ES2175286T3 - Procedimiento de produccion de acetato de vinilo y procedimiento para la preparacion de un catalizador. - Google Patents

Procedimiento de produccion de acetato de vinilo y procedimiento para la preparacion de un catalizador.

Info

Publication number
ES2175286T3
ES2175286T3 ES97308610T ES97308610T ES2175286T3 ES 2175286 T3 ES2175286 T3 ES 2175286T3 ES 97308610 T ES97308610 T ES 97308610T ES 97308610 T ES97308610 T ES 97308610T ES 2175286 T3 ES2175286 T3 ES 2175286T3
Authority
ES
Spain
Prior art keywords
procedure
paladio
catalyst
vinyl acetate
acetate production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97308610T
Other languages
English (en)
Inventor
John William Couves
Simon James Kitchen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of ES2175286T3 publication Critical patent/ES2175286T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C07C69/01—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing

Abstract

PROCEDIMIENTO DE PRODUCCION DE ACETATO DE VINILO, QUE CONSISTE EN PONER EN CONTACTO ETILENO, ACIDO ACETICO Y UN GAS QUE CONTENGA OXIGENO, CON UN CATALIZADOR DE PALADIO SOPORTADO, MEDIANTE UN PROCEDIMIENTO QUE COMPRENDE LAS SIGUIENTES FASES: (A) IMPREGNAR UN SOPORTE DE CATALIZADOR CON UN COMPUESTO DE PALADIO, (B) CONVERTIR EL COMPUESTO DE PALADIO EN PALADIO BASICAMENTE METALICO, Y (C) SINTERIZAR EL PALADIO SOPORTADO A UNA TEMPERATURA SUPERIOR A 500 (GRADOS) C.
ES97308610T 1996-11-04 1997-10-28 Procedimiento de produccion de acetato de vinilo y procedimiento para la preparacion de un catalizador. Expired - Lifetime ES2175286T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9622911.7A GB9622911D0 (en) 1996-11-04 1996-11-04 Process

Publications (1)

Publication Number Publication Date
ES2175286T3 true ES2175286T3 (es) 2002-11-16

Family

ID=10802399

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97308610T Expired - Lifetime ES2175286T3 (es) 1996-11-04 1997-10-28 Procedimiento de produccion de acetato de vinilo y procedimiento para la preparacion de un catalizador.

Country Status (20)

Country Link
US (3) US5990344A (es)
EP (1) EP0839793B1 (es)
JP (1) JP4137204B2 (es)
KR (1) KR100535736B1 (es)
CN (1) CN1153755C (es)
AR (1) AR010544A1 (es)
BR (1) BR9709477B1 (es)
CA (1) CA2219966C (es)
DE (1) DE69711320T2 (es)
ES (1) ES2175286T3 (es)
GB (1) GB9622911D0 (es)
ID (1) ID18766A (es)
MY (1) MY120308A (es)
NO (1) NO975057L (es)
NZ (1) NZ329092A (es)
RU (1) RU2197472C2 (es)
SA (1) SA98190191A (es)
SG (1) SG63770A1 (es)
TW (1) TW411329B (es)
ZA (1) ZA979733B (es)

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US6407283B2 (en) * 1996-11-04 2002-06-18 Bp Chemicals Limited Process for the production of vinyl acetate
DE19755022C2 (de) * 1997-12-11 2000-03-09 Celanese Chem Europe Gmbh Katalysator und Verfahren zur Herstellung von Vinylacetat
US6602481B1 (en) * 1998-03-09 2003-08-05 Osaka Gas Company Limited Catalyst for removing hydrocarbons from exhaust gas and method for clarification of exhaust gas
GB9810928D0 (en) * 1998-05-22 1998-07-22 Bp Chem Int Ltd Catalyst and process
GB9817363D0 (en) * 1998-08-11 1998-10-07 Bp Chem Int Ltd Process for the production of vinyl acetate
GB9817365D0 (en) 1998-08-11 1998-10-07 Bp Chem Int Ltd Process for the production of vinyl acetate
US6358882B1 (en) 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
DE19914066A1 (de) * 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
KR100887001B1 (ko) 2001-03-30 2009-03-04 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 8족 금속을 함유한 촉매의 제조방법과 알케닐카르복실레이트 제조 시의 용도
US6620965B1 (en) 2002-03-08 2003-09-16 Catalytic Distillation Technologies Process for vinyl acetate
JP4421201B2 (ja) 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
US6762324B2 (en) * 2002-05-01 2004-07-13 Air Products And Chemicals, Inc. Metal modified Pd/Ni catalysts
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US7294734B2 (en) 2003-05-02 2007-11-13 Velocys, Inc. Process for converting a hydrocarbon to an oxygenate or a nitrile
TW200539941A (en) * 2003-12-19 2005-12-16 Celanese Int Corp Methods of making alkenyl alkanoates
JP4551109B2 (ja) * 2004-04-14 2010-09-22 エヌ・イーケムキャット株式会社 触媒の製造方法
US7468455B2 (en) 2004-11-03 2008-12-23 Velocys, Inc. Process and apparatus for improved methods for making vinyl acetate monomer (VAM)
WO2006068764A2 (en) 2004-12-20 2006-06-29 Celanese International Corporation Modified support materials for catalysts
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US7605106B2 (en) * 2005-11-15 2009-10-20 Nova Chemicals (International) S.A. Telomerization of dienes
US7842639B2 (en) * 2006-05-19 2010-11-30 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Mechanical alloying of a hydrogenation catalyst used for the remediation of contaminated compounds
US7825204B2 (en) * 2006-12-19 2010-11-02 Lyondell Chemical Technology, L.P. Inorganic oxide extrudates
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007043447B4 (de) 2007-09-12 2014-02-13 Süd-Chemie Ip Gmbh & Co. Kg Katalysatorträger mit erhöhter thermischer Leitfähigkeit
DE102007043446B4 (de) 2007-09-12 2013-08-22 Süd-Chemie Ip Gmbh & Co. Kg Katalysatorträger mit erhöhter Wärmeleitfähigkeit
RU2375113C1 (ru) * 2008-09-29 2009-12-10 Бонсанко Текнолоджи АГ Способ получения палладийсодержащих катализаторов
DE102008059342A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung
DE202008017277U1 (de) 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
DE102008059340A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Katalysatorträger, Verfahren zu seiner Herstellung sowie dessen Verwendung
FR2950365B1 (fr) * 2009-09-21 2012-07-06 Commissariat Energie Atomique Procede de depot d'un metal sur une couche en carbone poreux
US20120149939A1 (en) 2010-12-10 2012-06-14 Celanese International Corporation Recovery of Acetic Acid from Heavy Ends in Vinyl Acetate Synthesis Process
DE102011018532A1 (de) * 2011-04-26 2012-10-31 Süd-Chemie AG Basische Katalysatorträgerkörper mit niedriger Oberfläche
EP2671641A1 (en) * 2012-06-07 2013-12-11 Univerza V Ljubljani A method of deposition of Pt or Pd catalysts using gaseous reducing agents
WO2013191399A1 (ko) * 2012-06-18 2013-12-27 삼성비피화학(주) 초산, 초산비닐 및 폴리비닐알코올의 통합 제조방법
CA2928999C (en) * 2013-11-06 2022-04-12 Yoel Sasson A method for storage and release of hydrogen
DE102014222176A1 (de) * 2014-10-30 2016-05-04 Wacker Chemie Ag Verfahren zur Herstellung von Vinylacetat
US9998896B1 (en) 2017-08-18 2018-06-12 Verizon Patent And Licensing Inc. Dedicated APN access using default network access key for profile download
RU2712593C1 (ru) * 2019-03-15 2020-01-29 Акционерное общество "Электростальское научно-производственное объединение "Неорганика" (АО "ЭНПО "Неорганика") Способ получения палладиевого катализатора на основе оксида алюминия
TW202128605A (zh) 2019-12-19 2021-08-01 美商瑟蘭斯國際股份有限公司 於乙酸乙烯酯製造期間監測各式流之可燃性之方法及系統
TW202204892A (zh) 2020-06-29 2022-02-01 美商瑟蘭斯國際股份有限公司 於乙酸乙烯酯製造之金屬離子原位分析

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US4145314A (en) * 1977-06-17 1979-03-20 Exxon Research & Engineering Co. Preparation of highly dispersed supported group viii metal catalysts and the redispersion of sintered or agglomerated supported group viii metal catalysts by the addition of phosphorus
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Also Published As

Publication number Publication date
KR19980042071A (ko) 1998-08-17
NZ329092A (en) 1998-01-26
DE69711320D1 (de) 2002-05-02
TW411329B (en) 2000-11-11
EP0839793B1 (en) 2002-03-27
DE69711320T2 (de) 2002-07-25
RU2197472C2 (ru) 2003-01-27
NO975057D0 (no) 1997-11-03
ID18766A (id) 1998-05-07
BR9709477B1 (pt) 2008-11-18
JP4137204B2 (ja) 2008-08-20
CN1153755C (zh) 2004-06-16
CA2219966C (en) 2006-02-07
SA98190191A (ar) 2005-12-03
US6492299B1 (en) 2002-12-10
JPH10139727A (ja) 1998-05-26
EP0839793A1 (en) 1998-05-06
AR010544A1 (es) 2000-06-28
USRE37744E1 (en) 2002-06-11
MY120308A (en) 2005-10-31
BR9709477A (pt) 2000-05-02
US5990344A (en) 1999-11-23
CA2219966A1 (en) 1998-05-04
ZA979733B (en) 1999-04-29
NO975057L (no) 1998-05-05
GB9622911D0 (en) 1997-01-08
CN1184808A (zh) 1998-06-17
SG63770A1 (en) 1999-03-30
KR100535736B1 (ko) 2006-06-22

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