ES2139266T3 - Procedimiento para la obtencion de acroleina, acido acrilico, o su mezcla a partir de propano. - Google Patents

Procedimiento para la obtencion de acroleina, acido acrilico, o su mezcla a partir de propano.

Info

Publication number
ES2139266T3
ES2139266T3 ES96103300T ES96103300T ES2139266T3 ES 2139266 T3 ES2139266 T3 ES 2139266T3 ES 96103300 T ES96103300 T ES 96103300T ES 96103300 T ES96103300 T ES 96103300T ES 2139266 T3 ES2139266 T3 ES 2139266T3
Authority
ES
Spain
Prior art keywords
propane
obtaining
acrylic acid
acrolein
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96103300T
Other languages
English (en)
Inventor
Werner Hefner
Otto Machhammer
Hans-Peter Neumann
Andreas Tenten
Wilhelm Ruppel
Herbert Vogel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19508558A external-priority patent/DE19508558A1/de
Priority claimed from DE1995125504 external-priority patent/DE19525504A1/de
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2139266T3 publication Critical patent/ES2139266T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN PROCEDIMIENTO PARA LA OBTENCION DE ACROLEINA, ACIDO ACRILICO O SUS MEZCLAS A PARTIR DE PROPANO, EN UNA PRIMERA FASE SE DESHIDRATA PARCIALMENTE PROPANO Y OBTENIENDO PROPILENO, LA MEZCLA DE GAS OBTENIDA, DESPUES DE SEPARAR HIDROGENO Y VAPOR DE AGUA SE UTILIZA COMO ALIMENTACION EN UN REACTOR DE OXIDACION, EL PROPILENO FORMADO POR DESHIDRATACION SE OXIDA PARCIALMENTE CON OXIGENO MOLECULAR EN PRESENCIA DEL PROPANO NO DESHIDRATADO COMO GAS INERTE DE ENRARECIMIENTO DANDO ACROLEINA, ACIDO ACRILICO O SU MEZCLA, Y EL PROPANO QUE CONTIENE LA MEZCLA DE GAS DE LA OXIDACION PARCIAL SE HACE VOLVER A LA ETAPA A DE DESHIDRATACION.
ES96103300T 1995-03-10 1996-03-04 Procedimiento para la obtencion de acroleina, acido acrilico, o su mezcla a partir de propano. Expired - Lifetime ES2139266T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19508558A DE19508558A1 (de) 1995-03-10 1995-03-10 Verfahren zur Herstellung von Acrolein, Acrylsäure oder deren Gemisch aus Propan
DE1995125504 DE19525504A1 (de) 1995-07-13 1995-07-13 Verfahren zur Herstellung von Acrolein, Acrylsäure oder deren Gemisch aus Propan

Publications (1)

Publication Number Publication Date
ES2139266T3 true ES2139266T3 (es) 2000-02-01

Family

ID=26013226

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96103300T Expired - Lifetime ES2139266T3 (es) 1995-03-10 1996-03-04 Procedimiento para la obtencion de acroleina, acido acrilico, o su mezcla a partir de propano.

Country Status (11)

Country Link
US (1) US5705684A (es)
EP (1) EP0731077B1 (es)
JP (1) JPH08245494A (es)
KR (1) KR960034158A (es)
CN (1) CN1086690C (es)
CA (1) CA2171417A1 (es)
CZ (1) CZ73396A3 (es)
DE (1) DE59603316D1 (es)
ES (1) ES2139266T3 (es)
SG (1) SG40844A1 (es)
TW (1) TW328534B (es)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6057481A (en) * 1996-04-01 2000-05-02 Union Carbide Chemicals & Plastics Technology Corporation Processes for the manufacture of methylmercaptopropanal
US6492548B1 (en) 1996-04-01 2002-12-10 Union Carbide Chemicals & Plastics Technology Corporation Process for the oxidation of alkanes
DE19740252A1 (de) 1997-09-12 1999-03-18 Basf Ag Verfahren zur Herstellung von Acrylsäure und Methacrylsäure
SG81982A1 (en) * 1998-05-18 2001-07-24 Nippon Catalytic Chem Ind Method for production of acrolein and acrylic acid
DE19833049A1 (de) 1998-07-22 2000-01-27 Basf Ag Verfahren zur Herstellung von Acrylsäure
DE19838795A1 (de) 1998-08-26 2000-03-02 Basf Ag Verfahren zur kontinuierlichen Gewinnung von (Meth)acrylsäure
MY140522A (en) 2000-06-14 2009-12-31 Basf Ag Preparation of acrolein and/or acrylic acid
DE10122027A1 (de) * 2001-05-07 2002-05-23 Basf Ag Verfahren zur Herstellung von Acrylsäure durch heterogen katalysierte Partialoxidation von Propan
DE10028582A1 (de) * 2000-06-14 2001-12-20 Basf Ag Verfahren zur Herstellung von Acrolein oder Acrylsäure oder deren Gemischen aus Propan
DE10031518A1 (de) * 2000-06-28 2002-01-10 Basf Ag Verfahren zur Herstellung von Hydroformylierungsprodukten des Propylens und von Acrylsäure und/oder Acrolein
US6407031B1 (en) * 2000-09-28 2002-06-18 Rohm And Haas Company Promoted multi-metal oxide catalyst
KR100814702B1 (ko) * 2000-09-28 2008-03-18 롬 앤드 하스 캄파니 불포화 니트릴 제조방법
US6734136B2 (en) * 2000-09-28 2004-05-11 Rohm And Haas Company IR and/or SM promoted multi-metal oxide catalyst
US6403525B1 (en) * 2000-09-28 2002-06-11 Rohm And Haas Company Promoted multi-metal oxide catalyst
KR100823054B1 (ko) * 2000-09-29 2008-04-18 롬 앤드 하스 캄파니 재순환 방법
FR2844262B1 (fr) * 2002-09-10 2004-10-15 Atofina Procede de fabrication d'acide acrylique a partir de propane, en l'absence d'oxygene moleculaire
US7326802B2 (en) 2002-09-27 2008-02-05 Basf Aktiengesellschaft Preparation of at least one partial oxidation and/or ammoxidation product of propylene
DE10316039A1 (de) 2003-04-07 2004-10-21 Basf Ag Verfahren zur Herstellung von wenigstens einem partiellen Oxidations-und/oder Ammoxidationsprodukt eines Kohlenwasserstoffs
US7589046B2 (en) 2003-06-04 2009-09-15 Basf Aktiengesellschaft Thermal treatment of the precursor material of a catalytically active material
JP2005144432A (ja) * 2003-11-18 2005-06-09 Rohm & Haas Co アルカンをアルケン、およびそれらの対応する酸素化生成物に転化するための触媒系
TWI303584B (en) * 2004-04-08 2008-12-01 Rohm & Haas Improved catalytic (amm)oxidation process for conversion of lower alkanes
RU2415126C2 (ru) * 2004-07-01 2011-03-27 Басф Акциенгезельшафт Способ снижения температуры горячей точки неподвижного слоя катализатора в процессе получения акриловой кислоты путем двухстадийного способа гетерогенно катализируемого частичного окисления в газовой фазе пропилена
TWI344953B (en) * 2004-07-01 2011-07-11 Basf Ag Preparation of acrolein or acrylic acid or a mixture thereof from propane
KR101259649B1 (ko) * 2004-07-01 2013-04-30 바스프 에스이 프로필렌의 불균질 촉매화 부분 기상 산화를 사용한아크롤레인, 아크릴산 또는 그의 혼합물의 제조 방법
US8431743B2 (en) * 2004-07-01 2013-04-30 Basf Aktiengesellschaft Preparation of acrylic acid by heterogeneously catalyzed partial gas phase oxidation of propylene
US7361622B2 (en) * 2005-11-08 2008-04-22 Rohm And Haas Company Multi-staged catalyst systems and process for converting alkanes to alkenes and to their corresponding oxygenated products
FR2881136B1 (fr) * 2005-01-21 2007-03-23 Arkema Sa Procede de preparation de l'acide acrylique comprenant une oxydation partielle du propane en propylene
DE102005038412A1 (de) * 2005-08-12 2007-02-15 Basf Ag Verfahren zur Deckung des Bedarfs an Polymerisaten I, die zu wenigstens 90% ihres Gewichtes Acrylsäure, deren Salze und/oder Alkylester der Acrylsäure radikalisch einpolymerisiert enthalten
US20070106088A1 (en) * 2005-11-08 2007-05-10 Abraham Benderly Hybrid catalyst systems and hybrid process for converting alkanes to alkenes and to their corresponding oxygenated products
KR101370749B1 (ko) 2005-11-24 2014-03-06 바스프 에스이 프로판으로부터 아크롤레인 또는 아크릴산, 또는 그의혼합물의 제조 방법
MY143542A (en) * 2005-11-24 2011-05-31 Basf Se Process for preparing acrolein or acrylic acid or a mixture thereof from propane
DE102005061626A1 (de) 2005-12-21 2007-06-28 Basf Ag Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung wenigstens eines zu dehydrierenden Kohlenwasserstoffs
DE102006024901A1 (de) 2006-05-24 2007-11-29 Basf Ag Verfahren zur Herstellung von Acrolein, oder Acrylsäure oder deren Gemisch aus Propan
DE102006029790A1 (de) 2006-06-27 2008-01-03 Basf Ag Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung wenigstens eines zu dehydrierenden Kohlenwasserstoffs
DE102007006647A1 (de) 2007-02-06 2008-08-07 Basf Se Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts
JP2009035543A (ja) * 2007-07-11 2009-02-19 Sumitomo Chemical Co Ltd 混合ガスの製造方法および製造装置、ならびにエポキシ化合物の製造装置および製造方法
JP2009035544A (ja) * 2007-07-11 2009-02-19 Sumitomo Chemical Co Ltd エポキシ化合物の製造装置および製造方法
MX2008015540A (es) 2007-12-26 2009-06-26 Rohm Ahd Haas Company Un proceso integrado para preparar un acido carboxilico a partir de un alcano.
DE102008020688B3 (de) * 2008-04-24 2009-11-05 Evonik Stockhausen Gmbh Verfahren zur Herstellung und Aufreinigung wässriger Phasen
DE602009000800D1 (de) * 2008-07-10 2011-04-14 Rohm & Haas Autothermisches katalytisches Hybrid-Verfahren zur Umwandlung von Alkanen in Alkene und Katalysatoren dafür
EP2143704A1 (en) 2008-07-10 2010-01-13 Rohm and Haas Company An integrated process for preparing a carboxylic acid from an alkane
DE102008044946B4 (de) * 2008-08-29 2022-06-15 Evonik Superabsorber Gmbh Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren
EP2506963B1 (de) * 2009-12-01 2014-11-05 Basf Se Reaktor zur durchführung von autothermen gasphasendehydrierungen
EP2768794B1 (en) * 2011-10-18 2017-08-23 Rohm and Haas Company Method for preparing acrylic acid from propane and propylene
FI130603B (en) * 2018-08-03 2023-12-08 Neste Oyj THE METHOD PRODUCES BIORENEWABLE PROPENE FROM OILS AND FATS

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2251364B2 (de) * 1971-10-22 1975-07-03 Asahi Glass Co. Ltd., Tokio Verfahren zur Herstellung von Acrylsäure bzw. Methacrylsäure aus Acrolein bzw. Methacrolein
CA1217502A (en) * 1982-04-14 1987-02-03 Sargis Khoobiar Conversion of alkanes to unsaturated aldehydes
EP0117146B1 (en) * 1983-02-22 1986-12-30 The Halcon Sd Group, Inc. Conversion of propane to acrylic acid
US5198578A (en) * 1986-07-17 1993-03-30 Union Carbide Chemicals Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
US5218146A (en) * 1987-05-27 1993-06-08 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for production of acrylic acid
US5262547A (en) * 1990-10-31 1993-11-16 The Boc Group, Inc. Process for the production of petrochemicals
US5466837A (en) * 1993-09-30 1995-11-14 The Boc Group, Inc. Process for the production of hydrocarbon partial oxidation products

Also Published As

Publication number Publication date
DE59603316D1 (de) 1999-11-18
SG40844A1 (es) 1997-06-14
US5705684A (en) 1998-01-06
CN1143068A (zh) 1997-02-19
EP0731077A3 (es) 1996-09-25
CN1086690C (zh) 2002-06-26
JPH08245494A (ja) 1996-09-24
EP0731077A2 (de) 1996-09-11
TW328534B (en) 1998-03-21
KR960034158A (ko) 1996-10-22
CA2171417A1 (en) 1996-09-11
EP0731077B1 (de) 1999-10-13
CZ73396A3 (en) 1996-09-11

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