MX350643B - Procedimiento para la produccion de acetato de vinilo. - Google Patents
Procedimiento para la produccion de acetato de vinilo.Info
- Publication number
- MX350643B MX350643B MX2015002914A MX2015002914A MX350643B MX 350643 B MX350643 B MX 350643B MX 2015002914 A MX2015002914 A MX 2015002914A MX 2015002914 A MX2015002914 A MX 2015002914A MX 350643 B MX350643 B MX 350643B
- Authority
- MX
- Mexico
- Prior art keywords
- vinyl acetate
- reaction mixture
- heat capacity
- processes
- oxygen
- Prior art date
Links
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 6
- 239000011541 reaction mixture Substances 0.000 abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invención describe un procedimiento para la formación de acetato de vinilo; el procedimiento comprende el paso de proporcionar una mezcla de reacción que tiene una capacidad calorífica inicial; la mezcla de reacción comprende ácido acético, oxigeno, etileno y opcionalmente agua; el procedimiento además comprende el paso de agregar a la mezcla de reacción por lo menos un modificador de capacidad calorífica para formar una mezcla de reacción de capacidad calorífica incrementada; el procedimiento además comprende el paso de poner en contacto el ácido acético, oxígeno y etileno sobre un catalizador bajo condiciones efectivas para formar un producto de acetato de vinilo crudo; el producto de acetato de vinilo crudo comprende acetato de vinilo y agua.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261697611P | 2012-09-06 | 2012-09-06 | |
| PCT/US2013/056598 WO2014039304A1 (en) | 2012-09-06 | 2013-08-26 | Processes for producing vinyl acetate |
| US13/975,552 US9573877B2 (en) | 2012-09-06 | 2013-08-26 | Process for producing vinyl acetate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2015002914A MX2015002914A (es) | 2015-06-03 |
| MX350643B true MX350643B (es) | 2017-09-11 |
Family
ID=50188402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2015002914A MX350643B (es) | 2012-09-06 | 2013-08-26 | Procedimiento para la produccion de acetato de vinilo. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9573877B2 (es) |
| EP (1) | EP2892871B1 (es) |
| CN (1) | CN104736512B (es) |
| MX (1) | MX350643B (es) |
| RS (1) | RS58692B1 (es) |
| SG (1) | SG11201501463QA (es) |
| WO (1) | WO2014039304A1 (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2974418B1 (fr) | 2011-04-20 | 2013-05-31 | Commissariat Energie Atomique | Detecteur d'oscillations |
| WO2019175732A1 (en) | 2018-03-13 | 2019-09-19 | Nova Chemicals (International) S.A. | Process to produce ethylene and vinyl acetate monomer and derivatives thereof |
| US11254636B2 (en) * | 2019-08-05 | 2022-02-22 | Lyondellbasell Acetyls, Llc | Ethyl acetate removal during VAM production |
| TW202515844A (zh) | 2019-12-19 | 2025-04-16 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造期間監測各式流之可燃性之方法及系統 |
| CN115093324B (zh) * | 2022-02-22 | 2023-12-26 | 上海交通大学 | 一种酯化烷烃的制备方法 |
| EP4565366A1 (en) | 2022-08-05 | 2025-06-11 | Celanese International Corporation | Catalyst for olefin acetoxylation |
| CN119654306A (zh) | 2022-08-05 | 2025-03-18 | 国际人造丝公司 | 区催化剂装载以及使用其使烯烃乙酰氧基化的方法 |
| WO2025054329A1 (en) | 2023-09-06 | 2025-03-13 | Celanese International Corporation | Incorporation of alkene hydrogenation in vinyl acetate production systems and methods |
| US20250236583A1 (en) | 2024-01-24 | 2025-07-24 | Celanese International Corporation | Catalyst and methods for olefin acetoxylation |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1146731A (en) * | 1965-06-23 | 1969-03-26 | Nat Distillers Chem Corp | Process for the preparation of vinyl acetate |
| US3855280A (en) * | 1972-12-08 | 1974-12-17 | Celanese Corp | Process for producing an alkenyl alkanoate from an olefin and a carboxylic acid |
| US4048096A (en) | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
| CA1299195C (en) | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
| DE3803900A1 (de) | 1988-02-09 | 1989-08-17 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
| US5185308A (en) | 1991-05-06 | 1993-02-09 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
| US5821111A (en) | 1994-03-31 | 1998-10-13 | Bioengineering Resources, Inc. | Bioconversion of waste biomass to useful products |
| USRE35377E (en) | 1993-05-27 | 1996-11-12 | Steinberg; Meyer | Process and apparatus for the production of methanol from condensed carbonaceous material |
| ES2287994T3 (es) | 1994-02-22 | 2007-12-16 | The Standard Oil Company | Procedimiento para la preparacion de soporte de catalizador de acetato de vinilo de lecho fluidizado. |
| FR2717462A1 (fr) | 1994-03-15 | 1995-09-22 | Omnium Traitement Valorisa | Procédé et installation de traitement des produits de dessablage. |
| US5599976A (en) | 1995-04-07 | 1997-02-04 | Hoechst Celanese Corporation | Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process |
| DE19613791C2 (de) | 1996-04-04 | 2002-01-31 | Celanese Chem Europe Gmbh | Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat |
| US5691267A (en) | 1996-04-16 | 1997-11-25 | Hoechst Celanese Corporation | Two step gold addition method for preparing a vinyl acetate catalyst |
| IN192600B (es) | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
| EP0845453A3 (en) | 1997-05-13 | 1998-09-09 | Celanese International Corporation | Safety system |
| US5952523A (en) | 1997-07-24 | 1999-09-14 | Praxair Technology, Inc. | Method for producing vinyl acetate |
| DE19734974A1 (de) | 1997-08-13 | 1999-02-25 | Hoechst Ag | Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat |
| GB9817362D0 (en) | 1998-08-11 | 1998-10-07 | Bp Chem Int Ltd | Improved process for the production if vinyl acetate |
| GB9826754D0 (en) | 1998-12-04 | 1999-01-27 | Bp Chem Int Ltd | Process for the production of vinyl acetate |
| US7074603B2 (en) | 1999-03-11 | 2006-07-11 | Zeachem, Inc. | Process for producing ethanol from corn dry milling |
| CN100575331C (zh) | 1999-03-11 | 2009-12-30 | 齐凯姆公司 | 一种生产乙醇的方法 |
| US6232352B1 (en) | 1999-11-01 | 2001-05-15 | Acetex Limited | Methanol plant retrofit for acetic acid manufacture |
| MXPA02011423A (es) | 2000-05-19 | 2004-09-06 | Celanese Int Corp | Procedimiento para la produccion de acetato de vinilo. |
| US6627770B1 (en) | 2000-08-24 | 2003-09-30 | Celanese International Corporation | Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process |
| GB0026241D0 (en) | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
| US6657078B2 (en) | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
| US6685754B2 (en) | 2001-03-06 | 2004-02-03 | Alchemix Corporation | Method for the production of hydrogen-containing gaseous mixtures |
| US6420595B1 (en) * | 2001-09-10 | 2002-07-16 | Millennium Petrochemicals, Inc. | Process control for vinyl acetate manufacture |
| US7115772B2 (en) | 2002-01-11 | 2006-10-03 | Celanese International Corporation | Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream |
| US7005541B2 (en) | 2002-12-23 | 2006-02-28 | Celanese International Corporation | Low water methanol carbonylation process for high acetic acid production and for water balance control |
| MX279852B (es) | 2004-01-29 | 2010-10-08 | Zeachem Inc | Recuperacion de acidos organicos. |
| US7208624B2 (en) | 2004-03-02 | 2007-04-24 | Celanese International Corporation | Process for producing acetic acid |
| EP2121946A4 (en) | 2007-02-09 | 2012-08-29 | Zeachem Inc | ENERGY-EFFICIENT METHOD FOR MANUFACTURING PRODUCTS |
| MX302494B (es) | 2008-05-07 | 2012-08-17 | Zeachem Inc | Recuperacion de acidos organicos. |
| US7884253B2 (en) | 2008-12-11 | 2011-02-08 | Range Fuels, Inc. | Methods and apparatus for selectively producing ethanol from synthesis gas |
| CN102381966A (zh) | 2011-11-11 | 2012-03-21 | 天津大学 | 一种醋酸乙烯生产方法 |
-
2013
- 2013-08-26 EP EP13759090.7A patent/EP2892871B1/en active Active
- 2013-08-26 MX MX2015002914A patent/MX350643B/es active IP Right Grant
- 2013-08-26 WO PCT/US2013/056598 patent/WO2014039304A1/en not_active Ceased
- 2013-08-26 CN CN201380054000.3A patent/CN104736512B/zh active Active
- 2013-08-26 SG SG11201501463QA patent/SG11201501463QA/en unknown
- 2013-08-26 RS RS20190460A patent/RS58692B1/sr unknown
- 2013-08-26 US US13/975,552 patent/US9573877B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2892871B1 (en) | 2019-02-27 |
| EP2892871A1 (en) | 2015-07-15 |
| MX2015002914A (es) | 2015-06-03 |
| CN104736512B (zh) | 2017-08-25 |
| US20140066649A1 (en) | 2014-03-06 |
| WO2014039304A1 (en) | 2014-03-13 |
| US9573877B2 (en) | 2017-02-21 |
| CN104736512A (zh) | 2015-06-24 |
| RS58692B1 (sr) | 2019-06-28 |
| SG11201501463QA (en) | 2015-03-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |