WO2010053864A1 - Process for making porous activated carbon - Google Patents

Process for making porous activated carbon Download PDF

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Publication number
WO2010053864A1
WO2010053864A1 PCT/US2009/062961 US2009062961W WO2010053864A1 WO 2010053864 A1 WO2010053864 A1 WO 2010053864A1 US 2009062961 W US2009062961 W US 2009062961W WO 2010053864 A1 WO2010053864 A1 WO 2010053864A1
Authority
WO
WIPO (PCT)
Prior art keywords
carbon
cycle
activating agent
heating cycle
activated carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2009/062961
Other languages
English (en)
French (fr)
Inventor
Kishor P Gadkaree
Jia Liu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corning Inc
Original Assignee
Corning Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corning Inc filed Critical Corning Inc
Priority to EP09825278.6A priority Critical patent/EP2362851B1/en
Priority to JP2011535614A priority patent/JP5400892B2/ja
Publication of WO2010053864A1 publication Critical patent/WO2010053864A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/34—Carbon-based characterised by carbonisation or activation of carbon
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/30—Active carbon
    • C01B32/312—Preparation
    • C01B32/342—Preparation characterised by non-gaseous activating agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/30—Active carbon
    • C01B32/312—Preparation
    • C01B32/342—Preparation characterised by non-gaseous activating agents
    • C01B32/348—Metallic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors

Definitions

  • the present invention relates to a process for making porous activated carbon and more specifically to a two-cycle carbonization/activation process for making porous activated carbon materials.
  • the invention relates also to porous activated carbon made according to the inventive process.
  • Energy storage devices such as electric - also called electrochemical - double layer capacitors (EDLCs), a.k.a. supercapacitors or ultracapacitors may be used in many applications where a discrete power pulse is required. Such applications range from cell phones to electric/hybrid vehicles.
  • EDLCs electrochemical - double layer capacitors
  • An important characteristic of an energy storage device is the energy density that it can provide.
  • the energy density of the device which typically comprises one or more carbon-based electrode(s) separated by a porous separator and/or an organic or inorganic electrolyte, is largely determined by the properties of the carbon-based electrodes and, thus, by the properties of the carbon material used to form the electrodes.
  • a first cycle comprises heating a mixture of a carbon precursor and a chemical additive at a first (intermediate) temperature, followed by a second cycle in which the material derived from the first cycle is heated at a second (elevated) carbonization/activation temperature.
  • the mixture heated in the first cycle comprises a cured mixture.
  • a 3 1 KOH:phenolic resin mixture was cured in the manner described above.
  • a known quantity (25 grams) of the cured mixture was initially processed through a first heating cycle in a first furnace in which the furnace temperature was increased at 200°C/hr to 460°C, held at 460 0 C for 2 hours, and then cooled down naturally.
  • the resulting (volume-expanded) material was ground into a powder, the volume of which was about the same as that of the cured mixture prior to the first cycle.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Power Engineering (AREA)
  • Materials Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Carbon And Carbon Compounds (AREA)
PCT/US2009/062961 2008-11-04 2009-11-02 Process for making porous activated carbon Ceased WO2010053864A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP09825278.6A EP2362851B1 (en) 2008-11-04 2009-11-02 Process for making porous activated carbon
JP2011535614A JP5400892B2 (ja) 2008-11-04 2009-11-02 多孔質の活性炭の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/264,348 US8252716B2 (en) 2008-11-04 2008-11-04 Process for making porous activated carbon
US12/264,348 2008-11-04

Publications (1)

Publication Number Publication Date
WO2010053864A1 true WO2010053864A1 (en) 2010-05-14

Family

ID=42131647

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/062961 Ceased WO2010053864A1 (en) 2008-11-04 2009-11-02 Process for making porous activated carbon

Country Status (4)

Country Link
US (1) US8252716B2 (enExample)
EP (1) EP2362851B1 (enExample)
JP (1) JP5400892B2 (enExample)
WO (1) WO2010053864A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013049086A3 (en) * 2011-09-28 2013-08-08 Corning Incorporated Method for making alkali activated carbon
CN104140100A (zh) * 2014-08-18 2014-11-12 福建师范大学 一种真空冷冻干燥制备气体吸附用微孔活性炭的方法

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102000545A (zh) * 2010-10-21 2011-04-06 桂林理工大学 氯化铝改性蔗渣活性炭的制备方法
US10087405B2 (en) 2013-06-28 2018-10-02 3M Innovative Properties Company Wipe with a guanidinyl-containing polymer
US20150110707A1 (en) * 2013-10-22 2015-04-23 Corning Incorporated Process for making chemically activated carbon
US20160023910A1 (en) 2014-07-23 2016-01-28 Corning Incorporated Apparatus and method of making alkali activated carbon
CN105692580B (zh) * 2014-11-28 2018-08-21 中国科学院大连化学物理研究所 一种多孔碳材料及其制备和应用
KR101689479B1 (ko) * 2015-10-15 2016-12-23 지에스에너지 주식회사 전기이중층 커패시터 전극용 활성탄 및 이의 제조방법
WO2017192728A1 (en) 2016-05-03 2017-11-09 Virginia Commonwealth University Heteroatom -doped porous carbons for clean energy applications and methods for their synthesis
CN106887340A (zh) * 2017-03-24 2017-06-23 桂林电子科技大学 一种基于胞嘧啶的掺氮多孔碳材料及其制备方法和应用
US10090117B1 (en) * 2018-01-16 2018-10-02 King Saud University Method of making a porous nano-carbon electrode from biomass
CN108947533B (zh) * 2018-08-31 2022-02-15 万华化学集团股份有限公司 一种多孔炭材料的制备方法及得到的多孔炭材料的用途
CN109336109A (zh) * 2018-10-31 2019-02-15 广东韩研活性炭科技股份有限公司 一种活性炭的制备方法
CN110002425A (zh) * 2019-04-22 2019-07-12 天津大学 一种离子液体超级电容器用三维多孔碳材料的制备方法
CN110255558A (zh) * 2019-05-27 2019-09-20 榆林学院 一种利用物理化学活化法制备活性炭的方法
CN110247064B (zh) * 2019-06-26 2023-01-20 中国林业科学研究院林产化学工业研究所 一种速生构树制备催化氧还原反应(orr)活性炭的新方法
CN113120904B (zh) * 2019-12-31 2022-11-11 中国石油化工股份有限公司 一种活性炭处理方法
CN111422871B (zh) * 2020-03-31 2022-03-29 大连理工大学 一种多效串联负压热解制备高品质活性炭联产合成气的工艺
CN111841494A (zh) * 2020-07-02 2020-10-30 江苏竹溪活性炭有限公司 空气净化用活性炭
US12110456B2 (en) 2020-08-28 2024-10-08 Florrent, Inc. Biomass-based method and composition
CN111892069B (zh) * 2020-08-28 2022-05-24 江苏理工学院 一种针状C-Na2CO3的制备方法
CN112093799B (zh) * 2020-09-22 2023-09-22 广东金甸种植有限公司 一种种植用活性碳、含活性碳的肥料的制备方法和应用
CN112592495A (zh) * 2021-01-05 2021-04-02 天津科技大学 一种木质基微球及其活性炭球的制备方法
KR102684620B1 (ko) * 2022-03-14 2024-07-15 충남대학교산학협력단 계층적 기공구조를 포함하는 활성탄 및 이의 제조방법
CN114538435B (zh) * 2022-03-14 2023-09-19 桂东县湘浙活性炭有限公司 一种用于油料加工的植物活性炭的制备方法
CN119038547B (zh) * 2024-10-28 2025-01-28 河津市华辉杰能源有限公司 一种活性炭加工装置

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4082694A (en) 1975-12-24 1978-04-04 Standard Oil Company (Indiana) Active carbon process and composition
US4656153A (en) * 1983-02-28 1987-04-07 Standard Oil Company (Indiana) Active carbon containing a dispersion of a metal component and method for making same
US4753717A (en) * 1985-03-25 1988-06-28 Kanebo Ltd. Porous article having open pores prepared from aromatic condensation polymer and use thereof
US4775655A (en) * 1985-11-18 1988-10-04 Internationale Octrooi Maatschappij "Octropa" Porous carbon structures and methods for their preparation
EP0467486A1 (en) 1990-07-20 1992-01-22 Ucar Carbon Technology Corporation Process for producing high surface area activated carbon
EP0774296A2 (en) 1995-11-17 1997-05-21 Corning Incorporated Method of making activated carbon bodies having improved adsorption properties
US5882621A (en) * 1995-12-07 1999-03-16 Sandia Corporation Method of preparation of carbon materials for use as electrodes in rechargeable batteries
US6241956B1 (en) * 1997-08-27 2001-06-05 Nisshinbo Industries, Inc. Glassy carbon and process for production thereof
US20020027305A1 (en) * 1997-10-17 2002-03-07 Nec Corporation Activated carbon/carbon composite electrode suitable as a polarizable electrode for use in an electric double-layer capacitor and method of producing the same
US20020048144A1 (en) * 2000-07-25 2002-04-25 Kuraray Co., Ltd. Kurashiki-Shi Japan Activated carbon, process for producing the same, polarizable electrode, and electric double layer capacitor
US20030161781A1 (en) * 2001-10-01 2003-08-28 Israel Cabasso Novel carbon materials and carbon/carbon composites based on modified poly (phenylene ether) for energy production and storage devices, and methods of making them

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61222916A (ja) * 1985-03-29 1986-10-03 Kanebo Ltd 多孔性活性炭の製造法
JPH0630260B2 (ja) * 1985-03-25 1994-04-20 鐘紡株式会社 有機電解質電池
JPH02302308A (ja) * 1989-02-08 1990-12-14 Osaka Gas Co Ltd 活性炭の製造方法
US5451444A (en) * 1993-01-29 1995-09-19 Deliso; Evelyn M. Carbon-coated inorganic substrates
JP3854333B2 (ja) * 1996-02-02 2006-12-06 日本エンバイロケミカルズ株式会社 電気二重層コンデンサの電極用活性炭およびその製造法
DE69709047T2 (de) * 1996-08-28 2003-04-03 Nisshinbo Industries, Inc. Glasartiger kohlenstoff und verfahren zu dessen herstellung
US6156697A (en) * 1997-11-04 2000-12-05 Corning Incorporated Method of producing high surface area carbon structures
JP4877441B2 (ja) * 2000-07-25 2012-02-15 株式会社クラレ 活性炭、その製造方法、分極性電極及び電気二重層キャパシタ
JP2003168635A (ja) * 2001-11-30 2003-06-13 Asahi Kasei Corp 電気二重層キャパシタ電極用活性炭
JP4392223B2 (ja) * 2003-10-31 2009-12-24 Ｊｆｅケミカル株式会社 活性炭の製造方法およびその製造装置
US7799733B2 (en) * 2004-03-31 2010-09-21 Council Of Scientific And Industrial Research Process for preparing high surface area carbon
US7893004B2 (en) * 2004-09-06 2011-02-22 Japan Envirochemicals, Ltd. Oxidation reaction catalyst and process for producing a compound using the same
US7722705B2 (en) * 2006-05-11 2010-05-25 Corning Incorporated Activated carbon honeycomb catalyst beds and methods for the use thereof
US8541338B2 (en) * 2008-11-04 2013-09-24 Corning Incorporated Highly porous activated carbon with controlled oxygen content
JP5027849B2 (ja) * 2009-06-30 2012-09-19 関西熱化学株式会社 活性炭の製造方法、および該製造方法により得られた活性炭を用いた電気二重層キャパシタ

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4082694A (en) 1975-12-24 1978-04-04 Standard Oil Company (Indiana) Active carbon process and composition
US4656153A (en) * 1983-02-28 1987-04-07 Standard Oil Company (Indiana) Active carbon containing a dispersion of a metal component and method for making same
US4753717A (en) * 1985-03-25 1988-06-28 Kanebo Ltd. Porous article having open pores prepared from aromatic condensation polymer and use thereof
US4775655A (en) * 1985-11-18 1988-10-04 Internationale Octrooi Maatschappij "Octropa" Porous carbon structures and methods for their preparation
EP0467486A1 (en) 1990-07-20 1992-01-22 Ucar Carbon Technology Corporation Process for producing high surface area activated carbon
EP0774296A2 (en) 1995-11-17 1997-05-21 Corning Incorporated Method of making activated carbon bodies having improved adsorption properties
US5882621A (en) * 1995-12-07 1999-03-16 Sandia Corporation Method of preparation of carbon materials for use as electrodes in rechargeable batteries
US6241956B1 (en) * 1997-08-27 2001-06-05 Nisshinbo Industries, Inc. Glassy carbon and process for production thereof
US20020027305A1 (en) * 1997-10-17 2002-03-07 Nec Corporation Activated carbon/carbon composite electrode suitable as a polarizable electrode for use in an electric double-layer capacitor and method of producing the same
US20020048144A1 (en) * 2000-07-25 2002-04-25 Kuraray Co., Ltd. Kurashiki-Shi Japan Activated carbon, process for producing the same, polarizable electrode, and electric double layer capacitor
US20030161781A1 (en) * 2001-10-01 2003-08-28 Israel Cabasso Novel carbon materials and carbon/carbon composites based on modified poly (phenylene ether) for energy production and storage devices, and methods of making them

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2362851A4

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013049086A3 (en) * 2011-09-28 2013-08-08 Corning Incorporated Method for making alkali activated carbon
US8809231B2 (en) 2011-09-28 2014-08-19 Corning Incorporated Method for making alkali activated carbon
CN104140100A (zh) * 2014-08-18 2014-11-12 福建师范大学 一种真空冷冻干燥制备气体吸附用微孔活性炭的方法
CN104140100B (zh) * 2014-08-18 2016-08-24 福建师范大学 一种真空冷冻干燥制备气体吸附用微孔活性炭的方法

Also Published As

Publication number Publication date
EP2362851A1 (en) 2011-09-07
EP2362851B1 (en) 2017-02-15
EP2362851A4 (en) 2014-01-22
JP2012507470A (ja) 2012-03-29
US8252716B2 (en) 2012-08-28
JP5400892B2 (ja) 2014-01-29
US20100111811A1 (en) 2010-05-06

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