AR105389A1 - Compuestos basados en ferroceno y catalizadores de paladio basados en los mismos para la alcoxicarbonilación de compuestos etilénicamente instaurados - Google Patents

Compuestos basados en ferroceno y catalizadores de paladio basados en los mismos para la alcoxicarbonilación de compuestos etilénicamente instaurados

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Publication number
AR105389A1
AR105389A1 ARP160102179A ARP160102179A AR105389A1 AR 105389 A1 AR105389 A1 AR 105389A1 AR P160102179 A ARP160102179 A AR P160102179A AR P160102179 A ARP160102179 A AR P160102179A AR 105389 A1 AR105389 A1 AR 105389A1
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Argentina
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alkyl
compounds
cycloalkyl
heteroaryl
aryl
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ARP160102179A
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English (en)
Inventor
Dr Geilen Frank
Fridag Dirk
Marie Dr Dyballa Katrin
Dr Hess Dieter
Prof Dr Franke Robert
Prof Dr Beller Matthias
Dr Jackstell Ralf
Dr Neumann Helfried
Dr Dong Kaiwu
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Evonik Degussa Gmbh
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Publication of AR105389A1 publication Critical patent/AR105389A1/es

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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
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    • C07C67/00—Preparation of carboxylic acid esters
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    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
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    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
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    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
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Abstract

Compuestos de fórmula (1), donde R¹, R², R³, R⁴ son, cada uno, independientemente seleccionados entre -alquilo-C₁₋₁₂, -cicloalquilo-C₃₋₁₂, -heterocicloalquilo-C₃₋₁₂, -arilo-C₆₋₂₀, -heteroarilo-C₃₋₂₀; por lo menos uno de los radicales R¹, R², R³, R⁴ es un radical -heteroarilo-C₆₋₂₀ que tiene por lo menos seis átomos en el anillo; y R¹, R², R³, R⁴, si son -alquilo-C₁₋₁₂, -cicloalquilo-C₃₋₁₂, -heterocicloalquilo-C₃₋₁₂, -arilo-C₆₋₂₀, -heteroarilo-C₃₋₂₀ o heteroarilo-C₆₋₂₀, cada uno puede estar sustituido independientemente por uno o más sustituyentes seleccionados entre -alquilo-C₁₋₁₂, -cicloalquilo-C₃₋₁₂, -heterocicloalquilo-C₃₋₁₂, -O-alquilo-C₁₋₁₂, -O-alquil-C₁₋₁₂-arilo-C₆₋₂₀, -O-cicloalquilo-C₃₋₁₂, -S-alquilo-C₁₋₁₂, -S-cicloalquilo-C₃₋₁₂, -COO-alquilo-C₁₋₁₂, -COO-cicloalquilo-C₃₋₁₂, -CONH-alquilo-C₁₋₁₂, -CONH-cicloalquilo-C₃₋₁₂, -CO-alquilo-C₁₋₁₂, -CO-cicloalquilo-C₃₋₁₂, -N-[-alquilo-C₁₋₁₂]₂, -arilo-C₆₋₂₀,-aril-C₆₋₂₀-alquilo-C₁₋₁₂, -aril-C₆₋₂₀-O-alquilo-C₁₋₁₂, -heteroarilo-C₃₋₂₀, -heteroaril-C₃₋₂₀-alquilo-C₁₋₁₂, -heteroaril-C₃₋₂₀-O-alquilo-C₁₋₁₂, -COOH, -OH, -SO₃H, -NH₂, halógeno. Precursores para la preparación del compuesto, complejos de Pd que comprenden el compuesto y uso de los mismos en la alcoxicarbonilación. Reivindicación 8: El compuesto de acuerdo con cualquiera de las reivindicaciones 1 a 7, de una de las fórmulas (2), (3) y (4).
ARP160102179A 2015-07-23 2016-07-19 Compuestos basados en ferroceno y catalizadores de paladio basados en los mismos para la alcoxicarbonilación de compuestos etilénicamente instaurados AR105389A1 (es)

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ARP160102178A AR105388A1 (es) 2015-07-23 2016-07-19 Ligandos de difosfina a base de benceno para alcoxicarbonilación

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US (8) US20170022138A1 (es)
EP (6) EP3121179B1 (es)
JP (2) JP6714459B2 (es)
KR (2) KR101828687B1 (es)
CN (7) CN106632476B (es)
AR (2) AR105389A1 (es)
BR (2) BR102016016726B1 (es)
CA (2) CA2936723C (es)
ES (6) ES2703563T3 (es)
MX (2) MX2016009397A (es)
MY (1) MY172677A (es)
PL (3) PL3121180T3 (es)
SG (3) SG10201806584VA (es)
TW (2) TWI634947B (es)
ZA (2) ZA201605000B (es)

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EP3272732B1 (de) 2016-07-19 2019-09-18 Evonik Degussa GmbH Verfahren zur alkoxycarbonylierung ethylenisch ungesättigter verbindungen mit monophosphinliganden
EP3272729B1 (de) 2016-07-19 2019-09-04 Evonik Degussa GmbH Verfahren zur herstellung von estern durch carbonylierung von ethern
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ES2740998T3 (es) 2016-07-19 2020-02-07 Evonik Operations Gmbh Ligandos de 1,1'-bis(fosfino)ferroceno para alcoxicarbonilación
EP3272733B1 (de) 2016-07-19 2019-01-02 Evonik Degussa GmbH Verfahren zur alkoxycarbonylierung von olefinen in einem medium mit geringer brønstedsäurenkonzentration
EP3272728B1 (de) 2016-07-19 2019-06-19 Evonik Degussa GmbH Verfahren zur alkoxycarbonylierung von alkoholen
EP3272731B1 (de) 2016-07-19 2019-05-01 Evonik Degussa GmbH Verfahren zur herstellung von di- oder tricarbonsäureestern durch alkoxycarbonylierung von dienen mit konjugierten doppelbindungen
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RU2732499C1 (ru) * 2017-03-18 2020-09-18 Катарский Фонд Образования, Науки И Общественного Развития Катализируемое металлом алкоксикарбонилирование лактона
EP3421478B1 (en) 2017-06-29 2020-03-25 Evonik Operations GmbH Markovnikov-selective palladium catalyst for carbonylation of alkynes with heteroarenes
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