BRPI0408629A - processo para a oxidação parcial de propeno a ácido acrìlico em fase gasosa - Google Patents
processo para a oxidação parcial de propeno a ácido acrìlico em fase gasosaInfo
- Publication number
- BRPI0408629A BRPI0408629A BRPI0408629-5A BRPI0408629A BRPI0408629A BR PI0408629 A BRPI0408629 A BR PI0408629A BR PI0408629 A BRPI0408629 A BR PI0408629A BR PI0408629 A BRPI0408629 A BR PI0408629A
- Authority
- BR
- Brazil
- Prior art keywords
- propene
- acrylic acid
- fixed catalyst
- catalyst bed
- reaction stage
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
Abstract
"PROCESSO PARA A OXIDAçãO PARCIAL DE PROPENO A áCIDO ACRìLICO EM FASE GASOSA". A invenção refere-se a um método para a oxidação em fase gasosa heterogeneamente catalisada de propeno para formar ácido acrílico. De acordo com o referido método, a mistura inicial do gás da reação contendo propeno é oxidada, em um primeiro estágio de reação, em um leito de leito de catalisador fixo (a), que consiste de uma pluralidade de zonas de leito de leito de catalisador fixo, e dispostas em duas zonas de temperatura sucessivas A e B. A mistura de gás do produto contendo acroleína do primeiro estágio de reação é então oxidada, em um segundo estágio de reação, em um leito de catalisador fixo (2), que consiste de uma pluralidade de leitos de leito de catalisador fixo e dispostos em duas zonas de temperatura sucessivas C e D. A transição a partir de uma zona de temperatura para outra zona de temperatura não coincide espacialmente com uma transição a partir de uma zona de leito de leito de catalisador fixo para outra zona de leito de leito de catalisador fixo dentro de um estágio de reação.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2003113213 DE10313213A1 (de) | 2003-03-25 | 2003-03-25 | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
US47579003P | 2003-06-05 | 2003-06-05 | |
PCT/EP2004/002936 WO2004085369A1 (de) | 2003-03-25 | 2004-03-20 | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propen zu acrylsäure |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0408629A true BRPI0408629A (pt) | 2006-03-28 |
BRPI0408629B1 BRPI0408629B1 (pt) | 2013-06-25 |
Family
ID=33099282
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0408629-5B1A BRPI0408629B1 (pt) | 2003-03-25 | 2004-03-20 | processo para a oxidaÇço parcial de propeno a Ácido acrÍlico em fase gasosa |
Country Status (9)
Country | Link |
---|---|
US (1) | US7164039B2 (pt) |
EP (1) | EP1611077B1 (pt) |
JP (1) | JP4504356B2 (pt) |
KR (1) | KR101013249B1 (pt) |
AT (1) | ATE389630T1 (pt) |
BR (1) | BRPI0408629B1 (pt) |
DE (1) | DE502004006577D1 (pt) |
ES (1) | ES2300754T3 (pt) |
WO (1) | WO2004085369A1 (pt) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0408539B8 (pt) * | 2003-03-25 | 2021-02-02 | Basf Ag | processo para a oxidação parcial de acroleína para ácido acrílico em fase gasosa |
DE502004006577D1 (de) | 2003-03-25 | 2008-04-30 | Basf Se | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propen zu acrylsäure |
TWI311131B (en) * | 2003-03-25 | 2009-06-21 | Basf Ag | Heterogeneously catalyzed partial gas phase oxidation of propene to acrolein |
DE10313212A1 (de) * | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrolein |
DE10313214A1 (de) * | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure |
EP1687249B1 (de) | 2003-08-06 | 2009-12-02 | Basf Se | Verfahren zum betreiben einer kontinuierlichen heterogen katalysierten gasphasen-partialoxidation wenigstens einer organischen verbindung |
US7012157B2 (en) | 2003-09-23 | 2006-03-14 | Basf Aktiengesellschaft | Preparation of (meth)acrylic acid |
US7019169B2 (en) * | 2003-09-23 | 2006-03-28 | Basf Aktiengesellschaft | Preparation of (meth)acrylic acid |
US7592483B2 (en) * | 2004-07-01 | 2009-09-22 | Basf Aktiengesellschaft | Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation of propylene |
EP1734030A1 (de) | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung |
WO2008058918A1 (de) * | 2006-11-15 | 2008-05-22 | Basf Se | Verfahren zum betreiben einer exothermen heterogen katalysierten partiellen gasphasenoxidation einer organischen ausgangsverbindung zu einer organischen zielverbindung |
DE102007019597A1 (de) * | 2007-04-24 | 2008-05-15 | Basf Ag | Verfahren der Inbetriebnahme einer heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure oder von Methacrolein zu Methacrylsäure |
DE102007025869A1 (de) * | 2007-06-01 | 2008-07-03 | Basf Se | Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett |
DE102008042061A1 (de) * | 2008-09-12 | 2010-03-18 | Basf Se | Verfahren zur Herstellung von geometrischen Katalysatorformkörpern |
DE102008042064A1 (de) * | 2008-09-12 | 2010-03-18 | Basf Se | Verfahren zur Herstellung von geometrischen Katalysatorformkörpern |
DE102008054586A1 (de) * | 2008-12-12 | 2010-06-17 | Basf Se | Verfahren zur kontinuierlichen Herstellung von geometrischen Katalysatorformkörpern K |
DE102009047291A1 (de) | 2009-11-30 | 2010-09-23 | Basf Se | Verfahren zur Herstellung von (Meth)acrolein durch heterogen katalysierte Gasphasen-Partialoxidation |
DE102010048405A1 (de) | 2010-10-15 | 2011-05-19 | Basf Se | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein |
DE102011076931A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base |
DE102012204436A1 (de) | 2012-03-20 | 2012-10-04 | Basf Se | Thermisches Trennverfahren |
DE102013202048A1 (de) | 2013-02-07 | 2013-04-18 | Basf Se | Verfahren zur Herstellung einer katalytisch aktiven Masse, die ein Gemisch aus einem die Elemente Mo und V enthaltenden Multielementoxid und wenigstens einem Oxid des Molybdäns ist |
CN105899481A (zh) | 2013-11-11 | 2016-08-24 | 巴斯夫欧洲公司 | 制备不饱和醛和/或不饱和羧酸的方法 |
CN105899480B (zh) | 2013-11-11 | 2018-11-13 | 巴斯夫欧洲公司 | 用于烯烃气相氧化以获得不饱和醛和/或不饱和羧酸的机械上稳定的中空圆柱形模制催化剂体 |
CN109153627B (zh) * | 2016-04-21 | 2022-08-02 | 罗门哈斯公司 | 在单体生产中使用大孔惰性材料的方法 |
EP3770145A1 (en) | 2019-07-24 | 2021-01-27 | Basf Se | A process for the continuous production of either acrolein or acrylic acid as the target product from propene |
EP4139047A1 (de) | 2020-04-21 | 2023-03-01 | Basf Se | Verfahren zur herstellung eines die elemente mo, w, v und cu enthaltenden katalytisch aktiven multielementoxids |
WO2022090019A1 (de) | 2020-10-29 | 2022-05-05 | Basf Se | Verfahren zur herstellung eines schalenkatalysators |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5673041A (en) * | 1979-11-19 | 1981-06-17 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
DE19910508A1 (de) * | 1999-03-10 | 2000-09-21 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
DE19927624A1 (de) | 1999-06-17 | 2000-12-21 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
DE19948523A1 (de) | 1999-10-08 | 2001-04-12 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
DE19948248A1 (de) | 1999-10-07 | 2001-04-12 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
MY121878A (en) | 1999-03-10 | 2006-02-28 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrylic acid |
MY119958A (en) | 1999-03-10 | 2005-08-30 | Basf Ag | Catalytic gas-phase oxidation of propene to acrylic acid |
MY121141A (en) * | 1999-03-10 | 2005-12-30 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrolein |
JP3732080B2 (ja) * | 1999-08-31 | 2006-01-05 | 株式会社日本触媒 | 接触気相酸化反応器 |
JP2001137688A (ja) * | 1999-08-31 | 2001-05-22 | Nippon Shokubai Co Ltd | 多管式反応器 |
DE19955168A1 (de) * | 1999-11-16 | 2001-05-17 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
US6620968B1 (en) | 1999-11-23 | 2003-09-16 | Rohm And Haas Company | High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids |
DE10313208A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
DE10313212A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrolein |
TWI311131B (en) | 2003-03-25 | 2009-06-21 | Basf Ag | Heterogeneously catalyzed partial gas phase oxidation of propene to acrolein |
DE502004006577D1 (de) | 2003-03-25 | 2008-04-30 | Basf Se | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propen zu acrylsäure |
BRPI0408539B8 (pt) | 2003-03-25 | 2021-02-02 | Basf Ag | processo para a oxidação parcial de acroleína para ácido acrílico em fase gasosa |
-
2004
- 2004-03-20 DE DE502004006577T patent/DE502004006577D1/de not_active Expired - Lifetime
- 2004-03-20 ES ES04722160T patent/ES2300754T3/es not_active Expired - Lifetime
- 2004-03-20 KR KR1020057017975A patent/KR101013249B1/ko active IP Right Grant
- 2004-03-20 WO PCT/EP2004/002936 patent/WO2004085369A1/de active IP Right Grant
- 2004-03-20 EP EP04722160A patent/EP1611077B1/de not_active Expired - Lifetime
- 2004-03-20 AT AT04722160T patent/ATE389630T1/de not_active IP Right Cessation
- 2004-03-20 BR BRPI0408629-5B1A patent/BRPI0408629B1/pt active IP Right Grant
- 2004-03-20 JP JP2006504769A patent/JP4504356B2/ja not_active Expired - Lifetime
- 2004-03-25 US US10/808,282 patent/US7164039B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
BRPI0408629B1 (pt) | 2013-06-25 |
JP2006521318A (ja) | 2006-09-21 |
JP4504356B2 (ja) | 2010-07-14 |
EP1611077A1 (de) | 2006-01-04 |
ATE389630T1 (de) | 2008-04-15 |
US7164039B2 (en) | 2007-01-16 |
WO2004085369A1 (de) | 2004-10-07 |
DE502004006577D1 (de) | 2008-04-30 |
KR101013249B1 (ko) | 2011-02-09 |
EP1611077B1 (de) | 2008-03-19 |
KR20050115312A (ko) | 2005-12-07 |
ES2300754T3 (es) | 2008-06-16 |
US20040192965A1 (en) | 2004-09-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B15K | Others concerning applications: alteration of classification |
Free format text: ALTERADA A CLASSIFICACAO DE C07C 57/05 PARA INT. CL. C07C 51/25, C07C 57/05 Ipc: C07C 57/05 (2006.01) |
|
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B15K | Others concerning applications: alteration of classification |
Free format text: ALTERADA A CLASSIFICACAO DE C07C 57/05 PARA INT.CL. 2013.01 C07C 51/25 Ipc: C07C 51/25 (2006.01) |
|
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 20/03/2004, OBSERVADAS AS CONDICOES LEGAIS. |
|
B25D | Requested change of name of applicant approved |