WO2011129313A1 - 発光装置の製造方法 - Google Patents
発光装置の製造方法 Download PDFInfo
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- WO2011129313A1 WO2011129313A1 PCT/JP2011/059042 JP2011059042W WO2011129313A1 WO 2011129313 A1 WO2011129313 A1 WO 2011129313A1 JP 2011059042 W JP2011059042 W JP 2011059042W WO 2011129313 A1 WO2011129313 A1 WO 2011129313A1
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/44—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the coatings, e.g. passivation layer or anti-reflective coating
- H01L33/46—Reflective coating, e.g. dielectric Bragg reflector
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/62—Arrangements for conducting electric current to or from the semiconductor body, e.g. lead-frames, wire-bonds or solder balls
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L24/28—Structure, shape, material or disposition of the layer connectors prior to the connecting process
- H01L24/29—Structure, shape, material or disposition of the layer connectors prior to the connecting process of an individual layer connector
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- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/74—Apparatus for manufacturing arrangements for connecting or disconnecting semiconductor or solid-state bodies
- H01L24/75—Apparatus for connecting with bump connectors or layer connectors
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- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L24/83—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
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- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/64—Heat extraction or cooling elements
- H01L33/641—Heat extraction or cooling elements characterized by the materials
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/15—Structure, shape, material or disposition of the bump connectors after the connecting process
- H01L2224/16—Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
- H01L2224/161—Disposition
- H01L2224/16151—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/16221—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/16225—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L2224/28—Structure, shape, material or disposition of the layer connectors prior to the connecting process
- H01L2224/29—Structure, shape, material or disposition of the layer connectors prior to the connecting process of an individual layer connector
- H01L2224/29001—Core members of the layer connector
- H01L2224/29099—Material
- H01L2224/29198—Material with a principal constituent of the material being a combination of two or more materials in the form of a matrix with a filler, i.e. being a hybrid material, e.g. segmented structures, foams
- H01L2224/29298—Fillers
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L2224/31—Structure, shape, material or disposition of the layer connectors after the connecting process
- H01L2224/32—Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
- H01L2224/321—Disposition
- H01L2224/32151—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/32221—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/32225—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73201—Location after the connecting process on the same surface
- H01L2224/73203—Bump and layer connectors
- H01L2224/73204—Bump and layer connectors the bump connector being embedded into the layer connector
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/74—Apparatus for manufacturing arrangements for connecting or disconnecting semiconductor or solid-state bodies and for methods related thereto
- H01L2224/75—Apparatus for connecting with bump connectors or layer connectors
- H01L2224/7525—Means for applying energy, e.g. heating means
- H01L2224/753—Means for applying energy, e.g. heating means by means of pressure
- H01L2224/75301—Bonding head
- H01L2224/75314—Auxiliary members on the pressing surface
- H01L2224/75315—Elastomer inlay
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/74—Apparatus for manufacturing arrangements for connecting or disconnecting semiconductor or solid-state bodies and for methods related thereto
- H01L2224/75—Apparatus for connecting with bump connectors or layer connectors
- H01L2224/7525—Means for applying energy, e.g. heating means
- H01L2224/753—Means for applying energy, e.g. heating means by means of pressure
- H01L2224/75301—Bonding head
- H01L2224/75314—Auxiliary members on the pressing surface
- H01L2224/75315—Elastomer inlay
- H01L2224/75316—Elastomer inlay with retaining mechanisms
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L2224/83—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
- H01L2224/831—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector the layer connector being supplied to the parts to be connected in the bonding apparatus
- H01L2224/83101—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector the layer connector being supplied to the parts to be connected in the bonding apparatus as prepeg comprising a layer connector, e.g. provided in an insulating plate member
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/06—Polymers
- H01L2924/078—Adhesive characteristics other than chemical
- H01L2924/0781—Adhesive characteristics other than chemical being an ohmic electrical conductor
- H01L2924/07811—Extrinsic, i.e. with electrical conductive fillers
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/10—Details of semiconductor or other solid state devices to be connected
- H01L2924/11—Device type
- H01L2924/12—Passive devices, e.g. 2 terminal devices
- H01L2924/1204—Optical Diode
- H01L2924/12041—LED
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
- H01L33/54—Encapsulations having a particular shape
Definitions
- the present invention relates to a method of manufacturing a light emitting device in which a light emitting element such as an LED element is anisotropically conductively connected to a wiring board.
- the connection strength by the gold wire is not sufficient, and the coefficient of thermal expansion between the sealing resin and the sealing resin is not sufficient.
- the connection reliability was low due to the large difference.
- the light extraction efficiency (light emission efficiency) is lowered due to light absorption of the gold wire, and a problem that the mounting tact time is increased because the curing speed of the die bond used for fixing the LED element to the wiring board is slow. .
- An object of the present invention is to solve the above-described problems of the prior art, and light-emitting elements such as light-emitting diodes (LEDs) are flip-chip mounted on a wiring board using an anisotropic conductive adhesive to emit light.
- LEDs light-emitting diodes
- the present inventors can prevent the light emission efficiency from being lowered. It has been found that the luminous efficiency of the light emitting device can be prevented from being lowered by blending the reflective insulating particles.
- the present inventors generally change the material of the heat-pressing head of the bonder from metal to elastomer so that the light-emitting element is pressed so as not to be cracked or chipped without impairing connection reliability.
- the light-reflective insulating particles as described above are blended with the anisotropic conductive adhesive, it is found that the light-emitting element may be cracked or chipped.
- an elastomer having a specific rubber hardness may be used as the elastomer to be used, and the present invention has been completed.
- the present invention provides the following steps (A) and (B) in a method for producing a light emitting device in which a light emitting element is anisotropically conductively connected to a wiring board: Step (A) Disposing a light-reflective anisotropic conductive adhesive containing a thermosetting resin composition, conductive particles, and light-reflective insulating particles between the light-emitting element and the wiring board to which the light-emitting element is to be connected And step (B) Provided is a manufacturing method including a step of performing anisotropic conductive connection by heating and pressing a light emitting element to a wiring board with an elastomer head having a Shore A rubber hardness (JIS K6253) of 40 to less than 90 on a pressing surface. .
- This production method further includes the following step (C): Process (C) You may have the process of sealing the light emitting element by which anisotropic conductive connection was carried out on the wiring board using transparent resin.
- the present invention also provides a light emitting device manufactured by the above manufacturing method.
- the light-reflective anisotropic conductive adhesive used in the method for manufacturing a light-emitting device of the present invention contains light-reflective insulating particles, it can reflect light emitted from the light-emitting element. Therefore, the method for manufacturing a light emitting device of the present invention can anisotropically connect the light emitting element to the wiring board without reducing the light emission efficiency of the light emitting element.
- the heating and pressing head used in the method for manufacturing a light emitting device of the present invention is an elastomer head set to an optimum hardness, the light emitting element is uniformly pressurized and heated to the wiring board with an optimum pressure. Can do. Therefore, in the method for manufacturing a light emitting device of the present invention, a crack or a chip occurs in the light emitting element when the anisotropic conductive connection is performed using the light reflective anisotropic conductive adhesive containing the light reflective insulating particles. This can be prevented.
- the present invention is a method of manufacturing a light emitting device in which a light emitting element is anisotropically conductively connected to a wiring board, and a thermosetting resin composition is provided between the light emitting element and the wiring board to which the light emitting element is to be connected.
- the method may include a step (C) of sealing the light emitting element that is anisotropically conductively connected on the wiring board with a transparent resin.
- bumps may be formed on either or both of these electrodes 1a and 2a by a known technique for improving connection reliability.
- a light emitting element similar to that used in a conventional light emitting device can be used.
- the wiring board 2 used in the present invention a wiring board similar to that used in the conventional light emitting device can be used.
- a silicon semiconductor substrate, a glass wiring board, a ceramic wiring board, or the like is used. be able to.
- a conventionally well-known structure can be employ
- the light-reflective anisotropic conductive adhesive 3 used in the step (A) not only contributes to the anisotropic conductive connection between the light-emitting element 1 and the wiring board 2 but also reflects the light emitted from the light-emitting element 1. It contributes to the improvement of luminous efficiency, and contains the thermosetting resin composition 3a, the conductive particles 3b and the light-reflective insulating particles 3c dispersed therein.
- the light-reflective insulating particle 3c reflects light incident on the anisotropic conductive adhesive to the outside and imparts light reflectivity to the anisotropic conductive adhesive.
- the particles having light reflectivity include metal particles, particles coated with metal particles, inorganic particles such as metal oxides, metal nitrides, metal sulfides, and the like that are gray to white under natural light, resin
- corrugation on the surface are contained irrespective of the material of particle
- the light-reflective insulating particles that can be used in the present invention do not include metal particles because they are required to exhibit insulating properties.
- light-reflective insulating particles 3c include silicon oxide (SiO 2 ), titanium oxide (TiO 2 ), boron nitride (BN), zinc oxide (ZnO), and aluminum oxide (Al 2 O 3 ). , Barium titanate, strontium titanate, zinc sulfide, lead white, barium sulfate, magnesium oxide, zinc sulfide, calcium carbonate, aluminum hydroxide, mica, viscosity mineral and the like. These light-reflective insulating particles 3c can be used in combination of two or more.
- the refractive index of the thermosetting resin composition 3a used by the refractive index thereof can be preferably used, specifically, titanium oxide (TiO 2 ), boron nitride (BN), zinc oxide (ZnO), aluminum oxide (Al 2 O 3 ) and the like can be preferably used, Titanium oxide (TiO 2 ) can be preferably used.
- the shape of the light-reflective insulating particles 3c may be spherical, scaly, indeterminate, acicular, etc. In consideration of the reflection efficiency, spherical and scaly are preferable. Further, the average particle diameter is the Mie region where the scattering efficiency is highest when the particle diameter is 1 ⁇ 2 of the incident wavelength, the incident light to the particle is reflected without loss, and the visible light wavelength is 380 to In consideration of 780 nm, the thickness is preferably 150 nm to 500 nm, more preferably 190 to 390 nm. In this case, it is preferable to determine the particle size according to the emission wavelength of the light emitting element.
- the emission wavelength is distributed in the range of 400 to 550 nm, so that the preferable average particle diameter is 200 to 275 nm.
- the particle diameter in the case of scale-like particles is preferably based on the major axis.
- the “average” particle size means an average particle size measured with a laser diffraction particle size distribution analyzer (for example, SALD-2000J, manufactured by Shimadzu Corporation).
- the inorganic particles described above may be used as light-reflective insulating particles, but resin-coated metal particles obtained by coating the surface of scale-like or spherical metal particles with a transparent insulating resin are light-reflective insulating. It may be used as particles.
- the metal particles include nickel, silver, and aluminum.
- the shape of the particles include an amorphous shape, a spherical shape, a scaly shape, and a needle shape. Among these, a spherical shape is preferable from the viewpoint of the light diffusion effect, and a scaly shape is preferable from the viewpoint of the total reflection effect. Particularly preferred are scaly silver particles in terms of light reflectance. Before these metal particles are coated with an insulating resin, it is preferable that a ⁇ -glycidoxy group, a vinyl group, or the like is previously introduced to the metal surface with a silane coupling agent.
- the average particle diameter is preferably 0.1 to 30 ⁇ m, more preferably 0.2 to 10 ⁇ m.
- the average major axis is preferably 0.1 to 100 ⁇ m, more preferably 1 to 50 ⁇ m, and the average thickness is preferably 0.01 to 10 ⁇ m, more preferably 0.1 to 5 ⁇ m.
- the size of the photoreactive particles is the size including the insulating coating when the insulating coating is applied.
- a cured product of acrylic resin can be preferably used.
- a preferable example is a resin obtained by radical copolymerization of methyl methacrylate and 2-hydroxyethyl methacrylate in the presence of a radical initiator such as an organic peroxide such as benzoyl peroxide.
- a radical initiator such as an organic peroxide such as benzoyl peroxide.
- it is more preferably crosslinked with an isocyanate-based crosslinking agent such as 2,4-tolylene diisocyanate.
- such resin-coated metal particles are prepared by adding metal particles and a silane coupling agent in a solvent such as toluene and stirring the mixture at room temperature for about 1 hour, and then, if necessary, a radical monomer and a radical polymerization initiator. Then, a crosslinking agent is added, and the mixture is stirred by heating to the radical polymerization starting temperature.
- the amount of the light-reflective insulating particles 3c described above in the light-reflective anisotropic conductive adhesive is too small, sufficient light reflection cannot be realized, and if it is too large, it is used in combination. Since the connection based on the conductive particles is hindered, it is preferably 1 to 50% by volume, more preferably 2 to 25% by volume, and further preferably 3 to 20% by volume in the thermosetting resin composition.
- metal particles used in conventional conductive particles for anisotropic conductive connection can be used.
- examples thereof include gold, nickel, copper, silver, solder, palladium, aluminum, alloys thereof, multilayered products thereof (for example, nickel plating / gold flash plating products), and the like.
- gold, nickel, and copper turn the conductive particles brown, so that the effects of the present invention can be enjoyed over other metal materials.
- metal-coated resin particles obtained by coating resin particles with a metal material can be used.
- resin particles include styrene resin particles, benzoguanamine resin particles, and nylon resin particles.
- a method of coating the resin particles with a metal material a conventionally known method can be employed, and an electroless plating method, an electrolytic plating method, or the like can be used.
- the layer thickness of the metal material to be coated is sufficient to ensure good connection reliability, and is usually 0.1 to 3 ⁇ m although it depends on the particle size of the resin particles and the type of metal.
- the particle size of the resin particle is too small, poor conduction tends to occur, and if it is too large, there is a tendency for a short circuit between patterns to occur. Therefore, it is preferably 1 to 20 ⁇ m, more preferably 3 to 10 ⁇ m, and particularly preferably 3 to 5 ⁇ m. is there.
- the shape of the core particle 1 is preferably a spherical shape, but may be a flake shape or a rugby ball shape.
- the metal-coated resin particles have a spherical shape, and if the particle size is too large, the connection reliability is lowered. Therefore, it is preferably 1 to 20 ⁇ m, more preferably 3 to 10 ⁇ m.
- the conductive particles it is preferable to use, as the conductive particles, light reflective conductive particles obtained by imparting light reflectivity to the conductive particles as described above.
- 2A and 2B are cross-sectional views of such light reflective conductive particles 200 and multilayered light reflective conductive particles 300. First, the light reflective conductive particles in FIG. 2A will be described.
- the light reflective conductive particles 200 are selected from core particles 21 coated with a metal material, and titanium oxide (TiO 2 ) particles, zinc oxide (ZnO) particles, or aluminum oxide (Al 2 O 3 ) particles on the surface thereof. And a light reflection layer 23 formed of at least one kind of inorganic particles 22. Titanium oxide particles, zinc oxide particles, or aluminum oxide particles are inorganic particles that exhibit a white color under sunlight. Accordingly, the light reflecting layer 23 formed from them exhibits white to gray.
- the expression of white to gray means that the wavelength dependency of the reflection characteristic for visible light is small and the visible light is easily reflected.
- Zinc oxide which is not catalytic and has a high refractive index can be preferably used.
- the surface thereof is made of a metal material.
- the surface is coated with a metal material, as described above, an aspect in which the core particle 21 itself is a metal material, or an aspect in which the surface of the resin particle is coated with a metal material can be cited.
- the particle thickness of the core particles 21 is preferably 0.5 to 50%, more preferably 1 to 25%.
- the particle size of the inorganic particles 22 constituting the light-reflecting layer 23 is preferably 0.02 to 4 ⁇ m, more preferably 0.1 to 1 ⁇ m, and particularly preferably 0.2 to 0.5 ⁇ m.
- the particle size of the inorganic particles 22 is set so that the light to be reflected (that is, the light emitted from the light emitting element) is not transmitted. It is preferable that it is 50% or more.
- examples of the shape of the inorganic particles 22 include an amorphous shape, a spherical shape, a scaly shape, and a needle shape.
- a spherical shape is preferable from the viewpoint of the light diffusion effect
- a scaly shape is preferable from the viewpoint of the total reflection effect.
- the light-reflective conductive particle 200 in FIG. 2A is a known film formation technique (a so-called mechanofusion method) in which a film composed of small particle diameter particles is formed on the surface of large particle diameter particles by physically colliding large and small powders. ).
- the inorganic particles 22 are fixed so as to bite into the metal material on the surface of the core particle 21, and on the other hand, the inorganic particles are not easily fused and fixed together, so that the monolayer of the inorganic particles constitutes the light reflecting layer 23. Therefore, in the case of FIG. 2A, the layer thickness of the light reflecting layer 23 is considered to be equal to or slightly thinner than the particle size of the inorganic particles 22.
- the multilayered light reflective conductive particles 300 in FIG. 2B will be described.
- the light-reflecting layer 23 contains a thermoplastic resin 24 that functions as an adhesive, and the inorganic particles 22 are also fixed together by this thermoplastic resin 24, so that the inorganic particles 22 are multilayered. It differs from the light-reflective conductive particle 200 of FIG. 2A in that it is multi-layered (for example, two or three layers). By including such a thermoplastic resin 24, the mechanical strength of the light reflecting layer 23 is improved, and the inorganic particles are less likely to be peeled off.
- thermoplastic resin 24 a halogen-free thermoplastic resin can be preferably used for the purpose of reducing the environmental load.
- polyolefins such as polyethylene and polypropylene, polystyrene, acrylic resins, and the like can be preferably used.
- Such multilayered light-reflective conductive particles 300 can also be manufactured by a mechanofusion method. If the particle size of the thermoplastic resin 24 applied to the mechano-fusion method is too small, the adhesion function is lowered, and if it is too large, it is difficult to adhere to the core particles. Therefore, it is preferably 0.02 to 4 ⁇ m, more preferably 0.1. ⁇ 1 ⁇ m. Further, when the amount of the thermoplastic resin 24 is too small, the adhesive function is deteriorated. When the amount is too large, an aggregate of particles is formed. The amount is 2 to 500 parts by mass, more preferably 4 to 25 parts by mass.
- thermosetting resin composition 3a constituting the light-reflective anisotropic conductive adhesive 3 used in the present invention it is preferable to use a colorless and transparent material as much as possible. This is because the light reflection efficiency of the light-reflective insulating particles or the like in the anisotropic conductive adhesive is not lowered, and the incident light is reflected without changing the light color.
- colorless and transparent means that the cured product of the anisotropic conductive adhesive has a light transmittance of 1 cm with respect to visible light having a wavelength of 380 to 780 nm (measured in accordance with JIS K7105) of 80% or more, Preferably, it means 90% or more.
- the blending amount of the conductive particles 3b with respect to 100 parts by mass of the thermosetting resin composition 3a is too small, poor conduction occurs, and if it is too large, a short circuit between patterns occurs.
- thermosetting resin composition 3a constituting the light-reflective anisotropic conductive adhesive 3 used in the present invention
- those used in conventional anisotropic conductive adhesives and anisotropic conductive films are utilized. be able to.
- a thermosetting resin composition is obtained by blending a curing agent with an insulating binder resin.
- the insulating binder resin include epoxy resins mainly composed of an alicyclic epoxy compound, a heterocyclic epoxy compound, a hydrogenated epoxy compound, and the like.
- Preferred examples of the alicyclic epoxy compound include those having two or more epoxy groups in the molecule. These may be liquid or solid. Specific examples include glycidyl hexahydrobisphenol A, 3,4-epoxycyclohexenylmethyl-3 ′, 4′-epoxycyclohexene carboxylate, and the like. Among these, glycidyl hexahydrobisphenol A, 3,4-epoxycyclohexenylmethyl-3 ′, 4 is preferable because it can ensure light transmission suitable for mounting LED elements on the cured product and is excellent in rapid curing. '-Epoxycyclohexenecarboxylate can be preferably used.
- heterocyclic epoxy compound examples include an epoxy compound having a triazine ring, and 1,3,5-tris (2,3-epoxypropyl) -1,3,5-triazine-2,4 is particularly preferable. , 6- (1H, 3H, 5H) -trione.
- hydrogenated epoxy compound hydrogenated products of the above-described alicyclic epoxy compounds and heterocyclic epoxy compounds, and other known hydrogenated epoxy resins can be used.
- An alicyclic epoxy compound, a heterocyclic epoxy compound, a hydrogenated epoxy compound, and the like may be used alone, but two or more kinds may be used in combination. In addition to these epoxy compounds, other epoxy compounds may be used in combination as long as the effects of the present invention are not impaired.
- the curing agent examples include an acid anhydride curing agent, an imidazole compound curing agent, a dicyan curing agent, and a dian curing agent.
- an acid anhydride-based curing agent that hardly changes the color of the cured product particularly an alicyclic acid anhydride-based curing agent, can be preferably used.
- methylhexahydrophthalic anhydride etc. can be mentioned preferably.
- thermosetting resin composition 3a of the light-reflective anisotropic conductive adhesive 3 used in the present invention when an alicyclic epoxy compound and an alicyclic acid anhydride-based curing agent are used, each usage amount is If the amount of the alicyclic acid anhydride curing agent is too small, the amount of the uncured epoxy compound is increased. If the amount is too large, the corrosion of the adherend material tends to be accelerated by the influence of the excess curing agent.
- the alicyclic acid anhydride curing agent is preferably used in an amount of 80 to 120 parts by mass, more preferably 95 to 105 parts by mass with respect to 100 parts by mass of the epoxy compound.
- the equivalent ratio of the epoxy resin and the acid anhydride curing agent is preferably 0.85 to 1.2, more preferably 0.9 to 1.1. Within this range, good heat-resistant light characteristics can be realized.
- the light-reflective anisotropic conductive adhesive 3 includes a curing accelerator such as DBU-p-toluenesulfonate, quaternary ammonium salt, organic phosphine, and epoxy resin for improving heat-resistant light characteristics.
- the amount can be blended in a proportion of preferably 0.1 to 5 parts by mass, more preferably 0.5 to 3 parts by mass with respect to 100 parts by mass in total with the acid anhydride curing agent.
- the light-reflective anisotropic conductive adhesive 3 includes a primary antioxidant (a radical chain inhibitor supplementing a peroxide radical (ROO.) Generated in the deterioration process) as an anti-aging agent, for example, phenol-based aging.
- a primary antioxidant a radical chain inhibitor supplementing a peroxide radical (ROO.) Generated in the deterioration process
- an anti-aging agent for example, phenol-based aging.
- Antioxidants and amine-based anti-aging agents and secondary antioxidants (peroxide decomposing agents that capture unstable volatile peroxides (ROOH) and actively decompose them into stable compounds, for example, sulfur-based compounds)
- Antioxidants and phosphorus antioxidants can be blended.
- Such an anti-aging agent is preferably 0.1 to 5 parts by mass, more preferably 0.5 to 2 parts by mass with respect to 100 parts by mass in total of the epoxy resin and the acid anhydride curing agent. Can be blended.
- the light-reflective anisotropic conductive adhesive 3 may be blended with additives such as an ultraviolet absorber, a coupling agent, and a flame retardant as necessary.
- the light-reflective anisotropic conductive adhesive 3 used in the present invention can be produced by uniformly mixing the thermosetting resin composition 3a, the conductive particles 3b, and the light-reflective insulating particles 3c.
- a solvent such as toluene
- the reflection characteristics of the light-reflective anisotropic conductive adhesive described above are obtained over the entire wavelength range of 380 to 780 nm of the cured product of the light-reflective anisotropic conductive adhesive in order to improve the light emission efficiency of the light-emitting element.
- Spectral reflectance is preferably 30% or more, more preferably 50% or more, and further preferably 80% or more.
- the spectral reflectance (measured in accordance with JIS K7105) for light having a wavelength of 450 nm is preferably 30% or more, more preferably 50% or more, and even more preferably 80% or more.
- the reflection characteristics and blending amount of the light-reflective insulating particles to be used, the blending composition of the thermosetting resin composition, and the like may be appropriately adjusted. Usually, if the amount of light-reflective insulating particles having good reflection characteristics is increased, the reflectance tends to increase.
- the reflection characteristics of the light-reflective anisotropic conductive adhesive can be evaluated from the viewpoint of refractive index. That is, if the refractive index of the cured product is larger than the refractive index of the cured product of the thermosetting resin composition excluding the conductive particles and the light-reflective insulating particles, the light-reflective insulating particles and the thermosetting surrounding them. This is because the amount of light reflection at the interface with the cured product of the conductive resin composition increases.
- the refractive index of the light-reflective insulating particles may be larger than the refractive index of the cured product of the thermosetting resin composition (measured according to JIS K7142).
- the difference between the two is 0.02 or more, more preferably 0.2 or more.
- the refractive index of a thermosetting resin composition mainly composed of an epoxy resin is about 1.5.
- anisotropic conductive connection is performed by heating and pressurizing the light emitting element to the wiring board.
- an elastomer head 4 for heating and pressing is set at a position where the light emitting element 1 can be pressed, and a pressing surface 4a of the elastomer head 4 is required as shown in FIG. 1C. Accordingly, the light-emitting element 1 is pressed against the wiring board 2 through a protective film (not shown) and heated and pressurized.
- the light-reflective anisotropic conductive adhesive 3 is flowed and then cured, whereby the light-emitting element 1 can be anisotropically conductively connected to the wiring board 2, and the light-emitting device 100 shown in FIG. 1D can be obtained. it can.
- the light emitting device 100 light emitted from the light emitting element 1 toward the wiring board 2 side is light reflective insulating particles 3c in a cured product 3 ′ of a light reflective anisotropic conductive adhesive. And is emitted from the upper surface of the light emitting device 100. Accordingly, it is possible to prevent a decrease in luminous efficiency.
- the elastomer head 4 used in this step is deformed at the time of anisotropic conductive connection, the unevenness of the anisotropic conductive connection portion can be canceled and the in-plane uniformity of pressing can be realized. Accordingly, even when a light emitting device is manufactured by anisotropically connecting a plurality of light emitting elements to a wiring board by the manufacturing method of the present invention by using the elastomer head 4, the shape and thickness of the connection electrodes are also reduced. Differences and dimensional errors can be canceled, and a plurality of light emitting elements can be collectively connected to the wiring board by anisotropic conductive connection. Further, the fillet portion 3d formed from the light-reflective anisotropic conductive adhesive 3 protruding from between the light-emitting element 1 and the wiring board 2 can be heated and pressed to be sufficiently cured. It can also improve the performance.
- the elastomer head 4 has a pressing surface 4a having a Shore A rubber hardness (JIS K6253 (5-35 ° C.)) of 40 or more and less than 90, preferably 65 or more and 80 or less.
- Shore A rubber hardness JIS K6253 (5-35 ° C.)
- the Shore A rubber hardness is less than 40, the pressure on the light emitting element is insufficient and the initial resistance and the connection reliability tend to decrease.
- the Shore A rubber hardness is 90 or more, the light emitting element is cracked or chipped. Because there is a tendency to.
- the elastomer head 4 having a Shore A rubber hardness of 40 or more and less than 90, even if the light-reflective insulating particles 3c and the conductive particles 3b are blended with the light-reflective anisotropic conductive adhesive 3, Can be heated and pressed so as not to cause cracks or chipping in the light emitting element 1 at the time of conductive connection.
- any of natural rubber, synthetic rubber, thermosetting or thermoplastic elastomer, etc. can be used, but from the viewpoint of heat resistance and pressure resistance, silicone rubber, fluorine rubber, etc. should be used. Is preferred.
- such an elastomer head 4 is normally held by a metal head base 5 such as stainless steel in which a heater for heating (not shown) is built.
- the size of the pressing surface 4a of the elastomer head 4 is set to a size that can press the fillet portion of the light-reflective anisotropic conductive adhesive protruding from between the light emitting element 1 and the wiring board 2 when pressed. It is preferable.
- the thickness of the elastomer head 4 is preferably at least equal to or greater than the maximum thickness of the light emitting element 1.
- the degree of heating at the time of anisotropic conductive connection is such that the light-reflective anisotropic conductive adhesive 3 has a melt viscosity within a suitable range in order to improve connection reliability and the like. It is preferable to heat the anisotropic conductive adhesive 3. Specifically, when the melt viscosity of the light-reflective anisotropic conductive adhesive is less than 1.0 ⁇ 10 2 mPa ⁇ s, the fluidity of the binder resin at the time of heating and pressing is large, and voids are generated in the initial stage.
- the melt viscosity is greater than 1.0 ⁇ 10 5 mPa ⁇ s
- the binder resin cannot be completely removed in the connection electrode part during heating and pressurization, and voids are generated, resulting in an initial resistance.
- the connection reliability tends to be inferior
- the light-reflective anisotropic conductive adhesive 3 has a melt viscosity of preferably 1.0 ⁇ 10 2 to 1.0 ⁇ 10 5 mPa ⁇ s, more preferably 1 Heating is preferably performed so that the pressure becomes 0.0 ⁇ 10 3 to 1.0 ⁇ 10 4 mPa ⁇ s.
- the surface temperature of the elastomer head 4 can be appropriately set depending on the composition of the light-reflective anisotropic conductive adhesive 3 and the like, for example, the pressing surface 4a of the elastomer head 4 Heat the surface temperature to 50-350 ° C.
- the wiring board 2 is connected to the light emitting element from the wiring board 2 side during the heating and pressurization. It is preferable to heat so that the temperature is higher than 1.
- the surface of the pressing surface 4a of the elastomer head 4 is heated so as to be about 100 ° C.
- the temperature of the light-reflective anisotropic conductive adhesive 3 is heated so as to be about 200 ° C. It is preferable to do.
- the pressure at the time of anisotropic conductive connection is preferably about 2 to 50 Pa for one light emitting element 1 and is preferably pressed for about 10 to 60 seconds.
- the light emitting device 100 obtained in step (B) shown in FIG. 1D may be sealed using a transparent sealing resin 6 so as to cover the entire light emitting element 1 as shown in FIG. 1E. Thereby, the light emitting device 110 with improved durability is obtained.
- the transparent sealing resin 6 is not particularly limited as long as it is a general resin used for resin sealing of the light emitting element 1.
- the cured product has low adhesiveness, little deterioration with time, and short curing time.
- a silicone-based or acrylic-based transparent sealing resin can be preferably used.
- the resin sealing method is not particularly limited as long as it is a general method used for resin sealing of a light-emitting element, and examples thereof include casting methods, potting methods, molding methods, and printing methods.
- the potting method is preferred.
- Example 1 (Preparation of light-reflective anisotropic conductive adhesive) 50 parts by mass of alicyclic epoxy resin (2021P, Daicel Chemical Industries, Ltd.) as the main agent, 50 parts by mass of methylhexahydrophthalic anhydride as the curing agent, and Au-coated resin conductive particles having an average particle size of 5 ⁇ m as conductive particles (Spherical acrylic resin particles having an average particle diameter of 4.6 ⁇ m and electroless gold plating having a thickness of 0.2 ⁇ m (Bright 20GNB4.6EH, Nippon Chemical Industry Co., Ltd.)) 15 parts by mass, and an organic phosphine curing accelerator (TPP-BF, Hokuko Chemical Industry Co., Ltd.) A thermosetting epoxy anisotropic conductive adhesive composed of 3 parts by mass and phosphorous anti-coloring agent (HCA, Sanko Co., Ltd.) 0.5 parts by mass By mixing silicon dioxide powder (Seahoster KE-E30, Nippon Shokubai Co
- a bump bonder (Anisotropic conductive connection between light emitting element and wiring board) A bump bonder (FB700, Kaijo Corp.) is formed on a connecting electrode of a glass epoxy wiring board having a predetermined shape of a wiring formed by plating Ni / Au (5.0 ⁇ m thickness / 0.3 ⁇ m thickness) on a 100 ⁇ m pitch copper wiring. ) Was used to form gold bumps 15 ⁇ m high.
- the light-reflective anisotropic conductive adhesive obtained above is applied to the glass epoxy wiring board with gold bumps, and a blue LED element having a 0.3 mm square and a 0.1 mm thickness (peak wavelength: 455 nm, rated)
- An elastomer head (length 50 mm ⁇ width 50 mm, thickness 10 mm) having a pressing surface of Shore A rubber hardness (JIS K6253) 65 is arranged at 250 ° C. (elastomer head) with a current of 20 mA and a rated voltage of 3.2 V. Philip chip mounting was performed under the conditions of (pressing surface temperature), 30 seconds, and 1 N / chip to obtain an LED module as a light emitting device.
- the light-emitting device obtained above is resin-sealed by a cast method using addition-curable methylsilicone resin (KER2500, Shin-Etsu Chemical Co., Ltd.), and a light-emitting device (LED module) sealed with a transparent resin Got.
- KER2500 addition-curable methylsilicone resin
- LED module light-emitting device
- Example 2 As light-reflective insulating particles, instead of silicon dioxide powder, zinc oxide powder having an average particle size of 225 nm (JIS standard zinc oxide, 1 type, Hakusuitec Co., Ltd.) is used in the same manner as in Example 1 except that 15 vol% is used. Thus, a paste-like light-reflective anisotropic conductive adhesive having a white appearance color was obtained, and further, an LED module sealed with a transparent resin was obtained using this light-reflective anisotropic conductive adhesive.
- JIS standard zinc oxide, 1 type, Hakusuitec Co., Ltd. JIS standard zinc oxide, 1 type, Hakusuitec Co., Ltd.
- Example 3 As light-reflective insulating particles, instead of silicon dioxide powder, titanium dioxide powder having an average particle diameter of 210 nm (KR-380, Titanium Industry Co., Ltd.) was used in the same manner as in Example 1, except that 15 vol% was used. A paste-like light-reflective anisotropic conductive adhesive having a white appearance color was obtained, and further, an LED module sealed with a transparent resin was obtained using this light-reflective anisotropic conductive adhesive.
- KR-380 Titanium Industry Co., Ltd.
- Example 4 In the same manner as in Example 1, except that 15% by volume of titanium dioxide powder (KR-380, Titanium Industry Co., Ltd.) having an average particle diameter of 190 nm was used as the light-reflective insulating particles instead of silicon dioxide powder, the appearance was A paste-like light-reflective anisotropic conductive adhesive having a white color was obtained, and an LED module sealed with a transparent resin was obtained using the light-reflective anisotropic conductive adhesive.
- titanium dioxide powder KR-380, Titanium Industry Co., Ltd.
- Example 5 In the same manner as in Example 1, except that 15% by volume of titanium dioxide powder (KR-380, Titanium Industry Co., Ltd.) having an average particle diameter of 300 nm was used as the light-reflective insulating particles instead of silicon dioxide powder, the appearance was A paste-like light-reflective anisotropic conductive adhesive having a white color was obtained, and an LED module sealed with a transparent resin was obtained using the light-reflective anisotropic conductive adhesive.
- titanium dioxide powder KR-380, Titanium Industry Co., Ltd.
- Example 6 In the same manner as in Example 1, except that 5% by volume of titanium dioxide powder (KR-380, Titanium Industry Co., Ltd.) having an average particle diameter of 210 nm was used as the light-reflective insulating particles instead of silicon dioxide powder, the appearance was changed. A paste-like light-reflective anisotropic conductive adhesive having a white color was obtained, and an LED module sealed with a transparent resin was obtained using the light-reflective anisotropic conductive adhesive.
- titanium dioxide powder KR-380, Titanium Industry Co., Ltd.
- Example 7 In the same manner as in Example 1, except that 25% by volume of titanium dioxide powder (KR-380, Titanium Industry Co., Ltd.) having an average particle diameter of 210 nm was used as the light-reflective insulating particles instead of silicon dioxide powder, the appearance was A paste-like light-reflective anisotropic conductive adhesive having a white color was obtained, and an LED module sealed with a transparent resin was obtained using the light-reflective anisotropic conductive adhesive.
- titanium dioxide powder KR-380, Titanium Industry Co., Ltd.
- Example 8 As the light-reflective insulating particles, instead of silicon dioxide powder, titanium dioxide powder (KR-380, Titanium Industry Co., Ltd.) having an average particle diameter of 210 nm was used in an amount of 15% by volume and replaced with an elastomer head having a Shore A rubber hardness of 60. A paste-like light-reflective anisotropic conductive adhesive having a white appearance color was obtained in the same manner as in Example 1 except that an elastomer head having a Shore A rubber hardness of 40 was used. An LED module sealed with a transparent resin using an adhesive was obtained.
- silicon dioxide powder KR-380, Titanium Industry Co., Ltd.
- Example 9 As the light-reflective insulating particles, instead of silicon dioxide powder, titanium dioxide powder having an average particle diameter of 210 nm (KR-380, Titanium Industry Co., Ltd.) is used in an amount of 15% by volume, and replaced with an elastomer head having a Shore A rubber hardness of 60. A paste-like light-reflective anisotropic conductive adhesive having a white appearance color was obtained in the same manner as in Example 1 except that an elastomer head having a Shore A rubber hardness of 80 was used. Further, this light-reflective anisotropy was obtained. An LED module sealed with a transparent resin using a conductive adhesive was obtained.
- KR-380 Titanium Industry Co., Ltd.
- Example 10 As light-reflective insulating particles, instead of silicon dioxide powder, 15% by volume of light-reflective insulating particles having an average particle diameter of 1.2 ⁇ m prepared as described below was used in the same manner as in Example 1. Thus, a paste-like light-reflective anisotropic conductive adhesive having a white appearance color was obtained, and further, an LED module sealed with a transparent resin was obtained using this light-reflective anisotropic conductive adhesive.
- Insulation-coated silver particles were obtained as light-reflective insulating particles.
- the average particle diameter of the light-reflective insulating particles including the insulating coating was 1.2 ⁇ m.
- the appearance color of the light-reflective insulating particles was gray.
- Example 11 A paste-like light whose appearance color is white in the same manner as in Example 1, except that light-reflective conductive particles having an average particle diameter of 5 ⁇ m prepared as described below are used in place of the Au-coated resin conductive particles. A reflective anisotropic conductive adhesive was obtained, and further, an LED module sealed with a transparent resin using this light reflective anisotropic conductive adhesive was obtained.
- (Creation of light-reflective conductive particles) 4 parts by mass of titanium oxide powder (KR-380, Titanium Industry Co., Ltd.) having an average particle size of 0.5 ⁇ m and Au coated resin conductive particles having an average particle size of 5 ⁇ m with a brown appearance color (spherical shape having an average particle size of 4.6 ⁇ m) 20 parts by mass of particles (electroless gold-plated 0.2 ⁇ m thick on acrylic resin particles) are put into a mechanofusion apparatus (AMS-GMP, Hosokawa Micron Corporation), and the surface of the conductive particles is made of titanium oxide particles.
- a light reflective conductive particle was obtained by forming a light reflective layer having a thickness of about 0.5 ⁇ m.
- the appearance color of the light reflective conductive particles was gray.
- Comparative Example 1 (Preparation of anisotropic conductive adhesive) 10 parts by mass of a bisphenol A type epoxy resin (Epicoat 828, JER Co., Ltd.) as a main agent, 1 part by mass of an aliphatic polyamine-based curing agent (Adeka Hardener EH4357S, ADEKA Co., Ltd.), and an average particle size of 5 ⁇ m as conductive particles It consists of 10 parts by mass of Au-coated resin conductive particles (particles obtained by electroless gold plating of 0.2 ⁇ m thickness on spherical acrylic resin particles having an average particle size of 4.6 ⁇ m (Bright 20GNB4.6EH, Nippon Chemical Industry Co., Ltd.), A paste-like anisotropic conductive adhesive having a brown appearance color was obtained.
- a bisphenol A type epoxy resin Epicoat 828, JER Co., Ltd.
- an aliphatic polyamine-based curing agent Alka Hardener EH4357S, ADEKA Co
- Comparative Example 2 A transparent resin-sealed LED module was obtained in the same manner as in Example 1 except that the anisotropic conductive adhesive obtained in Comparative Example 1 was used instead of the light-reflective anisotropic conductive adhesive. .
- Comparative Example 4 A paste-like anisotropic conductive adhesive having a brown appearance color was obtained in the same manner as in Example 1 except that the light-reflective insulating particles were not blended, and further using this light-reflective anisotropic conductive adhesive. A transparent resin-sealed LED module was obtained.
- Comparative Example 5 A transparent resin-sealed LED module was obtained in the same manner as in Example 1 except that a stainless steel metal head was used instead of the Shore A rubber hardness 60 elastomer head.
- Comparative Example 6 As the light-reflective insulating particles, 15% by volume of titanium dioxide powder (KR-380, Titanium Industry Co., Ltd.) having an average particle diameter of 210 nm is used instead of silicon dioxide powder, and the elastomer head having a Shore A rubber hardness of 60 is used. A paste-like anisotropic conductive adhesive having a white appearance color was obtained in the same manner as in Example 1 except that an elastomer head having a Shore A rubber hardness of 90 was used. Further, this light-reflective anisotropic conductive adhesive was obtained. An LED module sealed with a transparent resin using an agent was obtained.
- the die shear strength per one 300 ⁇ m square LED element of the LED module was measured using a die shear strength tester (PTR-1100, Inc.). And a shear rate of 20 ⁇ m / sec. The measurement was performed on two samples of an LED module in an initial state before lighting and an LED module after lighting continuously for 300 hours in a high temperature and high humidity environment of 85 ° C. and 85% RH. The obtained results are shown in Table 1.
- the die shear strength is practically 300 gf / chip or more, preferably 400 gf / chip or more, as measured by the above measurement method.
- the light emitting devices manufactured in Examples 1 to 11 use an anisotropic conductive adhesive having a spectral reflectance of more than 60%, and different in the elastomer head having a Shore A hardness of 40 or more and less than 90. Since the anisotropic conductive connection is made, the LED element is not chipped (Examples 1 to 7 and 9 to 11) or hardly (Example 8). In addition, it showed a stable and good die shear strength. Since this stable and good die shear strength is shown, it can be seen that good connection reliability is realized in the light emitting devices manufactured in Examples 1 to 11.
- Example 10 In the case of Example 10 in which insulating coated Ag particles are used as the light-reflective insulating particles, the particle diameter is 1.2 ⁇ m larger than in the other examples. Although the ratio of geometric scattering was increased, the optical characteristics were better than those of Comparative Example 4 under the same conditions except that such light-reflective insulating particles were not used. Further, in the case of Example 11 in which the light-reflective conductive particles having the light-reflecting layer provided on the surface of the Au-coated conductive particles are used, compared to Example 3 under the same conditions except that the Au-coated resin conductive particles are used. Although the optical characteristics were slightly lowered, the optical characteristics were better than those of Comparative Example 4 in which Au-coated resin conductive particles were used but no light-reflective insulating particles were used.
- Example 8 in which the Shore A hardness of the elastomer head is 40, the rubber head is flexible, and thus the pressure is applied so as to wrap the entire LED element. As a result, a load may be applied to the etched portion of the LED element. In the case of collective pressing, chip chipping may occur extremely rarely, but since chip chipping frequency is extremely low, it can be positioned as an example. It is. Therefore, it can be seen that it is necessary to use an elastomer head having a Shore A hardness of 40 (Example 8) or more and less than 90 (Comparative Example 6 and Example 9) in the anisotropic conductive connection.
- Example 1 SiO 2 , refractive index 1.46
- Example 2 ZnO, 1.9 to 2.01
- Example 3 TiO 2 , In the case of a refractive index of 2.72 or 2.52), it can be seen that as the refractive index increases, both the spectral reflectance and the LED total luminous flux are improved.
- Example 6 From Example 6 (5 vol%), Example 3 (15 vol%) and Example 7 (25 vol%) in which the content of the reflective insulating particles is different, the resin cured product increases when the content of the light reflective insulating particles increases. It becomes clear that the die shear strength tends to decrease because the material becomes too hard at the same time, and the total luminous flux tends to decrease as the content decreases. In addition, when content falls, there exists a tendency for the handleability as a paste-form adhesive to fall.
- a light-reflective anisotropic conductive adhesive is used when mounting the light emitting element on the wiring board, the light emitting element is mounted on the wiring board without reducing the light emission efficiency of the light emitting element.
- An anisotropic conductive connection can be made.
- an elastomer head having a specific surface hardness is used for heating and pressurizing during anisotropic conductive connection, light-reflective anisotropic conductivity is prevented while preventing cracks and chips from occurring in the light-emitting element.
- An anisotropic conductive connection with excellent connection reliability can be performed using an adhesive.
- the manufacturing method of the light emitting device of the present invention and the light emitting device manufactured thereby are electronic devices such as a display device, a lighting device, a backlight, and an inspection light source using a light emitting element such as an LED element, and the manufacturing thereof. It is useful in the field of
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Abstract
Description
工程(A)
発光素子と、該発光素子が接続されるべき配線板との間に、熱硬化性樹脂組成物、導電粒子及び光反射性絶縁粒子を含有する光反射性異方性導電接着剤を配置する工程; 及び
工程(B)
配線板に対して発光素子を、押圧面のショアAゴム硬度(JIS K6253)が40以上90未満であるエラストマーヘッドで加熱加圧することにより異方性導電接続を行う工程
を有する製造方法を提供する。なお、この製造方法は、更に、以下の工程(C)
工程(C)
配線板上に異方性導電接続された発光素子を、透明樹脂を用いて封止する工程
を有していてもよい。
まず、図1Aに示すように、発光素子1と、発光素子1が接続されるべき配線板2との間に、通常、互いに接続されるべき発光素子1の電極1aと配線板の電極2aとを互いに対向させた間に、光反射性異方性導電接着剤3をその形態(液状、ペースト状、フィルム状等)などに応じて公知の手法、例えば、スクリーン印刷法、パッド転写法、ディスペンス塗布法等により配置する。具体的には、配線板2の少なくとも電極2a上に光反射性異方性導電接着剤3を仮貼着し、その光反射性異方性導電接着剤3を挟み込むように発光素子1の電極1aを配線板2の電極2aに対向させる。
工程(A)の後、配線板に対して発光素子を加熱加圧することにより異方性導電接続を行う。具体的には、図1Bに示すように、発光素子1を押圧できる位置に、加熱加圧するためのエラストマーヘッド4をセットし、図1Cに示すように、エラストマーヘッド4の押圧面4aを、必要に応じて保護フィルム(図示せず)を介して、発光素子1を配線板2に押し当て、加熱加圧する。これにより、光反射性異方性導電接着剤3を流動させた後硬化させて発光素子1を配線板2に異方性導電接続することができ、図1Dに示す発光装置100を得ることができる。この発光装置100では、発光素子1が発した光のうち、配線板2側に向かって発した光は、光反射性異方性導電接着剤の硬化物3′中の光反射性絶縁粒子3cで反射し、発光装置100の上面から出射する。従って、発光効率の低下を防止することができる。
図1Dに示す、工程(B)で得られた発光装置100に対し、図1Eに示すように、発光素子1全体を覆うように、透明封止樹脂6を用いて封止してもよい。これにより、耐久性が向上した発光装置110となる。この透明封止樹脂6としては、発光素子1の樹脂封止に用いられる一般的な樹脂であれば特に制限されないが、例えば、硬化物の粘着性が低く、経時劣化が少なく、硬化時間が短い等の観点から、シリコーン系又はアクリル系の透明封止樹脂を好ましく使用することができる。
(光反射性異方性導電接着剤の調製)
主剤として脂環式エポキシ樹脂(2021P、ダイセル化学工業(株))50質量部と、硬化剤としてメチルヘキサヒドロフタル酸無水物50質量部と、導電粒子として平均粒径5μmのAu被覆樹脂導電粒子(平均粒径4.6μmの球状アクリル樹脂粒子に0.2μm厚の無電解金メッキを施した粒子(ブライト20GNB4.6EH、日本化学工業(株)))15質量部と、有機ホスフィン系硬化促進剤(TPP-BF、北興化学工業(株))3質量部と、リン系着色防止剤(HCA、三光(株))0.5質量部とからなる熱硬化型エポキシ系異方性導電接着剤に、光反射性絶縁粒子として平均粒径210nmの二酸化ケイ素粉末(シーホスター KE-E30、日本触媒(株))を15体積%となるように配合し、均一に混合することにより、外観色が白色のペースト状の光反射性異方性導電接着剤を得た。
100μmピッチの銅配線にNi/Au(5.0μm厚/0.3μm厚)メッキ処理した所定の形状の配線を有するガラスエポキシ配線板の接続用電極上に、バンプボンダー(FB700、カイジョー(株))を用いて15μm高の金バンプを形成した。この金バンプ付きガラスエポキシ配線板に、上記で得た光反射性異方性導電接着剤を適用し、その上に、0.3mm角で0.1mm厚の青色LED素子(ピーク波長455nm、定格電流20mA、定格電圧3.2V)20個を配置し、ショアAゴム硬度(JIS K6253)65の押圧面を有するエラストマーヘッド(縦50mm×横50mm、厚さ10mm)を用い、250℃(エラストマーヘッド押圧面温度)、30秒、1N/チップという条件でフィリップチップ実装し、発光装置としてLEDモジュールを得た。
上記で得られた発光装置に対し、付加硬化型メチルシリコーン樹脂(KER2500、信越化学工業(株))を用いてキャスト法により樹脂封止を行い、透明樹脂封止された発光装置(LEDモジュール)を得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径225nmの酸化亜鉛粉末(JIS規格酸化亜鉛1種、ハクスイテック(株))を15体積%で用いること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径210nmの二酸化チタン粉末(KR-380、チタン工業(株))を15体積%で用いること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径190nmの二酸化チタン粉末(KR-380、チタン工業(株))を15体積%用いること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径300nmの二酸化チタン粉末(KR-380、チタン工業(株))を15体積%用いること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径210nmの二酸化チタン粉末(KR-380、チタン工業(株))を5体積%用いること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径210nmの二酸化チタン粉末(KR-380、チタン工業(株))を25体積%用いること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径210nmの二酸化チタン粉末(KR-380、チタン工業(株))を15体積%用い且つショアAゴム硬度60のエラストマーヘッドに代えてショアAゴム硬度40のエラストマーヘッドを用いること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径210nmの二酸化チタン粉末(KR-380、チタン工業(株))を15体積%用い、且つショアAゴム硬度60のエラストマーヘッドに代えてショアAゴム硬度80のエラストマーヘッドを用いること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、以下に説明するように調製した平均粒径1.2μmの光反射性絶縁粒子を15体積%使用すること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
攪拌機つきフラスコに粒状銀粒子(平均粒径1μm)5gとトルエン50mlとを投入し、攪拌しながらフラスコにシランカップリング剤(3-メタクリロキシプロピルトリエトキシシラン)0.25gを投入し、25℃で60分間攪拌した。次に、この混合物に、メタクリル酸メチル2gとメタクリル酸-2-ヒドロキシエチル2gとベンゾイルパーオキサイド0.04gと2,4-トリレンジイソシアネート1gとを投入し、80℃で12時間攪拌することにより、光反射性絶縁粒子として絶縁被覆銀粒子を得た。絶縁被覆を含めた光反射性絶縁粒子の平均粒径は1.2μmであった。この光反射性絶縁粒子の外観色は灰色であった。
Au被覆樹脂導電粒子に代えて、以下に説明するように調製した平均粒径5μmの光反射性導電粒子を使用すること以外、実施例1と同様にして、外観色が白色のペースト状の光反射性異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
平均粒子径0.5μmの酸化チタン粉末(KR-380、チタン工業(株))4質量部と、外観色が茶色の平均粒径5μmのAu被覆樹脂導電粒子(平均粒径4.6μmの球状アクリル樹脂粒子に0.2μm厚の無電解金メッキを施した粒子)20質量部とを、メカノフュージョン装置(AMS-GMP、ホソカワミクロン(株))に投入し、導電粒子の表面に酸化チタン粒子からなる約0.5μm厚の光反射層を成膜することにより、光反射性導電粒子を得た。この光反射性導電粒子の外観色は灰色であった。
(異方性導電接着剤の調製)
主剤としてビスフェノールA型エポキシ樹脂(エピコート828、JER(株))10質量部と、脂肪族ポリアミン系硬化剤(アデカハードナー EH4357S、(株)ADEKA)1質量部と、導電粒子として平均粒径5μmのAu被覆樹脂導電粒子(平均粒径4.6μmの球状アクリル樹脂粒子に0.2μm厚の無電解金メッキを施した粒子(ブライト20GNB4.6EH、日本化学工業(株))10質量部とからなる、外観色が茶色のペースト状の異方性導電接着剤を得た。
光反射性異方性導電接着剤に代えて上記で得た異方性導電接着剤を用い且つショアAゴム硬度が65のエラストマーヘッドに代えてステンレススチール製の金属ヘッドを用いること以外、実施例1と同様にして透明樹脂封止されたLEDモジュールを得た。
光反射性異方性導電接着剤に代えて、上記の比較例1で得た異方性導電接着剤を用いること以外、実施例1と同様にして透明樹脂封止されたLEDモジュールを得た。
(異方性導電接着剤の調製)
付加硬化型メチルシリコーン樹脂(KER2500、信越化学工業(株))100質量部に、導電粒子として平均粒径5μmのAu被覆樹脂導電粒子(平均粒径4.6μmの球状アクリル樹脂粒子に0.2μm厚の無電解金メッキを施した粒子(ブライト20GNB4.6EH、日本化学工業(株))10質量部を均一に混合することにより、外観色が茶色のペースト状の異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて、実施例1と同様にして透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子を配合しないこと以外、実施例1と同様にして、外観色が茶色のペースト状の異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
ショアAゴム硬度60のエラストマーヘッドに代えてステンレススチール製の金属ヘッドを用いること以外、実施例1と同様にして、透明樹脂封止されたLEDモジュールを得た。
光反射性絶縁粒子として、二酸化ケイ素粉末に代えて、平均粒径210nmの二酸化チタン粉末(KR-380、チタン工業(株))を15体積%用い且つショアAゴム硬度が60のエラストマーヘッドに代えてショアAゴム硬度が90のエラストマーヘッドを用いること以外、実施例1と同様にして、外観色が白色のペースト状の異方性導電接着剤を得、更にこの光反射性異方性導電接着剤を用いて透明樹脂封止されたLEDモジュールを得た。
(光反射率評価試験)
実施例及び比較例で得られた異方性導電接着剤を、ガラスエポキシ基板に、10mm角で乾燥厚で0.3mmとなるように塗布し、250℃で30秒間加熱して硬化させた。この硬化物に対し、キセノンランプ光源から光で照射し、積分球を用いる分光側色計(CM3600d、コニカミノルタ(株))を用いて、波長450nmの光に対する反射率(JIS K7150)を、硬化物に垂直な軸と8度の角度の光について測定した。反射率は、実用上30%以上であることが望まれる。
実施例及び比較例で作成した各LEDモジュールについて、20個のLED素子の外観を目視観察し、亀裂又は欠けが発生しているLED素子の個数をカウントした。得られた結果を表1に示す。なお、「チップの欠け」評価の「0~1」の意味は、通常は20個のLED素子に亀裂又は欠けが生ずることがないが、極めて稀にチップの欠けが生ずる場合があることを意味する。
実施例及び比較例で作成した各LEDモジュールにおけるLED素子と配線板との接着力として、LEDモジュールの300μm角LED素子1チップ当たりのダイシェア強度を、ダイシェア強度試験機(PTR-1100、(株)レスカ)を用い、剪断速度20μm/secの条件で測定した。測定は、点灯前の初期状態のLEDモジュールと、85℃、85%RHの高温高湿環境下において300時間連続点灯後のLEDモジュールの2つのサンプルについて行った。得られた結果を表1に示す。ダイシェア強度は、上記の測定方法で測定して、実用上300gf/チップ以上、好ましくは400gf/チップ以上であることが望まれる。
実施例及び比較例で作成した各LEDモジュールについて、透明性維持性の評価として、全光束測定システム(積分全球)(LE-2100、大塚電子(株))を用いて全光束量を測定した(測定条件:If=20mA(定電流制御))。測定は、点灯前の初期状態のLEDモジュールと、85℃、85%RHの高温高湿環境下において300時間連続点灯後のLEDモジュールの2つのサンプルについて行った。得られた結果を表1に示す。全光束量は、上記の測定方法で測定して、実用上200mlm以上、好ましくは350mlm以上であることが望まれる。
1a 発光素子の電極
2 配線板
2a 配線板の電極
3 光反射性異方性導電接着剤
3a 熱硬化性樹脂組成物
3b 導電粒子
3c 光反射性絶縁粒子
3d フィレット部
4 エラストマーヘッド
4a エラストマーヘッドの押圧面
5 ヘッドベース
6 透明封止樹脂
21 コア粒子
22 無機粒子
23 光反射層
24 熱可塑性樹脂
100、110 発光装置
200 光反射性導電粒子
300 多層化光反射性導電粒子
Claims (14)
- 発光素子を配線板に異方性導電接続してなる発光装置の製造方法において、以下の工程(A)及び(B):
工程(A)
発光素子と、該発光素子が接続されるべき配線板との間に、熱硬化性樹脂組成物、導電粒子及び光反射性絶縁粒子を含有する光反射性異方性導電接着剤を配置する工程; 及び
工程(B)
配線板に対して発光素子を、押圧面のショアAゴム硬度(JIS K6253)が40以上90未満であるエラストマーヘッドで加熱加圧することにより異方性導電接続を行う工程
を有する製造方法。 - 光反射性異方性導電接着剤の波長450nmの光に対する分光反射率(JIS K7105)が、30%以上である請求項1記載の製造方法。
- 光反射性絶縁粒子が、酸化ケイ素、酸化チタン、窒化ホウ素、酸化亜鉛及び酸化アルミニウムからなる群より選択される少なくとも一種の無機粒子である請求項1又は2記載の製造方法。
- 光反射性絶縁粒子の平均粒子径が、150nm~550nmである請求項1~3のいずれかに記載の製造方法。
- 光反射性絶縁粒子の屈折率(JIS K7142)が、熱硬化性樹脂組成物の硬化物の屈折率(JIS K7142)よりも大きい請求項1~4のいずれかに記載の製造方法。
- 光反射性絶縁粒子が、鱗片状又は球状銀粒子の表面を絶縁性樹脂で被覆した樹脂被覆金属粒子である請求項1~5のいずれかに記載の製造方法。
- 熱硬化性樹脂組成物中における光反射性絶縁粒子の配合量が、1~50体積%である請求項1~6のいずれかに記載の製造方法。
- 熱硬化性樹脂組成物が、エポキシ樹脂と酸無水物系硬化剤とを含有する請求項1~7のいずれかに記載の製造方法。
- エラストマーヘッドの押圧面のショアAゴム硬度(JIS K6253)が、65以上80以下である請求項1~8のいずれかに記載の製造方法。
- 更に、以下の工程(C)
(C)配線板上に異方性導電接続された発光素子を、透明樹脂を用いて封止する工程
を有する請求項1~9のいずれかに記載の製造方法。 - 導電粒子が、金属材料で被覆されているコア樹脂粒子と、その表面に酸化チタン粒子、酸化亜鉛粒子又は酸化アルミニウム粒子から選択された少なくとも一種の無機粒子から形成された光反射層とからなる光反射性導電粒子である請求項1~10のいずれかに記載の製造方法。
- 熱硬化性樹脂組成物100質量部に対する光反射性導電粒子の配合量が、1~100質量部である請求項11記載の製造方法。
- 請求項1~12のいずれかに記載の製造方法により製造された発光装置。
- 発光素子が、発光ダイオードである請求項13記載の発光装置。
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KR20120135006A (ko) | 2012-12-12 |
TWI529980B (zh) | 2016-04-11 |
JP5402804B2 (ja) | 2014-01-29 |
TW201145620A (en) | 2011-12-16 |
CN102823084A (zh) | 2012-12-12 |
KR101892753B1 (ko) | 2018-08-28 |
JP2011222830A (ja) | 2011-11-04 |
CN102823084B (zh) | 2015-11-25 |
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