BR0008880A - Processos para a oxidação catalìtica em fase gasosa de propeno de acroelìna e, para a preparação de ácido acrìlico - Google Patents

Processos para a oxidação catalìtica em fase gasosa de propeno de acroelìna e, para a preparação de ácido acrìlico

Info

Publication number
BR0008880A
BR0008880A BR0008880-3A BR0008880A BR0008880A BR 0008880 A BR0008880 A BR 0008880A BR 0008880 A BR0008880 A BR 0008880A BR 0008880 A BR0008880 A BR 0008880A
Authority
BR
Brazil
Prior art keywords
propene
processes
preparation
acrylic acid
oxidation
Prior art date
Application number
BR0008880-3A
Other languages
English (en)
Other versions
BR0008880B1 (pt
Inventor
Heiko Arnold
Signe Unverricht
Ulrich Hammon
Hans-Peter Neumann
Klaus Harth
Andreas Tenten
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19910506A external-priority patent/DE19910506A1/de
Priority claimed from DE1999148241 external-priority patent/DE19948241A1/de
Application filed by Basf Ag filed Critical Basf Ag
Publication of BR0008880A publication Critical patent/BR0008880A/pt
Publication of BR0008880B1 publication Critical patent/BR0008880B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J35/19—

Abstract

"PROCESSOS PARA A OXIDAçãO CATALìTICA EM FASE GASOSA DE PROPENO DE ACROELìNA E, PARA A PREPARAçãO DE áCIDO ACRìLICO". A invenção refere-se a um processo para a oxidação catalítica em fase gasosa de propeno a acroleína em que a mistura inicial gasosa de reação, com uma carga de propeno <242> 160 N1/1.h, é alimentada sobre um catalisador em leito fixo que está acomodado em duas zonas de reação A, B dispostas em uma maneira espacialmente sucessiva, sendo que a temperatura da zona de reação B é mantida a uma temperatura mais alta do que àquela da zona da reação A.
BRPI0008880-3A 1999-03-10 2000-02-28 processos para a oxidação catalìtica em fase gasosa de propeno de acroleìna e, para a preparação de ácido acrìlico. BR0008880B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE19910506A DE19910506A1 (de) 1999-03-10 1999-03-10 Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrolein
DE19910506.5 1999-03-10
DE1999148241 DE19948241A1 (de) 1999-10-07 1999-10-07 Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrolein
DE19948241.1 1999-10-07
PCT/EP2000/001634 WO2000053556A1 (de) 1999-03-10 2000-02-28 Verfahren der katalytischen gasphasenoxidation von propen zu acrolein

Publications (2)

Publication Number Publication Date
BR0008880A true BR0008880A (pt) 2002-01-22
BR0008880B1 BR0008880B1 (pt) 2010-11-30

Family

ID=26052271

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0008880-3A BR0008880B1 (pt) 1999-03-10 2000-02-28 processos para a oxidação catalìtica em fase gasosa de propeno de acroleìna e, para a preparação de ácido acrìlico.

Country Status (9)

Country Link
US (1) US6395936B1 (pt)
EP (1) EP1159244B1 (pt)
JP (1) JP5031946B2 (pt)
CN (1) CN1170799C (pt)
BR (1) BR0008880B1 (pt)
DE (1) DE50004251D1 (pt)
ES (1) ES2209854T3 (pt)
MY (1) MY121141A (pt)
WO (1) WO2000053556A1 (pt)

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MY119958A (en) 1999-03-10 2005-08-30 Basf Ag Catalytic gas-phase oxidation of propene to acrylic acid
US6620968B1 (en) 1999-11-23 2003-09-16 Rohm And Haas Company High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids
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DE10101695A1 (de) * 2001-01-15 2002-07-18 Basf Ag Verfahren zur heterogen katalysierten Gasphasenpartialoxidation von Vorläuferverbindungen der (Meth)acrylsäure
US7115776B2 (en) 2002-07-18 2006-10-03 Basf Aktiengesellschaft Heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound
US6958414B2 (en) * 2002-12-16 2005-10-25 Basf Aktiengesellschaft Preparation of at least one organic compound by heterogeneously catalyzed partial gas-phase oxidation
US7229946B2 (en) * 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
TWI311131B (en) * 2003-03-25 2009-06-21 Basf Ag Heterogeneously catalyzed partial gas phase oxidation of propene to acrolein
JP4504356B2 (ja) * 2003-03-25 2010-07-14 ビーエーエスエフ ソシエタス・ヨーロピア プロペンからアクリル酸への不均一系接触部分気相酸化法
DE10313208A1 (de) * 2003-03-25 2004-10-07 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure
DE10313212A1 (de) 2003-03-25 2004-10-07 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrolein
US7294734B2 (en) * 2003-05-02 2007-11-13 Velocys, Inc. Process for converting a hydrocarbon to an oxygenate or a nitrile
US7220390B2 (en) 2003-05-16 2007-05-22 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
US7524792B2 (en) * 2003-06-04 2009-04-28 Basf Aktiengesellschaft Preparation of catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu
EP1687249B1 (de) * 2003-08-06 2009-12-02 Basf Se Verfahren zum betreiben einer kontinuierlichen heterogen katalysierten gasphasen-partialoxidation wenigstens einer organischen verbindung
WO2005016861A1 (de) * 2003-08-14 2005-02-24 Basf Aktiengesellschaft Verfahren zur herstellung von (meth)acrolein und/oder (meth)acrylsäure
US7253310B2 (en) * 2003-08-19 2007-08-07 Basf Aktiengesellschaft Preparation of (meth)acrylic acid
TWI302147B (en) * 2003-09-01 2008-10-21 Lg Chemical Ltd Method of producing unsaturated aldehyde and unsaturated acid in fixed-bed catalytic partial oxidation reactor with enhanced heat control system
US7019169B2 (en) * 2003-09-23 2006-03-28 Basf Aktiengesellschaft Preparation of (meth)acrylic acid
US7012157B2 (en) 2003-09-23 2006-03-14 Basf Aktiengesellschaft Preparation of (meth)acrylic acid
MY139735A (en) * 2003-11-18 2009-10-30 Basf Ag Preparation of acrolein by heterogeneously catalyzed partial gas phase oxidation of propene
DE10353954A1 (de) 2003-11-18 2005-06-09 Basf Ag Verfahren zur Herstellung von Acrolein durch heterogen katalysierte partielle Gasphasenoxidation von Propen
US8431743B2 (en) * 2004-07-01 2013-04-30 Basf Aktiengesellschaft Preparation of acrylic acid by heterogeneously catalyzed partial gas phase oxidation of propylene
RU2416595C2 (ru) * 2004-07-01 2011-04-20 Басф Акциенгезельшафт Способ снижения температуры горячей точки неподвижного слоя катализатора в процессе получения акролеина или акриловой кислоты или их смеси гетерогенно катализируемым частичным окислением в газовой фазе
JP4947917B2 (ja) 2005-04-18 2012-06-06 株式会社日本触媒 気相接触酸化用の固定床反応器およびアクロレインまたはアクリル酸の製造方法
DE102006000996A1 (de) 2006-01-05 2007-07-12 Basf Ag Verfahren der heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Ausgangsverbindung
EP1734030A1 (de) 2006-01-18 2006-12-20 BASF Aktiengesellschaft Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung
WO2008058918A1 (de) * 2006-11-15 2008-05-22 Basf Se Verfahren zum betreiben einer exothermen heterogen katalysierten partiellen gasphasenoxidation einer organischen ausgangsverbindung zu einer organischen zielverbindung
US9149799B2 (en) 2010-04-28 2015-10-06 Basf Se Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body
DE102010048405A1 (de) 2010-10-15 2011-05-19 Basf Se Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein
KR101554318B1 (ko) * 2013-05-24 2015-09-18 주식회사 엘지화학 아크롤레인 및 아크릴산 제조용 촉매와 이의 제조 방법
EP3068753A1 (de) 2013-11-11 2016-09-21 Basf Se Mechanisch stabiler hohlzylindrischer katalysatorformkörper zur gasphasenoxidation eines alkens zu einem ungesättigten aldehyd und/oder einer ungesättigten carbonsäure
CN105899481A (zh) 2013-11-11 2016-08-24 巴斯夫欧洲公司 制备不饱和醛和/或不饱和羧酸的方法
CN111068697A (zh) * 2018-10-18 2020-04-28 中国石油化工股份有限公司 用于合成丙烯醛的催化剂及其应用
CN111068696B (zh) * 2018-10-18 2023-05-02 中国石油化工股份有限公司 负载型丙烯醛催化剂及其应用
CN111068698A (zh) * 2018-10-18 2020-04-28 中国石油化工股份有限公司 丙烯氧化制丙烯醛的催化剂及其应用
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene

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Also Published As

Publication number Publication date
EP1159244A1 (de) 2001-12-05
CN1343190A (zh) 2002-04-03
DE50004251D1 (de) 2003-12-04
WO2000053556A1 (de) 2000-09-14
US6395936B1 (en) 2002-05-28
ES2209854T3 (es) 2004-07-01
JP5031946B2 (ja) 2012-09-26
BR0008880B1 (pt) 2010-11-30
EP1159244B1 (de) 2003-10-29
CN1170799C (zh) 2004-10-13
MY121141A (en) 2005-12-30
JP2002539100A (ja) 2002-11-19

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 30/11/2010, OBSERVADAS AS CONDICOES LEGAIS.

B25D Requested change of name of applicant approved

Owner name: BASF SE (DE)

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 30.11.2020