BR0104335A - Estabilização de catalisadores de ródio para a hidroformilação de olefinas - Google Patents

Estabilização de catalisadores de ródio para a hidroformilação de olefinas

Info

Publication number
BR0104335A
BR0104335A BR0104335-8A BR0104335A BR0104335A BR 0104335 A BR0104335 A BR 0104335A BR 0104335 A BR0104335 A BR 0104335A BR 0104335 A BR0104335 A BR 0104335A
Authority
BR
Brazil
Prior art keywords
olefins
hydroformylation
stabilization
catalysts
rhodium catalysts
Prior art date
Application number
BR0104335-8A
Other languages
English (en)
Inventor
Klaus-Diether Wiese
Martin Trocha
Dirk Roettger
Walter Toetsch
Alfred Kaizik
Wilfried Bueschken
Original Assignee
Oxeno Olefinchemie Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxeno Olefinchemie Gmbh filed Critical Oxeno Olefinchemie Gmbh
Publication of BR0104335A publication Critical patent/BR0104335A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Patente de Invenção: "ESTABILIZAçãO DE CATALISADORES DE RóDIO PARA A HIDROFORMILAçãO DE OLEFINAS". A invenção refere-se a um processo para preparação de aldeídos com 3 até 21 átomos de carbono por hidroformilação das respectivas olefinas com catalisadores de ródio, sendo que a descarga do reator de hidroformilação é separada em uma fase gasosa e uma fase líquida, b) a fase líquida é separada em uma fração de topo, contendo olefinas e aldeídos não-reagidos, e uma fração de fundo contendo o catalisador de ródio e c) a fração de fundo é resfriada abaixo da temperatura da solução do reator de hidroformilação e submetida a um gás contendo monóxido de carbono.
BR0104335-8A 2000-09-29 2001-09-27 Estabilização de catalisadores de ródio para a hidroformilação de olefinas BR0104335A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10048301A DE10048301A1 (de) 2000-09-29 2000-09-29 Stabilisierung von Rhodiumkatalysatoren für die Hydroformylierung von Olefinen

Publications (1)

Publication Number Publication Date
BR0104335A true BR0104335A (pt) 2002-05-07

Family

ID=7658106

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0104335-8A BR0104335A (pt) 2000-09-29 2001-09-27 Estabilização de catalisadores de ródio para a hidroformilação de olefinas

Country Status (19)

Country Link
US (1) US6500991B2 (pt)
EP (1) EP1193239B1 (pt)
JP (1) JP5226922B2 (pt)
KR (1) KR100717984B1 (pt)
CN (1) CN1200923C (pt)
AR (1) AR030811A1 (pt)
AT (1) ATE284375T1 (pt)
BR (1) BR0104335A (pt)
CA (1) CA2357856A1 (pt)
DE (2) DE10048301A1 (pt)
ES (1) ES2231358T3 (pt)
MX (1) MXPA01009756A (pt)
MY (1) MY121533A (pt)
PL (1) PL201587B1 (pt)
RU (1) RU2270829C2 (pt)
SA (1) SA01220521B1 (pt)
SG (1) SG94863A1 (pt)
TW (1) TWI224094B (pt)
ZA (1) ZA200107977B (pt)

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DE50211172D1 (de) * 2001-09-26 2007-12-20 Oxeno Olefinchemie Gmbh Phthalsäurealkylestergemische mit kontrollierter viskosität
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DE10210918B4 (de) 2002-03-13 2004-06-03 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Bisphosphiten
DE10220801A1 (de) 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
DE10223593A1 (de) * 2002-05-27 2003-12-11 Degussa Hydroxydiphosphine und deren Verwendung in der Katalyse
DE10225565A1 (de) 2002-06-10 2003-12-18 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
JP2005537330A (ja) 2002-08-31 2005-12-08 オクセノ　オレフィンヒェミー　ゲゼルシャフト　ミット　ベシュレンクテル　ハフツング 環状カルボン酸エステルの存在で非変性金属錯体により触媒活性されるオレフィン不飽和化合物のヒドロホルミル化によりアルデヒドを製造する方法
CA2496838A1 (en) * 2002-08-31 2004-03-11 Oxeno Olefinchemie Gmbh Process for the hydroformylation of olefinically unsaturated compounds, in particular olefins, in the presence of cyclic carbonic esters
DE10257499A1 (de) 2002-12-10 2004-07-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen
DE10329042A1 (de) * 2003-06-27 2005-01-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Octen aus Crack-C4
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DE102005042464A1 (de) * 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
DE102005046250B4 (de) * 2005-09-27 2020-10-08 Evonik Operations Gmbh Anlage zur Abtrennung von organischen Übergangsmetallkomplexkatalysatoren
JP4835228B2 (ja) * 2006-03-29 2011-12-14 三菱化学株式会社 アルデヒドの製造方法
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CN102470329B (zh) 2009-07-23 2015-06-24 赢创纤维有限公司 由聚合溶液制成的聚酰亚胺膜
KR101229195B1 (ko) 2009-10-07 2013-02-01 주식회사 엘지화학 올레핀으로부터 고 수율의 알데히드 제조 방법 및 이에 사용되는 반응 장치
DE102009047351A1 (de) 2009-12-01 2011-06-09 Evonik Goldschmidt Gmbh Komposit-Siliconmembranen mit hoher Trennwirkung
CN102826971B (zh) * 2011-06-17 2015-01-07 中国石油化工股份有限公司 连续氢甲酰化工艺中催化剂的使用方法
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DE102012202779A1 (de) 2012-02-23 2013-08-29 Evonik Oxeno Gmbh Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches
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RU2557062C1 (ru) * 2014-06-26 2015-07-20 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "РН-ЦИР") Технологическая установка получения альдегидов, преимущественно из бутенов или пропилена, с применением родиевых катализаторов
MY184826A (en) * 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
CN107141204B (zh) 2016-03-01 2022-03-15 陶氏技术投资有限责任公司 氢甲酰化工艺
GB201603558D0 (en) * 2016-03-01 2016-04-13 Johnson Matthey Davy Technologies Ltd Apparatus and process
CN108395370B (zh) * 2017-02-08 2021-04-06 中国石化扬子石油化工有限公司 一种氧化苯乙烯制备苯甲醛的方法
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Also Published As

Publication number Publication date
KR20020025747A (ko) 2002-04-04
DE50104749D1 (de) 2005-01-13
MXPA01009756A (es) 2002-04-15
JP5226922B2 (ja) 2013-07-03
KR100717984B1 (ko) 2007-05-16
DE10048301A1 (de) 2002-04-11
CN1346821A (zh) 2002-05-01
EP1193239A1 (de) 2002-04-03
SG94863A1 (en) 2003-03-18
ATE284375T1 (de) 2004-12-15
ZA200107977B (en) 2002-05-29
PL349832A1 (en) 2002-04-08
CA2357856A1 (en) 2002-03-29
AR030811A1 (es) 2003-09-03
US6500991B2 (en) 2002-12-31
CN1200923C (zh) 2005-05-11
SA01220521B1 (ar) 2006-05-23
TWI224094B (en) 2004-11-21
EP1193239B1 (de) 2004-12-08
MY121533A (en) 2006-01-28
RU2270829C2 (ru) 2006-02-27
US20020065437A1 (en) 2002-05-30
ES2231358T3 (es) 2005-05-16
JP2002161063A (ja) 2002-06-04
PL201587B1 (pl) 2009-04-30

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Legal Events

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

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B25D Requested change of name of applicant approved

Owner name: EVONIK OXENO GMBH (DE)

Free format text: NOME ALTERADO DE: OXENO OLEFINCHEMIE GMBH

B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.