ZA200100800B - Fire resistant styrene polymer foams with reduced brominated fire retardant. - Google Patents
Fire resistant styrene polymer foams with reduced brominated fire retardant. Download PDFInfo
- Publication number
- ZA200100800B ZA200100800B ZA200100800A ZA200100800A ZA200100800B ZA 200100800 B ZA200100800 B ZA 200100800B ZA 200100800 A ZA200100800 A ZA 200100800A ZA 200100800 A ZA200100800 A ZA 200100800A ZA 200100800 B ZA200100800 B ZA 200100800B
- Authority
- ZA
- South Africa
- Prior art keywords
- percent
- styrene polymer
- formula
- weight
- polymer
- Prior art date
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 305
- 229920000642 polymer Polymers 0.000 title claims description 202
- 239000003063 flame retardant Substances 0.000 title claims description 71
- 239000006260 foam Substances 0.000 title description 76
- 230000009970 fire resistant effect Effects 0.000 title description 4
- 239000000203 mixture Substances 0.000 claims description 88
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims description 62
- 238000009472 formulation Methods 0.000 claims description 42
- 150000003018 phosphorus compounds Chemical class 0.000 claims description 29
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 claims description 16
- 229910019142 PO4 Inorganic materials 0.000 claims description 14
- 235000021317 phosphate Nutrition 0.000 claims description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 13
- 125000001931 aliphatic group Chemical group 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- 150000003003 phosphines Chemical class 0.000 claims description 6
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 6
- 150000004714 phosphonium salts Chemical class 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 claims description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 2
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 2
- RYUJRXVZSJCHDZ-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC(C)C)OC1=CC=CC=C1 RYUJRXVZSJCHDZ-UHFFFAOYSA-N 0.000 claims description 2
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 claims description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 2
- 229940093635 tributyl phosphate Drugs 0.000 claims description 2
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 claims description 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 claims description 2
- RXPQRKFMDQNODS-UHFFFAOYSA-N tripropyl phosphate Chemical compound CCCOP(=O)(OCCC)OCCC RXPQRKFMDQNODS-UHFFFAOYSA-N 0.000 claims description 2
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical group CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 claims 5
- RCRYBQKHEDNBDN-UHFFFAOYSA-N 6-methylheptyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCC(C)C)OC1=CC=CC=C1 RCRYBQKHEDNBDN-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 1
- VOWPVJACXJNHBC-UHFFFAOYSA-N methyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OC)OC1=CC=CC=C1 VOWPVJACXJNHBC-UHFFFAOYSA-N 0.000 claims 1
- 239000004604 Blowing Agent Substances 0.000 description 17
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 16
- 238000012360 testing method Methods 0.000 description 11
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 10
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 9
- 229910052794 bromium Inorganic materials 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 3
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- SZGBUFROANKUNE-UHFFFAOYSA-N [1-(1-phenylcyclohexyl)cyclohexyl]benzene Chemical group C1CCCCC1(C1(CCCCC1)C=1C=CC=CC=1)C1=CC=CC=C1 SZGBUFROANKUNE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- MWSVUOSVPYCABB-UHFFFAOYSA-N bis(2-bromobutan-2-yl)diazene Chemical compound CCC(C)(Br)N=NC(C)(Br)CC MWSVUOSVPYCABB-UHFFFAOYSA-N 0.000 description 1
- FJDFMHRXSYNDIR-UHFFFAOYSA-N bis(2-chlorobutan-2-yl)diazene Chemical compound CCC(C)(Cl)N=NC(C)(Cl)CC FJDFMHRXSYNDIR-UHFFFAOYSA-N 0.000 description 1
- ZGXHUGQEDPPKGZ-UHFFFAOYSA-N bis(2-methylbutan-2-yl)diazene Chemical compound CCC(C)(C)N=NC(C)(C)CC ZGXHUGQEDPPKGZ-UHFFFAOYSA-N 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- CAAULPUQFIIOTL-UHFFFAOYSA-N methyl dihydrogen phosphate Chemical compound COP(O)(O)=O CAAULPUQFIIOTL-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- -1 phosphate compound Chemical class 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0019—Use of organic additives halogenated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9821698P | 1998-08-28 | 1998-08-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200100800B true ZA200100800B (en) | 2001-08-07 |
Family
ID=22268086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200100800A ZA200100800B (en) | 1998-08-28 | 2001-01-29 | Fire resistant styrene polymer foams with reduced brominated fire retardant. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6579911B1 (zh) |
| EP (1) | EP1112308A1 (zh) |
| JP (1) | JP2002523586A (zh) |
| KR (1) | KR20010072979A (zh) |
| CN (1) | CN1317031A (zh) |
| AU (1) | AU5900699A (zh) |
| BR (1) | BR9914313A (zh) |
| CA (1) | CA2339258A1 (zh) |
| HU (1) | HUP0103400A2 (zh) |
| IL (1) | IL141265A0 (zh) |
| TR (1) | TR200100601T2 (zh) |
| WO (1) | WO2000012593A1 (zh) |
| ZA (1) | ZA200100800B (zh) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1164158A4 (en) | 1999-10-27 | 2004-04-07 | Kaneka Corp | EXTRUDED POLYSTYRENE FOAM AND PRODUCTION METHOD THEREFOR |
| EP1248817A1 (en) * | 1999-12-03 | 2002-10-16 | The Dow Chemical Company | Halogenated fire-retardant compositions and foams and fabricated articles therefrom |
| WO2002051918A1 (fr) | 2000-12-22 | 2002-07-04 | Kaneka Corporation | Mousse a base de resine de styrene extrudee et son procede de production |
| CN100384916C (zh) * | 2000-12-22 | 2008-04-30 | 钟渊化学工业株式会社 | 苯乙烯类树脂挤出泡沫体及其制造方法 |
| ES2318025T3 (es) * | 2001-05-25 | 2009-05-01 | The Usa, Represented By The Administrator Of National Aeronautics And Space Administration | Agente supresor de llama, sistema y usos. |
| US7144925B2 (en) | 2002-05-09 | 2006-12-05 | Dow Global Technologies Inc. | Fire resistance acoustic foam |
| JP4755399B2 (ja) * | 2004-02-26 | 2011-08-24 | 第一工業製薬株式会社 | 難燃性スチレン系樹脂組成物 |
| DE602005013975D1 (de) * | 2004-07-19 | 2009-05-28 | Bromine Compounds Ltd | Neue flammhemmende polystyrene |
| EP1773744B1 (en) * | 2004-07-19 | 2013-01-16 | Bromine Compounds Ltd. | SYNTHESIS OF PENTABROMOBENZYL BROMIDE (PBB-Br) |
| JP4395840B2 (ja) | 2004-09-01 | 2010-01-13 | 第一工業製薬株式会社 | プラスチック用臭素系難燃剤組成物 |
| DE102004044380A1 (de) * | 2004-09-10 | 2006-03-30 | Basf Ag | Halogenfreie, flammgeschützte Polymerschaumstoffe |
| JP4914000B2 (ja) * | 2004-11-12 | 2012-04-11 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板 |
| JP2008525573A (ja) * | 2004-12-22 | 2008-07-17 | アルベマール・コーポレーシヨン | 難燃性押出し加工ポリスチレンフォーム組成物 |
| ITMO20050135A1 (it) * | 2005-06-03 | 2006-12-04 | Coopbox Europ S P A | Procedimento per la produzione di polistirolo espanso. |
| CN101511927B (zh) * | 2005-11-21 | 2012-01-25 | 溴化合物有限公司 | 阻燃的溴苄基体系 |
| KR20090068217A (ko) * | 2006-09-26 | 2009-06-25 | 알베마를 코포레이션 | 난연성 압출성형된 폴리스티렌 발포체 조성물 |
| US8084511B2 (en) * | 2007-03-08 | 2011-12-27 | Chemtura Corporation | Flame retardants for use in styrenic foams |
| WO2009035880A2 (en) * | 2007-09-13 | 2009-03-19 | Dow Global Technologies, Inc. | Expanded styrenic polymers containing aromatic phosphonate fr additives |
| US8080592B2 (en) * | 2007-11-02 | 2011-12-20 | Dow Global Technologies Llc | Extruded polymer foams containing brominated fatty acid-based flame retardant additives |
| WO2010099020A2 (en) | 2009-02-26 | 2010-09-02 | Icl-Ip America Inc. | Styrenic polymer composition |
| JP5471013B2 (ja) * | 2009-04-27 | 2014-04-16 | 株式会社カネカ | スチレン系樹脂押出発泡体及びその製造方法 |
| ES2545331T3 (es) * | 2009-12-16 | 2015-09-10 | Basf Se | Agente ignífugo |
| CN102127269B (zh) | 2010-01-12 | 2014-01-29 | 盛亚军 | 一种阻燃聚合物泡沫材料及其制备方法 |
| CN102250447B (zh) * | 2010-05-21 | 2014-10-22 | 台燿科技股份有限公司 | 无卤素的阻燃性环氧树脂组合物及由其制成的预浸材和印刷电路板 |
| US9051449B2 (en) | 2011-06-08 | 2015-06-09 | Italmatch Chemicals S.P.A. | Flame retarded extruded polystyrene foams |
| EP2692786A1 (de) * | 2012-08-02 | 2014-02-05 | Basf Se | Flammgeschützter und wärmeformbeständiger Extrusionsschaumstoff aus Styrolcopolymeren |
| EP2961793A1 (en) * | 2013-02-26 | 2016-01-06 | Dow Global Technologies LLC | Thermoplastic polymeric foam pipe insulation |
| CA3023668C (en) | 2016-05-11 | 2024-02-06 | Owens Corning Intellectual Capital, Llc | Polymeric foam comprising low levels of brominated flame retardant and method of making same |
| EP3504261B1 (en) * | 2016-08-29 | 2023-08-02 | ICL-IP America Inc. | Flame-retarded polyamide composition |
| KR102000183B1 (ko) | 2017-08-11 | 2019-07-15 | 손민일 | 건축용 단열재 및 이를 포함하는 건축물의 바닥 시공구조 |
| KR102160267B1 (ko) | 2018-04-25 | 2020-09-25 | 손민일 | 폐플라스틱을 이용한 난연성 건축자재 |
| KR102160266B1 (ko) | 2018-04-25 | 2020-09-25 | 손민일 | Cpvc를 이용한 난연성 건축자재 및 그 제조방법 |
| CN112280204A (zh) * | 2020-10-31 | 2021-01-29 | 三益(玉田)新材料科技有限公司 | 一种聚苯乙烯挤塑板及其制备工艺 |
| WO2022200987A1 (en) | 2021-03-22 | 2022-09-29 | Versalis S.P.A. | Reactive polymeric mixtures, hybrid polymeric foams and process for producing the same |
| KR20240053588A (ko) | 2021-08-09 | 2024-04-24 | 이탈마치 케미칼스 에스피에이 | 난연성 핵생성 조성물 및 폴리스티렌 폼을 위한 상응하는 제제 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL127714C (zh) | 1965-04-01 | |||
| DE1244396B (de) | 1965-11-30 | 1967-07-13 | Basf Ag | Styrolpolymerisate enthaltende Formmassen zur Herstellung selbstverloeschender Formkoerper |
| GB1182964A (en) | 1967-09-01 | 1970-03-04 | Monsanto Chemicals | Process for the Production of Foamed or Foamable Resin Compositions. |
| AT316879B (de) | 1972-05-18 | 1974-07-25 | Isovolta | Schwer entflammbar ausgerüsteter Strukturschaum aus Polystyrol und Verfahren zu seiner Herstellung |
| DD130482B1 (de) | 1977-04-21 | 1982-03-31 | Gruetzmacher | Verfahren zur herstellung von schwerentflammbaren schaumfaehigen styrolpolymerisaten |
| DE2861556D1 (en) | 1977-11-09 | 1982-03-04 | Basf Wyandotte Corp | Particles of expandable polystyrene with improved flame-retardant properties |
| CS201748B1 (cs) | 1978-08-11 | 1980-11-28 | Zdenek Horak | Lehcený polymerní materiál se sníženou hořlavostí |
| JPS5712048A (en) | 1980-06-26 | 1982-01-21 | Teijin Chem Ltd | Flame-retardant, expandable styrene resin bead composition |
| JPH01247434A (ja) | 1988-03-30 | 1989-10-03 | Sekisui Plastics Co Ltd | 難燃性スチレン系樹脂発泡体の製造方法 |
| JPH0277435A (ja) | 1988-09-14 | 1990-03-16 | Sekisui Plastics Co Ltd | 難燃性スチレン系樹脂板状発泡体の製造方法 |
| CA2083137C (en) * | 1990-06-14 | 2000-12-05 | William G. Stobby | Fire resistant alkenylaromatic foams |
| JPH089678B2 (ja) | 1990-10-31 | 1996-01-31 | 積水化成品工業株式会社 | スチレン系樹脂発泡体の製造方法 |
| JPH07106591B2 (ja) | 1990-11-26 | 1995-11-15 | 積水化成品工業株式会社 | スチレン系樹脂発泡体 |
| JPH04307228A (ja) | 1991-04-03 | 1992-10-29 | Kanegafuchi Chem Ind Co Ltd | ポリスチレン系樹脂押出発泡体 |
| WO1993012163A1 (en) | 1991-12-13 | 1993-06-24 | The Dow Chemical Company | Fire resistant alkenylaromatic foams |
| JP3198676B2 (ja) | 1992-11-19 | 2001-08-13 | 三菱化学フォームプラスティック株式会社 | 鋳造原型用熱可塑性樹脂発泡粒子 |
| DE4240109A1 (de) | 1992-11-28 | 1994-06-01 | Basf Ag | Feinteilige, expandierbare Styrolpolymerisate, insbesondere für das Recycling von Polystyrol-Partikelschaumstoffen |
| JPH06329824A (ja) | 1993-05-26 | 1994-11-29 | Kanegafuchi Chem Ind Co Ltd | 切削加工性に優れたポリスチレン系樹脂発泡体 |
| DE19508939A1 (de) | 1995-03-13 | 1996-09-19 | Basf Ag | Verfahren zur Herstellung von flammgeschützten, Polystyrolschaum-Recyclat enthaltenden Polystyrol-Partikelschaumstoffen |
| DE19508935A1 (de) * | 1995-03-13 | 1996-09-19 | Basf Ag | Flammgeschützte thermoplastische Formmassen, enthaltend als wesentliche Komponenten |
| DE19624827A1 (de) | 1996-06-21 | 1998-01-02 | Basf Ag | Flammgeschützte Polystyrolschaumstoffe |
| DE19632439A1 (de) | 1996-08-12 | 1998-02-19 | Basf Ag | Durch Extrusion hergestellte Schaumstoffplatten |
-
1999
- 1999-08-26 IL IL14126599A patent/IL141265A0/xx unknown
- 1999-08-26 AU AU59006/99A patent/AU5900699A/en not_active Abandoned
- 1999-08-26 US US09/744,005 patent/US6579911B1/en not_active Expired - Fee Related
- 1999-08-26 JP JP2000567601A patent/JP2002523586A/ja active Pending
- 1999-08-26 CA CA002339258A patent/CA2339258A1/en not_active Abandoned
- 1999-08-26 CN CN99810541A patent/CN1317031A/zh active Pending
- 1999-08-26 EP EP99946638A patent/EP1112308A1/en not_active Withdrawn
- 1999-08-26 WO PCT/US1999/019408 patent/WO2000012593A1/en not_active Application Discontinuation
- 1999-08-26 HU HU0103400A patent/HUP0103400A2/hu unknown
- 1999-08-26 TR TR2001/00601T patent/TR200100601T2/xx unknown
- 1999-08-26 KR KR1020017002426A patent/KR20010072979A/ko not_active Application Discontinuation
- 1999-08-26 BR BR9914313-5A patent/BR9914313A/pt not_active Application Discontinuation
-
2001
- 2001-01-29 ZA ZA200100800A patent/ZA200100800B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2000012593A1 (en) | 2000-03-09 |
| HUP0103400A2 (hu) | 2002-01-28 |
| TR200100601T2 (tr) | 2001-06-21 |
| US6579911B1 (en) | 2003-06-17 |
| EP1112308A1 (en) | 2001-07-04 |
| BR9914313A (pt) | 2001-06-19 |
| KR20010072979A (ko) | 2001-07-31 |
| IL141265A0 (en) | 2002-03-10 |
| AU5900699A (en) | 2000-03-21 |
| CA2339258A1 (en) | 2000-03-09 |
| CN1317031A (zh) | 2001-10-10 |
| JP2002523586A (ja) | 2002-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6579911B1 (en) | Fire resistant styrene polymer foams with reduced brominated fire retardant | |
| EP2438111B1 (en) | Infrared attenuated polymeric foam insulation with flame retardant performance | |
| EP2960272B1 (en) | Styrenic resin extruded foam and method for recycling same | |
| EP3070118B1 (en) | Extruded styrenic resin foam and method for manufacturing same | |
| EP1786853B1 (en) | Novel flame-retardant polystyrenes | |
| EP2406307A2 (en) | Styrenic polymer composition | |
| JP6139294B2 (ja) | スチレン系樹脂押出発泡体及びその製造方法 | |
| JP2012136674A (ja) | スチレン系樹脂押出発泡体及びその製造方法 | |
| WO2012057060A1 (ja) | スチレン系樹脂押出発泡体及びその製造方法 | |
| JP2013124281A (ja) | ポリスチレン系樹脂押出発泡体の製造方法 | |
| JP5877023B2 (ja) | ポリオレフィン系樹脂発泡体 | |
| JP5740177B2 (ja) | スチレン系樹脂押出発泡体及びその製造方法 | |
| MXPA01002166A (en) | Fire resistant styrene polymer foams with reduced brominated fire retardant | |
| KR101977818B1 (ko) | 압출 폴리스티렌 발포체용 난연 마스터 배치 조성물 및 이를 이용한 압출 폴리스티렌 발포체 | |
| JP4222916B2 (ja) | 難燃性ポリスチレン系樹脂押出発泡体及びその製造方法 | |
| US11939445B2 (en) | Flame retardant masterbatch composition for foams containing a pH moderator | |
| JP3913460B2 (ja) | スチレン系樹脂発泡体およびその製造方法 | |
| JP4474733B2 (ja) | スチレン系樹脂発泡体の製造方法 | |
| JP2007153964A (ja) | スチレン系樹脂押出発泡体の製造方法 | |
| JP2024157337A (ja) | ポリスチレン系樹脂押出発泡板の製造方法 | |
| JPH0277435A (ja) | 難燃性スチレン系樹脂板状発泡体の製造方法 | |
| JP2007146048A (ja) | スチレン系樹脂押出発泡体およびその製造方法 | |
| JP2006124495A (ja) | 難燃性ポリスチレン系樹脂押出発泡体及びその製造方法 | |
| JP2010053162A (ja) | スチレン系樹脂押出発泡体およびその製造方法 |