WO2013125095A1 - 空気入りタイヤ - Google Patents
空気入りタイヤ Download PDFInfo
- Publication number
- WO2013125095A1 WO2013125095A1 PCT/JP2012/077530 JP2012077530W WO2013125095A1 WO 2013125095 A1 WO2013125095 A1 WO 2013125095A1 JP 2012077530 W JP2012077530 W JP 2012077530W WO 2013125095 A1 WO2013125095 A1 WO 2013125095A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- adhesive sheet
- tire
- carcass
- less
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0041—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers
- B60C11/005—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers with cap and base layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0008—Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0008—Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
- B60C2011/0016—Physical properties or dimensions
- B60C2011/0025—Modulus or tan delta
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0008—Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
- B60C2011/0016—Physical properties or dimensions
- B60C2011/0033—Thickness of the tread
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C2011/0091—Tyre tread bands; Tread patterns; Anti-skid inserts built-up by narrow strip winding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/01—Shape of the shoulders between tread and sidewall, e.g. rounded, stepped or cantilevered
- B60C2011/016—Shape of the shoulders between tread and sidewall, e.g. rounded, stepped or cantilevered different rubber for tread wings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C13/00—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof
- B60C13/04—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof having annular inlays or covers, e.g. white sidewalls
- B60C2013/045—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof having annular inlays or covers, e.g. white sidewalls comprising different sidewall rubber layers
Definitions
- the present invention relates to a pneumatic tire. Specifically, the present invention relates to a tire in which a tread includes a base layer and a cap layer.
- a typical tread has a base layer and a cap layer.
- the base layer is made of a crosslinked rubber having excellent adhesiveness.
- the cap layer is made of a crosslinked rubber having excellent wear resistance.
- a strip wind method is known as a method for forming the base layer and the cap layer.
- a ribbon-like first strip made of uncrosslinked rubber is spirally wound to form a base layer laminate.
- a ribbon-like second strip made of another uncrosslinked rubber is spirally wound on the laminate, thereby forming a cap layer laminate.
- the laminate for the cap layer is joined to the laminate for the base layer by the adhesiveness of the uncrosslinked rubber, and the two are integrated.
- This strip winding method is disclosed in Japanese Patent Laid-Open No. 2002-160508.
- the second strip When the second strip is wound, the second strip may not be sufficiently bonded to the base layer laminate. Insufficient bonding is likely to occur near the end of the tread. When the bonding is insufficient, air remains between the two laminates. The raw cover including the tread is discarded.
- the end of the tread may be stacked on the carcass. Even between the end portion and the carcass, air may remain due to poor bonding. The raw cover in which this residue has occurred is discarded.
- This tire employs a cap layer that can suppress rolling resistance.
- This cap layer has a low adhesion index. In molding of a raw cover provided with this cap layer, joint failure is particularly likely to occur.
- An object of the present invention is to provide a pneumatic tire that is unlikely to cause poor bonding between members during molding.
- the pneumatic tire according to the present invention is (1) A tread including a base layer and a cap layer that is positioned radially outside the base layer and laminated with the base layer; (2) a pair of sidewalls each extending substantially inward in the radial direction from the end of the tread; (3) a pair of beads each positioned substantially radially inward of the sidewalls; (4) A part of the carcass and (5) the base layer and the cap layer sandwiched between the beads and along the tread and the side wall, and the remaining part is the axis of the side wall.
- a pair of adhesive sheet layers laminated with the carcass is provided on the inner side in the direction.
- the width of the portion of the adhesive sheet layer sandwiched between the base layer and the cap layer is 5 mm or more and 20 mm or less.
- stacked with the carcass of the adhesive sheet layer is 10 mm or more and 20 mm or less.
- the thickness of the adhesive sheet layer is 0.5 mm or more and 2.0 mm or less.
- the ratio between the adhesive strength of the adhesive sheet layer and the adhesive strength of the cap layer is 1.30 or more.
- the loss tangent tan ⁇ in the cap layer is 0.30 or less, and the complex elastic modulus E * is 10.5 or more.
- Loss tangent tan ⁇ and complex elastic modulus E * are as follows: initial strain is 10%, dynamic strain is ⁇ 2%, frequency is 10 Hz, deformation mode is tensile, and temperature is 30 ° C. Measured.
- the base layer and the cap layer are firmly joined by the adhesive sheet layer. Further, in this tire, the tread and the carcass can be firmly joined by the adhesive sheet layer.
- FIG. 1 is a cross-sectional view showing a part of a pneumatic tire according to an embodiment of the present invention.
- FIG. 2 is an enlarged cross-sectional view showing a part of the tire of FIG.
- FIG. 3 is a perspective view showing an adhesive sheet layer of the tire of FIG. 1.
- FIG. 1 shows a pneumatic tire 2.
- the vertical direction is the radial direction of the tire 2
- the horizontal direction is the axial direction of the tire 2
- the direction perpendicular to the paper surface is the circumferential direction of the tire 2.
- an alternate long and short dash line CL represents the equator plane of the tire 2.
- the shape of the tire 2 is symmetrical with respect to the equator plane except for the tread 4 pattern.
- the tire 2 includes a tread 4, a sidewall 6, a clinch portion 8, a bead 10, a carcass 12, a belt 14, a band 16, an edge band 18, an inner liner 20, an insulation 22, a cushion layer 24, a chafer 26, and an adhesive sheet.
- Layer 28 is provided.
- the tire 2 is a tubeless type.
- the tire 2 according to this embodiment is mounted on a passenger car.
- the tread 4 has a shape protruding outward in the radial direction.
- the tread 4 forms a tread surface that contacts the road surface.
- Grooves 30 are carved on the tread surface.
- the groove 30 forms a tread pattern.
- the tread 4 has a base layer 32 and a cap layer 34.
- the cap layer 34 is located on the outer side in the radial direction of the base layer 32.
- the cap layer 34 is laminated on the base layer 32.
- the base layer 32 is made of a crosslinked rubber having excellent adhesiveness.
- a typical base rubber of the base layer 32 is natural rubber.
- the cap layer 34 is made of a crosslinked rubber having excellent wear resistance, heat resistance, and grip properties.
- the sidewall 6 extends from the end of the tread 4 substantially inward in the radial direction. A radially outer end of the sidewall 6 is joined to the tread 4. At the joint portion, the sidewall 6 is located on the outer side in the axial direction of the tread 4.
- the tire 2 has an SOT structure (sidewall over tread structure). The radially inner end of the sidewall 6 is joined to the clinch portion 8.
- the sidewall 6 is made of a crosslinked rubber having excellent cut resistance and light resistance. This sidewall 6 prevents the carcass 12 from being damaged.
- the sidewall 6 includes a rib 36. The rib 36 protrudes outward in the axial direction. The ribs 36 prevent damage to the flange of the rim to which the tire 2 is mounted.
- the clinch portion 8 is located substantially inside the sidewall 6 in the radial direction.
- the clinch portion 8 is located outside the bead 10 and the carcass 12 in the axial direction.
- the clinching portion 8 is made of a crosslinked rubber having excellent wear resistance.
- the clinch portion 8 abuts on the flange of the rim.
- the bead 10 is located inside the sidewall 6 in the radial direction.
- the bead 10 includes a core 38 and an apex 40 that extends radially outward from the core 38.
- the core 38 is ring-shaped and includes a wound non-stretchable wire.
- a typical material for the wire is steel.
- the apex 40 is tapered outward in the radial direction.
- the apex 40 is made of a highly hard crosslinked rubber.
- the carcass 12 includes a first carcass ply 42 and a second carcass ply 44.
- the first carcass ply 42 and the second carcass ply 44 are bridged between the beads 10 on both sides, and extend along the tread 4 and the sidewall 6.
- the first carcass ply 42 is folded around the core 38 from the inner side to the outer side in the axial direction. Due to this folding, a main portion 46 and a folding portion 48 are formed in the first carcass ply 42.
- the second carcass ply 44 is folded around the core 38 from the inner side to the outer side in the axial direction. Due to this folding, a main portion 50 and a folding portion 52 are formed in the second carcass ply 44.
- the end of the folded portion of the first carcass ply 42 is located outside the end of the folded portion of the second carcass ply 44 in the radial direction.
- each of the carcass plies 42 and 44 includes a large number of cords arranged in parallel and a topping rubber.
- the absolute value of the angle formed by each cord with respect to the equator plane is 45 ° to 90 °, and further 75 ° to 90 °.
- the carcass 12 has a radial structure.
- the cord is made of organic fiber. Examples of preferable organic fibers include polyester fibers, nylon fibers, rayon fibers, polyethylene naphthalate fibers, and aramid fibers.
- the carcass 12 may be formed from a single carcass ply.
- the belt 14 is located outside the carcass 12 in the radial direction.
- the belt 14 is laminated with the carcass 12.
- the belt 14 reinforces the carcass 12.
- the belt 14 includes an inner layer 54 and an outer layer 56.
- the width of the inner layer 54 is slightly larger than the width of the outer layer 56 in the axial direction.
- each of the inner layer 54 and the outer layer 56 includes a plurality of cords arranged in parallel and a topping rubber. Each cord is inclined with respect to the equator plane.
- the absolute value of the tilt angle is usually 10 ° to 35 °.
- the inclination direction of the cord of the inner layer 54 with respect to the equator plane is opposite to the inclination direction of the cord of the outer layer 56 with respect to the equator plane.
- a preferred material for the cord is steel.
- An organic fiber may be used for the cord.
- the axial width of the belt 14 is preferably 0.7 times or more the maximum width of the tire 2.
- the belt 14 may include three or more layers.
- the band 16 is located outside the belt 14 in the radial direction. In the axial direction, the width of the band 16 is larger than the width of the belt 14.
- the band 16 is composed of a cord and a topping rubber.
- the cord is wound in a spiral.
- the band 16 has a so-called jointless structure.
- the cord extends substantially in the circumferential direction.
- the angle of the cord with respect to the circumferential direction is 5 ° or less, and further 2 ° or less. Since the belt 14 is restrained by this cord, lifting of the belt 14 is suppressed.
- the cord is made of organic fiber. Examples of preferable organic fibers include nylon fibers, polyester fibers, rayon fibers, polyethylene naphthalate fibers, and aramid fibers.
- the belt 14 and the band 16 constitute a reinforcing layer.
- the reinforcing layer may be formed only from the belt 14.
- a reinforcing layer may be formed only from the band 16.
- the edge band 18 is located on the outer side in the radial direction of the belt 14 and in the vicinity of the end of the belt 14.
- the edge band 18 is made of a cord and a topping rubber.
- the cord is wound in a spiral.
- the band 16 has a so-called jointless structure.
- the cord extends substantially in the circumferential direction.
- the angle of the cord with respect to the circumferential direction is 5 ° or less, and further 2 ° or less. Since the end of the belt 14 is restrained by this cord, the lifting of the belt 14 is suppressed.
- the cord is made of organic fiber. Examples of preferable organic fibers include nylon fibers, polyester fibers, rayon fibers, polyethylene naphthalate fibers, and aramid fibers.
- the inner liner 20 is joined to the inner peripheral surface of the carcass 12 in the vicinity of the equator plane CL.
- the inner liner 20 is made of a crosslinked rubber.
- the inner liner 20 is made of rubber having excellent air shielding properties.
- a typical base rubber of the inner liner 20 is butyl rubber or halogenated butyl rubber.
- the inner liner 20 holds the internal pressure of the tire 2.
- the insulation 22 is located inside the sidewall 6 in the axial direction.
- the insulation 22 is sandwiched between the carcass 12 and the inner liner 20.
- the insulation 22 is made of a crosslinked rubber having excellent adhesiveness.
- the insulation 22 is firmly joined to the carcass 12 and is also firmly joined to the inner liner 20.
- the insulation 22 prevents the inner liner 20 from being peeled from the carcass 12 on the inner side in the axial direction of the sidewall 6.
- the cushion layer 24 is laminated with the carcass 12 in the vicinity of the end of the belt 14.
- the cushion layer 24 is made of a soft crosslinked rubber.
- the cushion layer 24 absorbs stress at the end of the belt 14.
- the cushion layer 24 suppresses the lifting of the belt 14.
- the chafer 26 is located in the vicinity of the bead 10. When the tire 2 is incorporated into the rim, the chafer 26 comes into contact with the rim. By this contact, the vicinity of the bead 10 is protected.
- the chafer 26 is integral with the clinch portion 8. Therefore, the material of the chafer 26 is the same as that of the clinch portion 8.
- the chafer 26 may be made of cloth and rubber impregnated in the cloth.
- a part of the pressure-sensitive adhesive sheet layer 28 is sandwiched between the base layer 32 and the cap layer 34.
- this portion is referred to as a clamping portion 58.
- Portions of the adhesive sheet layer 28 other than the sandwiching portion 58 are laminated with the carcass 12.
- this portion is referred to as a protruding portion 60.
- the pressure-sensitive adhesive sheet layer 28 is obtained by crosslinking a rubber composition.
- This rubber composition (before crosslinking) is excellent in adhesiveness. Since this rubber composition is excellent in adhesiveness, the base layer 32 and the cap layer 34 are sufficiently bonded via the sandwiching portion 58 when the raw cover is molded. The sandwiching portion 58 suppresses remaining of air between the base layer 32 and the cap layer 34.
- the tread 4 is sufficiently joined to the carcass 12 by the protruding portion 60.
- the protruding portion 60 suppresses the remaining of air between the tread 4 and the carcass 12. In the manufacture of the tire 2, the low cover defect rate is low.
- the loss tangent tan ⁇ of the cap layer 34 is 0.30 or less and the complex elastic modulus E * is 10.5 or more, the remaining of air is suppressed.
- the cap layer 34 having a loss tangent tan ⁇ of 0.30 or less and a complex elastic modulus E * of 10.5 or more can contribute to low fuel consumption of the tire 2.
- the loss tangent tan ⁇ and the complex elastic modulus E * are measured in accordance with the rules of “JIS K 6394”. The measurement conditions are as follows. Viscoelastic spectrometer: "VESF-3" from Iwamoto Seisakusho Initial strain: 10% Dynamic strain: ⁇ 2% Frequency: 10Hz Deformation mode: Tensile Measurement temperature: 30 ° C
- the adhesiveness of the adhesive sheet layer 28 can be enhanced.
- the amount of the tackifier is preferably 1 part by mass or more and particularly preferably 5 parts by mass or more with respect to 100 parts by mass of the base rubber. This amount is preferably 10 parts by mass or less.
- Natural rubber 40 parts by weight Polybutadiene: 60 parts by weight Carbon black: 50 parts by weight Tackifier: 5 parts by weight Mineral oil: 10 parts by weight Anti-aging agent: 3 parts by weight Wax: 2 parts by weight Stearic acid: 3 parts by weight Zinc oxide : 3 parts by mass Sulfur: 2 parts by mass Vulcanization accelerator NS: 1.5 parts by mass
- the ratio of the adhesive strength of the adhesive sheet layer 28 to the adhesive strength of the cap layer 34 is preferably 1.30 or more, more preferably 1.50 or more, and particularly preferably 1.75 or more. This ratio is preferably 2.5 or less.
- the adhesive strength is measured by the product name “PICMA Tack Test” of Toyo Seiki Seisakusho.
- the measurement conditions are as follows. Ascent speed: 30mm / min Measurement time: 2.5 seconds Temperature: 23 ° C Humidity: 55%
- the Mooney viscosity (ML 1 + 4 (100 ° C.)) of the rubber composition of the pressure-sensitive adhesive sheet layer 28 is preferably 45 or more. With the rubber composition having a Mooney viscosity of 45 or more, remaining of air can be suppressed. In this respect, the Mooney viscosity is particularly preferably 60 or more. The Mooney viscosity is preferably 80 or less.
- the ratio of the adhesive strength of the base layer 32 and the adhesive strength of the cap layer 34 is preferably 1.10 or more and 1.80 or less.
- the ratio between the adhesive strength of the topping rubber of the carcass 12 and the adhesive strength of the cap layer 34 is preferably 1.10 or more and 1.65 or less.
- the width of the clamping portion 58 is preferably 5 mm or greater and 20 mm or less. Due to the sandwiching portion 58 having the width W1 of 5 mm or more, remaining of air between the base layer 32 and the cap layer 34 is suppressed. In this respect, the width W1 is particularly preferably 10 mm or more.
- the tire 2 having the sandwiching portion 58 having a width W1 of 20 mm or less is lightweight and can be obtained at low cost. Furthermore, in the tire 2 having the sandwiching portion 58 having the width W1 of 20 mm or less, a good contact shape can be obtained. A good grounding shape contributes to wear resistance. In this respect, the width W1 is particularly preferably 15 mm or less.
- the width of the protruding portion 60 is preferably 10 mm or greater and 20 mm or less.
- the protrusion 60 having a width W2 of 10 mm or more suppresses air remaining between the tread 4 and the carcass 12.
- the width W2 is particularly preferably equal to or greater than 13 mm.
- the tire 2 having the protruding portion 60 having a width W2 of 20 mm or less is measured and can be obtained at a low cost.
- the tire 2 having the protruding portion 60 whose width W2 is 20 mm or less is excellent in durability. From these viewpoints, the width W2 is particularly preferably 17 mm or less.
- FIG. 3 shows the pressure-sensitive adhesive sheet layer 28 before being subjected to the molding process.
- the pressure-sensitive adhesive sheet layer 28 is wound in the circumferential direction on the end of the base layer 32. The number of turns is 1.
- the width W of the pressure-sensitive adhesive sheet layer 28 is preferably 15 mm or more and 40 mm or less. Air remaining is suppressed by the pressure-sensitive adhesive sheet layer 28 having a width of 15 mm or more. In this respect, the width W is particularly preferably 20 mm or more. The tire 2 having the pressure-sensitive adhesive sheet layer 28 having a width W of 40 mm or less can be obtained at low cost. In this respect, the width W is particularly preferably equal to or less than 35 mm.
- the thickness T of the pressure-sensitive adhesive sheet layer 28 is preferably 0.5 mm or more and 2.0 mm or less. Air remaining is suppressed by the adhesive sheet layer 28 having a thickness T of 0.5 mm or more. In this respect, the thickness T is particularly preferably equal to or greater than 1.0 mm. The tire 2 having the pressure-sensitive adhesive sheet layer 28 having a thickness T of 2.0 mm or less can be obtained at low cost. In this respect, the thickness T is particularly preferably equal to or less than 1.5 mm.
- the inner layer 54 and the outer layer 56 of the belt 14 are wound on the drum of the molding machine.
- a band 16 is wound on the belt 14.
- a ribbon-like rubber strip is supplied to the drum, and the base layer 32 is formed by spirally winding and laminating.
- An adhesive sheet layer 28 is wound in the vicinity of the end of the base layer 32.
- a part of the pressure-sensitive adhesive sheet layer 28 is wound on the base layer 32, and the remaining part is wound on the drum.
- Another rubber strip is supplied to the molding machine, and the cap layer 34 is molded by being spirally wound and laminated.
- a part of the adhesive sheet layer 28 is sandwiched between the base layer 32 and the cap layer 34.
- the belt 14, the band 16, the tread 4, and the adhesive sheet layer 28 are joined to the carcass 12 formed at another stage. A portion of the adhesive sheet layer 28 that is not sandwiched between the base layer 32 and the cap layer 34 is laminated and bonded to the carcass 12.
- the dimension and angle of each member of the tire are measured in a state where the tire is incorporated in a regular rim and the tire is filled with air so as to have a regular internal pressure. During the measurement, no load is applied to the tire.
- the normal rim means a rim defined in a standard on which a tire depends.
- “Standard rim” in the JATMA standard, “Design Rim” in the TRA standard, and “Measuring Rim” in the ETRTO standard are regular rims.
- the normal internal pressure means an internal pressure defined in a standard on which the tire depends.
- Maximum air pressure in JATMA standard “Maximum value” published in “TIRE LOAD LIMITS AT VARIOUS COLD INFLATION PRESSURES” in TRA standard, and “INFLATION PRESSURE” in ETRTO standard are normal internal pressures. In the case of passenger car tires, the dimensions and angles are measured with an internal pressure of 180 kPa.
- Example 1 The pneumatic tire shown in FIG. 1 was manufactured.
- the size of the tire was “235 / 45R18 94Y”.
- This tire includes an adhesive sheet layer.
- the adhesive strength index of this adhesive sheet layer was 140 when the adhesive strength of the cap layer of Comparative Example 2 described later was 100.
- the pressure-sensitive adhesive sheet layer had a loss tangent tan ⁇ of 0.30 and a complex elastic modulus E * of 10.5.
- the pressure sensitive adhesive sheet layer had a thickness T of 0.5 mm.
- the width W1 of the clamping part of this pressure-sensitive adhesive sheet layer was 5 mm, and the width W2 of the protruding part was 10 mm.
- Comparative Example 1 A tire of Comparative Example 1 was obtained in the same manner as Example 1 except that the adhesive sheet layer was not provided.
- Example 2-4 A tire of Example 2-4 was obtained in the same manner as in Example 1 except that the thickness T of the pressure-sensitive adhesive sheet layer was changed as shown in Table 1 below.
- Example 5-9 A tire of Example 5-9 was obtained in the same manner as Example 1 except that the widths W1 and W2 were as shown in Table 2 below.
- Example 10 A tire of Example 10 was obtained in the same manner as Example 1, except that the thickness T of the adhesive sheet layer and the widths W1 and W2 were as shown in Table 3 below.
- Example 11-12 Tires of Examples 11-12 were obtained in the same manner as in Example 1 except that the composition of the adhesive sheet layer was changed and the adhesive strength was changed as shown in Table 3 below.
- Example 13 A tire of Example 13 was obtained in the same manner as in Example 1 except that the composition of the cap layer was changed and the complex elastic modulus E * was changed as shown in Table 3 below.
- Comparative Example 2 The tire of Comparative Example 2 was obtained in the same manner as in Example 1 except that the composition of the cap layer was changed, the loss tangent tan ⁇ was as shown in Table 3 below, and the adhesive sheet layer was not provided.
- a tire was incorporated in a regular rim, and the tire was filled with air so that the internal pressure was 230 kPa.
- a load of 4.2 kN was applied to the tire, and the ground contact shape was measured with a static testing machine. The measurement results of each tire were rated based on the following criteria.
- a tire was incorporated into a regular rim, and the tire was filled with air to adjust the internal pressure to 230 kPa.
- This tire was mounted on a drum-type running test machine, and a vertical load of 4.14 kN was applied to the tire.
- This tire was run on a drum having a radius of 1.7 m at a speed of 80 km / h. The distance traveled until the tire broke was measured.
- Each tire was rated based on the measurement results. The results are shown in Table 1-3 below.
- Rolling resistance The tire was incorporated into a regular rim, and rolling resistance was measured under the following measurement conditions using a rolling resistance tester. Internal pressure: 230 kPa Load: 4.41kN Speed: 80km / h The measurement results of each tire were rated based on the following criteria. A: Rolling resistance is 110 or less. B: The rolling resistance is more than 110 and 114 or less. C: The rolling resistance exceeds 114. The results are shown in Table 1-3 below.
- Steping stability A tire was incorporated in a regular rim, and the tire was filled with air so that the internal pressure was 230 kPa. This tire was mounted on a passenger car having a displacement of 4300 cc. The driver was driven on the racing circuit. This driver was rated for handling stability based on criteria. A: Steering stability is good. B: Steering stability is slightly poor. C: Steering stability is poor. The results are shown in Table 1-3 below.
- the pneumatic tire according to the present invention can be mounted on various vehicles.
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Abstract
Description
(1)ベース層と、このベース層の半径方向外側に位置しておりこのベース層と積層されたキャップ層とを備えたトレッド、
(2)それぞれが、トレッドの端から半径方向略内向きに延びる一対のサイドウォール、
(3)それぞれが、サイドウォールよりも半径方向略内側に位置する一対のビード、
(4)トレッド及びサイドウォールに沿っており、両ビードの間に架け渡されたカーカス及び
(5)ベース層とキャップ層とにその一部が挟まれており、残余の部分がサイドウォールの軸方向内側においてカーカスと積層された一対の粘着シート層
を備える。
粘弾性スペクトロメーター:岩本製作所の「VESF-3」
初期歪み:10%
動歪み:±2%
周波数:10Hz
変形モード:引張
測定温度:30℃
天然ゴム:40質量部
ポリブタジエン:60質量部
カーボンブラック:50質量部
粘着付与剤:5質量部
鉱物油:10質量部
老化防止剤:3質量部
ワックス:2質量部
ステアリン酸:3質量部
酸化亜鉛:3質量部
硫黄:2質量部
加硫促進剤NS:1.5質量部
上昇スピード:30mm/min
測定時間:2.5秒
温度:23℃
湿度:55%
図1に示された空気入りタイヤを製作した。このタイヤのサイズは、「235/45R18 94Y」であった。このタイヤは、粘着シート層を備えている。この粘着シート層の粘着力の指数は、後述される比較例2のキャップ層の粘着力が100とされたとき、140であった。この粘着シート層の、損失正接tanδは0.30であり、複素弾性率E*は10.5であった。この粘着シート層の厚みTは、0.5mmであった。この粘着シート層の、挟持部の幅W1は5mmであり、はみ出し部の幅W2は10mmであった。
粘着シート層を設けなかった他は実施例1と同様にして、比較例1のタイヤを得た。
粘着シート層の厚みTを下記の表1に示される通りとした他は実施例1と同様にして、実施例2-4のタイヤを得た。
幅W1及びW2を下記の表2に示される通りとした他は実施例1と同様にして、実施例5-9のタイヤを得た。
粘着シート層の厚みT並び幅W1及びW2を下記の表3に示される通りとした他は実施例1と同様にして、実施例10のタイヤを得た。
粘着シート層の組成を変更し、その粘着力を下記の表3に示される通りとした他は実施例1と同様にして、実施例11-12のタイヤを得た。
キャップ層の組成を変更し、その複素弾性率E*を下記の表3に示される通りとした他は実施例1と同様にして、実施例13のタイヤを得た。
キャップ層の組成を変更し、その損失正接tanδを下記の表3に示される通りとし、かつ粘着シート層を設けなかった他は実施例1と同様にして、比較例2のタイヤを得た。
100本のローカバーを製作した。これらのローカバーを目視で観察し、トレッドの端の近傍にエアーが残存しているものを不良とした。各タイヤの不良率を算出し、下記の基準に基づいて格付けした。
A:不良率が、1%以下である。
B:不良率が、1%を超えて5%以下である。
C:不良率が、5%を超えている。
この結果が、下記の表1-3に示されている。
タイヤを正規リムに組み込み、このタイヤに内圧が230kPaとなるように空気を充填した。このタイヤに4.2kNの荷重を負荷し、静的試験機にて接地形状を測定した。各タイヤの測定結果を、下記の基準に基づいて格付けした。
A:接地形状が、良好である。
B:接地形状が、やや不良である。
C:接地形状が、不良である。
この結果が、下記の表1-3に示されている。
タイヤを正規リムに組み込み、このタイヤに空気を充填して内圧を230kPaとした。このタイヤをドラム式走行試験機に装着し、4.14kNの縦荷重をタイヤに負荷した。このタイヤを、80km/hの速度で、半径が1.7mであるドラムの上を走行させた。タイヤが破壊するまでの走行距離を、測定した。測定結果に基づき、各タイヤを格付けした。この結果が、下記の表1-3に示されている。
タイヤを正規リムに組み込み、転がり抵抗試験機を用いて下記の測定条件で転がり抵抗を測定した。
内圧:230kPa
荷重:4.41kN
速度:80km/h
各タイヤの測定結果を、下記の基準に基づいて格付けした。
A:転がり抵抗が、110以下である。
B:転がり抵抗が、110を超えて114以下である。
C:転がり抵抗が、114を超えている。
この結果が、下記の表1-3に示されている。
タイヤを正規リムに組み込み、このタイヤに内圧が230kPaとなるように空気を充填した。このタイヤを、排気量が4300ccである乗用車に装着した。ドライバーに、この乗用車をレーシングサーキットで運転させた。このドライバーに、基準に基づいて操縦安定性及を格付けさせた。
A:操縦安定性が、良好である。
B:操縦安定性が、やや不良である。
C:操縦安定性が、不良である。
この結果が、下記の表1-3に示されている。
4・・・トレッド
6・・・サイドウォール
8・・・クリンチ部
10・・・ビード
12・・・カーカス
14・・・ベルト
16・・・バンド
18・・・エッジバンド
20・・・インナーライナー
22・・・インスレーション
24・・・クッション層
26・・・チェーファー
28・・・粘着シート層
32・・・ベース層
34・・・キャップ層
58・・・挟持部
60・・・はみ出し部
Claims (6)
- ベース層と、このベース層の半径方向外側に位置しておりこのベース層と積層されたキャップ層とを備えたトレッド、
それぞれが上記トレッドの端から半径方向略内向きに延びる一対のサイドウォール、
それぞれが上記サイドウォールよりも半径方向略内側に位置する一対のビード、
上記トレッド及び上記サイドウォールに沿っており、両ビードの間に架け渡されたカーカス、
及び
上記ベース層と上記キャップ層とにその一部が挟まれており、残余の部分が上記サイドウォールの軸方向内側において上記カーカスと積層された一対の粘着シート層
を備えた空気入りタイヤ。 - 上記粘着シート層の、上記ベース層と上記キャップ層とに挟まれた部分の幅が5mm以上20mm以下である請求項1に記載のタイヤ。
- 上記粘着シート層の、上記カーカスと積層された部分の幅が10mm以上20mm以下である請求項1に記載のタイヤ。
- 上記粘着シート層の厚みが0.5mm以上2.0mm以下である請求項1に記載のタイヤ。
- 上記粘着シート層の粘着力と上記キャップ層の粘着力との比が1.30以上である請求項1に記載のタイヤ。
- 初期歪みが10%であり、動歪みが±2%であり、周波数が10Hzであり、変形モードが引張であり、温度が30℃である条件下で測定された、上記キャップ層における、損失正接tanδが0.30以下であり、複素弾性率E*が10.5以上である請求項1に記載のタイヤ。
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EP12869148.2A EP2818332B1 (en) | 2012-02-21 | 2012-10-25 | Pneumatic tire |
US14/375,033 US10239351B2 (en) | 2012-02-21 | 2012-10-25 | Pneumatic tire |
KR1020147026249A KR101585822B1 (ko) | 2012-02-21 | 2012-10-25 | 공기 타이어 |
CN201280070101.5A CN104114379B (zh) | 2012-02-21 | 2012-10-25 | 充气轮胎 |
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JP2012034817A JP5363600B2 (ja) | 2012-02-21 | 2012-02-21 | 空気入りタイヤ |
JP2012-034817 | 2012-02-21 |
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WO2013125095A1 true WO2013125095A1 (ja) | 2013-08-29 |
Family
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PCT/JP2012/077530 WO2013125095A1 (ja) | 2012-02-21 | 2012-10-25 | 空気入りタイヤ |
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US (1) | US10239351B2 (ja) |
EP (1) | EP2818332B1 (ja) |
JP (1) | JP5363600B2 (ja) |
KR (1) | KR101585822B1 (ja) |
CN (1) | CN104114379B (ja) |
WO (1) | WO2013125095A1 (ja) |
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DE102015213403A1 (de) | 2015-07-16 | 2017-01-19 | Continental Reifen Deutschland Gmbh | Fahrzeugluftreifen |
JP6994297B2 (ja) * | 2016-12-19 | 2022-02-04 | Toyo Tire株式会社 | 空気入りタイヤ |
US11260017B2 (en) | 2017-05-31 | 2022-03-01 | L'oréal | Volumizing and lengthening eyelash coating compositions |
WO2018222794A1 (en) * | 2017-05-31 | 2018-12-06 | L'oreal | Volumizing and lengthening compositions and applicators therefor |
CN117048248A (zh) * | 2019-06-26 | 2023-11-14 | 住友橡胶工业株式会社 | 充气轮胎 |
JP7278899B2 (ja) * | 2019-07-31 | 2023-05-22 | Toyo Tire株式会社 | 空気入りタイヤ |
JP7264008B2 (ja) * | 2019-10-23 | 2023-04-25 | 住友ゴム工業株式会社 | タイヤ |
KR102560544B1 (ko) * | 2021-06-15 | 2023-07-28 | 넥센타이어 주식회사 | 주행성능이 향상된 공기입 타이어 |
KR102602875B1 (ko) * | 2021-07-06 | 2023-11-16 | 넥센타이어 주식회사 | 벨트 간 분리방지형 타이어 |
JP2023031458A (ja) * | 2021-08-25 | 2023-03-09 | 住友ゴム工業株式会社 | タイヤ |
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- 2012-02-21 JP JP2012034817A patent/JP5363600B2/ja active Active
- 2012-10-25 CN CN201280070101.5A patent/CN104114379B/zh active Active
- 2012-10-25 WO PCT/JP2012/077530 patent/WO2013125095A1/ja active Application Filing
- 2012-10-25 EP EP12869148.2A patent/EP2818332B1/en active Active
- 2012-10-25 KR KR1020147026249A patent/KR101585822B1/ko active IP Right Grant
- 2012-10-25 US US14/375,033 patent/US10239351B2/en active Active
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JPH0752609A (ja) * | 1993-08-11 | 1995-02-28 | Bridgestone Corp | 高内圧重荷重用空気入りラジアルタイヤ |
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Also Published As
Publication number | Publication date |
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EP2818332A1 (en) | 2014-12-31 |
JP2013169882A (ja) | 2013-09-02 |
US20150007916A1 (en) | 2015-01-08 |
CN104114379A (zh) | 2014-10-22 |
EP2818332A4 (en) | 2015-11-18 |
KR20140132372A (ko) | 2014-11-17 |
EP2818332B1 (en) | 2017-01-18 |
KR101585822B1 (ko) | 2016-01-22 |
US10239351B2 (en) | 2019-03-26 |
JP5363600B2 (ja) | 2013-12-11 |
CN104114379B (zh) | 2016-09-28 |
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