AU641584B2 - Ethylene oxide catalyst and process - Google Patents

Ethylene oxide catalyst and process Download PDF

Info

Publication number
AU641584B2
AU641584B2 AU10341/92A AU1034192A AU641584B2 AU 641584 B2 AU641584 B2 AU 641584B2 AU 10341/92 A AU10341/92 A AU 10341/92A AU 1034192 A AU1034192 A AU 1034192A AU 641584 B2 AU641584 B2 AU 641584B2
Authority
AU
Australia
Prior art keywords
oxide
catalyst
weight
percent
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU10341/92A
Other languages
English (en)
Other versions
AU1034192A (en
Inventor
John Edward Buffum
William Herman Gerdes
Ruth Mary Kowaleski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of AU1034192A publication Critical patent/AU1034192A/en
Application granted granted Critical
Publication of AU641584B2 publication Critical patent/AU641584B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AU10341/92A 1991-01-22 1992-01-20 Ethylene oxide catalyst and process Ceased AU641584B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US64360691A 1991-01-22 1991-01-22
US643606 1991-01-22

Publications (2)

Publication Number Publication Date
AU1034192A AU1034192A (en) 1992-07-30
AU641584B2 true AU641584B2 (en) 1993-09-23

Family

ID=24581537

Family Applications (1)

Application Number Title Priority Date Filing Date
AU10341/92A Ceased AU641584B2 (en) 1991-01-22 1992-01-20 Ethylene oxide catalyst and process

Country Status (20)

Country Link
US (1) US5145824A (enExample)
EP (1) EP0496470B1 (enExample)
JP (1) JP3302387B2 (enExample)
KR (1) KR100225874B1 (enExample)
CN (1) CN1035161C (enExample)
AU (1) AU641584B2 (enExample)
BR (1) BR9200166A (enExample)
CA (1) CA2059711C (enExample)
CZ (1) CZ281977B6 (enExample)
DE (1) DE69200450T2 (enExample)
DK (1) DK0496470T3 (enExample)
ES (1) ES2061309T3 (enExample)
IN (1) IN184775B (enExample)
MX (1) MX9200243A (enExample)
PL (1) PL174992B1 (enExample)
RU (1) RU2014114C1 (enExample)
SA (1) SA92120369B1 (enExample)
SK (1) SK279174B6 (enExample)
TR (1) TR25623A (enExample)
ZA (1) ZA92376B (enExample)

Families Citing this family (100)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5447897A (en) * 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
KR100354430B1 (ko) * 1993-07-07 2003-01-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화촉매
DE69426321T2 (de) * 1993-08-06 2001-04-05 Sumitomo Chemical Co., Ltd. Verfahren zur Herstellung von Olefinoxiden
US5418202A (en) * 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
US5545603A (en) * 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
US5705661A (en) * 1995-09-25 1998-01-06 Mitsubishi Chemical Corporation Catalyst for production of ethylene oxide
US5763630A (en) * 1996-03-18 1998-06-09 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts
US5733842A (en) * 1996-04-30 1998-03-31 Norton Checmical Process Products Corporation Method of making porous catalyst carrier without the addition of pore forming agents
RU2189378C2 (ru) * 1996-07-01 2002-09-20 Дзе Дау Кемикал Компани Способ получения олефиноксидов прямым окислением олефинов, каталитический состав для этого процесса и способ его регенерации
US5864047A (en) * 1997-04-10 1999-01-26 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing rhenium and potassium promoters
US5861519A (en) * 1997-05-23 1999-01-19 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters
JPH11191963A (ja) * 1997-12-25 1999-07-13 Fujitsu Ltd 電源装置
US6455713B1 (en) 1998-09-14 2002-09-24 Eastman Chemical Company Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene
DE69924453T2 (de) * 1998-11-17 2006-02-16 Nippon Shokubai Co., Ltd. Katalysatorträger zur Verwendung in der Herstellung von Ethylenoxid
RU2141378C1 (ru) * 1999-02-22 1999-11-20 Сотников Валерий Васильевич Носитель серебросодержащего катализатора получения оксида этилена и способ его получения
US6172245B1 (en) 1999-12-16 2001-01-09 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
JP2004515331A (ja) * 2000-05-01 2004-05-27 サイエンティフィック・デザイン・カンパニー・インコーポレーテッド エチレンオキシド触媒
RU2190466C2 (ru) * 2000-12-04 2002-10-10 Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" Носитель для катализаторов
ZA200200049B (en) * 2001-01-25 2002-07-16 Nippon Catalytic Chem Ind Fixed-bed shell-and-tube reactor and its usage.
JP4050041B2 (ja) * 2001-11-06 2008-02-20 株式会社日本触媒 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法
US7193094B2 (en) * 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
WO2003072246A2 (en) * 2002-02-25 2003-09-04 Shell Internationale Research Maatschappij B.V. Supported silver catalyst and an epoxidation process using the catalyst
US6831037B2 (en) * 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
BR0312244B1 (pt) * 2002-06-28 2013-06-25 mÉtodo para melhorar a seletividade de um catalisador e um processo para a epoxidaÇço de uma olefina
WO2004039790A1 (en) * 2002-10-28 2004-05-13 Shell Internationale Research Maatschappij B.V. Olefin oxide catalysts
DE602004009776T2 (de) * 2003-04-01 2008-08-28 Shell Internationale Research Maatschappij B.V. Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
RU2342993C2 (ru) 2003-05-07 2009-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализаторы, содержащие серебро, получение таких катализаторов и их применение
US8148555B2 (en) 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
RU2372342C2 (ru) * 2003-08-22 2009-11-10 Дау Текнолоджи Инвестментс Ллс. Улучшенные носители из оксида алюминия и катализаторы на основе серебра для получения алкиленоксидов
CN101757914A (zh) * 2003-10-16 2010-06-30 陶氏技术投资有限责任公司 用于烯化氧制备的具有提高稳定性、效率和/或活性的催化剂
US6939979B2 (en) * 2003-11-10 2005-09-06 Scientific Design Co., Inc. Oxidation process and catalyst
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
TW200616989A (en) 2004-06-18 2006-06-01 Shell Int Research A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
ATE554080T1 (de) 2004-06-18 2012-05-15 Shell Int Research Verfahren zur herstellung eines olefinoxids, 1,2- diols, a 1,2-diolethers oder alkanolamins
US7767619B2 (en) * 2004-07-09 2010-08-03 Sud-Chemie Inc. Promoted calcium-aluminate supported catalysts for synthesis gas generation
BRPI0514207A (pt) * 2004-08-12 2008-06-03 Shell Int Research método para a preparação de um catalisador moldado, o catalisador, e uso do catalisador
KR20070058576A (ko) 2004-09-01 2007-06-08 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀 에폭시화 방법, 이 방법에 사용되는 촉매, 이촉매의 제조에 사용되는 담체, 및 이 담체의 제조방법
US8536083B2 (en) 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
AU2005289799A1 (en) * 2004-09-24 2006-04-06 Shell Internationale Research Maatschappij B.V. A process for selecting shaped particles, a process for installing a system, a process for reacting a gaseous feedstock in such a system, a computer program product, and a computer system
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
DE102005023955A1 (de) * 2005-05-20 2006-11-23 Basf Ag Inertmaterial für den Einsatz in exothermen Reaktionen
BRPI0611817A2 (pt) * 2005-06-07 2011-12-20 Saint Gobain Ceramics veìculo catalisador e um processo para preparação do veìculo catalisador
WO2006133183A2 (en) 2005-06-07 2006-12-14 Shell Internationale Research Maatschappij B.V. A catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
CN101272853A (zh) * 2005-08-11 2008-09-24 国际壳牌研究有限公司 成型催化剂的制备方法、催化剂和催化剂的用途
CN100577289C (zh) * 2006-01-28 2010-01-06 中国石油化工股份有限公司 环氧乙烷生产用银催化剂的载体、其制备方法及其应用
US20070185339A1 (en) * 2006-02-03 2007-08-09 Jian Lu Process for treating a catalyst, the catalyst, and use of the catalyst
WO2007095453A2 (en) * 2006-02-10 2007-08-23 Shell Oil Company A process for preparing a catalyst, the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
CN101426573B (zh) * 2006-04-18 2015-08-05 陶氏环球技术公司 环氧烷催化剂及其应用
US20070280877A1 (en) * 2006-05-19 2007-12-06 Sawyer Technical Materials Llc Alpha alumina supports for ethylene oxide catalysts and method of preparing thereof
DE102007017080A1 (de) 2007-04-10 2008-10-16 Basf Se Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres
BRPI0811305B1 (pt) 2007-05-09 2020-02-27 Shell Internationale Research Maatschappij B.V. Catalisador de epoxidação, um processo para preparação do catalisador e um processo para a produção de um óxido de olefina, um 1,2-diol, um éter de 1,2-diol, um 1,2-carbonato ou uma alcanolamina
JP2010527352A (ja) 2007-05-11 2010-08-12 ビリッグ，バリー，ジェイ． 酸化オレフィンプラントにおける高選択性触媒の開始
CN101687159B (zh) 2007-05-18 2013-04-03 国际壳牌研究有限公司 反应器系统、吸收剂和用于使原料反应的方法
EP2155358A2 (en) * 2007-05-18 2010-02-24 Shell Internationale Research Maatschappij B.V. A reactor system, and a process for preparing an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate and an alkanolamine
DE102007028333A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors
DE102007028332A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst
JP5581058B2 (ja) * 2008-01-11 2014-08-27 株式会社日本触媒 エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
CA2723160A1 (en) * 2008-04-30 2009-11-05 Dow Technology Investments Llc Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
EP2293872A1 (en) * 2008-04-30 2011-03-16 Dow Technology Investments LLC Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
CN102015101B (zh) * 2008-04-30 2013-11-06 陶氏技术投资有限公司 多孔体前体,成形多孔体,它们的制备方法和基于它们的终端产品
WO2009137427A2 (en) 2008-05-07 2009-11-12 Shell Oil Company A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
KR101629038B1 (ko) * 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
BRPI0912718B1 (pt) 2008-05-15 2017-12-26 Shell Internationale Research Maataschappij B.V Method for producing an alkylene carbonate and / or an alkylene glycol
CA2724084A1 (en) * 2008-05-15 2009-11-19 Shell Internationale Research Maatschappij B.V. Process for the preparation of an alkylene carbonate and an alkylene glycol
WO2010001732A1 (ja) 2008-06-30 2010-01-07 株式会社日本触媒 固定床多管式反応器への固体粒状物の充填方法
WO2010007011A1 (en) * 2008-07-14 2010-01-21 Basf Se Process for making ethylene oxide
WO2010009021A2 (en) * 2008-07-14 2010-01-21 Velocys Inc. Process for making ethylene oxide using microchannel process technology
US8349765B2 (en) 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
JP2010234264A (ja) * 2009-03-31 2010-10-21 Nippon Shokubai Co Ltd エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
WO2010113963A1 (ja) * 2009-03-31 2010-10-07 株式会社日本触媒 エチレンオキシド製造用触媒およびエチレンオキシドの製造方法
CA2759496C (en) * 2009-04-21 2018-05-01 Dow Technology Investments Llc Epoxidation reactions and operating conditions thereof
US8362284B2 (en) * 2009-04-21 2013-01-29 Dow Technology Investments Llc Method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst
CA2758818C (en) * 2009-04-21 2018-05-29 Dow Technology Investments Llc Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages
US8524927B2 (en) * 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
JP2011121048A (ja) * 2009-12-09 2011-06-23 Rohm & Haas Co 固体触媒物質をブレンドし、管状構造物に装填する方法
JP2012522061A (ja) * 2009-12-28 2012-09-20 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー アルキレンオキサイドの製造における銀触媒上への塩化銀の生成の制御方法
US8937031B2 (en) 2010-03-01 2015-01-20 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
US20110275842A1 (en) * 2010-05-10 2011-11-10 Hoflund Gar B Nanostructured catalyst pellets, catalyst surface treatment and highly selective catalyst for ethylene epoxidation
US9018126B2 (en) 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
WO2013095888A1 (en) 2011-12-19 2013-06-27 Dow Technology Investments Llc Method of formulating alkylene oxide catalyst in relation to catalyst reference properties
CN103357437B (zh) * 2012-03-28 2016-03-30 中国石油化工股份有限公司 制备用于银催化剂的氧化铝载体的方法及其银催化剂
JP6090567B2 (ja) 2012-12-18 2017-03-08 京進工業株式会社 拡管装置
FR3001969B1 (fr) 2013-02-12 2015-08-21 IFP Energies Nouvelles Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermiquement integre
FR3001968B1 (fr) 2013-02-12 2015-02-27 IFP Energies Nouvelles Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermo-mecaniquement integre
TWI632138B (zh) * 2013-05-16 2018-08-11 科學設計股份有限公司 具有降低鈉含量之建基於銀之環氧乙烷觸媒
CN104549543B (zh) * 2013-10-29 2017-08-25 中国石油化工股份有限公司 氧化铝载体、由其制成的银催化剂及其应用
JP2019524439A (ja) 2016-08-08 2019-09-05 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ エチレンのエチレンオキシドへの酸化用触媒
PL3548471T3 (pl) 2016-12-02 2021-10-25 Shell Internationale Research Maatschappij B.V. Sposoby kondycjonowania katalizatora epoksydowania etylenu oraz powiązane sposoby wytwarzania tlenku etylenu
CN108283943B (zh) * 2017-01-10 2021-07-02 中国石油化工股份有限公司 氧化铝载体及其制备方法、乙烯环氧化反应用银催化剂及乙烯环氧化制备环氧乙烷的方法
TWI808125B (zh) * 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
CN111072803B (zh) * 2018-10-19 2022-07-12 中国石油化工股份有限公司 烯烃聚合催化剂载体及其制备方法和应用
TW202239752A (zh) 2020-12-29 2022-10-16 荷蘭商蜆殼國際研究所 用於生產環氧乙烷之製程
TW202237260A (zh) * 2021-01-19 2022-10-01 美商科學設計有限公司 用於製造管間距減小的立式沸騰反應器的管與管板焊接
CN115382525B (zh) * 2021-05-24 2024-05-10 中国石油化工股份有限公司 一种α-氧化铝载体及其制备方法和银催化剂和应用
CN116943746A (zh) * 2022-04-13 2023-10-27 中国石油化工股份有限公司 乙烯环氧化用银催化剂的载体、银催化剂和乙烯环氧化生产环氧乙烷的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3725307A (en) * 1967-01-30 1973-04-03 Halcon International Inc Process for preparing a silver-supported catalyst
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
EP0247414A2 (en) * 1986-05-09 1987-12-02 Mitsubishi Petrochemical Co., Ltd. Silver-deposited catalyst and its use for production of ethylene oxide

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8501862A (nl) * 1985-06-28 1987-01-16 Shell Int Research Werkwijze ter bereiding van een zilver-houdende katalysator.
IN169589B (enExample) * 1986-10-31 1991-11-16 Shell Int Research
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
GB8626687D0 (en) * 1986-11-07 1986-12-10 Shell Int Research Preparing silver catalyst
GB8716653D0 (en) * 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
US4874879A (en) * 1988-07-25 1989-10-17 Shell Oil Company Process for starting-up an ethylene oxide reactor
EP0357293B1 (en) * 1988-08-30 1996-02-28 Union Carbide Corporation Catalysts for the production of ethylene oxide and their preparation processes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3725307A (en) * 1967-01-30 1973-04-03 Halcon International Inc Process for preparing a silver-supported catalyst
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
EP0247414A2 (en) * 1986-05-09 1987-12-02 Mitsubishi Petrochemical Co., Ltd. Silver-deposited catalyst and its use for production of ethylene oxide

Also Published As

Publication number Publication date
CZ281977B6 (cs) 1997-04-16
KR100225874B1 (ko) 1999-10-15
CA2059711A1 (en) 1992-07-23
KR920014515A (ko) 1992-08-25
AU1034192A (en) 1992-07-30
PL293237A1 (en) 1992-11-02
SA92120369B1 (ar) 2004-07-12
IN184775B (enExample) 2000-09-30
PL174992B1 (pl) 1998-10-30
ZA92376B (en) 1992-09-30
EP0496470A1 (en) 1992-07-29
BR9200166A (pt) 1992-10-06
JP3302387B2 (ja) 2002-07-15
SK279174B6 (sk) 1998-07-08
EP0496470B1 (en) 1994-09-28
JPH0584440A (ja) 1993-04-06
CS16692A3 (en) 1992-08-12
DE69200450T2 (de) 1995-02-23
CA2059711C (en) 2002-07-30
CN1063427A (zh) 1992-08-12
ES2061309T3 (es) 1994-12-01
DE69200450D1 (de) 1994-11-03
MX9200243A (es) 1992-07-01
US5145824A (en) 1992-09-08
RU2014114C1 (ru) 1994-06-15
CN1035161C (zh) 1997-06-18
DK0496470T3 (da) 1994-10-24
TR25623A (tr) 1993-07-01

Similar Documents

Publication Publication Date Title
AU641584B2 (en) Ethylene oxide catalyst and process
US5100859A (en) Catalyst carrier
CA2171213C (en) Epoxidation catalyst and process
AU711973B2 (en) Epoxidation catalyst and process
EP0808215B1 (en) Alkylene oxide catalyst and process
CN102145285A (zh) 环氧乙烷生产用银催化剂的载体、其制备方法及其应用
MXPA97005608A (en) Alkylene oxide catalyst and proc
CA1284985C (en) Process for the preparation of a silver-containing catalyst
JP2013534465A (ja) 酸化エチレン触媒用のキャリア
WO1996023648A1 (en) Process for the manufacture of moulded articles that are partly coloured or have regions of different colours
CN112007625B (zh) 一种α-氧化铝载体及制备方法和银催化剂与应用