ES2141604T3 - Catalizador y procedimiento para la fabricacion de acetato de vinilo. - Google Patents

Catalizador y procedimiento para la fabricacion de acetato de vinilo.

Info

Publication number
ES2141604T3
ES2141604T3 ES97914254T ES97914254T ES2141604T3 ES 2141604 T3 ES2141604 T3 ES 2141604T3 ES 97914254 T ES97914254 T ES 97914254T ES 97914254 T ES97914254 T ES 97914254T ES 2141604 T3 ES2141604 T3 ES 2141604T3
Authority
ES
Spain
Prior art keywords
catalyst
compounds
procedure
vinyl acetate
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97914254T
Other languages
English (en)
Inventor
Roland Abel
Ioan Nicolau
Erich Hopf
Rainer Kiemel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Sales Germany GmbH
Original Assignee
Celanese Chemicals Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Chemicals Europe GmbH filed Critical Celanese Chemicals Europe GmbH
Application granted granted Critical
Publication of ES2141604T3 publication Critical patent/ES2141604T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C07C69/01—Vinyl esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE ACETATO DE VINILO EN FASE GASEOSA A PARTIR DE ETILENO, ACIDO ACETICO Y OXIGENO O GASES QUE CONTIENEN OXIGENO CON UNA BAJA FORMACION SIMULTANEA DE COMPUESTOS CON ELEVADO PUNTO DE EBULLICION EN UN CATALIZADOR, QUE CONTIENE PALADIO Y/O SUS COMPUESTOS, ORO Y/O SUS COMPUESTOS, ASI COMO COMPUESTOS DE METAL ALCALINO SOBRE UN SOPORTE, CARACTERIZADO PORQUE EL CATALIZADOR CONTIENE ADEMAS BORO O COMPUESTOS DE BORO.
ES97914254T 1996-04-04 1997-03-17 Catalizador y procedimiento para la fabricacion de acetato de vinilo. Expired - Lifetime ES2141604T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19613791A DE19613791C2 (de) 1996-04-04 1996-04-04 Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat

Publications (1)

Publication Number Publication Date
ES2141604T3 true ES2141604T3 (es) 2000-03-16

Family

ID=7790648

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97914254T Expired - Lifetime ES2141604T3 (es) 1996-04-04 1997-03-17 Catalizador y procedimiento para la fabricacion de acetato de vinilo.

Country Status (18)

Country Link
US (1) US6114571A (es)
EP (1) EP0891226B1 (es)
JP (1) JP3999269B2 (es)
KR (1) KR100439454B1 (es)
CN (1) CN1090534C (es)
AT (1) ATE186476T1 (es)
AU (1) AU711272B2 (es)
BR (1) BR9708504A (es)
CZ (1) CZ291509B6 (es)
DE (2) DE19613791C2 (es)
ES (1) ES2141604T3 (es)
HU (1) HUP9901871A3 (es)
NO (1) NO984550L (es)
NZ (1) NZ331900A (es)
PL (1) PL329215A1 (es)
TR (1) TR199801982T2 (es)
WO (1) WO1997037759A1 (es)
YU (1) YU42798A (es)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19754992C2 (de) * 1997-12-11 2000-03-23 Celanese Chem Europe Gmbh Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
DE19755023C2 (de) * 1997-12-11 2000-03-09 Celanese Chem Europe Gmbh Katalysator und Verfahren zur Herstellung von Vinylacetat
DE19754991C2 (de) * 1997-12-11 2000-03-23 Celanese Chem Europe Gmbh Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
DE19914066A1 (de) * 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19920390C2 (de) * 1999-05-04 2002-08-01 Celanese Chem Europe Gmbh Katalysator und Verfahren zur Herstellung von Vinylacetat
MY139952A (en) * 2001-03-30 2009-11-30 Shell Int Research A process for preparing a catalyst, the catalyst and a use of the catalyst
JP4421201B2 (ja) * 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
TW200539941A (en) * 2003-12-19 2005-12-16 Celanese Int Corp Methods of making alkenyl alkanoates
PL380018A1 (pl) * 2003-12-19 2006-12-11 Celanese International Corporation Warstwowy materiał nośnika do katalizatorów
JP4551109B2 (ja) * 2004-04-14 2010-09-22 エヌ・イーケムキャット株式会社 触媒の製造方法
KR100978977B1 (ko) * 2004-12-20 2010-08-30 셀라니즈 인터내셔날 코포레이션 촉매용 개질된 지지체 물질
US8227369B2 (en) * 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US8338650B2 (en) 2008-07-31 2012-12-25 Celanese International Corporation Palladium catalysts for making ethanol from acetic acid
US8680317B2 (en) 2008-07-31 2014-03-25 Celanese International Corporation Processes for making ethyl acetate from acetic acid
US8471075B2 (en) 2008-07-31 2013-06-25 Celanese International Corporation Processes for making ethanol from acetic acid
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8637714B2 (en) 2008-07-31 2014-01-28 Celanese International Corporation Process for producing ethanol over catalysts containing platinum and palladium
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US8309773B2 (en) 2010-02-02 2012-11-13 Calanese International Corporation Process for recovering ethanol
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US8304586B2 (en) 2010-02-02 2012-11-06 Celanese International Corporation Process for purifying ethanol
US7855303B2 (en) * 2008-11-14 2010-12-21 Celanese International Corporation Integrated process for the production of vinyl acetate from acetic acid via ethylene
US8178715B2 (en) * 2008-12-31 2012-05-15 Celanese International Corporation Integrated process for the production of vinyl acetate from acetic acid via acetaldehyde
US7820853B2 (en) * 2008-12-31 2010-10-26 Celanese International Corporation Integrated process for the production of vinyl acetate from acetic acid via ethyl acetate
US8450535B2 (en) 2009-07-20 2013-05-28 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US8710277B2 (en) * 2009-10-26 2014-04-29 Celanese International Corporation Process for making diethyl ether from acetic acid
US8680321B2 (en) 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
US8211821B2 (en) * 2010-02-01 2012-07-03 Celanese International Corporation Processes for making tin-containing catalysts
US8344186B2 (en) 2010-02-02 2013-01-01 Celanese International Corporation Processes for producing ethanol from acetaldehyde
US8460405B2 (en) 2010-02-02 2013-06-11 Celanese International Corporation Ethanol compositions
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8858659B2 (en) 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
US8541633B2 (en) 2010-02-02 2013-09-24 Celanese International Corporation Processes for producing anhydrous ethanol compositions
US8728179B2 (en) 2010-02-02 2014-05-20 Celanese International Corporation Ethanol compositions
US8668750B2 (en) 2010-02-02 2014-03-11 Celanese International Corporation Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels
US8314272B2 (en) 2010-02-02 2012-11-20 Celanese International Corporation Process for recovering ethanol with vapor separation
EP2531291A1 (en) 2010-02-02 2012-12-12 Celanese International Corporation Preparation and use of a catalyst for producing ethanol comprising a crystalline support modifier
US8747492B2 (en) 2010-02-02 2014-06-10 Celanese International Corporation Ethanol/fuel blends for use as motor fuels
EP2531292A2 (en) 2010-02-02 2012-12-12 Celanese International Corporation Processes for producing ethanol from acetaldehyde
US8222466B2 (en) 2010-02-02 2012-07-17 Celanese International Corporation Process for producing a water stream from ethanol production
US8680343B2 (en) 2010-02-02 2014-03-25 Celanese International Corporation Process for purifying ethanol
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8680342B2 (en) 2010-05-07 2014-03-25 Celanese International Corporation Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water
US8754267B2 (en) 2010-05-07 2014-06-17 Celanese International Corporation Process for separating acetaldehyde from ethanol-containing mixtures
RS60732B1 (sr) 2010-10-28 2020-09-30 Celanese Int Corp Metodi za proizvodnju sastava sa vinil acetatom koji ima nizak sadržaj nečistoća
US8350098B2 (en) 2011-04-04 2013-01-08 Celanese International Corporation Ethanol production from acetic acid utilizing a molybdenum carbide catalyst
US8536382B2 (en) 2011-10-06 2013-09-17 Celanese International Corporation Processes for hydrogenating alkanoic acids using catalyst comprising tungsten
US8658843B2 (en) 2011-10-06 2014-02-25 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation
US8648220B2 (en) 2011-10-11 2014-02-11 Celanese International Corporation Process for producing ethanol using a crude vinyl acetate feed
US8703868B2 (en) 2011-11-28 2014-04-22 Celanese International Corporation Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol
US8697802B2 (en) 2011-11-28 2014-04-15 Celanese International Corporation Process for producing polyvinyl alcohol or a copolymer thereof
US8884052B2 (en) 2011-12-15 2014-11-11 Celanese International Corporation Production of diacetoxyethylene by direct acetoxylation
US9233899B2 (en) 2011-12-22 2016-01-12 Celanese International Corporation Hydrogenation catalysts having an amorphous support
US9000234B2 (en) 2011-12-22 2015-04-07 Celanese International Corporation Calcination of modified support to prepare hydrogenation catalysts
US8907142B2 (en) 2011-12-29 2014-12-09 Celanese International Corporation Process for promoting catalyst activity for ethyl acetate conversion
MX350643B (es) 2012-09-06 2017-09-11 Celanese Int Corp Procedimiento para la produccion de acetato de vinilo.
US8772553B2 (en) 2012-10-26 2014-07-08 Celanese International Corporation Hydrogenation reaction conditions for producing ethanol
US8853469B2 (en) 2012-11-20 2014-10-07 Celanese International Corporation Combined column for separating products of different hydrogenation reactors
JP6193723B2 (ja) * 2013-10-25 2017-09-06 日本酢ビ・ポバール株式会社 主鎖に１，２，３−トリオール基を有するポリビニルアルコール系樹脂およびその製造方法

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DE1252662B (es) * 1965-06-25
US3939199A (en) * 1971-01-06 1976-02-17 Hoechst Aktiengesellschaft Oxacylation of olefins in the gaseous phase
US4048096A (en) * 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
TW213869B (es) * 1991-06-21 1993-10-01 Hoechst Ag
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
ES2287994T3 (es) * 1994-02-22 2007-12-16 The Standard Oil Company Procedimiento para la preparacion de soporte de catalizador de acetato de vinilo de lecho fluidizado.
US5665667A (en) * 1994-06-02 1997-09-09 The Standard Oil Company Process for the preparation of vinyl acetate catalyst
US5688993A (en) * 1995-12-22 1997-11-18 E. I. Du Pont De Nemours And Company Method for modifying catalyst performance during the gas phase synthesis of vinyl acetate

Also Published As

Publication number Publication date
NO984550D0 (no) 1998-09-29
YU42798A (sh) 1999-07-28
DE59700698D1 (de) 1999-12-16
EP0891226B1 (de) 1999-11-10
DE19613791A1 (de) 1997-10-09
KR100439454B1 (ko) 2004-10-15
NZ331900A (en) 2000-05-26
AU2157097A (en) 1997-10-29
JP2000508575A (ja) 2000-07-11
HUP9901871A2 (hu) 1999-09-28
CN1090534C (zh) 2002-09-11
PL329215A1 (en) 1999-03-15
CN1215355A (zh) 1999-04-28
DE19613791C2 (de) 2002-01-31
KR20000005212A (ko) 2000-01-25
AU711272B2 (en) 1999-10-07
US6114571A (en) 2000-09-05
HUP9901871A3 (en) 2000-05-29
ATE186476T1 (de) 1999-11-15
TR199801982T2 (xx) 1999-02-22
WO1997037759A1 (de) 1997-10-16
EP0891226A1 (de) 1999-01-20
CZ314898A3 (cs) 1999-03-17
CZ291509B6 (cs) 2003-03-12
BR9708504A (pt) 2000-01-04
JP3999269B2 (ja) 2007-10-31
NO984550L (no) 1998-09-29

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