BR0212185B1 - compostos derivados de ácido carboxílico de pirazóis e dihidro-1hpirazóis 3-halo-1-aril-substituídos e métodos para a preparação dos mesmos - Google Patents
compostos derivados de ácido carboxílico de pirazóis e dihidro-1hpirazóis 3-halo-1-aril-substituídos e métodos para a preparação dos mesmosInfo
- Publication number
- BR0212185B1 BR0212185B1 BRPI0212185-9B1A BR0212185A BR0212185B1 BR 0212185 B1 BR0212185 B1 BR 0212185B1 BR 0212185 A BR0212185 A BR 0212185A BR 0212185 B1 BR0212185 B1 BR 0212185B1
- Authority
- BR
- Brazil
- Prior art keywords
- pyrazols
- dihydro
- halo
- aryl
- substituted
- Prior art date
Links
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical class C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 title 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/72—Hydrazones
- C07C251/74—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C251/76—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/76—Nitrogen atoms to which a second hetero atom is attached
- C07D213/77—Hydrazine radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/06—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/06—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D231/08—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with oxygen or sulfur atoms directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31191901P | 2001-08-13 | 2001-08-13 | |
| US34195801P | 2001-12-19 | 2001-12-19 | |
| US36966002P | 2002-04-02 | 2002-04-02 | |
| PCT/US2002/025614 WO2003016283A1 (en) | 2001-08-13 | 2002-08-13 | Substituted dihydro 3-halo-1h-pyrazole-5-carboxylates their preparation and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0212185A BR0212185A (pt) | 2004-10-05 |
| BR0212185B1 true BR0212185B1 (pt) | 2013-09-10 |
Family
ID=27405544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0212185-9B1A BR0212185B1 (pt) | 2001-08-13 | 2002-08-13 | compostos derivados de ácido carboxílico de pirazóis e dihidro-1hpirazóis 3-halo-1-aril-substituídos e métodos para a preparação dos mesmos |
Country Status (19)
| Country | Link |
|---|---|
| US (3) | US6965032B2 (enExample) |
| EP (1) | EP1417175B1 (enExample) |
| JP (1) | JP4564748B2 (enExample) |
| KR (1) | KR100953251B1 (enExample) |
| CN (1) | CN1307161C (enExample) |
| AU (1) | AU2002355952B2 (enExample) |
| BR (1) | BR0212185B1 (enExample) |
| CA (1) | CA2454306C (enExample) |
| DK (1) | DK1417175T3 (enExample) |
| ES (1) | ES2428888T3 (enExample) |
| HU (1) | HU230124B1 (enExample) |
| IL (1) | IL159507A0 (enExample) |
| IN (2) | IN215218B (enExample) |
| MX (1) | MXPA04001323A (enExample) |
| PL (1) | PL214276B1 (enExample) |
| PT (1) | PT1417175E (enExample) |
| TW (3) | TWI356822B (enExample) |
| WO (1) | WO2003016283A1 (enExample) |
| ZA (1) | ZA200309911B (enExample) |
Families Citing this family (93)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4448327B2 (ja) * | 2001-08-13 | 2010-04-07 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 新規置換１ｈ−ジヒドロピラゾール、それらの製造および使用 |
| TWI325302B (en) * | 2001-08-13 | 2010-06-01 | Du Pont | Benzoxazinone compounds |
| AR036872A1 (es) * | 2001-08-13 | 2004-10-13 | Du Pont | Compuesto de antranilamida, composicion que lo comprende y metodo para controlar una plaga de invertebrados |
| US7288554B2 (en) * | 2001-08-15 | 2007-10-30 | E.I. Du Pont De Nemours And Company | Ortho-substituted aryl amides for controlling invertebrate pests |
| ATE417829T1 (de) * | 2001-08-16 | 2009-01-15 | Du Pont | Substituierte anthranilamide und ihre verwendung als pesticide |
| TWI283164B (en) * | 2001-09-21 | 2007-07-01 | Du Pont | Anthranilamide arthropodicide treatment |
| US20040110777A1 (en) * | 2001-12-03 | 2004-06-10 | Annis Gary David | Quinazolinones and pyridinylpyrimidinones for controlling invertebrate pests |
| EP1467988B1 (en) * | 2002-01-22 | 2013-07-17 | E.I. Du Pont De Nemours And Company | Quinazoline(di)ones for invertebrate pest control |
| JP4287816B2 (ja) * | 2002-06-13 | 2009-07-01 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ピラゾールカルボキサミド殺虫剤 |
| TWI343376B (en) * | 2002-07-31 | 2011-06-11 | Du Pont | Method for preparing 3-halo-4, 5-dihydro-1h-pyrazoles |
| TWI326283B (en) * | 2002-07-31 | 2010-06-21 | Du Pont | Method for preparing fused oxazinones |
| US7666882B2 (en) * | 2002-11-15 | 2010-02-23 | E.I. Du Pont De Nemours And Company | Anthranilamide insecticides |
| KR100921594B1 (ko) * | 2003-01-28 | 2009-10-14 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 시아노 안트라닐아미드 살충제 |
| TWI367882B (en) * | 2003-03-26 | 2012-07-11 | Du Pont | Preparation and use of 2-substituted-5-oxo-3-pyrazolidinecarboxylates |
| WO2004111030A1 (en) * | 2003-06-12 | 2004-12-23 | E.I. Dupont De Nemours And Company | Method for preparing fused oxazinones |
| DE102004006075A1 (de) | 2003-11-14 | 2005-06-16 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden Eigenschaften |
| DE102004021564A1 (de) | 2003-11-14 | 2005-07-07 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden Eigenschaften |
| DE10353281A1 (de) * | 2003-11-14 | 2005-06-16 | Bayer Cropscience Ag | Wirkstoffkombination mit insektiziden und akariziden Eigenschaften |
| EP1691611A1 (de) | 2003-12-04 | 2006-08-23 | Bayer CropScience Aktiengesellschaft | Wirkstoffkombinationen mit insektiziden eigenschaften |
| DE10356550A1 (de) | 2003-12-04 | 2005-07-07 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden Eigenschaften |
| AR048669A1 (es) * | 2004-03-03 | 2006-05-17 | Syngenta Ltd | Derivados biciclicos de bisamida |
| RU2006139953A (ru) * | 2004-04-13 | 2008-05-20 | Е.И. Дюпон Де Немур Энд Компани (Us) | Антраниламидные инсектициды |
| DE102004031100A1 (de) * | 2004-06-28 | 2006-01-12 | Bayer Cropscience Ag | Anthranilamide |
| GT200500179BA (es) | 2004-07-01 | 2008-10-29 | Mezclas sinergistas de agentes de antranilamida para el control de plagas de invertebrados | |
| DE102004035134A1 (de) | 2004-07-20 | 2006-02-16 | Bayer Cropscience Ag | Selektive Insektizide auf Basis von Halogenalkylnicotinsäurederivaten, Anthranilsäureamiden oder Phthalsäurediamiden und Safenern |
| MY140912A (en) * | 2004-07-26 | 2010-01-29 | Du Pont | Mixtures of anthranilamide invertebrate pest control agents |
| UA93869C2 (en) | 2005-03-18 | 2011-03-25 | Э.И. Дю Пон Де Немур Энд Компани | Method for preparing pyrazoles |
| AU2006283181A1 (en) * | 2005-08-24 | 2007-03-01 | E. I. Du Pont De Nemours And Company | Anthranilamides for controlling invertebrate pests |
| DE102005044108A1 (de) | 2005-09-15 | 2007-03-29 | Bayer Cropscience Ag | Dioxazin- und Oxdiazin-substituierte Arylamide |
| DE102006032168A1 (de) | 2006-06-13 | 2007-12-20 | Bayer Cropscience Ag | Anthranilsäurediamid-Derivate mit heteroaromatischen Substituenten |
| JP5507045B2 (ja) * | 2006-12-15 | 2014-05-28 | 石原産業株式会社 | アントラニルアミド系化合物の製造方法 |
| CN104496901B (zh) * | 2006-12-15 | 2016-05-25 | 石原产业株式会社 | 邻氨基苯甲酰胺系化合物的制造方法 |
| JP2009001541A (ja) * | 2006-12-15 | 2009-01-08 | Ishihara Sangyo Kaisha Ltd | 新規ピラゾール化合物を中間体として用いるアントラニルアミド系化合物の製造方法 |
| TWI415827B (zh) | 2006-12-21 | 2013-11-21 | Du Pont | 製備２-胺基-５-氰基苯甲酸衍生物之方法 |
| ATE538113T1 (de) * | 2007-07-16 | 2012-01-15 | Syngenta Participations Ag | Kondensierte anthranilamid-insektizide |
| CN101550130B (zh) * | 2008-04-01 | 2012-11-07 | 中国中化股份有限公司 | 一种制备3-卤代-1-(3-氯-2-吡啶基)-1h-吡唑-5-甲酰卤的方法 |
| JP5406581B2 (ja) * | 2008-04-16 | 2014-02-05 | 石原産業株式会社 | アントラニルアミド系化合物の製造方法 |
| WO2010069502A2 (de) | 2008-12-18 | 2010-06-24 | Bayer Cropscience Ag | Tetrazolsubstituierte anthranilsäureamide als pestizide |
| AR076719A1 (es) * | 2009-06-02 | 2011-06-29 | Sanofi Aventis Deutschland | Modulo medicinal con derivacion y protector de aguja |
| ES2474015T3 (es) * | 2009-07-23 | 2014-07-08 | Bayer Cropscience Ag | Procedimiento para la preparación de pirazoles sustituidos con arilo |
| KR101042930B1 (ko) * | 2009-08-21 | 2011-06-21 | 문형태 | 아동용 베개 |
| CN102753531B (zh) * | 2009-12-15 | 2015-07-01 | 拜尔农作物科学股份公司 | 制备1-烷基-/1-芳基-5-吡唑羧酸衍生物的方法 |
| EP2533641B1 (de) | 2010-02-09 | 2016-07-13 | Bayer CropScience AG | Hydrazin-substituierte anthranilsäurederivate |
| KR20130052734A (ko) | 2010-04-16 | 2013-05-23 | 바이엘 크롭사이언스 아게 | 농약으로서의 트리아졸-치환된 안트라닐아미드 |
| JP6046035B2 (ja) | 2010-06-15 | 2016-12-14 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ | 環状側鎖を有するアントラニル酸ジアミド誘導体 |
| KR20130089232A (ko) | 2010-06-15 | 2013-08-09 | 바이엘 인텔렉쳐 프로퍼티 게엠베하 | 안트라닐산 디아미드 유도체 |
| BR112012032259A2 (pt) | 2010-06-15 | 2015-09-15 | Bayer Ip Gmbh | "novos derivados de arilamida orto-substituída". |
| MX339033B (es) | 2010-06-15 | 2016-05-05 | Bayer Ip Gmbh | Derivados de acido antranilico. |
| CN103080102B (zh) | 2010-07-09 | 2016-08-24 | 拜耳知识产权有限责任公司 | 作为杀虫剂的邻氨基苯甲酰胺衍生物 |
| EP2621907A1 (en) | 2010-09-29 | 2013-08-07 | E.I. Du Pont De Nemours And Company | Fungicidal imidazoles |
| EP2668153B1 (en) | 2011-01-28 | 2015-03-04 | E.I. Du Pont De Nemours And Company | Method for preparing 2-aminobenzamide derivatives |
| CN102399211A (zh) * | 2011-07-29 | 2012-04-04 | 山东永农作物科学有限公司 | 3-溴-1-(3-氯-2-吡啶基)-4,5-二氢-1h-吡唑-5-甲酸酯的制备方法 |
| AU2012357896B9 (en) | 2011-12-19 | 2016-12-15 | Bayer Cropscience Ag | Use of anthranilic acid diamide derivatives for pest control in transgenic crops |
| EP2606732A1 (en) | 2011-12-19 | 2013-06-26 | Bayer CropScience AG | Use of an anthranilic diamide derivatives with heteroaromatic and heterocyclic substituents in combination with a biological control agent |
| ES2834959T3 (es) | 2012-12-06 | 2021-06-21 | Celgene Quanticel Res Inc | Inhibidores de histona desmetilasa |
| US9609868B2 (en) | 2013-03-06 | 2017-04-04 | Bayer Cropscience Ag | Alkoximino-substituted anthranilic acid diamides as pesticides |
| MX2016004946A (es) | 2013-10-17 | 2016-06-28 | Dow Agrosciences Llc | Procesos para la preparacion de compuestos plaguicidas. |
| CA2925873A1 (en) * | 2013-10-17 | 2015-04-23 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| EP3057431A4 (en) | 2013-10-17 | 2017-04-05 | Dow AgroSciences LLC | Processes for the preparation of pesticidal compounds |
| KR20160075565A (ko) | 2013-10-17 | 2016-06-29 | 다우 아그로사이언시즈 엘엘씨 | 살충성 화합물의 제조 방법 |
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| JP2016536296A (ja) | 2013-10-17 | 2016-11-24 | ダウ アグロサイエンシィズ エルエルシー | 有害生物防除性化合物の製造方法 |
| WO2015058028A1 (en) | 2013-10-17 | 2015-04-23 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| CN103755700B (zh) * | 2013-12-26 | 2015-07-29 | 青岛科技大学 | 一种吡唑酰胺类化合物及其用途 |
| US9029555B1 (en) | 2014-07-31 | 2015-05-12 | Dow Agrosciences Llc | Process for the preparation of 3-(3-chloro-1H-pyrazol-1-yl)pyridine |
| AR098110A1 (es) * | 2014-07-31 | 2016-05-04 | Dow Agrosciences Llc | Proceso para la preparación de 3-(3-cloro-1h-pirazol-1-il)piridina |
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| BR112017002735A2 (pt) | 2014-08-19 | 2017-12-19 | Dow Agrosciences Llc | processo para a preparação de 3-(3-cloro-1h-pirazol-1-il)piridina |
| KR20170058388A (ko) | 2014-09-12 | 2017-05-26 | 다우 아그로사이언시즈 엘엘씨 | 3-(3-클로로-1h-피라졸-1-일)피리딘의 제조 방법 |
| CN106187998A (zh) * | 2016-07-20 | 2016-12-07 | 南通雅本化学有限公司 | 一种1‑（3‑氯吡啶‑2‑基）‑3‑溴‑1h‑吡唑‑5‑甲酸的制备工艺 |
| WO2018125817A1 (en) | 2016-12-29 | 2018-07-05 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| CN110139853B (zh) | 2016-12-29 | 2023-06-16 | 美国陶氏益农公司 | 用于制备杀有害生物化合物的方法 |
| US12024510B2 (en) | 2017-12-20 | 2024-07-02 | Pi Industries Ltd. | Pyrazolopyridine-diamides, their use as insecticide and processes for preparing the same |
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