ES2098120T3 - Procedimiento para la obtencion de 3,4-epoxi en 1-buteno. - Google Patents

Procedimiento para la obtencion de 3,4-epoxi en 1-buteno.

Info

Publication number
ES2098120T3
ES2098120T3 ES94901917T ES94901917T ES2098120T3 ES 2098120 T3 ES2098120 T3 ES 2098120T3 ES 94901917 T ES94901917 T ES 94901917T ES 94901917 T ES94901917 T ES 94901917T ES 2098120 T3 ES2098120 T3 ES 2098120T3
Authority
ES
Spain
Prior art keywords
epoxy
butene
procedure
obtaining
epoxidization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94901917T
Other languages
English (en)
Inventor
Stefan Boeck
Klaus Herzog
Rolf Fischer
Herbert Vogel
Martin Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2098120T3 publication Critical patent/ES2098120T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/50Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/96Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCESO PARA LA ELABORACION DE 3,4 - EPOXI - 1 - BUTENO MEDIANTE EPOXIDIZACION DE FASE GASEOSA DE 1,3 - BUTADIENO POR MEDIO DE OXIGENO O GASES QUE CONTIENEN OXIGENO EN CATALIZADORES QUE CONTIENEN PLATA Y AISLAMIENTO DEL 3,4 - EPOXI - 1 - BUTENO A PARTIR DE LOS PRODUCTOS DE SALIDA DE REACCION, DONDE LA EPOXIDIZACION DE FASE GASEOSA SE REALIZA EN PRESENCIA DE 6 HASTA 8 % MOL DE VAPOR DE AGUA CON REFERENCIA A LA MEZCLA DE GAS GUIADA AL REACTOR.
ES94901917T 1992-12-11 1993-11-30 Procedimiento para la obtencion de 3,4-epoxi en 1-buteno. Expired - Lifetime ES2098120T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4241942A DE4241942A1 (de) 1992-12-11 1992-12-11 Verfahren zur Herstellung von 3,4-Epoxy-1-buten

Publications (1)

Publication Number Publication Date
ES2098120T3 true ES2098120T3 (es) 1997-04-16

Family

ID=6475082

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94901917T Expired - Lifetime ES2098120T3 (es) 1992-12-11 1993-11-30 Procedimiento para la obtencion de 3,4-epoxi en 1-buteno.

Country Status (10)

Country Link
US (2) US5618954A (es)
EP (1) EP0677047B1 (es)
JP (1) JPH08504413A (es)
KR (1) KR0184949B1 (es)
AT (1) ATE148696T1 (es)
AU (1) AU673713B2 (es)
CA (1) CA2151391A1 (es)
DE (2) DE4241942A1 (es)
ES (1) ES2098120T3 (es)
WO (1) WO1994013653A1 (es)

Families Citing this family (35)

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US5362890A (en) * 1993-10-04 1994-11-08 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
US6455713B1 (en) 1998-09-14 2002-09-24 Eastman Chemical Company Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene
US6018061A (en) * 1999-05-05 2000-01-25 Eastman Chemical Company Process for recovering 3,4-epoxy-1-butene
US6011163A (en) * 1999-05-20 2000-01-04 Eastman Chemical Company Use of fluorinated hydrocarbons as reaction media for selective epoxidation of olefins
DE19944536C2 (de) * 1999-09-17 2002-08-29 Xcellsis Gmbh Verfahren zur periodischen Reaktivierung eines kupferhaltigen Katalysatormaterials
DE60030056T2 (de) 1999-09-21 2007-02-15 Nippon Shokubai Co., Ltd. Katalysator für die Herstellung von Epoxiden und Verfahren für die Bereitung derselben und die Herstellung von Epoxiden
US6172245B1 (en) * 1999-12-16 2001-01-09 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
US6270739B1 (en) 2000-06-16 2001-08-07 Eastman Chemical Company Process for the removal of carbon dioxide from 3,4-epoxy-1-butene process recycle streams
US6392066B1 (en) 2001-02-22 2002-05-21 Sri International Epoxidation of olefins using lanthanide-promoted silver catalysts
US6509485B2 (en) 2001-02-22 2003-01-21 Sri International Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts
US6500970B1 (en) * 2001-07-20 2002-12-31 Eastman Chemical Company Recovery and purification of 3,4-epoxy-1-butene using high-boiling solvents
US6395913B1 (en) 2001-07-20 2002-05-28 Eastman Chemical Company Recovery and purification of 3,4-epoxy-1-butene
US6596882B2 (en) 2001-07-20 2003-07-22 Eastman Chemical Company Recovery and purification of 3,4-epoxy-1-butene using water-miscible solvents
US6582565B1 (en) 2002-01-17 2003-06-24 Eastman Chemical Company Recovery of 3,4-epoxy-1-butene by extractive distillation
US7319156B2 (en) 2003-03-25 2008-01-15 Sumitomo Chemical Company, Limited Process for producing olefin oxide
JP4572551B2 (ja) * 2003-03-25 2010-11-04 住友化学株式会社 酸化オレフィンの製造法
US7348444B2 (en) * 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
DE102004050506A1 (de) * 2004-10-15 2006-04-20 Degussa Ag Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung
BRPI0608552A2 (pt) * 2005-02-25 2010-01-12 Sumitomo Chemical Co processo para produção de óxido de olefina
US20070203348A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7704908B2 (en) * 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
US20070197808A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070213545A1 (en) * 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070151451A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the cooling, concentration or purification of ethylene oxide
US20070203352A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7459589B2 (en) * 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
US20070154377A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the removal of combustible volatile contaminant materials from a process stream
US20070203349A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197801A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
US8357812B2 (en) * 2005-12-22 2013-01-22 Shell Oil Company Process for preparing a rejuvenated epoxidation catalyst
US20070203350A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US20080154051A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
DE102008028760B9 (de) * 2008-06-17 2010-09-30 Zylum Beteiligungsgesellschaft Mbh & Co. Patente Ii Kg Verfahren zur Abtrennung von NOx aus einem epoxidhaltigen Gasstrom
CN110035998B (zh) 2016-12-02 2024-02-20 国际壳牌研究有限公司 调节乙烯环氧化催化剂的方法和生产环氧乙烷的相关方法

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Publication number Priority date Publication date Assignee Title
GB315412A (en) * 1928-07-13 1930-06-05 Cie Int Fab Essences & Petrole Improvements relating to the regeneration of catalysts
GB451130A (en) * 1934-04-24 1936-07-30 Fr De Catalyse Generalisee Soc Improved process for direct production of propylene oxide
US2353508A (en) * 1942-01-26 1944-07-11 Phillips Petroleum Co Process for reactivation of catalysts
US2479884A (en) * 1946-06-11 1949-08-23 Allied Chem & Dye Corp Process of reactivating a poisoned silver surface catalyst
GB1569974A (en) * 1976-03-05 1980-06-25 Ici Ltd Restoration of selectivity to catalysts used in the production of olefine oxides
SU910184A1 (ru) * 1979-06-15 1982-03-07 Предприятие П/Я Р-6913 Способ регенерации родийсодержащего катализатора деалкилировани алкилбензолов
US4429055A (en) * 1982-07-06 1984-01-31 E. I. Du Pont De Nemours & Company Oxidation catalyst
US4474997A (en) * 1982-07-06 1984-10-02 E. I. Du Pont De Nemours And Company Oxidation process and catalyst therefor
US4751210A (en) * 1987-05-21 1988-06-14 Intevep, S.A. Regeneration of an iron based natural catalyst used in the hydroconversion of heavy crudes and residues
US4950773A (en) * 1988-01-28 1990-08-21 Eastman Kodak Company Selective epoxidation of olefins
US4897498A (en) * 1988-01-28 1990-01-30 Eastman Kodak Company Selective monoepoxidation of olefins
DE3926147A1 (de) * 1989-08-08 1991-02-14 Basf Ag Verfahren zur herstellung von 2,5-dihydrofuranen
US5117013A (en) * 1990-05-03 1992-05-26 Eastman Kodak Company Process for the selective hydrogenation γ, δ-epoxyalkenes to epoxyalkanes
US5235121A (en) * 1991-08-02 1993-08-10 Phillips Petroleum Company Method for reforming hydrocarbons
US5117012A (en) * 1991-10-07 1992-05-26 Eastman Kodak Company Recovery of 3,4-epoxy-1-butene from 1,3-butadiene oxidation effluents

Also Published As

Publication number Publication date
KR0184949B1 (ko) 1999-05-01
DE4241942A1 (de) 1994-06-16
ATE148696T1 (de) 1997-02-15
US5618954A (en) 1997-04-08
EP0677047B1 (de) 1997-02-05
DE59305421D1 (de) 1997-03-20
AU673713B2 (en) 1996-11-21
AU5629294A (en) 1994-07-04
EP0677047A1 (de) 1995-10-18
KR950704285A (ko) 1995-11-17
CA2151391A1 (en) 1994-06-23
WO1994013653A1 (de) 1994-06-23
US5905161A (en) 1999-05-18
JPH08504413A (ja) 1996-05-14

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