WO2009090179A3 - Procédé pour produire des amines cycloaliphatiques - Google Patents

Procédé pour produire des amines cycloaliphatiques Download PDF

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Publication number
WO2009090179A3
WO2009090179A3 PCT/EP2009/050341 EP2009050341W WO2009090179A3 WO 2009090179 A3 WO2009090179 A3 WO 2009090179A3 EP 2009050341 W EP2009050341 W EP 2009050341W WO 2009090179 A3 WO2009090179 A3 WO 2009090179A3
Authority
WO
WIPO (PCT)
Prior art keywords
cycloaliphatic amines
production
hydrogenation
ruthenium
adjuncts
Prior art date
Application number
PCT/EP2009/050341
Other languages
German (de)
English (en)
Other versions
WO2009090179A2 (fr
Inventor
Joachim Pfeffinger
Willi Doell
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to CN200980102342.1A priority Critical patent/CN101910108B/zh
Priority to JP2010542614A priority patent/JP5449193B2/ja
Priority to EP09701997.0A priority patent/EP2231584B1/fr
Priority to US12/863,137 priority patent/US8987517B2/en
Publication of WO2009090179A2 publication Critical patent/WO2009090179A2/fr
Publication of WO2009090179A3 publication Critical patent/WO2009090179A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
    • C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé pour la production d'amines cycloaliphatiques par hydrogénation des composés aromatiques correspondants à l'aide d'un gaz contenant de l'hydrogène à une température comprise entre 30 et 280°C et une pression comprise entre 50 et 350 bars, en présence de catalyseurs contenant du ruthénium. Le procédé selon l'invention est caractérisé en ce qu'on procède à l'hydrogénation en présence de 1 % à 500 % en poids, par rapport au catalyseur (calculé en tant que ruthénium élémentaire (Ru)), de produits d'addition inorganiques en suspension. L'invention concerne également l'utilisation des amines cycloaliphatiques selon l'invention en tant que synthons.
PCT/EP2009/050341 2008-01-18 2009-01-14 Procédé pour produire des amines cycloaliphatiques WO2009090179A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN200980102342.1A CN101910108B (zh) 2008-01-18 2009-01-14 生产脂环族胺的方法
JP2010542614A JP5449193B2 (ja) 2008-01-18 2009-01-14 脂環式アミンの製造方法
EP09701997.0A EP2231584B1 (fr) 2008-01-18 2009-01-14 Procédé pour produire des amines cycloaliphatiques
US12/863,137 US8987517B2 (en) 2008-01-18 2009-01-14 Process for preparing cycloaliphatic amines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP08150395.5 2008-01-18
EP08150395 2008-01-18

Publications (2)

Publication Number Publication Date
WO2009090179A2 WO2009090179A2 (fr) 2009-07-23
WO2009090179A3 true WO2009090179A3 (fr) 2009-08-27

Family

ID=40585539

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/050341 WO2009090179A2 (fr) 2008-01-18 2009-01-14 Procédé pour produire des amines cycloaliphatiques

Country Status (6)

Country Link
US (1) US8987517B2 (fr)
EP (1) EP2231584B1 (fr)
JP (1) JP5449193B2 (fr)
CN (1) CN101910108B (fr)
TW (1) TWI392667B (fr)
WO (1) WO2009090179A2 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011003899A1 (fr) 2009-07-09 2011-01-13 Basf Se Procédé de transport de liquides
WO2011032877A1 (fr) * 2009-09-18 2011-03-24 Basf Se Utilisation d'un mélange de stéréoisomères de diaminométhylcyclohexane en tant que durcisseur pour résines époxy
CN102030657A (zh) * 2010-11-25 2011-04-27 浙江台州清泉医药化工有限公司 一种3,3′-二甲基-4,4′-二氨基二环己基甲烷的合成方法
WO2012152821A1 (fr) 2011-05-11 2012-11-15 Basf Se Catalyseurs pour l'hydrogénation d'amine aromatique
CN102627569B (zh) * 2012-03-01 2014-04-02 江苏清泉化学有限公司 一种合成3，3′-二甲基-4，4′-二氨基二环己基甲烷的方法
EP2883863B1 (fr) 2013-12-11 2017-05-03 Basf Se Procédé de preparation de 4,4'-dimethylaniline
EP2905273B1 (fr) 2014-02-05 2018-06-06 Covestro Deutschland AG Procédé d'hydrogénation de di- et poly-amines aromatiques
ES2614356T3 (es) 2014-02-05 2017-05-30 Covestro Deutschland Ag Procedimiento de hidrogenación de poliaminas y dipoliaminas aromáticas a poliaminas y dipoliaminas cicloalifáticas
DE102017125891A1 (de) 2016-11-29 2018-06-28 Basf Se Verfahren zur Stabilisierung von zumindest monoalkylsubstituierten Diaminocyclohexanen
CN109996784B (zh) 2016-11-29 2023-06-30 巴斯夫欧洲公司 用于稳定至少单烷基取代的二氨基环己烷的方法
CN108191671B (zh) * 2017-12-29 2021-03-26 本源精化环保科技有限公司 一种还原芳香胺化合物制备脂肪胺的方法
CN108440311B (zh) * 2018-03-29 2020-11-20 万华化学集团股份有限公司 一种加氢制备二氨基二环己基甲烷的方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5214212A (en) * 1992-02-27 1993-05-25 Olin Corporation Promoters for hydrogenation of aromatic amines
DE4404220A1 (de) * 1994-02-10 1995-08-17 Bayer Ag Ruthenium-Katalysatoren, deren Hersellung und ein Verfahren zur Herstellung von cycloaliphatischen Polyaminen unter Verwendung dieser Katalysatoren
DE19533718A1 (de) * 1995-09-12 1997-03-13 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Aminogruppe an einen aromatischen Kern gebunden ist
EP1251119A2 (fr) * 2001-04-19 2002-10-23 Bayer Ag Procédé continu de préparation de diamino dicyclohexyleméthane
EP1369447A1 (fr) * 2002-06-05 2003-12-10 EMS-Chemie AG Masses de moulage transparentes à base de polyamide avec transparence, résistance chimique et stabilité dynamique améliorées

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3864361A (en) * 1973-02-15 1975-02-04 Diamond Shamrock Corp Stereospecific hydrogenation process using unsupported RuO{HD 2 {B catalyst
DE3325895A1 (de) * 1983-07-19 1985-01-31 Basf Ag, 6700 Ludwigshafen Biscyclohexylaminalkane und verfahren zur bekaempfung von pilzen
JP2642696B2 (ja) * 1988-10-11 1997-08-20 工業技術院長 アルミナの比表面積の制御方法
AU3590693A (en) * 1992-02-05 1993-09-03 Olin Corporation Promoters for hydrogenation of aromatic amines
JP3879180B2 (ja) * 1996-06-24 2007-02-07 東レ株式会社 脂肪族ポリアミンの臭気除去方法
DE19827282A1 (de) * 1998-06-19 1999-12-23 Bayer Ag Verfahren zur Herstellung von cycloaliphatischen Aminen
DE10054347A1 (de) * 2000-11-02 2002-05-08 Degussa Verfahren zur katalytischen Hydrierung organischer Verbindungen und Trägerkatalysatoren hierfür
DE10119136A1 (de) * 2001-04-19 2002-11-14 Bayer Ag Ruthenium-Katalysator für die Hydrierung von Diaminodiphenylmethan zu Diaminodicyclohexylmethan
ATE422962T1 (de) * 2002-05-31 2009-03-15 Evonik Degussa Gmbh Geträgerter rutheniumkatalysator und verfahren zur hydrierung eines aromatischen amins in gegenwart dieses katalysators
DE10231119A1 (de) * 2002-07-10 2004-02-05 Degussa Ag Verfahren zur Selektivitätserhöhung der Hydrierung von 4,4'-Diaminodiphenylmethan zu 4,4'-Diaminodicyclohexylmethan in Gegenwart eines N-Alkyl-4,4'-Diaminodiphenylmethans
US7030053B2 (en) * 2002-11-06 2006-04-18 Conocophillips Company Catalyst composition comprising ruthenium and a treated silica support component and processes therefor and therewith for preparing high molecular weight hydrocarbons such as polymethylene
JP2005139241A (ja) * 2003-11-04 2005-06-02 Sanshin Chem Ind Co Ltd アミンを使用した加硫促進剤
US7816458B2 (en) * 2005-11-22 2010-10-19 E. I. Du Pont De Nemours And Company Aqueous dispersions containing ionomer resins and rust-preventive ionomeric coatings made therefrom

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5214212A (en) * 1992-02-27 1993-05-25 Olin Corporation Promoters for hydrogenation of aromatic amines
DE4404220A1 (de) * 1994-02-10 1995-08-17 Bayer Ag Ruthenium-Katalysatoren, deren Hersellung und ein Verfahren zur Herstellung von cycloaliphatischen Polyaminen unter Verwendung dieser Katalysatoren
DE19533718A1 (de) * 1995-09-12 1997-03-13 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Aminogruppe an einen aromatischen Kern gebunden ist
EP1251119A2 (fr) * 2001-04-19 2002-10-23 Bayer Ag Procédé continu de préparation de diamino dicyclohexyleméthane
EP1369447A1 (fr) * 2002-06-05 2003-12-10 EMS-Chemie AG Masses de moulage transparentes à base de polyamide avec transparence, résistance chimique et stabilité dynamique améliorées

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
T.S. CARSWELL ET AL: "Cyclohexylamine and Dicyclohexylamine", INDUSTRIAL AND ENGINEERING CHEMISTRY, vol. 29, no. 11, 10 September 1937 (1937-09-10), pages 1247 - 1251, XP002533816 *

Also Published As

Publication number Publication date
CN101910108A (zh) 2010-12-08
EP2231584B1 (fr) 2013-09-04
US20100292510A1 (en) 2010-11-18
JP2011509970A (ja) 2011-03-31
JP5449193B2 (ja) 2014-03-19
CN101910108B (zh) 2014-07-02
TWI392667B (zh) 2013-04-11
TW200944498A (en) 2009-11-01
EP2231584A2 (fr) 2010-09-29
WO2009090179A2 (fr) 2009-07-23
US8987517B2 (en) 2015-03-24

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