JPS5217448A - Symmetric synthesis of chrysanthemumic acid primary alcohol ester - Google Patents

Symmetric synthesis of chrysanthemumic acid primary alcohol ester

Info

Publication number
JPS5217448A
JPS5217448A JP50094349A JP9434975A JPS5217448A JP S5217448 A JPS5217448 A JP S5217448A JP 50094349 A JP50094349 A JP 50094349A JP 9434975 A JP9434975 A JP 9434975A JP S5217448 A JPS5217448 A JP S5217448A
Authority
JP
Japan
Prior art keywords
alcohol ester
primary alcohol
acid primary
chrysanthemumic acid
symmetric synthesis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP50094349A
Other languages
Japanese (ja)
Other versions
JPS5910336B2 (en
Inventor
Tadatoshi Akitani
Yukio Komeyoshi
Fumio Fujita
Tsuneyuki Nagase
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP50094349A priority Critical patent/JPS5910336B2/en
Priority to IL50100A priority patent/IL50100A/en
Priority to BE6045627A priority patent/BE844631A/en
Priority to SU762387252A priority patent/SU719491A3/en
Priority to CH977576A priority patent/CH621767A5/en
Priority to DK345276AA priority patent/DK142765B/en
Priority to GB31985/76A priority patent/GB1499094A/en
Priority to FR7623388A priority patent/FR2319623A1/en
Priority to CA000258220A priority patent/CA1121813A/en
Priority to IT68927/76A priority patent/IT1070323B/en
Priority to NL7608508A priority patent/NL7608508A/en
Priority to DE2634663A priority patent/DE2634663C3/en
Publication of JPS5217448A publication Critical patent/JPS5217448A/en
Priority to US05/847,471 priority patent/US4197408A/en
Publication of JPS5910336B2 publication Critical patent/JPS5910336B2/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C245/00—Compounds containing chains of at least two nitrogen atoms with at least one nitrogen-to-nitrogen multiple bond
    • C07C245/12—Diazo compounds, i.e. compounds having the free valencies of >N2 groups attached to the same carbon atom
    • C07C245/14—Diazo compounds, i.e. compounds having the free valencies of >N2 groups attached to the same carbon atom having diazo groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C245/18—Diazo compounds, i.e. compounds having the free valencies of >N2 groups attached to the same carbon atom having diazo groups bound to acyclic carbon atoms of a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

PURPOSE: Chrysanthemumic acid primary alcohol ester is prepared by the reaction of 2,5-dimethyl-2,4-hexadiene with diazoacetate in the presence of asymmetric copper complex derived from optical active Schiff's base as a catalyst.
COPYRIGHT: (C)1977,JPO&Japio
JP50094349A 1975-08-01 1975-08-01 Asymmetric synthesis method of primary chrysanthemum acid ester Expired JPS5910336B2 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
JP50094349A JPS5910336B2 (en) 1975-08-01 1975-08-01 Asymmetric synthesis method of primary chrysanthemum acid ester
IL50100A IL50100A (en) 1975-08-01 1976-07-22 Asymmetric synthesis of(cyclo)alkyl chrysanthemate esters
BE6045627A BE844631A (en) 1975-08-01 1976-07-28 PROCESS FOR THE PREPARATION OF OPTICALLY ACTIVE ALKYL CHRYSANTHEMATE AND PRODUCT OBTAINED
FR7623388A FR2319623A1 (en) 1975-08-01 1976-07-30 PROCESS FOR THE PRODUCTION OF AN OPTICALLY ACTIVE ALKYL CHRYSANTHEMATE
CH977576A CH621767A5 (en) 1975-08-01 1976-07-30 Process for the preparation of optically active alkyl chrysanthemates.
DK345276AA DK142765B (en) 1975-08-01 1976-07-30 Process for the preparation of optically active esters of chrysanthemic acid.
GB31985/76A GB1499094A (en) 1975-08-01 1976-07-30 Asymmetric synthesis of alkyl chrysanthemate
SU762387252A SU719491A3 (en) 1975-08-01 1976-07-30 Method of preparing optically active alkylchrysanthemate
CA000258220A CA1121813A (en) 1975-08-01 1976-07-30 Asymmetric synthesis of chrysanthemate
IT68927/76A IT1070323B (en) 1975-08-01 1976-07-30 PROCEDURE FOR THE PREPARATION OF OPTICALLY ACTIVE ALCHYL CHRYSANTHEMATE
NL7608508A NL7608508A (en) 1975-08-01 1976-07-30 PROCEDURE FOR PREPARING OPTICALLY ACTIVE ALKYL CHRYSANTHEMATES.
DE2634663A DE2634663C3 (en) 1975-08-01 1976-08-02 Process for the preparation of an optically active alkyl chrysanthemum monocarboxylic acid ester
US05/847,471 US4197408A (en) 1975-08-01 1977-10-31 Asymmetric synthesis of alkyl chrysanthemate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP50094349A JPS5910336B2 (en) 1975-08-01 1975-08-01 Asymmetric synthesis method of primary chrysanthemum acid ester

Publications (2)

Publication Number Publication Date
JPS5217448A true JPS5217448A (en) 1977-02-09
JPS5910336B2 JPS5910336B2 (en) 1984-03-08

Family

ID=14107796

Family Applications (1)

Application Number Title Priority Date Filing Date
JP50094349A Expired JPS5910336B2 (en) 1975-08-01 1975-08-01 Asymmetric synthesis method of primary chrysanthemum acid ester

Country Status (12)

Country Link
JP (1) JPS5910336B2 (en)
BE (1) BE844631A (en)
CA (1) CA1121813A (en)
CH (1) CH621767A5 (en)
DE (1) DE2634663C3 (en)
DK (1) DK142765B (en)
FR (1) FR2319623A1 (en)
GB (1) GB1499094A (en)
IL (1) IL50100A (en)
IT (1) IT1070323B (en)
NL (1) NL7608508A (en)
SU (1) SU719491A3 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59158260A (en) * 1983-02-28 1984-09-07 Seikei Giken:Kk Vacuum transfer apparatus
JPS59158261A (en) * 1983-07-19 1984-09-07 Seikei Giken:Kk Transfer apparatus
JPH01232619A (en) * 1988-03-11 1989-09-18 Toska Co Ltd Printing method for key top
JPH0671852A (en) * 1992-08-31 1994-03-15 Shizuoka Giken Sanki Kk Method and device for subjecting curved surface to heat transfer by vacuum press
JPH11279111A (en) * 1998-01-29 1999-10-12 Sumitomo Chem Co Ltd Production of optically active chrysanthemumic acid
US7723539B2 (en) * 2004-06-16 2010-05-25 Endura S.P.A. Catalysts based on metal complexes for the synthesis of optically active chrysanthemic acid
CN103789791A (en) * 2014-02-12 2014-05-14 华东师范大学 Electrochemical synthesis method of 2-phenylpropionic acid with optical activity
CN103789789A (en) * 2014-02-11 2014-05-14 华东师范大学 Method for electrochemical synthesis of styrene cyclic carbonate with optical activity

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2919820A1 (en) * 1979-05-16 1980-11-20 Bayer Ag FLUOR-SUBSTITUTED OXYALKENYL-CYCLOPROPANCARBONIC ACID ESTERS, METHODS FOR THE PRODUCTION THEREOF AND THEIR USE AS INSECTICIDES AND ACARICIDES
EP0023075A1 (en) * 1979-07-13 1981-01-28 Imperial Chemical Industries Plc Process for the preparation of cyclopropane carboxylic acid esters
EP0022608B1 (en) * 1979-07-13 1983-07-06 Imperial Chemical Industries Plc Process for the preparation of cyclopropane carboxylic acid esters
EP0024796A1 (en) * 1979-07-13 1981-03-11 Imperial Chemical Industries Plc Chiral amino-alcohol complexes and process for their preparation
EP0024795A1 (en) * 1979-07-13 1981-03-11 Imperial Chemical Industries Plc Chiral compounds and process for their preparation
EP0024797A1 (en) * 1979-07-13 1981-03-11 Imperial Chemical Industries Plc Chiral sugar complexes and process for their preparation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL44167A (en) * 1973-02-14 1979-09-30 Sumitomo Chemical Co Chiral copper-complex catalyst

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59158260A (en) * 1983-02-28 1984-09-07 Seikei Giken:Kk Vacuum transfer apparatus
JPH032063B2 (en) * 1983-02-28 1991-01-14 Seikei Giken Kk
JPS59158261A (en) * 1983-07-19 1984-09-07 Seikei Giken:Kk Transfer apparatus
JPH01232619A (en) * 1988-03-11 1989-09-18 Toska Co Ltd Printing method for key top
JPH0671852A (en) * 1992-08-31 1994-03-15 Shizuoka Giken Sanki Kk Method and device for subjecting curved surface to heat transfer by vacuum press
JPH11279111A (en) * 1998-01-29 1999-10-12 Sumitomo Chem Co Ltd Production of optically active chrysanthemumic acid
JP4576642B2 (en) * 1998-01-29 2010-11-10 住友化学株式会社 Process for producing optically active chrysanthemic acid
US7723539B2 (en) * 2004-06-16 2010-05-25 Endura S.P.A. Catalysts based on metal complexes for the synthesis of optically active chrysanthemic acid
CN103789789A (en) * 2014-02-11 2014-05-14 华东师范大学 Method for electrochemical synthesis of styrene cyclic carbonate with optical activity
CN103789789B (en) * 2014-02-11 2016-06-29 华东师范大学 Electrochemical synthesis has the method for optically active Styrene carbonate
CN103789791A (en) * 2014-02-12 2014-05-14 华东师范大学 Electrochemical synthesis method of 2-phenylpropionic acid with optical activity
CN103789791B (en) * 2014-02-12 2016-08-17 华东师范大学 A kind of electrochemical synthesis has optically active 2-benzenpropanoic acid method

Also Published As

Publication number Publication date
IT1070323B (en) 1985-03-29
JPS5910336B2 (en) 1984-03-08
NL7608508A (en) 1977-02-03
DK142765C (en) 1981-08-17
DE2634663A1 (en) 1977-03-17
CH621767A5 (en) 1981-02-27
SU719491A3 (en) 1980-02-29
BE844631A (en) 1976-11-16
IL50100A (en) 1982-02-28
DE2634663C3 (en) 1980-01-17
IL50100A0 (en) 1976-09-30
DE2634663B2 (en) 1979-05-31
FR2319623A1 (en) 1977-02-25
DK142765B (en) 1981-01-19
DK345276A (en) 1977-02-02
GB1499094A (en) 1978-01-25
FR2319623B1 (en) 1979-09-28
CA1121813A (en) 1982-04-13

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