AU708622B2 - Stereoselective ring opening reactions - Google Patents

Stereoselective ring opening reactions Download PDF

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Publication number
AU708622B2
AU708622B2 AU53639/96A AU5363996A AU708622B2 AU 708622 B2 AU708622 B2 AU 708622B2 AU 53639/96 A AU53639/96 A AU 53639/96A AU 5363996 A AU5363996 A AU 5363996A AU 708622 B2 AU708622 B2 AU 708622B2
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AU
Australia
Prior art keywords
chiral
cyclic
catalyst
independently
heterocycle
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Expired
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AU53639/96A
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AU5363996A (en
Inventor
Eric N Jacobsen
James L Leighton
Luis E Martinez
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Harvard University
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Harvard University
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
    • C07F7/083—Syntheses without formation of a Si-C bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B57/00—Separation of optically-active compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C247/00—Compounds containing azido groups
    • C07C247/14—Compounds containing azido groups with azido groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D317/34—Oxygen atoms
    • C07D317/36—Alkylene carbonates; Substituted alkylene carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1872—Preparation; Treatments not provided for in C07F7/20
    • C07F7/188—Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-O linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1872—Preparation; Treatments not provided for in C07F7/20
    • C07F7/1892—Preparation; Treatments not provided for in C07F7/20 by reactions not provided for in C07F7/1876 - C07F7/1888
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Pyrrole Compounds (AREA)
AU53639/96A 1995-03-14 1996-03-14 Stereoselective ring opening reactions Expired AU708622B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/403374 1995-03-14
US08/403,374 US5665890A (en) 1995-03-14 1995-03-14 Stereoselective ring opening reactions
PCT/US1996/003493 WO1996028402A1 (en) 1995-03-14 1996-03-14 Stereoselective ring opening reactions

Publications (2)

Publication Number Publication Date
AU5363996A AU5363996A (en) 1996-10-02
AU708622B2 true AU708622B2 (en) 1999-08-05

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
AU53639/96A Expired AU708622B2 (en) 1995-03-14 1996-03-14 Stereoselective ring opening reactions

Country Status (15)

Country Link
US (2) US5665890A (enExample)
EP (1) EP0817765B1 (enExample)
JP (2) JP4010562B2 (enExample)
KR (2) KR100473698B1 (enExample)
AT (1) ATE316950T1 (enExample)
AU (1) AU708622B2 (enExample)
CA (1) CA2213007C (enExample)
CZ (1) CZ298023B6 (enExample)
DE (1) DE69635779T2 (enExample)
ES (1) ES2258268T3 (enExample)
HU (1) HU225739B1 (enExample)
MX (1) MX220352B (enExample)
NO (1) NO974234L (enExample)
PL (1) PL184857B1 (enExample)
WO (1) WO1996028402A1 (enExample)

Families Citing this family (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6262278B1 (en) * 1995-03-14 2001-07-17 President And Fellows Of Harvard College Stereoselective ring opening reactions
BR9711805A (pt) 1996-06-20 2002-01-15 Regents The Univesity Of Texas Compostos e métodos para providenciar preparações farmacologicamente ativas e uso dos mesmos
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
CA2295006A1 (en) * 1997-06-20 1998-12-30 Erich S. Uffelman Homogeneous oxidation catalysis using metal complexes
GB9721559D0 (en) * 1997-10-11 1997-12-10 Bp Chem Int Ltd Novel polymerisation catalysts
US6130340A (en) * 1998-01-13 2000-10-10 President And Fellows Of Harvard College Asymmetric cycloaddition reactions
US6211370B1 (en) 1998-01-13 2001-04-03 Harvard University Asymmetric cycloaddition reactions
US6521561B1 (en) * 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
TW576843B (en) 1998-12-25 2004-02-21 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst
US6162924A (en) * 1999-04-09 2000-12-19 Eastman Chemical Company Process for halohydrin preparation
US6410746B1 (en) 1999-04-27 2002-06-25 Research Foundation Of State University Of New York, The Metal cataltsts and methods for making and using same
US6403777B1 (en) * 1999-07-06 2002-06-11 The Ohio State University Research Foundation Metalloligands for cleaving nucleic acids
KR100508382B1 (ko) * 2000-02-02 2005-08-17 주식회사 엘지생명과학 (5ｓ)-[ｎ-(벤질옥시카보닐)-아미노]-(3ｓ,4ｒ)-에폭시-ｎ-[2-메틸-(1ｒ)-[(페닐)카보닐]-프로필]-6-페닐헥산아미드의신규 제조 방법
EP1280753A1 (en) * 2000-04-21 2003-02-05 Rhodia/Chirex, Inc. Process for preparation of r-1-(aryloxy)propan-2-ol
WO2001089690A1 (en) * 2000-05-24 2001-11-29 Rstech Co., Ltd. Novel chiral salen catalysts, and a process for preparing chiral compounds from racemic epoxides for using them
JP2004505098A (ja) 2000-07-31 2004-02-19 ブランデイス　ユニヴァーシティー キラル２−および３−置換カルボン酸類の動力学的分割
US6562967B2 (en) 2000-07-31 2003-05-13 Brandeis University Kinetic resolutions of chiral 2-and-3-substituted carboxylic acids
KR100386552B1 (ko) * 2000-08-03 2003-06-02 한국화인케미칼주식회사 올레핀의 비대칭 에폭시화 반응에 유용한 고분자 키랄살렌 유도체
WO2002012171A1 (en) * 2000-08-05 2002-02-14 Korea Institute Of Science And Technology Method for preparing chiral compound by asymmetric ring opening reactions of epoxides
KR100342659B1 (en) 2000-12-15 2002-07-04 Rstech Co Ltd Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same
US7057057B2 (en) 2002-05-22 2006-06-06 Errant Gene Therapeutics, Llc Histone deacetylase inhibitors based on alpha-ketoepoxide compounds
WO2002085516A1 (en) 2001-04-18 2002-10-31 Sumitomo Chemical Company, Limited Complex catalyst, process for producing the complex catalyst, and process for producing alcohol derivative with the complex catalyst
KR100681326B1 (ko) * 2001-04-20 2007-02-15 주식회사 중외제약 신규한 망간-키랄성 화합물 및 그의 이용방법
JP3968076B2 (ja) * 2001-06-27 2007-08-29 アールエス テック コーポレイション 新しいキラルサレン化合物、キラルサレン触媒及びこれを利用したラセミックエポキシ化合物からキラル化合物を製造する方法
JP4463548B2 (ja) * 2001-07-12 2010-05-19 リアクサ・リミテッド マイクロカプセル化触媒、及びその製造法と使用法
US6639087B2 (en) 2001-08-22 2003-10-28 Rhodia Pharma Solutions Inc. Kinetic resolution method
CA2457211A1 (en) 2001-08-22 2003-03-06 Rhodia Pharma Solutions Inc. Improved hydrolytic kinetic resolution of epoxides
US6870004B1 (en) 2001-08-24 2005-03-22 Northwestern University Metal-ligand complexes and related methods of chemical CO2 fixation
WO2003018183A2 (en) 2001-08-27 2003-03-06 The Research Foundation Of State University Of New York Dirhodium catalyst compositions and methods for using same
WO2003018184A2 (en) 2001-08-27 2003-03-06 The Research Foundation Of State University Of New York Solid support dirhodium catalyst compositions and methods for making and using same
KR100472572B1 (ko) * 2001-10-08 2005-03-07 주식회사 한솔케미칼 라세믹화합물의 비대칭 개환반응에 의한 키랄화합물의제조방법
GB0128839D0 (en) * 2001-12-01 2002-01-23 Univ Cambridge Tech Encapsulated transition metal reagents for reactions in supercritical carbon dioxide
DE10164348A1 (de) * 2001-12-28 2003-07-17 Basf Ag Verfahren zur Herstellung von 1-Methoypropanol-2
US6982335B2 (en) * 2002-05-15 2006-01-03 Genzyme Corporation Synthesis of substituted thiazoline carboxylic acids
US6781006B2 (en) * 2002-09-17 2004-08-24 Rhodia Pharma Solutions Inc. Active catalysts for stereoselective ring-opening reactions
PL397715A1 (pl) * 2002-12-11 2012-03-26 Bristol-Myers Squibb Company Pochodna cyklopentadienowa i sposób jej wytwarzania
WO2005012209A2 (en) * 2003-06-10 2005-02-10 University Of North Carolina At Chapel Hill Catalyzed enantioselective transformation of alkenes
US7531662B2 (en) 2003-06-11 2009-05-12 Brandeis University Cinchona-alkaloid-based catalysts, and asymmetric alcoholysis of cyclic anhydrides using them
KR20070008573A (ko) 2004-01-27 2007-01-17 유니버시티 오브 사우스 플로리다 성장 인자-결합 화합물들과 사용 방법
US7700798B1 (en) 2005-06-08 2010-04-20 The Research Foundation Of State University Of New York Erogorgiaene congeners and methods and intermediates useful in the preparation of same
US7816536B2 (en) * 2005-06-10 2010-10-19 The Research Foundation Of State University Of New York 4-substituted and 7-substituted indoles, benzofurans, benzothiophenes, benzimidazoles, benzoxazoles, and benzothiazoles and methods for making same
US7385064B1 (en) 2005-11-30 2008-06-10 The Research Foundation Of State University Of New York Catalysts for use in enantioselective synthesis
WO2007081907A2 (en) 2006-01-05 2007-07-19 Teva Gyogyszergyar Zartkoruen Mukodo Reszvenytarsasag Crystalline forms of dolasetron base and processes for preparation thereof
JP4590607B2 (ja) * 2006-03-09 2010-12-01 独立行政法人科学技術振興機構 光学活性１，２−ジアミン化合物の製造方法及び光学活性ニオブ触媒
KR100880360B1 (ko) * 2006-08-07 2009-01-28 주식회사 알에스텍 이합체 살렌 촉매를 이용한 알킬렌 카보네이트의 제조방법
US20080114401A1 (en) * 2006-11-10 2008-05-15 Warsaw Orthopedic, Inc. Posterior Fixation Devices and Methods of Use
ES2391911T3 (es) * 2006-11-27 2012-12-03 Zach System S.P.A. Proceso para preparación de nebivolol
PL2285864T3 (pl) 2008-05-09 2017-07-31 Cornell University Polimery tlenku etylenu i ditlenku węgla
KR101823440B1 (ko) 2008-08-22 2018-03-14 사우디 아람코 테크놀로지스 컴퍼니 촉매 및 중합체 합성방법
CN111848940B (zh) 2008-09-08 2024-09-06 沙特阿美技术公司 聚碳酸酯多元醇组合物和方法
US8252891B2 (en) * 2008-09-17 2012-08-28 Novomer, Inc. Purification of polycarbonates
WO2010062703A1 (en) 2008-11-01 2010-06-03 Novomer, Inc. Polycarbonate block copolymers
KR101885503B1 (ko) 2009-12-24 2018-08-07 사우디 아람코 테크놀로지스 컴퍼니 폴리사이클릭 구아니딘 화합물의 합성방법
WO2012037282A2 (en) 2010-09-14 2012-03-22 Novomer, Inc. Catalysts and methods for polymer synthesis
US8859822B2 (en) 2010-09-22 2014-10-14 Novomer, Inc. Synthesis of substituted salicylaldehyde derivatives
MY180887A (en) * 2010-11-18 2020-12-11 Saudi Basic Ind Corp Process for preparing a polyester
JP6054950B2 (ja) 2011-05-09 2016-12-27 ノボマー， インコーポレイテッド ポリマー組成物および方法
KR20200096694A (ko) 2011-07-25 2020-08-12 사우디 아람코 테크놀로지스 컴퍼니 폴리우레탄에 이용하기 위한 지방족 폴리카보네이트
KR102070803B1 (ko) 2011-12-11 2020-03-02 사우디 아람코 테크놀로지스 컴퍼니 2가음이온성 반대이온을 갖는 살렌 착물
US9512269B2 (en) 2011-12-20 2016-12-06 Novomer, Inc. Methods for polymer synthesis
CN114774053A (zh) 2012-04-16 2022-07-22 沙特阿美技术公司 粘合剂组合物和方法
KR102159100B1 (ko) 2012-05-24 2020-09-23 사우디 아람코 테크놀로지스 컴퍼니 폴리카보네이트 폴리올 조성물 및 방법
KR102096761B1 (ko) 2012-08-24 2020-04-03 사우디 아람코 테크놀로지스 컴퍼니 금속 착물
EP2917257B1 (en) 2012-11-07 2019-09-11 Saudi Aramco Technologies Company High strength polyurethane foam compositions and methods
CN103242375B (zh) * 2013-05-08 2015-08-26 沈阳金久奇科技有限公司 一种制备手性环氧烷烃和二醇的高活性双功能催化剂及其应用
US10308759B2 (en) 2014-04-03 2019-06-04 Saudi Aramco Technologies Company Aliphatic polycarbonate polyol compositions
EP3781609A1 (en) 2018-04-18 2021-02-24 Saudi Aramco Technologies Company End-group isomerization of poly(alkylene carbonate) polymers
CN109012748B (zh) * 2018-07-27 2021-03-16 安徽师范大学 吡啶取代吡咯基稀土金属催化剂及其制备方法和应用
US11180609B2 (en) 2018-08-02 2021-11-23 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
US11634539B2 (en) 2018-09-24 2023-04-25 Saudi Aramco Technologies Company Polycarbonate block copolymers and methods thereof
KR20220074932A (ko) * 2019-09-30 2022-06-03 피티티 글로벌 케미컬 퍼블릭 컴퍼니 리미티드 Co2 및 에폭사이드로부터 환형 카보네이트 제조용 촉매 조성물
CN112724060B (zh) * 2021-01-15 2022-10-21 常州博海威医药科技股份有限公司 前列腺素的新制备方法以及中间体
KR20240034195A (ko) 2021-06-23 2024-03-13 사우디 아람코 테크놀로지스 컴퍼니 폴리올 조성물 및 방법

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5231865B2 (enExample) * 1971-08-16 1977-08-17
FR2348901A1 (fr) * 1976-04-23 1977-11-18 Roussel Uclaf Procede de transformation d'un ester d'acide chiral d'alcool secondaire alpha-cyane optiquement actif en ester d'acide chiral d'alcool secondaire alpha-cyane racemique
US4594439A (en) * 1980-08-06 1986-06-10 The Board Of Trustees Of The Leland Stanford Jr. University Method for asymmetric epoxidation
US4471130A (en) * 1980-08-06 1984-09-11 The Board Of Trustees Of The Leland Stanford Junior University Method for asymmetric epoxidation
US4538003A (en) * 1983-10-27 1985-08-27 E. I. Du Pont De Nemours And Company Monoorganylation of dihaloaromatics
US4663467A (en) * 1984-03-05 1987-05-05 The Dow Chemical Company Novel porphyrinate and amine composition useful as catalysts in the preparation of alkylene carbonates
US4565845A (en) * 1984-09-05 1986-01-21 Hitachi Chemical Company, Ltd. Process for producing polyester and block copolymer thereof
US4822899A (en) * 1985-04-12 1989-04-18 The University Of Michigan Metallic porphyrin complexes as catalysts in epoxidation reactions
US5093491A (en) * 1987-01-02 1992-03-03 Sun Refining And Marketing Company Hydrocarbon oxidations catalyzed by azide-activated metal coordination complexes
US4885376A (en) * 1987-10-13 1989-12-05 Iowa State University Research Foundation, Inc. New types of organometallic reagents and catalysts for asymmetric synthesis
US5126494A (en) * 1988-01-11 1992-06-30 Massachusetts Institute Of Technology Methods for catalytic asymmetric dihydroxylation of olefins
US4965364A (en) * 1988-02-23 1990-10-23 Massachusetts Institute Of Technology Ligand-accelerated catalytic asymmetric dihydroxylation
IT1217608B (it) * 1988-05-17 1990-03-30 Istituto Guido Donegami Spa Processo per la preparazione di epossidi
US5321143A (en) * 1988-05-26 1994-06-14 Massachusetts Institute Of Technology Ruthenium-catalyzed production of cyclic sulfates
US4870208A (en) * 1988-06-03 1989-09-26 Monsanto Company Asymmetric hydrogenolysis of epoxides
DK0521099T3 (da) * 1990-03-21 1998-09-07 Res Corp Technologies Inc Chirale katalysatorer og epoxidationsreaktioner katalyseret derved
US5175311A (en) * 1990-03-29 1992-12-29 Research Corporation Technologies, Inc. Method of enantioselective cyclopropanation using chiral catalysts
US5258553A (en) * 1991-04-26 1993-11-02 E. I. Dupont De Nemours And Company Chiral tridentate bis(phospholane) ligands
JP3070141B2 (ja) * 1991-05-20 2000-07-24 チッソ株式会社 光学活性アルケニルエチレングリコール類およびその製造方法
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
ES2171159T3 (es) * 1991-08-26 2002-09-01 Res Corp Technologies Inc Procedimiento para la preparacion de epoxicromanos con un catalizador quiral.
US5352814A (en) * 1991-08-30 1994-10-04 Nissan Chemical Industries, Ltd. Asymmetric epoxidation reaction
DE4129753C2 (de) * 1991-09-04 1995-05-04 Dainippon Ink & Chemicals Verfahren zur Herstellung von Cyclocarbonatverbindungen
US5175335A (en) * 1991-11-12 1992-12-29 E. I. Du Pont De Nemours And Company Enantioselective hydrocyanation of aromatic vinyl compounds
US5250731A (en) * 1992-03-17 1993-10-05 E. I. Du Pont De Nemours And Company Preparation of optically active hydrazines and amines
JPH0665159A (ja) * 1992-08-12 1994-03-08 Nippon Shokubai Co Ltd アルキレンアミン類の製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
J AM CHEM SOCIETY, 117, NO. 21, 1995, PP 5897-5898 *

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CA2213007A1 (en) 1996-09-19
HUP9801419A2 (hu) 1998-10-28
DE69635779T2 (de) 2006-09-21
ES2258268T3 (es) 2006-08-16
CZ287097A3 (cs) 1998-09-16
AU5363996A (en) 1996-10-02
JP2007112812A (ja) 2007-05-10
DE69635779D1 (de) 2006-04-13
HU225739B1 (en) 2007-07-30
MX220352B (en) 2004-05-12
EP0817765A1 (en) 1998-01-14
KR19980702982A (ko) 1998-09-05
JPH11502198A (ja) 1999-02-23
KR100473698B1 (ko) 2005-07-07
CZ298023B6 (cs) 2007-05-30
NO974234L (no) 1997-11-13
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PL327632A1 (en) 1998-12-21
CA2213007C (en) 2004-01-27
KR19987002982A (enExample) 1998-09-05
HUP9801419A3 (en) 1999-05-28
JP4010562B2 (ja) 2007-11-21
US5665890A (en) 1997-09-09
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US5929232A (en) 1999-07-27

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