WO2010014151A3 - Production directe et selective d’ethanol a partir d’acide acetique au moyen d’un catalyseur platine/etain - Google Patents
Production directe et selective d’ethanol a partir d’acide acetique au moyen d’un catalyseur platine/etain Download PDFInfo
- Publication number
- WO2010014151A3 WO2010014151A3 PCT/US2009/004195 US2009004195W WO2010014151A3 WO 2010014151 A3 WO2010014151 A3 WO 2010014151A3 US 2009004195 W US2009004195 W US 2009004195W WO 2010014151 A3 WO2010014151 A3 WO 2010014151A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ethanol
- acetic acid
- platinum
- direct
- selective production
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8966—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/08—Ethanol
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
UAA201101076A UA100576C2 (ru) | 2008-07-31 | 2009-07-20 | Прямое и селективное получение этилового спирта из уксусной кислоты с применением катализатора, который содержит платину и олово |
ES09788951T ES2382984T3 (es) | 2008-07-31 | 2009-07-20 | Producción directa y selectiva de etanol a partir de ácido acético utilizando un catalizador de platino/estaño |
JP2011521095A JP5611205B2 (ja) | 2008-07-31 | 2009-07-20 | 白金/スズ触媒を用いる酢酸からのエタノールの直接且つ選択的な製造 |
CA2732359A CA2732359C (fr) | 2008-07-31 | 2009-07-20 | Production directe et selective d'ethanol a partir d'acide acetique au moyen d'un catalyseur platine/etain |
AT09788951T ATE547391T1 (de) | 2008-07-31 | 2009-07-20 | Direkte und selektive herstellung von ethanol aus essigsäure unter verwendung eines platin/zinn- katalysators |
NZ591029A NZ591029A (en) | 2008-07-31 | 2009-07-20 | Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst |
AU2009277189A AU2009277189B2 (en) | 2008-07-31 | 2009-07-20 | Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst |
EP09788951A EP2318343B1 (fr) | 2008-07-31 | 2009-07-20 | Production directe et selective d'ethanol a partir d'acide acetique au moyen d'un catalyseur platine/etain |
CN200980134831.5A CN102149661B (zh) | 2008-07-31 | 2009-07-20 | 使用铂/锡催化剂由乙酸直接选择性制备乙醇 |
DK09788951.3T DK2318343T3 (da) | 2008-07-31 | 2009-07-20 | Direkte og selektiv fremstilling af ethanol ud fra eddikesyre under anvendelse af en platin/tin-katalysator |
PL09788951T PL2318343T3 (pl) | 2008-07-31 | 2009-07-20 | Mieszanki antyozonantu |
IL210945A IL210945A0 (en) | 2008-07-31 | 2011-01-30 | Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst |
ZA2011/00792A ZA201100792B (en) | 2008-07-31 | 2011-01-31 | Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/221,141 US7863489B2 (en) | 2008-07-31 | 2008-07-31 | Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst |
US12/221,141 | 2008-07-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010014151A2 WO2010014151A2 (fr) | 2010-02-04 |
WO2010014151A3 true WO2010014151A3 (fr) | 2010-05-27 |
Family
ID=41354066
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2009/004195 WO2010014151A2 (fr) | 2008-07-31 | 2009-07-20 | Production directe et selective d’ethanol a partir d’acide acetique au moyen d’un catalyseur platine/etain |
Country Status (22)
Country | Link |
---|---|
US (3) | US7863489B2 (fr) |
EP (3) | EP2392556A3 (fr) |
JP (2) | JP5611205B2 (fr) |
KR (1) | KR101650966B1 (fr) |
CN (3) | CN102149661B (fr) |
AR (1) | AR074712A1 (fr) |
AT (1) | ATE547391T1 (fr) |
AU (1) | AU2009277189B2 (fr) |
CA (1) | CA2732359C (fr) |
CO (1) | CO6541518A2 (fr) |
DK (1) | DK2318343T3 (fr) |
ES (1) | ES2382984T3 (fr) |
IL (1) | IL210945A0 (fr) |
NZ (2) | NZ591029A (fr) |
PL (1) | PL2318343T3 (fr) |
PT (1) | PT2318343E (fr) |
RU (1) | RU2011107274A (fr) |
SG (2) | SG10201506032XA (fr) |
TW (1) | TWI432406B (fr) |
UA (1) | UA100576C2 (fr) |
WO (1) | WO2010014151A2 (fr) |
ZA (1) | ZA201100792B (fr) |
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US8680342B2 (en) | 2010-05-07 | 2014-03-25 | Celanese International Corporation | Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water |
US8907141B2 (en) | 2011-04-26 | 2014-12-09 | Celanese International Corporation | Process to recover alcohol with secondary reactors for esterification of acid |
US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
US9000233B2 (en) | 2011-04-26 | 2015-04-07 | Celanese International Corporation | Process to recover alcohol with secondary reactors for hydrolysis of acetal |
US9447005B2 (en) | 2010-02-02 | 2016-09-20 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
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US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
US9447005B2 (en) | 2010-02-02 | 2016-09-20 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
US8569551B2 (en) | 2010-05-07 | 2013-10-29 | Celanese International Corporation | Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process |
US8680342B2 (en) | 2010-05-07 | 2014-03-25 | Celanese International Corporation | Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water |
US8907141B2 (en) | 2011-04-26 | 2014-12-09 | Celanese International Corporation | Process to recover alcohol with secondary reactors for esterification of acid |
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