WO2010006386A3 - Procédé catalytique de méthanation de co<sb>2</sb> - Google Patents

Procédé catalytique de méthanation de co<sb>2</sb> Download PDF

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Publication number
WO2010006386A3
WO2010006386A3 PCT/BE2009/000036 BE2009000036W WO2010006386A3 WO 2010006386 A3 WO2010006386 A3 WO 2010006386A3 BE 2009000036 W BE2009000036 W BE 2009000036W WO 2010006386 A3 WO2010006386 A3 WO 2010006386A3
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WO
WIPO (PCT)
Prior art keywords
hydrogen
catalytic
reaction
feed gas
comprised
Prior art date
Application number
PCT/BE2009/000036
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English (en)
Other versions
WO2010006386A2 (fr
Inventor
Patricio Ruiz
Marc Jacquemin
Nathalie Blangenois
Original Assignee
Universite Catholique De Louvain
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Publication date
Application filed by Universite Catholique De Louvain filed Critical Universite Catholique De Louvain
Publication of WO2010006386A2 publication Critical patent/WO2010006386A2/fr
Publication of WO2010006386A3 publication Critical patent/WO2010006386A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

L’invention concerne un procédé de production sélective de méthane avec une sélectivité d’environ 100 % par réaction d’un gaz d’alimentation contenant du CO2, avec de l’hydrogène ou une espèce de l’hydrogène, en présence d’un catalyseur solide de méthanation qui contient moins de 0,2 % en poids de ruthénium. Selon l’invention, la réaction est réalisée à une température inférieure à 150 °C et à une pression comprise entre 104 Pa et 100 105 Pa, le rapport atomique entre le C du CO2 du gaz d’alimentation et l’atome d’hydrogène de l’hydrogène ou de l’espèce de l’hydrogène étant compris entre 0,1 et 6.
PCT/BE2009/000036 2008-07-15 2009-09-15 Procédé catalytique de méthanation de co<sb>2</sb> WO2010006386A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP08447034 2008-07-15
EP08447034.3 2008-07-15

Publications (2)

Publication Number Publication Date
WO2010006386A2 WO2010006386A2 (fr) 2010-01-21
WO2010006386A3 true WO2010006386A3 (fr) 2010-05-20

Family

ID=41550750

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BE2009/000036 WO2010006386A2 (fr) 2008-07-15 2009-09-15 Procédé catalytique de méthanation de co<sb>2</sb>

Country Status (1)

Country Link
WO (1) WO2010006386A2 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103769106A (zh) * 2014-02-20 2014-05-07 厦门大学 原位生长碳纳米管促进的镍基甲烷化催化剂及其制备方法
RU2533710C1 (ru) * 2013-09-23 2014-11-20 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Способ получения метана из атмосферного диоксида углерода
CN106311242A (zh) * 2015-07-06 2017-01-11 中国石油化工股份有限公司 一种二氧化碳甲烷化催化剂及其制备方法
CN106732626A (zh) * 2016-12-17 2017-05-31 段清 一种Co‑Ce‑Cu催化剂、制备方法以及在二氧化碳甲烷化反应中的应用

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013053371A1 (fr) * 2011-10-12 2013-04-18 Solarfuel Gmbh Procédé destiné à préparer un produit gazeux riche en méthane et système approprié
DE102012112705A1 (de) * 2012-12-20 2014-06-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren zur Herstellung von Methanol aus Kohlendioxid
US9757714B2 (en) * 2013-02-27 2017-09-12 Haldor Topsoe A/S Methanation process using stabilized catalyst support comprising transition alumina
US9802872B2 (en) 2013-03-28 2017-10-31 Agency For Science, Technology And Research Methanation catalyst
SG2013050877A (en) 2013-06-28 2015-01-29 Agency Science Tech & Res Methanation catalyst
CN106995735A (zh) * 2017-05-03 2017-08-01 江苏天楹环保能源成套设备有限公司 一种填埋气或沼气的处置系统
JP6786054B2 (ja) * 2017-12-18 2020-11-18 株式会社豊田中央研究所 メタンの製造装置及びそれを用いたメタンの製造方法
EP3873878A4 (fr) * 2018-10-30 2022-08-03 ExxonMobil Chemical Patents Inc. Teneur en ions métalliques du groupe 1 de catalyseurs à tamis moléculaire microporeux
CN110252308B (zh) * 2019-06-21 2022-02-22 山东科技大学 一种活性金属在载体中呈原子级分散的负载型催化剂及其制备方法和用途
CN111729691A (zh) * 2020-05-14 2020-10-02 河南晋煤天庆煤化工有限责任公司 一种甲烷化镍基催化剂的钝化回收再利用方法
PT117138A (pt) * 2021-03-23 2022-09-23 Univ Do Porto Reator adsortivo cíclico e método para valorização de misturas de co2/ch4
CN114768804B (zh) * 2022-04-10 2023-11-10 南京大学 一种固溶体光热催化co2转化反应的应用
CN115504846A (zh) * 2022-09-20 2022-12-23 中国工程物理研究院材料研究所 一种利用电离辐射催化二氧化碳合成气制备有机物的方法

Citations (2)

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US3787468A (en) * 1970-09-01 1974-01-22 Inst Gas Technology Methanation of carbon monoxide and carbon dioxide
US3884838A (en) * 1970-09-01 1975-05-20 Inst Gas Technology Ruthenium-reduced amorphous tungsten oxide catalyst

Family Cites Families (14)

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NL6503410A (fr) 1963-02-21 1965-09-20
US3293192A (en) 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
US3929672A (en) 1971-10-20 1975-12-30 Union Oil Co Ammonia-stable Y zeolite compositions
US4028227A (en) 1974-09-24 1977-06-07 American Cyanamid Company Hydrotreating of petroleum residuum using shaped catalyst particles of small diameter pores
US3962140A (en) 1975-03-10 1976-06-08 The Harshaw Chemical Company Nickel-copper-molybdenum methanation catalyst
US4062809A (en) 1976-03-18 1977-12-13 Union Oil Company Of California Catalyst for production of middle distillate oils
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US4401556A (en) 1979-11-13 1983-08-30 Union Carbide Corporation Midbarrel hydrocracking
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GB8415475D0 (en) 1984-06-18 1984-07-25 Atomic Energy Authority Uk Catalyst device
GB8613131D0 (en) 1986-05-30 1986-07-02 Shell Int Research Hydrocarbon conversion
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US4847231A (en) 1988-06-08 1989-07-11 Gas Research Institute Mixed ruthenium catalyst
ZA200704881B (en) 2004-12-17 2008-09-25 Haldor Topsoe As Hydrocracking process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3787468A (en) * 1970-09-01 1974-01-22 Inst Gas Technology Methanation of carbon monoxide and carbon dioxide
US3884838A (en) * 1970-09-01 1975-05-20 Inst Gas Technology Ruthenium-reduced amorphous tungsten oxide catalyst

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2533710C1 (ru) * 2013-09-23 2014-11-20 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Способ получения метана из атмосферного диоксида углерода
CN103769106A (zh) * 2014-02-20 2014-05-07 厦门大学 原位生长碳纳米管促进的镍基甲烷化催化剂及其制备方法
CN106311242A (zh) * 2015-07-06 2017-01-11 中国石油化工股份有限公司 一种二氧化碳甲烷化催化剂及其制备方法
CN106311242B (zh) * 2015-07-06 2019-03-29 中国石油化工股份有限公司 一种二氧化碳甲烷化催化剂及其制备方法
CN106732626A (zh) * 2016-12-17 2017-05-31 段清 一种Co‑Ce‑Cu催化剂、制备方法以及在二氧化碳甲烷化反应中的应用

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Publication number Publication date
WO2010006386A2 (fr) 2010-01-21

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