WO2010061737A1 - 銅箔又は銅張り積層板の巻取り方法 - Google Patents
銅箔又は銅張り積層板の巻取り方法 Download PDFInfo
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- WO2010061737A1 WO2010061737A1 PCT/JP2009/069346 JP2009069346W WO2010061737A1 WO 2010061737 A1 WO2010061737 A1 WO 2010061737A1 JP 2009069346 W JP2009069346 W JP 2009069346W WO 2010061737 A1 WO2010061737 A1 WO 2010061737A1
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- Prior art keywords
- copper
- winding
- copper foil
- tape
- double
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C47/00—Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
- B21C47/24—Transferring coils to or from winding apparatus or to or from operative position therein; Preventing uncoiling during transfer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C47/00—Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
- B21C47/02—Winding-up or coiling
- B21C47/04—Winding-up or coiling on or in reels or drums, without using a moving guide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C47/00—Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
- B21C47/26—Special arrangements with regard to simultaneous or subsequent treatment of the material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H18/00—Winding webs
- B65H18/28—Wound package of webs
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0393—Flexible materials
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/022—Processes for manufacturing precursors of printed circuits, i.e. copper-clad substrates
Definitions
- the present invention relates to a method for winding a copper foil or a copper-clad laminate on a core.
- FCCL Flexible Copper Clad Laminate
- Copper foil includes rolled copper foil and electrolytic copper foil, each of which is wound around a core tube (also referred to as “core roll”). Coated polyimide composites have been manufactured.
- Patent Document 1 can be mentioned as the typical thing.
- a copper foil is wound around a core tube using a double-sided adhesive tape with a release paper, and is fixed by using two double-sided adhesive tapes with a release paper, in a winding method. Is.
- a method using such an adhesive tape or a method of applying an adhesive to a winding core tube has a big problem. That is, a step or a convex shape is formed at the starting end of the winding, and wrinkles and buggy are generated. This level difference occurs when the copper foil is not applied well or when the copper foil is not cut cleanly. However, since the start of the copper foil to be wound is inevitably generated, it can be said that it is inevitable.
- the problem is that an adhesive is added to the copper foil and the thickness of the starting edge increases. Since winding is repeated, a step always occurs as described above at the start end portion where the adhesive is added. Although improvement of adhesiveness is important in a sense in order to increase the winding strength, a copper foil having such a step is not preferable.
- the present invention has been made in view of the above-mentioned problems, and its object is to suppress the generation of wrinkles and buggies during winding and to increase the winding tension to prevent collapse.
- the present invention provides a method for winding a copper foil or a copper-clad laminate.
- the present invention is 1.
- two tapes with a small width double-sided adhesive having the same length as the width of the copper foil or copper-clad laminate and the length of copper
- the core tube is rotated so that the foil or copper-clad laminate circulates, and when the second double-sided adhesive tape is present, the copper foil or copper-clad laminate is attached to the second double-sided adhesive tape.
- the rotation of the core tube is stopped, and the first and second From the top of the double-sided adhesive tape and the copper foil or copper-clad laminate wrapped around it, a wide adhesive backup tape whose length is longer than the width of the copper foil or copper-clad laminate is a core tube 1.
- Winding method of copper foil or copper-clad laminate characterized in that winding is continued after pasting up. 2.
- the copper foil winding method according to 1 above wherein the width of the double-sided adhesive tape is 10 to 50 mm, and the gap between the first and second double-sided adhesive tapes is 0.1 to 30 mm. 3.
- the adhesive tape according to any one of the above 1 to 4 wherein the adhesive tape has a length that is 25 to 500 mm long from both ends of the copper foil or the copper-clad laminate. 5.
- Winding method of copper foil or copper clad laminate according to one item Any one of 1 to 5 above, wherein the double-sided adhesive tape with release paper is used, and the double-sided adhesive tape with release paper is previously attached to the core tube before starting the winding operation.
- a method for winding the copper foil or copper-clad laminate according to one item is provided.
- the present invention has an excellent effect that the yield of products can be improved and the productivity can be improved by suppressing the occurrence of wrinkles and buggies during winding and increasing the winding tension and preventing collapse.
- FIG. 1 shows a schematic explanatory diagram at the beginning of winding of a copper foil onto a core tube.
- FIG. 1 shows a state in which a copper foil 2 is wound around a winding core tube 1.
- the core tube 1 usually uses ABS, FRP rolls coated with epoxy resin or NBR, and phenol resin, but if the material has a certain level of wettability and does not soak water, aqueous solution or organic solvent, It is not necessarily limited to this roll.
- two tapes 3 and 4 having a small width and having the same length as the width of the copper foil 2 are prepared, and the length is copper.
- One wide adhesive backup tape 2 longer than the width of the foil is prepared.
- the size of the double-sided adhesive tapes 3 and 4 is not particularly limited, but can be changed depending on the size of the copper foil 2 and the size of the core tube 1. Usually, a double-sided adhesive tape with a width of 10 to 50 mm is used. As shown in FIG. 1, the first and second double-sided adhesive tapes 3 and 4 are attached to the surface of the core tube in parallel with the core tube axis with a gap therebetween. The gap between the first and second double-sided adhesive tapes 3 and 4 is optional, but is preferably 0.1 to 30 mm in consideration of efficiency. Next, as shown in FIG. 2, the copper foil 2 is applied with the first double-sided adhesive tape 3 as the starting end, and the copper foil 2 is opposite to the direction in which the adjacent second double-sided adhesive tape 4 exists.
- the core tube 1 is rotated so that the foil 2 goes around.
- the rotation reaches the position where the second double-sided adhesive tape 4 is present, the copper foil 2 is attached to the second double-sided adhesive tape 4 as shown in FIG.
- the rotation of the core tube is stopped at this point.
- the length is longer than the width of the copper foil 2 from above the first and second double-sided adhesive tapes 3, 4 and the copper foil 2 circulated thereon.
- a wide adhesive backup tape 5 is attached onto the core tube 1. Then, winding is continued.
- the wide adhesive backup tape 5 has adhesiveness on one side (attached surface).
- the strength of the application increases greatly, so that the winding tension can be increased. Thereby, generation
- the step generated by the narrow double-sided adhesive tapes 3 and 4 is alleviated by the wide adhesive backup tape 5, there is a great advantage that the step becomes inconspicuous.
- the width of the wide adhesive backup tape 5 is preferably 25 to 150 mm. As shown in FIG. 1, the width of the wide adhesive backup tape 5 is longer than the width of the copper foil and larger than the width of the double-sided adhesive tapes 3 and 4 and the gap between them. If it is a thing, although it does not restrict
- this double-sided tape is removed.
- the copper foil may be cut off, or conversely, the removal may be incomplete and the double-sided tape may remain.
- the copper foil is cut off, it is necessary to rewind it, and when it is wound up as it is, wrinkles are generated from it.
- the double-sided tape remains, dust adheres to the double-sided tape, causing contamination of the copper foil.
- the backup tape is used as in the present invention, it is not necessary to remove the double-sided tape, and the adhesive of the double-sided tape is covered.
- the wide adhesive backup tape 5 may be an adhesive backup tape having a length of 25 to 150 mm protruding from both ends of the copper foil.
- the double-sided adhesive tape with release paper may be attached to the core tube in advance. This has the advantage that the operation is not concentrated and simpler. As described above, the winding is not loosened or the winding is not broken. Further, when winding and unwinding (rewinding), winding of the copper foil product is not loosened or winding is not broken, and the copper foil can be used continuously.
- Example 1 A copper foil having a thickness of 12 ⁇ m and a width of 1280 mm is wound around a core tube having an outer diameter of 110 mm and a length of 1380 mm.
- Two tapes with a double-sided adhesive having a width of 15 mm and a length of 1285 mm longer than the width of the copper foil were prepared, and a core tube was attached as shown in FIGS. 1 and 2.
- the first and second double-sided adhesive tapes each had a gap of 2 mm.
- a wide adhesive backup tape having a width of 50 mm and a length of 25 mm protruding from both ends of the copper foil was prepared.
- the core tube is rotated so that the copper foil goes around the core tube, and the copper foil is attached to the double-sided adhesive tape at the position of the second double-sided adhesive tape, Furthermore, as shown in FIG.1 and FIG.4, the wide adhesive backup tape was stuck and fixed from there. Then, the film was wound for 700 to 900 m at a tension of 27 kg and a winding speed of 60 m / min. After starting winding, the presence or absence of defects such as wrinkles was confirmed at 5 to 50 m, and in the case of defects, copper foil was attached to the core again.
- the defect occurrence rate was as low as 1.0%, the product rate reached 99.9%, and the winding deviation occurrence rate was as low as 0.04%. Good results were obtained as compared with Comparative Examples described later.
- the film was wound for 700 to 900 m at a tension of 27 kg and a winding speed of 60 m / min.
- the presence or absence of defects such as wrinkles was confirmed at 5 to 50 m, and in the case of defects, copper foil was attached to the core again.
- the number of winding failures such as wrinkles and the length of the copper foil discarded at that time were recorded, and the failure occurrence rate, product rate, and winding deviation occurrence rate were obtained.
- the present invention suppresses the generation of wrinkles and buggy during winding of a copper foil or a copper-clad laminate, increases the winding tension, and prevents collapse, thereby improving product yield and improving productivity. In this way, it is possible to reduce the deterioration of the quality of the copper foil or the copper-clad laminate due to the step generated during winding, and to use the copper foil of the part as a product. By doing this, the product yield can be improved and the productivity can be improved.
- This is useful as a winding material for copper foil or copper-clad laminate used as a mounting material for electronic components such as flexible printed circuit boards, TAB, and COF (Chip on Film).
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Replacement Of Web Rolls (AREA)
- Storage Of Web-Like Or Filamentary Materials (AREA)
- Laminated Bodies (AREA)
- Winding, Rewinding, Material Storage Devices (AREA)
Abstract
Description
この特許文献1では、銅箔を芯管に離型紙付両面接着テープを用いて巻き付けし、巻取りロール状とする巻取り方法で、2個の離型紙付両面接着テープを用いて、固定するものである。
この段差は、銅箔をうまく貼り付けなかった場合又はきれいに切断しなかったような場合に発生するが、巻取りを行う銅箔の始端の発生はどうしても生ずるので、止むを得ない事情と言える。
1.芯管への銅箔又は銅張り積層板の巻取りに際し、長さが銅箔又は銅張り積層板の幅と同一長さである小幅の両面接着剤付テープを2本と、長さが銅箔又は銅張り積層板の幅よりも長い広幅の粘着性のバックアップテープ1本を用意し、1本目と2本目の両面接着剤付テープを、それぞれ隙間を空けて芯管の表面へ芯管軸と平行に貼り付け、次に銅箔又は銅張り積層板を1本目の両面接着剤付テープを始端として貼り付け、隣り合う2本目の両面接着剤付テープが存在する方向とは逆方向に銅箔又は銅張り積層板が周回するように芯管を回転させ、2本目の両面接着剤付テープが存在する位置に至ったところで、銅箔又は銅張り積層板を2本目の両面接着剤付テープを貼り付けると共に、この地点で芯管の回転を停止させ、さらに1本目と2本目の両面接着剤付テープとその上に周回された銅箔又は銅張り積層板の上から、前記長さが銅箔又は銅張り積層板の幅よりも長い広幅の粘着性のバックアップテープを芯管上へ貼り付けた後、巻取りを継続することを特徴とする銅箔又は銅張り積層板の巻取り方法
2.両面接着剤付テープの幅を10~50mmとすることを特徴とする上記1記載の銅箔の巻取り方法
3.1本目と2本目の両面接着剤付テープの隙間を0.1~30mmとすることを特徴とする上記1又は2記載の銅箔又は銅張り積層板の巻取り方法
4.広幅の粘着性のバックアップテープの幅を25~150mmとすることを特徴とする上記1~3のいずれか一項に記載の銅箔又は銅張り積層板の巻取り方法
5.広幅の粘着性のバックアップテープの長さが銅箔又は銅張り積層板の両端からそれぞれ25~500mm突出する長さの粘着性のバックアップテープを使用することを特徴とする上記1~4のいずれか一項に記載の銅箔又は銅張り積層板の巻取り方法
6.離型紙付両面接着剤付テープを使用し、巻取り操作を開始する前に、離型紙付両面接着剤付テープを芯管に予め貼り付けておくことを特徴とする上記1~5のいずれか一項に記載の銅箔又は銅張り積層板の巻取り方法を、提供する。
なお、本願発明は銅又は銅張り積層板に適用できるものであるが、以下の例では代表的に銅箔を用いて説明することとする。なお、当然のことではあるが、以下に説明する例において「銅箔」を「銅張り積層板」に置き換えることにより、銅張り積層板にも適用できることは容易に理解されるべきことである。
芯管1への銅箔2の巻取りに際しては、長さが銅箔2の幅と同一長さである小幅の両面接着剤付テープ3、4を2本用意し、また、長さが銅箔の幅よりも長い広幅の粘着性のバックアップテープ2を1本用意する。
1本目と2本目の両面接着剤付テープ3、4を、図1に示すように、それぞれ隙間を空けて、芯管の表面へ芯管軸と平行に貼り付ける。1本目と2本目の両面接着剤付テープ3、4の隙間も任意であるが、効率を考慮して0.1~30mmとするのが良い。
次に、図2に示すように、銅箔2を1本目の両面接着剤付テープ3を始端として貼り付け、隣り合う2本目の両面接着剤付テープ4が存在する方向とは逆方向に銅箔2が周回(一巡)するように芯管1を回転させる。
この回転により、2本目の両面接着剤付テープ4が存在する位置に至ったところで、図3に示すように、銅箔2を2本目の両面接着剤付テープ4に貼り付ける。同時に、この地点で芯管の回転を停止させる。
また、この広幅の粘着性のバックアップテープ5を貼り付けた後は、貼り付けの強度が大きく増すので、巻取りのテンション(張力)を上げることができる。これによってしわの発生や凸部の形成を抑制できる。
また、狭幅の両面接着剤付テープ3、4により発生する段差は、広幅の粘着性のバックアップテープ5によって緩和されるので、段差が目立たなくなるという大きな利点がある。
しかし、本願発明のように、バックアップテープを用いると、両面テープの除去が不要であり、両面テープの粘着剤を覆うことになるので、ごみの付着も防止できるという大きな効果を有する。
以上により、巻取りが緩むことあるいは巻き重ねが崩れることがない。また、巻きほごし(巻き戻し)に際しても、銅箔製品の巻取りが緩むことあるいは巻き重ねが崩れることはなく、銅箔の連続した使用が可能である。
(実施例)
厚さ12μm、幅1280mmの銅箔を、外形φ110mm、長さ1380mmの芯管に巻き取る。
幅が15mmであり、長さは銅箔の幅より長い1285mmとした両面接着剤付テープを2本用意し、これを図1及び図2に示すように芯管の貼付けた。1本目と2本目の両面接着剤付テープは、図1及び図2に示すように、それぞれ隙間2mmとした。
この他、幅50mmとし、銅箔の両端からそれぞれ25mm突出する長さの広幅の粘着性のバックアップテープを準備した。
そしてテンション27kg、巻き取り速度60m/minで700-900m巻き取った。巻き取り開始後、5mから50mで、しわ等の不良の有無を確認し、不良の場合は、再度、コアへ銅箔の貼り付けを実施した。
不良発生率=不良発生回数/製品ロール本数 ×100(%)
製品率=(製品長さ)/(製品長さ+廃棄した銅箔長さ)×100 (%)
巻きずれ発生率=巻きずれ発生ロール(本)/製品ロール(本)×100(%)この結果を表1に示す。
次に、バックアップテープ無しで巻取りを行った結果を示す。バックアップテープを使用しないこと以外は、実施例と同一条件とした。
すなわち、 図3に示すように、銅箔を芯管の周囲に一巡するように、芯管を回転し、2個目の両面接着剤付テープの位置で、銅箔を両面接着剤付テープに貼付け、さらにその上から、図1及び図4に示すように広幅の粘着性のバックアップテープを貼付け固定した。
そして、実施例と同様に、しわ等の巻付け不良が発生した回数、その時廃棄した銅箔の長さを記録し、不良発生率、製品率及び巻きずれ発生率を求めた。
これは実施例に比べ明らかに不良であり、これはバックアップテープを用いなかった結果である。したがって、バックアップテープという簡単な構造でありながら、その存在の有無は、製品に大きな影響を与えることが分かった。
2:銅箔
3:両面接着剤付テープ(1本目)
4:両面接着剤付テープ(2本目)
5:バックアップテープ
Claims (6)
- 芯管への銅箔又は銅張り積層板の巻取りに際し、長さが銅箔の幅と同一長さであるか、あるいは若干長い小幅の両面接着剤付テープを2本と、長さが前記両面接着剤付テープ及び銅箔又は銅張り積層板の幅よりも長い広幅の粘着性のバックアップテープ1本を用意し、1本目と2本目の両面接着剤付テープを、それぞれ隙間を空けて芯管の表面へ芯管軸と平行に貼り付け、次に銅箔又は銅張り積層板を1本目の両面接着剤付テープを始端として貼り付け、隣り合う2本目の両面接着剤付テープが存在する方向とは逆方向に銅箔又は銅張り積層板が周回するように芯管を回転させ、2本目の両面接着剤付テープが存在する位置に至ったところで、銅箔又は銅張り積層板を2本目の両面接着剤付テープを貼り付けると共に、この地点で芯管の回転を停止させ、さらに1本目と2本目の両面接着剤付テープとその上に周回された銅箔又は銅張り積層板の上から、前記長さが銅箔又は銅張り積層板の幅よりも長い広幅の粘着性のバックアップテープを芯管上へ貼り付けた後、巻取りを継続することを特徴とする銅箔又は銅張り積層板の巻取り方法。
- 両面接着剤付テープの幅を10~50mmとすることを特徴とする請求項1記載の銅箔又は銅張り積層板の巻取り方法。
- 1本目と2本目の両面接着剤付テープの隙間を0.1~30mmとすることを特徴とする請求項1又は2記載の銅箔又は銅張り積層板の巻取り方法。
- 広幅の粘着性のバックアップテープの幅を25~150mmとすることを特徴とする請求項1~3のいずれか一項に記載の銅箔又は銅張り積層板の巻取り方法。
- 広幅の粘着性のバックアップテープの長さが銅箔又は銅張り積層板の両端からそれぞれ25~150mm突出する長さの粘着性のバックアップテープを使用することを特徴とする請求項1~4のいずれか一項に記載の銅箔又は銅張り積層板の巻取り方法。
- 離型紙付両面接着剤付テープを使用し、巻取り操作を開始する前に、離型紙付両面接着剤付テープを芯管に予め貼り付けておくことを特徴とする請求項1~5のいずれか一項に記載の銅箔又は銅張り積層板の巻取り方法。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020117011649A KR101220595B1 (ko) | 2008-11-25 | 2009-11-13 | 동박 또는 동장 적층판의 권취 방법 |
JP2010540446A JP5236745B2 (ja) | 2008-11-25 | 2009-11-13 | 銅箔又は銅張り積層板の巻取り方法 |
EP09828985A EP2366469A1 (en) | 2008-11-25 | 2009-11-13 | Method of winding up copper foil or copper-clad laminate |
US13/130,240 US20110233320A1 (en) | 2008-11-25 | 2009-11-13 | Method of winding up copper foil or copper clad laminate |
CN2009801468571A CN102223960B (zh) | 2008-11-25 | 2009-11-13 | 铜箔或覆铜层压板的卷绕方法 |
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JP2008299446 | 2008-11-25 | ||
JP2008-299446 | 2008-11-25 |
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WO2010061737A1 true WO2010061737A1 (ja) | 2010-06-03 |
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Family Applications (1)
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PCT/JP2009/069346 WO2010061737A1 (ja) | 2008-11-25 | 2009-11-13 | 銅箔又は銅張り積層板の巻取り方法 |
Country Status (7)
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US (1) | US20110233320A1 (ja) |
EP (1) | EP2366469A1 (ja) |
JP (1) | JP5236745B2 (ja) |
KR (1) | KR101220595B1 (ja) |
CN (1) | CN102223960B (ja) |
TW (1) | TW201020039A (ja) |
WO (1) | WO2010061737A1 (ja) |
Cited By (1)
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CN104707877A (zh) * | 2013-12-17 | 2015-06-17 | 上海梅山钢铁股份有限公司 | 一种高强度、低温、厚规格热轧板带卷形控制方法 |
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- 2009-11-13 US US13/130,240 patent/US20110233320A1/en not_active Abandoned
- 2009-11-13 CN CN2009801468571A patent/CN102223960B/zh not_active Expired - Fee Related
- 2009-11-13 WO PCT/JP2009/069346 patent/WO2010061737A1/ja active Application Filing
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CN104707877A (zh) * | 2013-12-17 | 2015-06-17 | 上海梅山钢铁股份有限公司 | 一种高强度、低温、厚规格热轧板带卷形控制方法 |
CN104707877B (zh) * | 2013-12-17 | 2017-07-14 | 上海梅山钢铁股份有限公司 | 一种高强度、低温、厚规格热轧板带卷形控制方法 |
Also Published As
Publication number | Publication date |
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TW201020039A (en) | 2010-06-01 |
JPWO2010061737A1 (ja) | 2012-04-26 |
JP5236745B2 (ja) | 2013-07-17 |
CN102223960A (zh) | 2011-10-19 |
CN102223960B (zh) | 2013-09-04 |
KR101220595B1 (ko) | 2013-01-10 |
EP2366469A1 (en) | 2011-09-21 |
US20110233320A1 (en) | 2011-09-29 |
KR20110074783A (ko) | 2011-07-01 |
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