WO2010006386A2 - Procédé catalytique de méthanation de co<sb>2</sb> - Google Patents

Procédé catalytique de méthanation de co<sb>2</sb> Download PDF

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Publication number
WO2010006386A2
WO2010006386A2 PCT/BE2009/000036 BE2009000036W WO2010006386A2 WO 2010006386 A2 WO2010006386 A2 WO 2010006386A2 BE 2009000036 W BE2009000036 W BE 2009000036W WO 2010006386 A2 WO2010006386 A2 WO 2010006386A2
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catalyst
advantageously
volume
hydrogen
reaction
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PCT/BE2009/000036
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English (en)
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WO2010006386A3 (fr
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Patricio Ruiz
Marc Jacquemin
Nathalie Blangenois
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Universite Catholique De Louvain
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Publication of WO2010006386A2 publication Critical patent/WO2010006386A2/fr
Publication of WO2010006386A3 publication Critical patent/WO2010006386A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

Abstract

L’invention concerne un procédé de production sélective de méthane avec une sélectivité d’environ 100 % par réaction d’un gaz d’alimentation contenant du CO2, avec de l’hydrogène ou une espèce de l’hydrogène, en présence d’un catalyseur solide de méthanation qui contient moins de 0,2 % en poids de ruthénium. Selon l’invention, la réaction est réalisée à une température inférieure à 150 °C et à une pression comprise entre 104 Pa et 100 105 Pa, le rapport atomique entre le C du CO2 du gaz d’alimentation et l’atome d’hydrogène de l’hydrogène ou de l’espèce de l’hydrogène étant compris entre 0,1 et 6.
PCT/BE2009/000036 2008-07-15 2009-09-15 Procédé catalytique de méthanation de co<sb>2</sb> WO2010006386A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP08447034.3 2008-07-15
EP08447034 2008-07-15

Publications (2)

Publication Number Publication Date
WO2010006386A2 true WO2010006386A2 (fr) 2010-01-21
WO2010006386A3 WO2010006386A3 (fr) 2010-05-20

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PCT/BE2009/000036 WO2010006386A2 (fr) 2008-07-15 2009-09-15 Procédé catalytique de méthanation de co<sb>2</sb>

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WO (1) WO2010006386A2 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013053371A1 (fr) * 2011-10-12 2013-04-18 Solarfuel Gmbh Procédé destiné à préparer un produit gazeux riche en méthane et système approprié
CN103769106A (zh) * 2014-02-20 2014-05-07 厦门大学 原位生长碳纳米管促进的镍基甲烷化催化剂及其制备方法
DE102012112705A1 (de) 2012-12-20 2014-06-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren zur Herstellung von Methanol aus Kohlendioxid
CN105102125A (zh) * 2013-02-27 2015-11-25 托普索公司 稳定的包含过渡态氧化铝的催化剂载体和催化剂
JP2016515470A (ja) * 2013-03-28 2016-05-30 エージェンシー フォー サイエンス， テクノロジー アンド リサーチ メタン化触媒
CN106995735A (zh) * 2017-05-03 2017-08-01 江苏天楹环保能源成套设备有限公司 一种填埋气或沼气的处置系统
US9908104B2 (en) 2013-06-28 2018-03-06 Agency For Science, Technology And Research Methanation catalyst
JP2019108290A (ja) * 2017-12-18 2019-07-04 株式会社豊田中央研究所 メタンの製造装置及びそれを用いたメタンの製造方法
CN110252308A (zh) * 2019-06-21 2019-09-20 山东科技大学 一种活性金属在载体中呈原子级分散的负载型催化剂及其制备方法和用途
WO2020091969A1 (fr) * 2018-10-30 2020-05-07 Exxonmobil Chemical Patents Inc. Teneur en ions métalliques du groupe 1 de catalyseurs à tamis moléculaire microporeux
CN111729691A (zh) * 2020-05-14 2020-10-02 河南晋煤天庆煤化工有限责任公司 一种甲烷化镍基催化剂的钝化回收再利用方法
CN114768804A (zh) * 2022-04-10 2022-07-22 南京大学 一种固溶体光热催化材料的制备方法及应用
WO2022201061A1 (fr) * 2021-03-23 2022-09-29 Universidade Do Porto Réacteur d'adsorption cyclique pour la valorisation de mélanges de co2/ch4
CN115504846A (zh) * 2022-09-20 2022-12-23 中国工程物理研究院材料研究所 一种利用电离辐射催化二氧化碳合成气制备有机物的方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2533710C1 (ru) * 2013-09-23 2014-11-20 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Способ получения метана из атмосферного диоксида углерода
CN106311242B (zh) * 2015-07-06 2019-03-29 中国石油化工股份有限公司 一种二氧化碳甲烷化催化剂及其制备方法
CN106732626B (zh) * 2016-12-17 2019-04-26 南通金源催化剂有限公司 一种Co-Ce-Cu催化剂、制备方法以及在二氧化碳甲烷化反应中的应用

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US3449070A (en) 1963-02-21 1969-06-10 Grace W R & Co Stabilized zeolites
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Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013053371A1 (fr) * 2011-10-12 2013-04-18 Solarfuel Gmbh Procédé destiné à préparer un produit gazeux riche en méthane et système approprié
EP2595942B2 (fr) † 2011-10-12 2017-03-01 ETOGAS GmbH Procédé destiné à préparer un produit gazeux riche en méthane et système approprié
RU2641306C2 (ru) * 2012-12-20 2018-01-17 Л'Эр Ликид, Сосьете Аноним Пур Л'Этюд Э Л'Эксплутасьон Просед Жорж Клод Способ получения метанола из диоксида углерода
DE102012112705A1 (de) 2012-12-20 2014-06-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren zur Herstellung von Methanol aus Kohlendioxid
WO2014096226A1 (fr) * 2012-12-20 2014-06-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procédé de production de méthanol à partir de dioxyde de carbone
CN104903281A (zh) * 2012-12-20 2015-09-09 乔治·克劳德方法的研究开发空气股份有限公司 由二氧化碳生产甲醇的方法
CN104903281B (zh) * 2012-12-20 2017-06-27 乔治·克劳德方法的研究开发空气股份有限公司 由二氧化碳生产甲醇的方法
US9757714B2 (en) * 2013-02-27 2017-09-12 Haldor Topsoe A/S Methanation process using stabilized catalyst support comprising transition alumina
CN105102125A (zh) * 2013-02-27 2015-11-25 托普索公司 稳定的包含过渡态氧化铝的催化剂载体和催化剂
US20150360209A1 (en) * 2013-02-27 2015-12-17 Haldor Topsøes Allé 1 Stabilized catalyst support and catalyst comprising transition aluminia
US9802872B2 (en) 2013-03-28 2017-10-31 Agency For Science, Technology And Research Methanation catalyst
JP2016515470A (ja) * 2013-03-28 2016-05-30 エージェンシー フォー サイエンス， テクノロジー アンド リサーチ メタン化触媒
US9908104B2 (en) 2013-06-28 2018-03-06 Agency For Science, Technology And Research Methanation catalyst
CN103769106A (zh) * 2014-02-20 2014-05-07 厦门大学 原位生长碳纳米管促进的镍基甲烷化催化剂及其制备方法
CN106995735A (zh) * 2017-05-03 2017-08-01 江苏天楹环保能源成套设备有限公司 一种填埋气或沼气的处置系统
JP2019108290A (ja) * 2017-12-18 2019-07-04 株式会社豊田中央研究所 メタンの製造装置及びそれを用いたメタンの製造方法
WO2020091969A1 (fr) * 2018-10-30 2020-05-07 Exxonmobil Chemical Patents Inc. Teneur en ions métalliques du groupe 1 de catalyseurs à tamis moléculaire microporeux
CN110252308A (zh) * 2019-06-21 2019-09-20 山东科技大学 一种活性金属在载体中呈原子级分散的负载型催化剂及其制备方法和用途
CN110252308B (zh) * 2019-06-21 2022-02-22 山东科技大学 一种活性金属在载体中呈原子级分散的负载型催化剂及其制备方法和用途
CN111729691A (zh) * 2020-05-14 2020-10-02 河南晋煤天庆煤化工有限责任公司 一种甲烷化镍基催化剂的钝化回收再利用方法
WO2022201061A1 (fr) * 2021-03-23 2022-09-29 Universidade Do Porto Réacteur d'adsorption cyclique pour la valorisation de mélanges de co2/ch4
CN114768804A (zh) * 2022-04-10 2022-07-22 南京大学 一种固溶体光热催化材料的制备方法及应用
CN114768804B (zh) * 2022-04-10 2023-11-10 南京大学 一种固溶体光热催化co2转化反应的应用
CN115504846A (zh) * 2022-09-20 2022-12-23 中国工程物理研究院材料研究所 一种利用电离辐射催化二氧化碳合成气制备有机物的方法

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