CA1264055C - - Google Patents

Info

Publication number
CA1264055C
CA1264055C CA 472950 CA472950A CA1264055C CA 1264055 C CA1264055 C CA 1264055C CA 472950 CA472950 CA 472950 CA 472950 A CA472950 A CA 472950A CA 1264055 C CA1264055 C CA 1264055C
Authority
CA
Canada
Prior art keywords
diorganophosphite
transition metal
catalysts
well
ligands
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA 472950
Other languages
English (en)
Other versions
CA1262915A1 (fr
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to CA000580692A priority Critical patent/CA1264055A/fr
Publication of CA1262915A1 publication Critical patent/CA1262915A1/fr
Application granted granted Critical
Publication of CA1264055C publication Critical patent/CA1264055C/xx
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • C07F15/008Rhodium compounds without a metal-carbon linkage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574Esters of oxyacids of phosphorus
    • C07F9/65744Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6578Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and sulfur atoms with or without oxygen atoms, as ring hetero atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Steroid Compounds (AREA)
  • Materials For Medical Uses (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Saccharide Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
CA000472950A 1984-02-17 1985-01-25 Reactions catalytiques aux complexes de metal de transition Granted CA1262915A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA000580692A CA1264055A (fr) 1984-02-17 1988-10-19 Reactions catalysees par un complexe de metal de transition

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US58135284A 1984-02-17 1984-02-17
US581,352 1984-02-17
US06/685,025 US4599206A (en) 1984-02-17 1984-12-28 Transition metal complex catalyzed reactions
US685,025 1984-12-28

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA000580692A Division CA1264055A (fr) 1984-02-17 1988-10-19 Reactions catalysees par un complexe de metal de transition

Publications (2)

Publication Number Publication Date
CA1262915A1 CA1262915A1 (fr) 1989-11-14
CA1264055C true CA1264055C (fr) 1989-12-27

Family

ID=27078299

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000472950A Granted CA1262915A1 (fr) 1984-02-17 1985-01-25 Reactions catalytiques aux complexes de metal de transition

Country Status (21)

Country Link
US (1) US4599206A (fr)
EP (1) EP0155508B1 (fr)
JP (1) JPH0645633B2 (fr)
KR (1) KR920010519B1 (fr)
AT (1) ATE83230T1 (fr)
AU (2) AU579144B2 (fr)
BR (1) BR8505278A (fr)
CA (1) CA1262915A1 (fr)
CS (1) CS271311B2 (fr)
DE (1) DE3586878T2 (fr)
DK (1) DK473485A (fr)
ES (3) ES8609185A1 (fr)
FI (1) FI88709C (fr)
HU (1) HU202176B (fr)
MX (1) MX164254B (fr)
NO (1) NO165915C (fr)
PL (2) PL151491B1 (fr)
RO (1) RO92321B (fr)
SG (1) SG32193G (fr)
WO (1) WO1985003702A1 (fr)
YU (1) YU44255B (fr)

Families Citing this family (153)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2710040A (en) * 1953-10-29 1955-06-07 Joseph L Boyd Bending machine
US4737588A (en) * 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4885401A (en) * 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4668651A (en) 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4748261A (en) * 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4774361A (en) * 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US4835299A (en) * 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5001274A (en) * 1989-06-23 1991-03-19 Union Carbide Chemicals And Plastics Company Inc. Hydroformylation process
US5210318A (en) * 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
DE4026406A1 (de) * 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
DE69114297T2 (de) * 1990-08-31 1996-05-15 Univ Alberta Methanolcarbonylierung unter verwendung eines übergangsmetallkatalysator-vorläufers.
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
JP2946790B2 (ja) * 1991-03-14 1999-09-06 三菱化学株式会社 アルデヒド類の製造法
US5177019A (en) * 1991-05-20 1993-01-05 Eastman Kodak Company Method of quantitative analysis of organophosphorus compounds
TW213465B (fr) * 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
US5292785A (en) * 1992-05-05 1994-03-08 Ciba-Geigy Corporation Bis-phosphite stabilized compositions
US5312996A (en) * 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5310889A (en) * 1992-07-22 1994-05-10 Ciba-Geigy Corporation Carbohydrate substituted dibenzo(d,f)(1,3,2)dioxaphosphepin stabilizers
US5310890A (en) * 1992-07-22 1994-05-10 Ciba-Geigy Corporation Carbohydrate substituted dibenzoi(d,g)(1,3,2)dioxaphosphocin stabilizers
US5364950A (en) * 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
DE4242723A1 (de) * 1992-12-17 1994-06-23 Hoechst Ag Verfahren zur Herstellung von Aldehyden
EP0635513B1 (fr) * 1993-07-22 1999-04-21 General Electric Company Phosphite ester de néoalkyl alkylidène-2,2'-Bisphényle et biphényle
DK0730574T3 (da) * 1993-11-23 1999-05-25 Du Pont Fremgangsmåder og katalysatorsammensætninger til hydrocyanering af monoolefiner
US5512695A (en) * 1994-04-14 1996-04-30 E. I. Du Pont De Nemours And Company Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
JP3519410B2 (ja) 1994-04-14 2004-04-12 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー モノオレフィン類のヒドロシアン化用二座ホスファイトとニッケル触媒の組成物
US5543536A (en) * 1994-04-26 1996-08-06 E. I. Du Pont De Nemours And Company Monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation
US5633418A (en) * 1994-07-18 1997-05-27 Mitsubishi Chemical Corporation Method for dimerizing an olefin
US5756855A (en) * 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
TW315370B (fr) * 1994-10-07 1997-09-11 Du Pont
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
US5672766A (en) * 1994-12-12 1997-09-30 Mitsubishi Chemical Corporation Method for producing aldehydes
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5821378A (en) * 1995-01-27 1998-10-13 E. I. Du Pont De Nemours And Company Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
IN187044B (fr) * 1995-01-27 2002-01-05 Du Pont
US5744650A (en) * 1995-12-06 1998-04-28 Union Carbide Chemicals & Plastics Technology Corporation Metal-Ligand complex catalyzed processes
US5654455A (en) * 1995-12-21 1997-08-05 Ciba-Geigy Corporation Tris-phosphite ligands and their use in transitioin metal catalyzed processes
US5892119A (en) * 1996-11-26 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5962744A (en) * 1998-03-27 1999-10-05 The Research Foundation Of State University Of New York Process for hydrocarbonylations in supercritical carbon dioxide
JP3847466B2 (ja) * 1998-09-01 2006-11-22 三菱化学株式会社 オレフィンのヒドロホルミル化反応方法
JP3921853B2 (ja) * 1998-12-10 2007-05-30 三菱化学株式会社 アルデヒド類及びアルコール類の製造方法
CN1163463C (zh) 1998-12-10 2004-08-25 三菱化学株式会社 醛的制备方法
JP3928315B2 (ja) * 1998-12-14 2007-06-13 三菱化学株式会社 アルデヒドの製造方法
US6610891B1 (en) 1999-12-03 2003-08-26 Mitsubishi Chemical Corporation Method of producing aldehydes
WO2001051441A1 (fr) * 2000-01-12 2001-07-19 Eastman Chemical Company Procedes d'hydroformylation, pour la production d'aldehydes a partir d'olefines a encombrement sterique
JP3864668B2 (ja) * 2000-05-01 2007-01-10 三菱化学株式会社 アルデヒド類の製造方法
DE10027505A1 (de) * 2000-06-06 2001-12-13 Studiengesellschaft Kohle Mbh Chirale Monophosphite als Liganden für die asymmetrische Übergangsmetall-katalysierte Hydrierung
GB0021715D0 (en) * 2000-09-05 2000-10-18 Ici Plc Recovery of metals
DE10058383A1 (de) 2000-11-24 2002-05-29 Oxeno Olefinchemie Gmbh Neue Phosphininverbindungen und deren Metallkomplexe
DE10140086A1 (de) 2001-08-16 2003-02-27 Oxeno Olefinchemie Gmbh Neue Phosphitverbindungen und neue Phosphitmetallkomplexe
DE10148551A1 (de) * 2001-10-01 2003-04-10 Bayer Ag Chirale Monophosphorverbindungen
DE10149349A1 (de) * 2001-10-06 2003-04-17 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 6-Methylheptan-2-on und dessen Verwendung
DE60304034T2 (de) * 2002-03-11 2006-10-12 Union Carbide Chemicals & Plastics Technology Corp., Danbury Bisphosphit-ligande für carbonylierungsverfahren
DE10220801A1 (de) 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
CN1315767C (zh) 2002-08-31 2007-05-16 奥克森诺奥勒芬化学股份有限公司 烯属不饱和化合物,特别是烯烃在环状碳酸酯存在下的加氢甲酰基化方法
US7294729B2 (en) * 2002-10-15 2007-11-13 Union Carbide Chemicals & Plastics Technology Corporation Bis-chelating ligand and use thereof in carbonylation processes
KR20060096433A (ko) * 2003-10-21 2006-09-11 바스프 악티엔게젤샤프트 알데히드의 연속식 제조 방법
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
DE102004013514A1 (de) * 2004-03-19 2005-10-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen
US7291748B2 (en) 2005-07-28 2007-11-06 Basf Corporation C10/C7 ester mixtures based on 2-propylheptanol
DE102005042464A1 (de) 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
DE102006034442A1 (de) * 2006-07-26 2008-01-31 Oxeno Olefinchemie Gmbh Katalysatorvorstufe für einen Rh-Komplexkatalysator
AR064177A1 (es) 2006-12-07 2009-03-18 Basf Ag Composiciones y kits que comprenden un triazol fungicida y un alcohol alcoxilado, y sus usos
DE102006058682A1 (de) 2006-12-13 2008-06-19 Evonik Oxeno Gmbh Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung
US7586010B2 (en) * 2006-12-21 2009-09-08 Eastman Chemical Company Phosphonite-containing catalysts for hydroformylation processes
MY146608A (en) * 2007-03-20 2012-09-14 Dow Technology Investments Llc Hydroformylation process with improved control over product isomers
WO2008123740A1 (fr) * 2007-04-09 2008-10-16 Lg Chem, Ltd. Composition catalytique contenant des ligands phosphite et procede d'hydroformylation mettant en œuvre cette composition
DE102007023514A1 (de) 2007-05-18 2008-11-20 Evonik Oxeno Gmbh Stabile Katalysatorvorstufe von Rh-Komplexkatalysatoren
CN101796004B (zh) 2007-09-07 2013-11-13 陶氏环球技术公司 脂族二醛至脂族二醇的氢化
US7872156B2 (en) * 2007-12-26 2011-01-18 Eastman Chemical Company Fluorophosphite containing catalysts for hydroformylation processes
US7872157B2 (en) * 2007-12-26 2011-01-18 Eastman Chemical Company Phosphonite containing catalysts for hydroformylation processes
US7708912B2 (en) * 2008-06-16 2010-05-04 Polytronics Technology Corporation Variable impedance composition
CN101981042B (zh) * 2008-03-28 2014-02-19 联合碳化化学品及塑料技术公司 用于单氯代亚磷酸酯合成的淤浆方法
WO2010003073A1 (fr) 2008-07-03 2010-01-07 Dow Technology Investments Llc Procédé de régulation des métaux lourds dans un flux de catalyseur de recyclage
EP2328857B1 (fr) * 2008-08-19 2016-03-23 Dow Technology Investments LLC Procédé d'hydroformylation utilisant un ligand biphosphite symétrique pour un contrôle amélioré sur les isomères des produits
JP5746035B2 (ja) * 2008-10-08 2015-07-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ビスホスファイトの合成のためのスラリープロセス
CN102281948B (zh) 2008-11-14 2015-11-25 堪萨斯大学 聚合物负载的过渡金属催化剂络合物及使用方法
DE102009001225A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom
US7928267B1 (en) 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
DE102009029050A1 (de) 2009-08-31 2011-03-03 Evonik Oxeno Gmbh Organophosphorverbindungen basierend auf Tetraphenol(TP)-substituierten Strukturen
US8586800B2 (en) 2009-10-16 2013-11-19 Dow Technology Investments Llc Gas phase hydroformylation process
EP2496654B1 (fr) 2009-11-05 2014-04-02 Basf Se Adhésifs et matériaux d'étanchéité contenant un ester à base de 2-propylheptanol
WO2011087696A1 (fr) 2009-12-22 2011-07-21 Dow Technology Investments Llc Réglage du rapport aldéhyde normal:aldéhyde iso dans un procédé d'hydroformylation à ligand mixte par réglage de la pression partielle d'oléfine
JP2013515058A (ja) 2009-12-22 2013-05-02 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー シンガス分圧を制御することによる、混合配位子ヒドロホルミル化プロセスにおけるノルマル:イソアルデヒド比の制御
EP2942343B1 (fr) 2009-12-22 2019-09-04 Dow Technology Investments LLC Réglage du rapport aldéhyde normal:aldéhyde iso dans un procédé d'hydroformylation à ligand mixte
JP5652052B2 (ja) * 2010-08-24 2015-01-14 三菱化学株式会社 アルデヒドの製造方法
US8741173B2 (en) 2010-10-05 2014-06-03 Dow Technology Investments Llc Hydroformylation process
SA112330271B1 (ar) * 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
CN102826974B (zh) * 2011-06-17 2015-11-25 中国石油化工股份有限公司 一种丙烯氢甲酰化反应制备丁醛的方法
EP2751122B1 (fr) 2011-09-30 2018-10-24 Dow Technology Investments LLC Procedure de purification
DE102011085883A1 (de) 2011-11-08 2013-05-08 Evonik Oxeno Gmbh Neue Organophosphorverbindungen auf Basis von Anthracentriol
MY166881A (en) 2011-12-20 2018-07-24 Dow Technology Investments Llc A hydroformylation process
EP2855016A1 (fr) 2012-06-04 2015-04-08 Dow Technology Investments LLC Procédé d'hydroformylation
DE102012105878A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isopentanderivaten
MY181661A (en) 2012-08-29 2020-12-31 Dow Technology Investments Llc Catalyst preparation process
JP6068652B2 (ja) 2012-09-25 2017-01-25 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 分解に対してホスフィット配位子を安定化するためのプロセス
DE102013219512A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch aus verschiedenen unsymmetrischen Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
DE102013219506A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Unsymmetrisches Bisphosphit
DE102013219510A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch von Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
DE102013219508A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemische konstitutionsisomerer Bisphosphite
US9272973B2 (en) 2012-10-12 2016-03-01 Evonik Industries Ag Stable long-term method for producing C5-aldehydes
CN104837800B (zh) 2012-12-06 2017-08-29 陶氏技术投资有限责任公司 氢甲酰化方法
RU2527455C1 (ru) * 2013-03-28 2014-08-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения альдегидов
RU2536048C2 (ru) * 2013-03-28 2014-12-20 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ региоселективного получения н-пентаналя
CN104248860A (zh) 2013-06-27 2014-12-31 陶氏技术投资有限责任公司 热管理方法
DE102013020322B4 (de) 2013-12-05 2019-04-18 Oxea Gmbh Verfahren zur Gewinnung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen
DE102013020323B3 (de) 2013-12-05 2015-01-08 Oxea Gmbh Verfahren zur Herstellung von isomeren Hexansäuren aus den bei der Herstellung von Pentanalen anfallenden Nebenströmen
DE102013020320B4 (de) 2013-12-05 2019-04-04 Oxea Gmbh Verfahren zur Herstellung von 2-Methylbuttersäure mit einem vermindertem Gehalt an 3-Methylbuttersäure aus den bei der Herstellung von Pentansäuren anfallenden Nebenströmen
BR112016013001B1 (pt) 2013-12-19 2020-12-29 Dow Technology Investments Llc processo de hidroformilação
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
EP3126319B1 (fr) 2014-03-31 2019-07-17 Dow Technology Investments LLC Procédé d'hydroformylation
JP6694396B2 (ja) 2014-05-14 2020-05-13 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 安定化された有機リン化合物
DE102014209534A1 (de) 2014-05-20 2015-11-26 Evonik Degussa Gmbh Neue Monophosphitliganden mit einer Carbonat-Gruppe
DE102014209532A1 (de) 2014-05-20 2015-11-26 Evonik Degussa Gmbh Neue Monophosphitliganden mit einer tert-Butyloxycarbonyl-Gruppe
DE202014007136U1 (de) 2014-09-08 2014-10-16 Basf Se Härtbare Zusammensetzung, hergestellt mit einem aus (Meth)acrylaten von C10-Alkoholgemischen aufgebauten Copolymer
DE202014007140U1 (de) 2014-09-08 2014-10-22 Basf Se Öl-basierte Bohrflüssigkeiten mit Copolymeren aus Styrol, (Meth)acrylaten von C10-Alkoholgemischen und (Meth)acrylsäure
EP3031815B1 (fr) 2014-12-04 2019-02-20 Evonik Degussa GmbH Terphenyl-2-oxy-phosphites en tant que ligands dans catalysateurs de la hydroformylation
ES2670512T3 (es) * 2014-12-04 2018-05-30 Evonik Degussa Gmbh Ésteres monofosfitos de 9-antrol como ligandos para catalizadores de hidroformilación
ES2670039T3 (es) 2014-12-04 2018-05-29 Evonik Degussa Gmbh Monofosfitos que presentan un componente biarilo asimétrico
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
DE102015207870A1 (de) 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Sulfonatgruppe
DE102015207864A1 (de) 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Ethergruppe
DE102015207860A1 (de) 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Methylgruppe
DE102015207866A1 (de) 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Estergruppe
EP3147289B1 (fr) 2015-09-22 2017-11-22 Evonik Degussa GmbH Monophosphites presentant un derive du binol partiellement hydrogène
EP3147290A1 (fr) * 2015-09-22 2017-03-29 Evonik Degussa GmbH Monophosphites présentant un dérivé du binol
EP3147288A1 (fr) 2015-09-22 2017-03-29 Evonik Degussa GmbH Monophosphites presentant du cyclododecanol
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
PL3374340T3 (pl) 2015-11-10 2022-04-11 Dow Technology Investments Llc Sposób wytwarzania aldehydów
CN108698962B (zh) 2016-02-11 2022-02-25 陶氏技术投资有限责任公司 将烯烃转化成醇、醚或其组合的方法
DE102016205883A1 (de) 2016-04-08 2017-10-12 Evonik Degussa Gmbh Pinakolester von Antracen-9-yloxy substituierten Dioxaphospholanen
EP3296303A1 (fr) * 2016-09-16 2018-03-21 Evonik Degussa GmbH Monophosphites présentant du diphénol comportant un pont méthylène et résidu de diphényl-phényl
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
CN111212826B (zh) 2017-10-25 2023-05-23 陶氏技术投资有限责任公司 减少在加氢甲酰化过程中形成的包含醛化合物的溶液中重物质形成的方法
RU2020117417A (ru) 2017-11-13 2021-11-29 Дау Текнолоджи Инвестментс Ллк Способы извлечения родия из процесса гидроформилирования
TWI793216B (zh) 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
EP3887348B1 (fr) 2018-11-29 2022-11-02 Dow Technology Investments LLC Procédé d'hydroformylation
US10538472B1 (en) 2019-02-14 2020-01-21 Dairen Chemical Corporation Extraction process for high-boiling aldehyde product separation and catalyst recovery
US20220143590A1 (en) 2019-06-27 2022-05-12 Dow Technology Investments Llc Process to prepare solution from hydroformylation process for precious metal recovery
TW202126385A (zh) 2019-11-05 2021-07-16 美商陶氏科技投資有限公司 自氫甲醯化製程回收銠之方法
US11976017B2 (en) 2019-12-19 2024-05-07 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
KR20230120131A (ko) 2020-12-14 2023-08-16 다우 테크놀로지 인베스트먼츠 엘엘씨. 히드로포르밀화 공정에서 촉매 금속 책임량을 개선시키는 방법
CA3202991A1 (fr) 2020-12-22 2022-06-30 Jason F. GILES Procedes de reaction d'hydroformylation
CN118103532A (zh) 2021-11-11 2024-05-28 陶氏技术投资有限责任公司 用于从加氢甲酰化过程中回收铑的方法
WO2023095907A1 (fr) 2021-11-29 2023-06-01 三菱ケミカル株式会社 Procédé de production d'aldéhyde
WO2023114578A1 (fr) 2021-12-16 2023-06-22 Dow Technology Investments Llc Compositions de précurseurs de catalyseur d'hydroformylation de complexe de métal de transition comprenant de tels composés, et procédés d'hydroformylation
WO2023114579A1 (fr) 2021-12-16 2023-06-22 Dow Technology Investments Llc Composés, compositions précurseurs d'un catalyseur d'hydroformylation à base d'un complexe de métaux de transition et comprenant de tels composés, et procédés d'hydroformylation
GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3213155A (en) * 1961-05-19 1965-10-19 Exxon Research Engineering Co Monoolefin isomerization process
US3476699A (en) * 1961-12-18 1969-11-04 Argus Chem Polyvinyl chloride and olefin polymer compositions having improved resistance to deterioration comprising an organic phosphite ester having at least one aromatic polycarbocyclic group
NL297350A (fr) * 1962-08-31
US3297631A (en) * 1965-10-24 1967-01-10 Exxon Research Engineering Co Novel phenolic phosphorus stabilizers for polyolefins
US3437720A (en) * 1966-08-03 1969-04-08 Weston Chemical Corp Carboxylated hydroxy phosphites
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3491024A (en) * 1967-09-15 1970-01-20 Hooker Chemical Corp 2,6-disubstituted primary aryl phosphites,their salts and phosphorodihalidites and processes for the manufacture thereof
US3655832A (en) * 1969-02-18 1972-04-11 Argus Chem Polycarbocyclic phenolic phosphites
JPS4510729Y1 (fr) * 1969-06-02 1970-05-15
JPS4840326B1 (fr) * 1970-12-15 1973-11-30
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4247486A (en) * 1977-03-11 1981-01-27 Union Carbide Corporation Cyclic hydroformylation process
US4094855A (en) * 1976-07-30 1978-06-13 Ciba-Geigy Corporation Hindered phenyl phosphites
US4148430A (en) 1977-05-25 1979-04-10 Innovative Business Forms, Inc. Business form
CA1104587A (fr) * 1977-06-21 1981-07-07 Peter J. Davidson Hydroformylation catalytique d'olefines internes
US4351759A (en) * 1978-01-03 1982-09-28 Ciba-Geigy Corporation Alkylated 2,2'-biphenylene phosphites and stabilized compositions
US4196117A (en) * 1978-01-03 1980-04-01 Ciba-Geigy Corporation Alkylated 1,1'-biphenyl-2,2'-diyl phosphites and stabilized compositions
US4288391A (en) * 1978-01-03 1981-09-08 Ciba-Geigy Corporation Alkylated 2,2'-biphenylene phosphites
DE2837027A1 (de) * 1978-08-24 1980-03-06 Bayer Ag Neue phosphorigsaeureester und ihre verwendung zur stabilisierung von polyamiden
US4298541A (en) * 1979-02-12 1981-11-03 Exxon Research & Engineering Co. Trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous catalysts
DE2965157D1 (en) * 1979-03-21 1983-05-11 Davy Mckee London Process for the production of aldehydes by hydroformylation of alkenes
DE2965158D1 (en) * 1979-03-21 1983-05-11 Davy Mckee London Hydroformylation process
US4283562A (en) * 1979-10-26 1981-08-11 Union Carbide Corporation Hydroformylation process using stable rhodium catalyst
JPS5699246A (en) * 1980-01-10 1981-08-10 Adeka Argus Chem Co Ltd Stabilized synthetic resin composition
GB2068377B (en) * 1980-02-04 1983-09-28 Shell Int Research Process for the hydroformylation of olefins
US4330678A (en) * 1980-02-04 1982-05-18 Shell Oil Company Process for the hydroformylation of olefins
US4374219A (en) * 1980-11-24 1983-02-15 Ciba-Geigy Corporation Alkanolamine ester of 1,1-biphenyl-2,2-diyl-and alkylidene-1,1-biphenyl-2,2-diyl-cyclic phosphites
US4318845A (en) * 1980-11-24 1982-03-09 Ciba-Geigy Corporation Alkanolamine esters of 1,1'-biphenyl-2,2'-diyl-and alkylidene-1,1'-biphenyl-2,2'-diyl-cyclic phosphites
EP0054986A1 (fr) * 1980-12-22 1982-06-30 Shell Internationale Researchmaatschappij B.V. Procédé d'hydroformylation d'oléfines
CA1186342A (fr) * 1981-03-12 1985-04-30 Anthony G. Abatjoglou Procede d'extinction d'hydroperoxydes et d'aldehydes dans les allyl-alkyl ethers
US4388476A (en) * 1981-05-01 1983-06-14 Eastman Kodak Company Hydroformylation process with rhodium catalyst and oxygen stabilization thereof
US4400548A (en) * 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
DE3361212D1 (en) * 1982-06-11 1985-12-19 Davy Mckee London Hydroformylation process
ATE28183T1 (de) * 1982-06-11 1987-07-15 Davy Mckee London Hydroformylierungsverfahren.
EP0096986B1 (fr) * 1982-06-11 1987-04-22 DAVY McKEE (LONDON) LIMITED Procédé d'hydroformylation
DE3234701A1 (de) * 1982-09-18 1984-04-05 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
DE3341035A1 (de) * 1983-11-12 1985-05-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
CA1259331A (fr) * 1984-03-30 1989-09-12 Gregory J. Dembowski Methode pour separer un ligand de phosphore d'un aldehyde vaporise et le recuperer
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes

Also Published As

Publication number Publication date
JPH0645633B2 (ja) 1994-06-15
US4599206A (en) 1986-07-08
SG32193G (en) 1993-05-21
NO854113L (no) 1985-10-16
ES540439A0 (es) 1986-09-01
WO1985003702A1 (fr) 1985-08-29
YU44255B (en) 1990-04-30
MX164254B (es) 1992-07-27
NO165915B (no) 1991-01-21
HU202176B (en) 1991-02-28
AU579144B2 (en) 1988-11-17
NO165915C (no) 1991-05-02
RO92321B (ro) 1987-09-01
EP0155508B1 (fr) 1992-12-09
DK473485D0 (da) 1985-10-16
FI88709C (fi) 1993-06-28
AU2278888A (en) 1989-01-19
PL251973A1 (en) 1986-07-29
KR850700240A (ko) 1985-12-26
EP0155508A1 (fr) 1985-09-25
ES8609185A1 (es) 1986-09-01
CA1262915A1 (fr) 1989-11-14
DE3586878D1 (de) 1993-01-21
ES8706480A1 (es) 1987-07-01
CS271311B2 (en) 1990-09-12
KR920010519B1 (ko) 1992-12-04
DK473485A (da) 1985-12-11
HUT41724A (en) 1987-05-28
FI88709B (fi) 1993-03-15
DE3586878T2 (de) 1993-06-24
JPS61501268A (ja) 1986-06-26
AU3997085A (en) 1985-09-10
RO92321A (fr) 1987-08-31
AU617362B2 (en) 1991-11-28
ATE83230T1 (de) 1992-12-15
PL151491B1 (en) 1990-09-28
FI854059A0 (fi) 1985-10-17
YU22585A (en) 1988-02-29
BR8505278A (pt) 1986-02-18
ES549717A0 (es) 1986-11-16
FI854059L (fi) 1985-10-17
CS109185A2 (en) 1990-02-12
ES554326A0 (es) 1987-07-01
ES8701140A1 (es) 1986-11-16

Similar Documents

Publication Publication Date Title
CA1264055C (fr)
ES2001654A6 (es) Procedimiento de carbonilacion, particularmente hidroformilacion de compuestos organicos para obtener aldehidos.
ES2001416A6 (es) Procedimiento de carbonilacion,particularmente hidroformilacion de compuestos organicos para producir aldehidos.
SG42936A1 (en) Ferrocenyl diphosphines as ligands for homogeneous catalysts
DE3163355D1 (en) Phosphine compounds, transition metal complexes thereof and use thereof as chiral hydrogenation catalysts
DE3768506D1 (de) Chelat-liganden fuer niedrigdruck-hydroformylierungskatalysator und verfahren, die diese verwendungen.
AU627830B2 (en) Catalyst compositions
ES8102842A1 (es) Procedimiento de estabilizacion y regeneracion del cataliza-dor de hidroformilacion del propeno
ES484186A1 (es) Procedimiento para la obtencion de aldehidos
SG82543A1 (en) Process for producing aldehydes
TW283149B (fr)
DE3462882D1 (en) Catalytic system for the hydroformylation of olefins; hydroformalation process
IE841159L (en) Bis-platinum complexes, anti tumor agents.

Legal Events

Date Code Title Description
MKLA Lapsed