SG10201806584VA - Ferrocene-based compounds and palladium catalysts based thereon for the alkoxycarbonylation of ethylenically unsaturated compounds - Google Patents

Ferrocene-based compounds and palladium catalysts based thereon for the alkoxycarbonylation of ethylenically unsaturated compounds

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Publication number
SG10201806584VA
SG10201806584VA SG10201806584VA SG10201806584VA SG10201806584VA SG 10201806584V A SG10201806584V A SG 10201806584VA SG 10201806584V A SG10201806584V A SG 10201806584VA SG 10201806584V A SG10201806584V A SG 10201806584VA SG 10201806584V A SG10201806584V A SG 10201806584VA
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Singapore
Prior art keywords
alkyl
cycloalkyl
compounds
aryl
alkoxycarbonylation
Prior art date
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SG10201806584VA
Inventor
Kaiwu Dong Dr
Helfried Neumann Dr
Ralf Jackstell Dr
Dr Matthias Beller Prof
Dr Robert Franke Prof
Dieter Hess Dr
Katrin Marie Dyballa Dr
Fridag Dirk
Frank Geilen Dr
Original Assignee
Evonik Degussa Gmbh
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Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of SG10201806584VA publication Critical patent/SG10201806584VA/en

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Abstract

RPN R2 Fe a ,R 3 P 14 R (I) where R1 , R2 , R3 , R4 are each independently selected from -(C1 -C1 2)-alkyl, -(C3 -Ci2)-cycloalkyl, -(C 3 - 10 C12 )-heterocycloalkyl, -(C6-C20)-aryl, -(C 3 -C20 )-heteroaryl; at least one of the R 1 , R2 , R 3 , R4 radicals is a -(C6-C20)-heteroaryl radical having at least six ring atoms; and R1 , R2 , R3 , R4 , if they are -(C 1 -C12 )-alkyl, -(C3 -Ci 2)-cycloalkyl, -(C3 -C1 2)-heterocycloalkyl, -(C 6 - 15 C20 )-aryl, -(C3 -C20)-heteroaryl or -(C6-C20)-heteroaryl, may each independently be substituted by one or more substituents selected from -(C1 -C12 )-alkyl, -(C3 -C12 )-cycloalkyl, -(C3-Ci2)-heterocycloalkyl, -0-(C1 -C12)-alkyl, -0-(C1-C12)- alkyl-(C6-C20)-aryl, -0-(C3-C12)-cycloalkyl, -S-(C 1 -C12)-alkyl, -S-(C3 -C12)-cycloalkyl, -000-(Ci- C1 2)-alkyl, -000-(C3-C12)-cycloalkyl, -CONH-(C1-C12)-alkyl, -CONH-(C 3 -C12 )-cycloalkyl, -CO- 20 (C1-C12)-alkyl, -00-(C3-C12)-cycloalkyl, -N-[(C1 -C12 )-alkyl]2, -(C6-C20)-aryl, -(C6 -C20 )-aryl-(C1 - C12 )-alkyl, -(C6-C20)-aryl-0-(C1-C12)-alkyl, -(C3 -C20)-heteroaryl, -(C3-C20)-heteroary1-(Ci-Ci 2)- alkyl, -(C3 -C20 )-heteroary1-0-(C1 -C1 2)-alkyl, -COOH, -OH, -SO 3 H, -NH2, halogen. The invention further relates to precursors for preparation of the compound according to the 25 invention, to Pd complexes comprising the compound according to the invention and to the use thereof in alkoxycarbonylation. (No drawing to be published)
SG10201806584VA 2015-07-23 2016-07-19 Ferrocene-based compounds and palladium catalysts based thereon for the alkoxycarbonylation of ethylenically unsaturated compounds SG10201806584VA (en)

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