 | Inst Francais Du Petrole | Procede de craquage catalytique |
| JPH0685875B2 (ja) * | 1985-08-05 | 1994-11-02 | 触媒化成工業株式会社 | 炭化水素油の接触分解用触媒と接触分解法 |
| US4814316A (en) * | 1987-06-04 | 1989-03-21 | Uop | Novel catalyst composition, and processes for making and using same |
| US5160601A (en) * | 1988-09-30 | 1992-11-03 | Chevron Research Company | Hydrocarbon conversion with octane-enhancing catalysts |
| CN1043520A (zh) | 1988-12-21 | 1990-07-04 | 中国石油化工总公司石油化工科学研究院 | 一种生产低碳烯烃的裂解催化剂 |
| GB8829923D0 (en) * | 1988-12-22 | 1989-02-15 | Ici Plc | Zeolites |
| DE4042655C2 (de) * | 1990-07-11 | 1996-12-19 | Ecolith Zeolithe Gmbh | Verwendung eines synthetischen, kristallinen Alumosilikats mit der chemischen Zusammensetzung 0-3M¶2¶O : Al¶2¶O¶3¶ : 15-40SiO¶2¶ : 0-40H¶2¶O zur Gewinnung und Verarbeitung von Aromaten |
| CA2093412C (en) * | 1992-04-20 | 2002-12-31 | Gerald Verdell Nelson | Novel hydroconversion process employing catalyst with specified pore size distribution |
| CN1030313C (zh) | 1992-07-16 | 1995-11-22 | 中国石油化工总公司 | 重质烃类直接转化制取乙烯的方法 |
| CN1034223C (zh) * | 1993-03-29 | 1997-03-12 | 中国石油化工总公司 | 制取低碳烯烃的裂解催化剂 |
| CN1043311C (zh) * | 1993-12-16 | 1999-05-12 | 中国科学院大连化学物理研究所 | 高选择性吸附一氧化碳的沸石吸附剂的制备方法 |
| JPH07278567A (ja) * | 1994-04-06 | 1995-10-24 | Idemitsu Kosan Co Ltd | 炭化水素の接触転化方法 |
| CN1048428C (zh) * | 1994-07-15 | 2000-01-19 | 中国石油化工总公司 | 制取低碳烯烃的多沸石催化剂 |
| CN1077805C (zh) * | 1995-08-30 | 2002-01-16 | 中国科学院大连化学物理研究所 | 一种高耐磨颗粒型分子筛吸附剂的制备方法 |
| US5670131A (en) * | 1995-10-02 | 1997-09-23 | Mobil Oil Corporation | Synthetic porous crystalline MCM-61, its synthesis and use |
| CN1055877C (zh) | 1996-03-26 | 2000-08-30 | 中国石油化工总公司抚顺石油化工研究院 | 大孔径氧化铝载体及其制备方法 |
| CN1059133C (zh) | 1997-03-24 | 2000-12-06 | 中国石油化工总公司 | 具有mfi结构的含磷分子筛 |
| CN1102634C (zh) | 1997-10-15 | 2003-03-05 | 中国石油化工集团公司 | 催化热裂解制取低碳烯烃催化剂 |
| CN1069682C (zh) | 1997-12-23 | 2001-08-15 | 中国石油化工总公司 | 重油催化热裂解层柱粘土催化剂及其制备 |
| CN1100847C (zh) | 1999-07-10 | 2003-02-05 | 巴陵石化长岭炼油化工总厂 | 一种烃类催化裂化催化剂的制造方法 |
| CN1112247C (zh) | 1999-11-17 | 2003-06-25 | 中国石化集团齐鲁石油化工公司 | 含小晶粒y型分子筛的催化剂的制备 |
| CN1181162C (zh) | 2000-03-03 | 2004-12-22 | 中国石油化工集团公司 | 一种催化裂化催化剂的制备方法 |
| CN1142019C (zh) * | 2000-05-31 | 2004-03-17 | 中国石油化工集团公司 | 一种含磷的烃类裂化催化剂及制备 |
| CN1124892C (zh) * | 2000-11-17 | 2003-10-22 | 中国石油化工股份有限公司 | 生产富含异构烷烃汽油、丙烯及异丁烷的催化裂化催化剂 |
| BR0100680A (pt) * | 2001-02-21 | 2002-11-05 | Petroleo Brasileiro Sa | Composições catalìticas multiparticuladas para craqueamento catalìtico fluido (fcc), processo de craqueamento catalìtico fluido (fcc) e uso das mesmas |
| CN1393399A (zh) | 2001-06-29 | 2003-01-29 | 上海奥轮催化剂有限公司 | 一种耐磨球状NaY分子筛及其合成方法 |
| RU2328445C2 (ru) * | 2002-05-23 | 2008-07-10 | Консехо Супериор Де Инвестигасьонес Сьентификас | Микропористый кристаллический цеолитный материал (цеолит itq-22), способ его получения и применение в качестве катализатора |
| CN1176020C (zh) | 2002-06-27 | 2004-11-17 | 中国石油化工股份有限公司 | 一种含磷和过渡金属的mfi结构分子筛 |
| KR100903898B1 (ko) | 2002-08-29 | 2009-06-19 | 알베마를 네덜란드 비.브이. | 저급 올레핀 제조용 촉매 |
| CN1230496C (zh) | 2002-10-28 | 2005-12-07 | 中国石油化工股份有限公司 | 一种含稀土y型沸石的石油烃裂化催化剂及其制备方法 |
| CN1205306C (zh) * | 2002-11-29 | 2005-06-08 | 中国石油化工股份有限公司 | 一种石油烃裂解制取低碳烯烃的催化剂 |
| CN1243081C (zh) | 2002-12-19 | 2006-02-22 | 中国石油化工股份有限公司 | 加氢处理催化剂及其制备方法 |
| CN1234806C (zh) | 2003-06-30 | 2006-01-04 | 中国石油化工股份有限公司 | 一种制取乙烯和丙烯的石油烃催化热裂解方法 |
| CN1267533C (zh) | 2004-02-27 | 2006-08-02 | 中国石油化工股份有限公司 | 一种增产乙烯和丙烯的催化热裂解催化剂 |
| US7375048B2 (en) | 2004-04-29 | 2008-05-20 | Basf Catalysts Llc | ZSM-5 additive |
| AU2005254457B2 (en) | 2004-06-08 | 2010-05-27 | Exxonmobil Research And Engineering Company | FCC process using mesoporous catalyst |
| US7504021B2 (en) * | 2004-06-08 | 2009-03-17 | Exxonmobil Research And Engineering Company | FCC process using mesoporous catalyst |
| CN1311906C (zh) * | 2004-07-29 | 2007-04-25 | 中国石油化工股份有限公司 | 一种烃类裂化催化剂及其制备方法 |
| TWI379711B (en) | 2004-11-05 | 2012-12-21 | Grace W R & Co | Catalyst for light olefins and lpg in fluidized catalytic cracking units |
| CN100443170C (zh) | 2005-09-01 | 2008-12-17 | 中国石油天然气股份有限公司 | 乙苯脱氢制苯乙烯催化剂及其制备方法 |
-
2007
- 2007-06-27 CN CN200710118011XA patent/CN101332433B/zh active Active
-
2008
- 2008-06-27 US US12/666,711 patent/US9486795B2/en active Active
- 2008-06-27 EP EP08772994.3A patent/EP2161077B1/en active Active
- 2008-06-27 BR BRPI0813225-9A patent/BRPI0813225B1/pt active IP Right Grant
- 2008-06-27 RU RU2009148096/04A patent/RU2471553C2/ru active
- 2008-06-27 WO PCT/CN2008/001241 patent/WO2009000164A1/zh not_active Ceased
- 2008-06-27 JP JP2010513623A patent/JP5587185B2/ja active Active
- 2008-06-27 TW TW097124233A patent/TWI454316B/zh active
- 2008-06-27 CA CA2688051A patent/CA2688051C/en active Active
- 2008-06-27 ES ES08772994T patent/ES2937658T3/es active Active
- 2008-06-27 KR KR1020107001816A patent/KR101138779B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| TW201000209A (en) | 2010-01-01 |
| EP2161077A1 (en) | 2010-03-10 |
| US20100270210A1 (en) | 2010-10-28 |
| RU2009148096A (ru) | 2011-08-10 |
| KR20100041785A (ko) | 2010-04-22 |
| EP2161077B1 (en) | 2022-12-21 |
| KR101138779B1 (ko) | 2012-04-24 |
| RU2471553C2 (ru) | 2013-01-10 |
| CA2688051C (en) | 2016-04-05 |
| JP2010531219A (ja) | 2010-09-24 |
| CA2688051A1 (en) | 2008-12-31 |
| EP2161077A4 (en) | 2012-05-30 |
| US9486795B2 (en) | 2016-11-08 |
| ES2937658T3 (es) | 2023-03-30 |
| WO2009000164A1 (fr) | 2008-12-31 |
| CN101332433B (zh) | 2011-07-20 |
| JP5587185B2 (ja) | 2014-09-10 |
| BRPI0813225A2 (pt) | 2014-12-23 |
| TWI454316B (zh) | 2014-10-01 |
| CN101332433A (zh) | 2008-12-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0813225B1 (pt) | catalisador de craqueamento catalítico, seu processo de preparação e processo de craqueamento catalítico | |
| RU2749402C1 (ru) | Катализатор десульфуризации, его получение и применение | |
| BR112016013944B1 (pt) | Método de fabricação de um catalisador de fcc | |
| US10005072B2 (en) | High matrix surface area catalytic cracking catalyst stabilized with magnesium and silica | |
| BR112019024084A2 (pt) | Catalisadores e método para fabricar um catalisador | |
| WO2020001540A1 (zh) | 改性y型分子筛、包含它的催化裂化催化剂、及其制备和应用 | |
| CN109675616B (zh) | 一种多产丁烯的催化转化催化剂以及制备方法和多产丁烯的催化转化方法 | |
| CN110833857A (zh) | 催化裂化催化剂及其制备方法和应用 | |
| CN114054071B (zh) | 催化剂及其制备方法和在烷基化反应中提高催化剂周期寿命的方法 | |
| CN110833863B (zh) | 催化裂化催化剂及其制备方法和应用 | |
| US11027264B2 (en) | Fluid catalytic cracking catalysts for increasing butylene yields | |
| CN110833850A (zh) | 催化裂化催化剂及其制备方法和应用 | |
| CN110833854B (zh) | 催化裂化催化剂及其制备方法和应用 | |
| TW202202226A (zh) | 用於催化裂解的程序及平衡fcc催化劑 | |
| CN1978411B (zh) | 一种制取小分子烯烃的组合工艺方法 | |
| CN118767979B (zh) | 催化裂解催化剂及其制备方法和催化裂解方法 | |
| RU2799090C1 (ru) | Каталитическая композиция fcc и способ ее получения | |
| CN110833852A (zh) | 催化裂化催化剂及其制备方法和应用 | |
| CN1272406C (zh) | 一种多产低碳烯烃的催化剂 | |
| JP4592512B2 (ja) | 接触分解ガソリン用脱硫触媒およびその製造方法並びにその触媒を用いた接触分解ガソリンの脱硫方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |