AR105389A1 - Compuestos basados en ferroceno y catalizadores de paladio basados en los mismos para la alcoxicarbonilación de compuestos etilénicamente instaurados - Google Patents

Compuestos basados en ferroceno y catalizadores de paladio basados en los mismos para la alcoxicarbonilación de compuestos etilénicamente instaurados

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AR105389A1
AR105389A1 ARP160102179A ARP160102179A AR105389A1 AR 105389 A1 AR105389 A1 AR 105389A1 AR P160102179 A ARP160102179 A AR P160102179A AR P160102179 A ARP160102179 A AR P160102179A AR 105389 A1 AR105389 A1 AR 105389A1
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Argentina
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alkyl
compounds
cycloalkyl
heteroaryl
aryl
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ARP160102179A
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English (en)
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Dr Geilen Frank
Fridag Dirk
Marie Dr Dyballa Katrin
Dr Hess Dieter
Prof Dr Franke Robert
Prof Dr Beller Matthias
Dr Jackstell Ralf
Dr Neumann Helfried
Dr Dong Kaiwu
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Evonik Degussa Gmbh
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Publication of AR105389A1 publication Critical patent/AR105389A1/es

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    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
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    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
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    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
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    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
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    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
    • C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
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    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms
    • C07F9/655345—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms the sulfur atom being part of a five-membered ring
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    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/826—Metals not provided for in groups C08G63/83 - C08G63/86
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    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
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    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
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    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
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    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
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    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
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    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Abstract

Compuestos de fórmula (1), donde R¹, R², R³, R⁴ son, cada uno, independientemente seleccionados entre -alquilo-C₁₋₁₂, -cicloalquilo-C₃₋₁₂, -heterocicloalquilo-C₃₋₁₂, -arilo-C₆₋₂₀, -heteroarilo-C₃₋₂₀; por lo menos uno de los radicales R¹, R², R³, R⁴ es un radical -heteroarilo-C₆₋₂₀ que tiene por lo menos seis átomos en el anillo; y R¹, R², R³, R⁴, si son -alquilo-C₁₋₁₂, -cicloalquilo-C₃₋₁₂, -heterocicloalquilo-C₃₋₁₂, -arilo-C₆₋₂₀, -heteroarilo-C₃₋₂₀ o heteroarilo-C₆₋₂₀, cada uno puede estar sustituido independientemente por uno o más sustituyentes seleccionados entre -alquilo-C₁₋₁₂, -cicloalquilo-C₃₋₁₂, -heterocicloalquilo-C₃₋₁₂, -O-alquilo-C₁₋₁₂, -O-alquil-C₁₋₁₂-arilo-C₆₋₂₀, -O-cicloalquilo-C₃₋₁₂, -S-alquilo-C₁₋₁₂, -S-cicloalquilo-C₃₋₁₂, -COO-alquilo-C₁₋₁₂, -COO-cicloalquilo-C₃₋₁₂, -CONH-alquilo-C₁₋₁₂, -CONH-cicloalquilo-C₃₋₁₂, -CO-alquilo-C₁₋₁₂, -CO-cicloalquilo-C₃₋₁₂, -N-[-alquilo-C₁₋₁₂]₂, -arilo-C₆₋₂₀,-aril-C₆₋₂₀-alquilo-C₁₋₁₂, -aril-C₆₋₂₀-O-alquilo-C₁₋₁₂, -heteroarilo-C₃₋₂₀, -heteroaril-C₃₋₂₀-alquilo-C₁₋₁₂, -heteroaril-C₃₋₂₀-O-alquilo-C₁₋₁₂, -COOH, -OH, -SO₃H, -NH₂, halógeno. Precursores para la preparación del compuesto, complejos de Pd que comprenden el compuesto y uso de los mismos en la alcoxicarbonilación. Reivindicación 8: El compuesto de acuerdo con cualquiera de las reivindicaciones 1 a 7, de una de las fórmulas (2), (3) y (4).
ARP160102179A 2015-07-23 2016-07-19 Compuestos basados en ferroceno y catalizadores de paladio basados en los mismos para la alcoxicarbonilación de compuestos etilénicamente instaurados AR105389A1 (es)

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ARP160102178A AR105388A1 (es) 2015-07-23 2016-07-19 Ligandos de difosfina a base de benceno para alcoxicarbonilación

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US (8) US10077228B2 (es)
EP (6) EP3121186B1 (es)
JP (2) JP6714459B2 (es)
KR (2) KR101828687B1 (es)
CN (7) CN113845545A (es)
AR (2) AR105389A1 (es)
BR (2) BR102016016724B1 (es)
CA (2) CA2936724C (es)
ES (6) ES2702924T3 (es)
MX (2) MX2016009397A (es)
MY (1) MY172677A (es)
PL (3) PL3121180T3 (es)
SG (3) SG10201605921SA (es)
TW (2) TWI648283B (es)
ZA (2) ZA201605000B (es)

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