AR018396A1 - Metodo para preparar un catalizador para la produccion de acetato de vinilo. - Google Patents

Metodo para preparar un catalizador para la produccion de acetato de vinilo.

Info

Publication number
AR018396A1
AR018396A1 ARP990102503A ARP990102503A AR018396A1 AR 018396 A1 AR018396 A1 AR 018396A1 AR P990102503 A ARP990102503 A AR P990102503A AR P990102503 A ARP990102503 A AR P990102503A AR 018396 A1 AR018396 A1 AR 018396A1
Authority
AR
Argentina
Prior art keywords
catalyst
palladium
production
vinyl acetate
base
Prior art date
Application number
ARP990102503A
Other languages
English (en)
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of AR018396A1 publication Critical patent/AR018396A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un catalizador para al produccion de acetato de vinilo haciendo reaccionar etileno, oxígeno y ácido acético, que comprende una base porosa en cuyassuperficies porosas se depositan cantidades catalíticamente efectivas de cobre metálico, paladio yoro, y en donde dicho catalizador se ha preparado medianteel proceso que comprende los pasos de revestir previamente dicha base con una forma de cobre insoluble en agua; formar en la base revestida previamente uncompuesto de paladio insoluble enagua, re ducir el compuesto de paladio y, si no estuviera previamente reducida, a una cantidad catalíticamente efectiva delmetal libre; impregnar la base que contiene cobre y paladio con una solucion de aurato de potasio; y reducir el aurato depotasio a una cantidadcatalíticamente efectiva de oro metálico; método para preparar dicho catalizador, y proceso para la produccion de acetato de vinilo.
ARP990102503A 1998-06-02 1999-05-27 Metodo para preparar un catalizador para la produccion de acetato de vinilo. AR018396A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/088,287 US6017847A (en) 1998-06-02 1998-06-02 Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper

Publications (1)

Publication Number Publication Date
AR018396A1 true AR018396A1 (es) 2001-11-14

Family

ID=22210492

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP990102503A AR018396A1 (es) 1998-06-02 1999-05-27 Metodo para preparar un catalizador para la produccion de acetato de vinilo.

Country Status (28)

Country Link
US (1) US6017847A (es)
EP (1) EP1085942B1 (es)
JP (1) JP4503834B2 (es)
KR (1) KR100575968B1 (es)
CN (1) CN1129481C (es)
AR (1) AR018396A1 (es)
AT (1) ATE284271T1 (es)
AU (1) AU744959B2 (es)
BR (1) BR9910902A (es)
CA (1) CA2332988C (es)
CZ (1) CZ295778B6 (es)
DE (1) DE69922505T2 (es)
ES (1) ES2233050T3 (es)
HU (1) HUP0105163A2 (es)
ID (1) ID27053A (es)
MY (1) MY116609A (es)
NO (1) NO322773B1 (es)
NZ (1) NZ508273A (es)
PE (1) PE20000485A1 (es)
PL (1) PL201079B1 (es)
RU (1) RU2208481C2 (es)
SA (1) SA99200246B1 (es)
SK (1) SK285123B6 (es)
TR (1) TR200003534T2 (es)
TW (1) TW422741B (es)
UA (1) UA69409C2 (es)
WO (1) WO1999062633A1 (es)
ZA (1) ZA200006640B (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6303537B1 (en) * 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
US6509293B1 (en) * 2000-05-22 2003-01-21 Eastman Chemical Company Gold based heterogeneous carbonylation catalysts
US6420308B1 (en) * 2000-07-07 2002-07-16 Saudi Basic Industries Corp Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
TW201236755A (en) * 2003-12-19 2012-09-16 Celanese Int Corp Halide free precursors for catalysts
EP2380661A3 (en) * 2004-12-20 2012-02-01 Celanese International Corporation Modified support materials for catalysts
AU2005242218A1 (en) * 2005-01-14 2006-08-03 Rohm And Haas Company Plant growth regulation
US8227369B2 (en) * 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US7811968B2 (en) * 2007-05-11 2010-10-12 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025362A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025358A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025223A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102008059341A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung
GB201110850D0 (en) 2011-03-04 2011-08-10 Johnson Matthey Plc Catalyst and mehtod of preparation

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1286021B (de) * 1967-04-18 1969-01-02 Knapsack Ag Verfahren zur Herstellung von Estern von Carbonsaeuren mit ungesaettigten Alkoholen
DE1793519C3 (de) * 1968-09-28 1974-08-22 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Vinylestern
CH534005A (de) * 1968-02-01 1973-02-28 Bayer Ag Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators
DE2509251C3 (de) * 1975-03-04 1978-07-13 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung eines Palladiumkatalysators
GB1571910A (en) * 1975-12-18 1980-07-23 Nat Distillers Chem Corp Vinyl acetate process and catalyst therefor
US5179057A (en) * 1991-05-06 1993-01-12 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for alkenyl alkanoate production
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5314858A (en) * 1992-10-14 1994-05-24 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5347046A (en) * 1993-05-25 1994-09-13 Engelhard Corporation Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
SA97180048B1 (ar) * 1996-05-24 2005-12-21 هوكست سيلانس كوربوريشن محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل
US5693586A (en) * 1996-06-28 1997-12-02 Hoechst Celanese Corporation Palladium-gold catalyst for vinyl acetate production
JPH1072403A (ja) * 1996-08-28 1998-03-17 Showa Denko Kk 酢酸ビニルの製造法
US5731457A (en) * 1997-06-03 1998-03-24 Hoechst Celanese Corporation Vinyl acetate process utilizing a palladium-gold-copper catalyst

Also Published As

Publication number Publication date
CZ20004505A3 (cs) 2001-08-15
CN1129481C (zh) 2003-12-03
ZA200006640B (en) 2002-04-24
CN1304332A (zh) 2001-07-18
PE20000485A1 (es) 2000-06-05
SK18252000A3 (sk) 2001-08-06
EP1085942B1 (en) 2004-12-08
DE69922505D1 (de) 2005-01-13
WO1999062633A8 (en) 2000-01-27
ID27053A (id) 2001-02-22
KR100575968B1 (ko) 2006-05-02
DE69922505T2 (de) 2006-05-11
SK285123B6 (sk) 2006-06-01
CA2332988A1 (en) 1999-12-09
NO20006118L (no) 2000-12-01
RU2208481C2 (ru) 2003-07-20
AU4085099A (en) 1999-12-20
PL344577A1 (en) 2001-11-05
CA2332988C (en) 2007-06-26
KR20010052495A (ko) 2001-06-25
TW422741B (en) 2001-02-21
BR9910902A (pt) 2001-02-13
EP1085942A1 (en) 2001-03-28
TR200003534T2 (tr) 2001-04-20
NZ508273A (en) 2003-03-28
ES2233050T3 (es) 2005-06-01
WO1999062633A1 (en) 1999-12-09
NO20006118D0 (no) 2000-12-01
JP2002516748A (ja) 2002-06-11
AU744959B2 (en) 2002-03-07
UA69409C2 (uk) 2004-09-15
PL201079B1 (pl) 2009-03-31
HUP0105163A2 (hu) 2002-04-29
JP4503834B2 (ja) 2010-07-14
US6017847A (en) 2000-01-25
NO322773B1 (no) 2006-12-11
SA99200246B1 (ar) 2006-04-22
MY116609A (en) 2004-02-28
CZ295778B6 (cs) 2005-11-16
ATE284271T1 (de) 2004-12-15

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