WO2002098230A2 - Verwendung von fettalkoholethoxylaten als penetrationsförderer - Google Patents

Verwendung von fettalkoholethoxylaten als penetrationsförderer Download PDF

Info

Publication number
WO2002098230A2
WO2002098230A2 PCT/EP2002/003618 EP0203618W WO02098230A2 WO 2002098230 A2 WO2002098230 A2 WO 2002098230A2 EP 0203618 W EP0203618 W EP 0203618W WO 02098230 A2 WO02098230 A2 WO 02098230A2
Authority
WO
WIPO (PCT)
Prior art keywords
fatty alcohol
weight
formula
stands
plant treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2002/003618
Other languages
German (de)
English (en)
French (fr)
Other versions
WO2002098230A3 (de
Inventor
Frank Rosenfeldt
Peter Baur
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Bayer CropScience AG
Original Assignee
Bayer AG
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7681227&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2002098230(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to UA20031110186A priority Critical patent/UA77956C2/uk
Priority to PL363174A priority patent/PL206263B1/pl
Priority to MXPA03009191A priority patent/MXPA03009191A/es
Priority to AU2002316826A priority patent/AU2002316826B2/en
Priority to US10/474,115 priority patent/US7799737B2/en
Priority to EP02745202A priority patent/EP1379137B1/de
Priority to NZ528728A priority patent/NZ528728A/en
Priority to HU0303879A priority patent/HU229932B1/hu
Priority to BRPI0208776-6B1A priority patent/BR0208776B1/pt
Application filed by Bayer AG, Bayer CropScience AG filed Critical Bayer AG
Priority to DE50207852T priority patent/DE50207852D1/de
Priority to JP2003501280A priority patent/JP4319905B2/ja
Priority to IL15818002A priority patent/IL158180A0/xx
Priority to APAP/P/2003/002870A priority patent/AP1353A/en
Priority to KR1020037012944A priority patent/KR100842788B1/ko
Priority to CA2443741A priority patent/CA2443741C/en
Publication of WO2002098230A2 publication Critical patent/WO2002098230A2/de
Publication of WO2002098230A3 publication Critical patent/WO2002098230A3/de
Priority to IL158180A priority patent/IL158180A/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Definitions

  • the present invention relates to the new use of fatty alcohol ethoxylates as penetration enhancers for certain active ingredients with insecticidal properties.
  • agrochemical active substances in particular those with a systemic action, must penetrate into the plant so that they can develop their activity uniformly throughout the plant.
  • the penetration barrier of the cuticle must be overcome by the active ingredients.
  • the agrochemical active ingredients penetrate the plant quickly and over as large a surface as possible, otherwise there is a risk that the active components will be washed off by rain.
  • additives used in crop protection agents such as surfactants, mineral oils and vegetable oils, can promote the penetration of agrochemical active ingredients into the plant and thereby increase the activity of the active ingredients.
  • the additives can increase the wettability in individual cases, a better distribution of the spray coating on the surface
  • m stands for average values between 8.0 and 13.0 and
  • n stands for average values between 6.0 and 17.0
  • the weight ratio of insecticidal active ingredient from the group of neonicotinyls to fatty alcohol ethoxylate of the formula (I ) is between 1: 0.1 and 1: 2.0.
  • the invention therefore relates to the use of fatty alcohol ethoxylates of the formula (I) for the stated purpose.
  • the invention also relates to plant treatment agents which
  • fatty alcohol ethoxylates of the formula (I) are much better suited as penetration promoters for insecticidally active neonicotinyls than comparable substances which are used for the same purpose. It is also unexpected that very low concentrations of fatty alcohol ethoxylate of the formula (I) are sufficient to achieve the desired effect.
  • fatty alcohol ethoxylates of the formula (I) has a number of advantages. These fatty alcohol ethoxylates are products that are easy to handle and are also available in large quantities. They are also biodegradable and allow a significant increase in effectiveness when applying neonicotinylene.
  • Formula (I) generally defines the fatty alcohol ethoxylates which can be used according to the invention. These fatty alcohol ethoxylates are generally mixtures of substances of this type with different chain lengths. Average values are therefore calculated for the indices m and n, which can also deviate from whole numbers.
  • n stands for average values between 9.0 and 12.0 and
  • n stands for average values between 7.0 and 9.0.
  • n stands for the average value 8.4.
  • the fatty alcohol ethoxylates of the formula (I) and their use as surface-active substances are already known.
  • neonicotmyls having an antisecticidal effect are preferably to be understood as the following substances.
  • agrochemical active ingredients and crystallization inhibitors are suitable as additives which may be present in the plant treatment compositions according to the invention.
  • Suitable agrochemical active substances are preferably substances with insecticidal, acaricidal and / or fungicidal properties. Active substances from the group of the pyrethroids or the ketoenol derivatives are preferably suitable as insecticides or acaricides. May be mentioned as an example
  • Active ingredients from the group of azoles preferably, come as fungicides
  • Trifloxystrobin Trifloxystrobin, azoxystrobin,
  • Crystallization inhibitors which can be present in the plant treatment compositions according to the invention are all substances which can normally be used for such purposes in agrochemical compositions.
  • N-Alkyl-pyrrolidones such as N-octyl-pyrrolidone and N-dodecylpyrrolidone
  • furthermore copolymers of polyvinyl-pyrrolidone and polyvinyl alcohol such as, for example, the polyvinylpyrrolidone / polyvinyl alcohol known under the name Luviskol VA 64 (from BASF) -Copolymerisat, further Allcylcarbonkladimethylamide, such as decanoic acid-dimethylamide or the Cg ⁇ -alkanecarboxylic acid-dime ylamide mixture known under the name Hallcomid ® (Hall Comp.),
  • copolymers of ethylenediamine with ethylene oxide and propylene oxide such as to the
  • Suitable wetting agents are all substances which are customary for such purposes in plant treatment compositions. May be mentioned
  • Alkylphenol ethoxylates dialkyl sulfosuccinates such as sodium dioctyl sulfosuccinate, lauryl ether sulfates and polyoxyethylene sorbitan fatty acid esters.
  • Suitable emulsifiers are all customary nonionic, anionic, cationic and zwitterionic substances with surface-active properties, which are usually used in agrochemical compositions. These substances include reaction products of fatty acids, fatty acid esters, fatty alcohols, fatty amines, alkylphenols or alkylarylphenols with ethylene oxide and / or propylene oxide and / or butylene oxide, as well as their sulfuric acid esters, phosphoric acid monoesters and phosphoric acid di-esters, as well as reaction products of ethylene oxide with
  • Propylene oxide furthermore alkyl sulfonates, alkyl sulfates, aryl sulfates, tetra-alkylammonium halides, trialkylaryl-ammonium halides and alkylamine sulfonates.
  • the emulsifiers can be used individually or in a mixture.
  • reaction products of castor oil with ethylene oxide in a molar ratio of 1:20 to 1:60, reaction products of C 6 -C 2 o-alcohols with ethylene oxide in a molar ratio of 1: 5 to 1:50, reaction products of fatty amines with are preferably mentioned Ethylene oxide in a molar ratio of 1: 2 to 1:25, reaction products of 1 mol of phenol with 2 to 3 mol of styrene and 10 to 50 mol of ethylene oxide, reaction products of C - Ci 2 alkylphenols with ethylene oxide in a molar ratio of 1: 5 to 1:30, alkyl glycosides , Cg-Cig-alkylbenzene sulfonic acid salts, such as calcium, monoethanolammonium, diethanolammonium and triethanolammonium salts.
  • non-ionic emulsifiers examples include the products known under the names Pluronic PE 10 100 (from BASF) and Atlox 4913 (from Uniqema). Tristyrylphenyl ethoxylates are also suitable. Examples of anionic emulsifiers are Baykanol SL
  • fatty alcohol ethoxylates of the formula (I) When using fatty alcohol ethoxylates of the formula (I) according to the invention, the content of these products can be varied within a certain range.
  • fatty alcohol ethoxylates of the formula (I) are used in such an amount that they are present in the commercial formulations in concentrations between 0.1 and 30% by weight, preferably between 0.5 and 15% by weight.
  • the weight ratio of insecticidal active ingredient from the group of the neonicotinyls to fatty alcohol ethoxylate of the formula (I) is chosen so that it is generally between 1: 0.1 and 1: 2.0, preferably between 1: 0.2 and 1: 0 , 5 lies.
  • the content of the individual components can be varied within a certain range. Preference is given to those plant treatment agents in which the concentrations
  • fatty alcohol ethoxylate of the formula (I) between 0.5 and 15% by weight, of active ingredient from the group of neonicotinyls between 2.5 and 30% by weight,
  • fatty alcohol ethoxylate of formula (I) between 0.01 and 0.2% by weight, in active ingredient from the group of neonicotinyls between 0.001 and 0.03% by weight, in dimethyl sulfoxide, N-methylpyrrolidone and / or butyrolactone between 0 and
  • the plant treatment compositions according to the invention are produced by mixing the components with one another in the ratios desired in each case.
  • the general procedure is to introduce an active ingredient from the group of the neonicotinyls and then to add the remaining constituents in any order while stirring.
  • the temperatures can be varied within a certain range in the production of the plant treatment compositions according to the invention. Generally one works at temperatures between 10 ° C and 50 ° C, preferably at room temperature.
  • customary devices are used which are used for the preparation of agrochemical formulations.
  • the plant treatment compositions according to the invention can be applied either as such or after prior dilution with water or other diluents, for example as emulsions, suspensions, solutions or aerosols.
  • the application is carried out according to customary methods, for example by spraying, pouring, spraying, injecting or brushing.
  • the application rate of the plant treatment agents according to the invention can be varied within a substantial range. It depends on the active substances contained in each case and on their concentration in the formulations.
  • neonicotinyls can be applied to the plants and / or their habitat in a particularly advantageous manner.
  • the tendency to crystallize solid active substances is reduced, the penetration ability of the active substances is favored and the biological effectiveness of the active components is increased in comparison to conventional formulations.
  • Imidacloprid contained per liter. application rate
  • the second leaves were cut from barley plants freshly grown in the greenhouse at the 2-leaf stage. The remaining leaves of the horizontally placed plants were then fixed with the help of slides so that the application points on the leaves were not twisted within a range of 2 cm.
  • the ready-to-use active ingredient preparations were stirred at room temperature for 60 minutes after their preparation.
  • the treated plants were placed in a climatic cabinet for 22 or 46 hours. 24 or 48 hours after the application of the active compound preparations, the leaves of all plants were fixed again with slides. The application area was then covered with 30 .mu.l of a 5% solution of cellulose acetate in acetone busy. After the solution had dried completely, the resulting cellulose acetate film was removed and placed in scintillation bottles. Now the cellulose acetate film was mixed with 1 ml of acetone. The samples remained in closed vessels at room temperature until the substance contained was dissolved. Then 2 ml of scintillator were added. The leaf tips were previously cut in one piece and put in cardboard hats.
  • the cardboard hats and their contents were dried at 50 ° C. for 16 hours.
  • the radioactivity of all samples was then measured using the liquid and combustion scintillation method.
  • the percentage of active ingredient uptake and translocation is calculated from the values obtained. 0% means that no active ingredient has been taken up and translocated, while 100% means that the active ingredient has been taken up and translocated completely.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
PCT/EP2002/003618 2001-04-11 2002-04-02 Verwendung von fettalkoholethoxylaten als penetrationsförderer Ceased WO2002098230A2 (de)

Priority Applications (16)

Application Number Priority Date Filing Date Title
UA20031110186A UA77956C2 (en) 2001-04-11 2002-02-04 Insecticidal agent containing fatty alcohol ethoxylate
CA2443741A CA2443741C (en) 2001-04-11 2002-04-02 Use of fatty alcohol ethoxylates as penetration promoters
DE50207852T DE50207852D1 (de) 2001-04-11 2002-04-02 Verwendung von fettalkoholethoxylaten als penetrationsförderer
AU2002316826A AU2002316826B2 (en) 2001-04-11 2002-04-02 Use of fatty alcohol ethoxylates as penetration promoters
US10/474,115 US7799737B2 (en) 2001-04-11 2002-04-02 Use of fatty alcohols ethoxylates as penetration promoters
EP02745202A EP1379137B1 (de) 2001-04-11 2002-04-02 Verwendung von fettalkoholethoxylaten als penetrationsförderer
NZ528728A NZ528728A (en) 2001-04-11 2002-04-02 Use of fatty alcohol ethoxylates as penetrants for insecticidally active neonicotinyls even in very low concentrations
HU0303879A HU229932B1 (en) 2001-04-11 2002-04-02 Use of fatty alcohol ethoxylates as penetration promoters
BRPI0208776-6B1A BR0208776B1 (pt) 2001-04-11 2002-04-02 uso de etoxilatos de álcool graxo como promotores de penetração, bem como composições para tratamento de plantas.
PL363174A PL206263B1 (pl) 2001-04-11 2002-04-02 Zastosowanie oksyetylenowych alkoholi tłuszczowych, środek do traktowania roślin i gotowe do zastosowania środki do traktowania roślin
MXPA03009191A MXPA03009191A (es) 2001-04-11 2002-04-02 USO DE ETOXILATOS DE ALCOHOLES GRASOS COMO FAVORECEDORES DE LA PENETRACIoN.
JP2003501280A JP4319905B2 (ja) 2001-04-11 2002-04-02 浸透促進剤としての脂肪アルコールエトキシラートの使用
IL15818002A IL158180A0 (en) 2001-04-11 2002-04-02 Use of fatty alcohol ethoxylates as penetration promoters
APAP/P/2003/002870A AP1353A (en) 2001-04-11 2002-04-02 Use of fatty alcohol ethoxylates as penetration promoters
KR1020037012944A KR100842788B1 (ko) 2001-04-11 2002-04-02 침투제로서 지방 알코올 에톡실레이트의 용도
IL158180A IL158180A (en) 2001-04-11 2003-09-30 Use of fatty ethoxylates as aids in insertion

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10118076A DE10118076A1 (de) 2001-04-11 2001-04-11 Verwendung von Fettalkoholethoxylaten als Penetrationsförderer
DE10118076.4 2001-04-11

Publications (2)

Publication Number Publication Date
WO2002098230A2 true WO2002098230A2 (de) 2002-12-12
WO2002098230A3 WO2002098230A3 (de) 2003-09-25

Family

ID=7681227

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/003618 Ceased WO2002098230A2 (de) 2001-04-11 2002-04-02 Verwendung von fettalkoholethoxylaten als penetrationsförderer

Country Status (38)

Country Link
US (1) US7799737B2 (https=)
EP (1) EP1379137B1 (https=)
JP (1) JP4319905B2 (https=)
KR (1) KR100842788B1 (https=)
CN (1) CN100399901C (https=)
AP (1) AP1353A (https=)
AR (2) AR033136A1 (https=)
AT (1) ATE336169T1 (https=)
AU (1) AU2002316826B2 (https=)
BR (1) BR0208776B1 (https=)
CA (1) CA2443741C (https=)
CR (1) CR7107A (https=)
CU (1) CU23307B7 (https=)
DE (2) DE10118076A1 (https=)
DK (1) DK1379137T3 (https=)
DO (1) DOP2002000377A (https=)
EC (1) ECSP034783A (https=)
EG (1) EG23260A (https=)
ES (1) ES2268057T3 (https=)
GT (1) GT200200066A (https=)
HU (1) HU229932B1 (https=)
IL (2) IL158180A0 (https=)
MA (1) MA26312A1 (https=)
MX (1) MXPA03009191A (https=)
MY (1) MY131430A (https=)
NZ (1) NZ528728A (https=)
OA (1) OA12558A (https=)
PA (1) PA8541401A1 (https=)
PE (1) PE20021037A1 (https=)
PL (1) PL206263B1 (https=)
PT (1) PT1379137E (https=)
RU (1) RU2294641C2 (https=)
TW (1) TWI298995B (https=)
UA (1) UA77956C2 (https=)
UY (1) UY27249A1 (https=)
WO (1) WO2002098230A2 (https=)
YU (1) YU78903A (https=)
ZA (1) ZA200307848B (https=)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004100662A1 (ja) * 2003-05-19 2004-11-25 Nippon Soda Co., Ltd. 殺虫剤組成物
WO2005000020A2 (en) 2003-06-23 2005-01-06 Cognis Ip Management Gmbh Alcohol alkoxylate carriers for pesticide active ingredients
WO2005104844A1 (de) * 2004-04-27 2005-11-10 Bayer Cropscience Aktiengesellschaft Verwendung von alkylcarbonsäureamiden als penetrationsförderer
WO2005084441A3 (de) * 2004-03-06 2005-11-24 Bayer Cropscience Ag Suspensionskonzentrate auf ölbasis
EP1695621A2 (de) 2005-02-26 2006-08-30 Bayer CropScience AG Agrochemische Formulierung von Pflanzenschutzwirkstoffen zur Verbesserung ihrer Wirkung und Pflanzenverträglichkeit
WO2006111279A1 (de) * 2005-04-20 2006-10-26 Bayer Cropscience Ag Suspensionskonzentrate auf ölbasis
WO2007042152A1 (de) * 2005-10-11 2007-04-19 Bayer Cropscience Ag Suspensionskonzentrate auf ölbasis
WO2007068355A1 (de) * 2005-12-13 2007-06-21 Bayer Cropscience Ag Insektizide zusammensetzungen mit verbesserter wirkung
EP1905302A1 (de) * 2006-09-30 2008-04-02 Bayer CropScience AG Suspensionskonzentrate
WO2007028518A3 (de) * 2005-09-09 2008-04-03 Bayer Cropscience Ag Verwendung von cni-sl-formulierungen zur bekämpfung der weissen fliege
WO2007068428A3 (de) * 2005-12-13 2008-06-12 Bayer Cropscience Ag Insektizide zusammensetzungen, die phenylsubstituierte cyclische ketoenole enthalten
WO2007068427A3 (de) * 2005-12-13 2008-06-19 Bayer Cropscience Ag Herbizide zusammensetzungen mit verbesserter wirkung
CN100435638C (zh) * 2003-05-19 2008-11-26 日本曹达株式会社 杀虫剂组合物
WO2008145282A1 (de) * 2007-05-25 2008-12-04 Bayer Cropscience Ag Insektizide zusammensetzungen von 2-cyanobenzolsulfonamidverbindungen und ihre isomeren formen mit verbesserter wirkung
EP2000027A1 (de) * 2007-06-06 2008-12-10 Bayer CropScience AG Insektizide Zusammensetzungen mit verbesserter Wirkung
WO2009118025A1 (en) * 2008-03-27 2009-10-01 Bayer Cropscience Aktiengesellschaft Method for controlling animal pest and plant pathogenic fungi by applying an agrochemical composition into the culture medium, suitable formulation and use thereof
EP2271210A1 (en) 2008-04-02 2011-01-12 Bayer Cropscience LP Synergistic pesticide compositions
RU2769131C1 (ru) * 2021-10-06 2022-03-28 Акционерное общество "Щелково Агрохим" Агрохимическая смесь для защиты растений от насекомых

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10201391A1 (de) * 2002-01-16 2003-07-31 Bayer Cropscience Ag Verwendung von Alkoholethoxylaten als Penetrationsförderer
US20050245582A1 (en) * 2002-09-12 2005-11-03 The Hartz Mountain Corporation High concentration topical insecticides containing pyrethroids
JP3930896B1 (ja) * 2005-12-28 2007-06-13 株式会社メンテック 機能性組成物、及びそれを用いた湿紙の剥離性向上方法
MX2008013845A (es) * 2006-04-28 2009-01-20 Summit Vetpharma Llc Insecticida topico de alta concentracion que contiene regulador de crecimiento de insectos.
WO2007127966A2 (en) * 2006-04-28 2007-11-08 Summit Vetpharm, Llc High concentration dinotefuran formulations
DE102006055477A1 (de) 2006-11-24 2008-05-29 Bayer Cropscience Ag Pflanzenschutzgranulate zur Applikation auf die Blattoberfläche
RU2350078C1 (ru) * 2007-06-20 2009-03-27 Закрытое Акционерное Общество "Фирма "Август" Инсектицидная композиция для влажной обработки семян и способ защиты культурных растений от насекомых-вредителей
EP2422619A1 (en) * 2010-08-31 2012-02-29 Cheminova A/S Neonicotinyl formulations
MX355432B (es) 2010-09-14 2018-04-18 Basf Se Composiciones que contienen un insecticida de piripiropeno y una base.
JP6425887B2 (ja) 2010-09-14 2018-11-21 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ピリピロペン殺虫剤及び補助剤を含有する組成物
CN102687726A (zh) * 2012-01-05 2012-09-26 安徽迪邦药业有限公司 一种油膏
EP2825043B1 (en) 2012-03-12 2018-09-05 Basf Se Method for producing an aqueous suspension concentrate formulation of a pyripyropene insecticide
ES2566910T3 (es) 2012-03-12 2016-04-18 Basf Se Formulación de concentrado líquido que contiene un insecticida de piripiropeno II
BR112014022648B1 (pt) * 2012-03-13 2021-05-25 Basf Se formulação de concentrado líquido, preparação aquosa, métodos para proteger plantas, não-terapêutico para controlar pragas invertebradas e para proteção de material de propagação de planta contra pragas invertebradas, e usos de uma formulação
CN108882700B (zh) * 2016-03-17 2022-07-08 陶氏环球技术有限责任公司 可乳化浓缩物

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4013523A1 (de) 1990-04-27 1991-10-31 Bayer Ag Verwendung von n-alkyl-lactamen als kristallisationsinhibitoren
DE4319263A1 (de) 1992-07-03 1994-01-05 Schoenherr Joerg Pflanzenbehandlungsmittel
DE4239181A1 (de) * 1992-11-03 1994-05-05 Hoechst Ag Wirkungsverstärkung von Neophanen, Azaneophanen und anderen Wirkstoffen durch Penetrationsmittel
DE19601430C1 (de) * 1996-01-17 1997-04-24 Lohmann Therapie Syst Lts Verfahren zur Wirkstoffapplikation an Pflanzen und dafür geeignete Zubereitung
DE19624819A1 (de) * 1996-06-21 1998-01-02 Bayer Ag Stifte zur Pflanzenbehandlung
CA2259160A1 (en) * 1996-06-28 1998-01-08 Novartis Ag Pesticidal compositions
CN1187299A (zh) 1997-01-08 1998-07-15 张天良 一种高效杀虫剂
PL340691A1 (en) * 1997-11-25 2001-02-26 Cognis Corp Application of narrow-range fatty alcohol ethoxylates in agricultural pesticides and adjuvant preparations
ATE265138T1 (de) * 1998-04-30 2004-05-15 Basf Ag Retardformulierungen von pflanzenschutzwirkstoffen
CN1242940A (zh) * 1998-07-23 2000-02-02 吴华龙 高渗吡虫啉乳油
CN1245643A (zh) * 1998-08-24 2000-03-01 化工部农药剂型工程技术中心 增效吡虫啉系列制剂
DE19908559A1 (de) 1999-02-27 2000-09-07 Cognis Deutschland Gmbh PIT-Emulsionen
US20030224936A1 (en) * 1999-03-13 2003-12-04 Gerhard Kretzschmar Seed treatment composition
EP1036492A1 (en) * 1999-03-13 2000-09-20 Aventis Research & Technologies GmbH & Co. KG Seed treatment composition
FR2800242A1 (fr) * 1999-10-29 2001-05-04 Aventis Cropscience Sa Nouvelles compositions pesticides et/ou regulatrices de croissance a agent tensio-actif non ionique particulier

Cited By (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1625791A4 (en) * 2003-05-19 2006-06-14 Nippon Soda Co INSECTICIDE COMPOSITION
JPWO2004100662A1 (ja) * 2003-05-19 2006-07-13 日本曹達株式会社 殺虫剤組成物
CN100435638C (zh) * 2003-05-19 2008-11-26 日本曹达株式会社 杀虫剂组合物
WO2004100662A1 (ja) * 2003-05-19 2004-11-25 Nippon Soda Co., Ltd. 殺虫剤組成物
KR100734792B1 (ko) 2003-05-19 2007-07-03 닛뽕소다 가부시키가이샤 살충제 조성물
WO2005000020A2 (en) 2003-06-23 2005-01-06 Cognis Ip Management Gmbh Alcohol alkoxylate carriers for pesticide active ingredients
EP1635635A4 (en) * 2003-06-23 2010-11-24 Cognis Ip Man Gmbh ALKOXYLATE ALCOHOL VECTORS FOR ACTIVE PESTICIDE PRINCIPLES
US8664259B2 (en) 2004-03-06 2014-03-04 Bayer Cropscience Ag Oil-based suspension concentrates
WO2005084441A3 (de) * 2004-03-06 2005-11-24 Bayer Cropscience Ag Suspensionskonzentrate auf ölbasis
JP2007527426A (ja) * 2004-03-06 2007-09-27 バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト 油性懸濁液濃縮物
US8124564B2 (en) 2004-04-27 2012-02-28 Bayer Cropscience Ag Use of alkyl carboxylic acid amides as penetration enhancers
JP4922925B2 (ja) * 2004-04-27 2012-04-25 バイエル・クロップサイエンス・アーゲー アルキルカルボキサミドの浸透剤としての使用
WO2005104844A1 (de) * 2004-04-27 2005-11-10 Bayer Cropscience Aktiengesellschaft Verwendung von alkylcarbonsäureamiden als penetrationsförderer
JP2007534716A (ja) * 2004-04-27 2007-11-29 バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト アルキルカルボキサミドの浸透剤としての使用
AP2698A (en) * 2005-02-26 2013-07-17 Bayer Cropscience Ag Agrochemical formulation of plant protection active ingredients for improving the action and plant tolerance
WO2006089661A1 (de) * 2005-02-26 2006-08-31 Bayer Cropscience Ag Agrochemische formulierung von pflanzenschutzwirkstoffen zur verbesserung der wirkung und pflanzenverträglichkeit
EP1695621A2 (de) 2005-02-26 2006-08-30 Bayer CropScience AG Agrochemische Formulierung von Pflanzenschutzwirkstoffen zur Verbesserung ihrer Wirkung und Pflanzenverträglichkeit
AU2006218182B2 (en) * 2005-02-26 2011-04-21 Bayer Cropscience Aktiengesellschaft Agrochemical formulation of plant protection active ingredients for improving the action and plant tolerance
EP1695621A3 (de) * 2005-02-26 2007-02-28 Bayer CropScience AG Agrochemische Formulierung von Pflanzenschutzwirkstoffen zur Verbesserung ihrer Wirkung und Pflanzenverträglichkeit
EA013503B1 (ru) * 2005-02-26 2010-06-30 Байер Кропсайенс Аг Препарат биологически активного вещества для защиты растений, способ его получения, его применение для обработки растений, способ повышения эффективности биологически активного вещества для защиты растений и способ защиты растений от вредителей
WO2006111279A1 (de) * 2005-04-20 2006-10-26 Bayer Cropscience Ag Suspensionskonzentrate auf ölbasis
RU2416198C2 (ru) * 2005-04-20 2011-04-20 Байер Кропсайенс Аг Суспензионные концентраты на масляной основе
WO2007028518A3 (de) * 2005-09-09 2008-04-03 Bayer Cropscience Ag Verwendung von cni-sl-formulierungen zur bekämpfung der weissen fliege
AU2006289420B2 (en) * 2005-09-09 2011-04-07 Bayer Cropscience Ag Use of CNI-SL formulations for controlling white fly
WO2007042152A1 (de) * 2005-10-11 2007-04-19 Bayer Cropscience Ag Suspensionskonzentrate auf ölbasis
EA013647B1 (ru) * 2005-10-11 2010-06-30 Байер Кропсайенс Аг Суспензионные концентраты на масляной основе
EA015527B1 (ru) * 2005-12-13 2011-08-30 Байер Кропсайенс Аг Инсектицидные составы с улучшенной эффективностью
EA015464B1 (ru) * 2005-12-13 2011-08-30 Байер Кропсайенс Аг Гербицидные составы с улучшенной эффективностью
WO2007068355A1 (de) * 2005-12-13 2007-06-21 Bayer Cropscience Ag Insektizide zusammensetzungen mit verbesserter wirkung
US8247351B2 (en) 2005-12-13 2012-08-21 Bayer Cropscience Ag Insecticidal compositions having improved effect
WO2007068428A3 (de) * 2005-12-13 2008-06-12 Bayer Cropscience Ag Insektizide zusammensetzungen, die phenylsubstituierte cyclische ketoenole enthalten
EA015464B9 (ru) * 2005-12-13 2012-02-28 Байер Кропсайенс Аг Гербицидные составы с улучшенной эффективностью
AU2006326299B2 (en) * 2005-12-13 2011-11-03 Bayer Cropscience Ag Herbicidal compositions having improved effect
WO2007068427A3 (de) * 2005-12-13 2008-06-19 Bayer Cropscience Ag Herbizide zusammensetzungen mit verbesserter wirkung
US7977278B2 (en) 2006-09-30 2011-07-12 Bayer Cropscience Ag Suspension concentrates
WO2008037375A3 (de) * 2006-09-30 2008-05-29 Bayer Cropscience Ag Suspensionskonzentrate
CN101522031B (zh) * 2006-09-30 2013-03-27 拜尔农作物科学股份公司 悬浮剂
EP1905302A1 (de) * 2006-09-30 2008-04-02 Bayer CropScience AG Suspensionskonzentrate
WO2008145282A1 (de) * 2007-05-25 2008-12-04 Bayer Cropscience Ag Insektizide zusammensetzungen von 2-cyanobenzolsulfonamidverbindungen und ihre isomeren formen mit verbesserter wirkung
EP2534952A1 (de) * 2007-05-25 2012-12-19 Bayer CropScience AG Insektizide Zusammensetzungen von 2-Cyanobenzolsulfonamidverbindungen und ihre isomeren Formen mit verbesserter Wirkung
US8604068B2 (en) 2007-05-25 2013-12-10 Bayer Cropscience Ag Insecticidal compositions of 2-cyanobenzene sulfonamide compounds and isomeric forms thereof having improved effect
EP2000027A1 (de) * 2007-06-06 2008-12-10 Bayer CropScience AG Insektizide Zusammensetzungen mit verbesserter Wirkung
WO2008148483A1 (de) * 2007-06-06 2008-12-11 Bayer Cropscience Ag Insektizide zusammensetzungen mit verbesserter wirkung
WO2009118025A1 (en) * 2008-03-27 2009-10-01 Bayer Cropscience Aktiengesellschaft Method for controlling animal pest and plant pathogenic fungi by applying an agrochemical composition into the culture medium, suitable formulation and use thereof
EP2271210A1 (en) 2008-04-02 2011-01-12 Bayer Cropscience LP Synergistic pesticide compositions
US9028856B2 (en) 2008-04-02 2015-05-12 Bayer Cropscience Lp Synergistic pesticide compositions
RU2769131C1 (ru) * 2021-10-06 2022-03-28 Акционерное общество "Щелково Агрохим" Агрохимическая смесь для защиты растений от насекомых

Also Published As

Publication number Publication date
OA12558A (en) 2006-06-07
DE50207852D1 (de) 2006-09-28
TWI298995B (en) 2008-07-21
EP1379137A2 (de) 2004-01-14
PT1379137E (pt) 2006-11-30
MY131430A (en) 2007-08-30
AP2003002870A0 (en) 2003-09-30
JP4319905B2 (ja) 2009-08-26
CN100399901C (zh) 2008-07-09
IL158180A0 (en) 2004-03-28
CA2443741A1 (en) 2002-12-12
PE20021037A1 (es) 2002-12-12
CN1516551A (zh) 2004-07-28
BR0208776A (pt) 2004-06-22
AR033136A1 (es) 2003-12-03
HUP0303879A2 (hu) 2004-03-29
EP1379137B1 (de) 2006-08-16
PL206263B1 (pl) 2010-07-30
HUP0303879A3 (en) 2005-09-28
CR7107A (es) 2007-12-17
AP1353A (en) 2004-12-26
GT200200066A (es) 2002-12-24
RU2003133141A (ru) 2005-05-10
DK1379137T3 (da) 2006-12-11
UY27249A1 (es) 2002-11-29
UA77956C2 (en) 2007-02-15
KR20030088487A (ko) 2003-11-19
ES2268057T3 (es) 2007-03-16
YU78903A (sh) 2006-08-17
RU2294641C2 (ru) 2007-03-10
MXPA03009191A (es) 2004-02-17
EG23260A (en) 2004-10-31
BR0208776B1 (pt) 2013-08-06
PL363174A1 (en) 2004-11-15
AU2002316826B2 (en) 2006-10-19
JP2004527582A (ja) 2004-09-09
DOP2002000377A (es) 2002-10-15
MA26312A1 (fr) 2004-10-01
HU229932B1 (en) 2015-01-28
ATE336169T1 (de) 2006-09-15
KR100842788B1 (ko) 2008-07-01
PA8541401A1 (es) 2003-01-24
DE10118076A1 (de) 2002-10-17
US7799737B2 (en) 2010-09-21
AR062356A2 (es) 2008-11-05
ZA200307848B (en) 2004-10-08
CA2443741C (en) 2012-02-07
WO2002098230A3 (de) 2003-09-25
ECSP034783A (es) 2003-12-01
CU23307B7 (es) 2008-08-19
NZ528728A (en) 2005-03-24
US20040157743A1 (en) 2004-08-12
IL158180A (en) 2009-09-22

Similar Documents

Publication Publication Date Title
EP1379137B1 (de) Verwendung von fettalkoholethoxylaten als penetrationsförderer
EP0511611B1 (de) Flüssige herbizide Mittel
EP0113857B1 (de) Herbizide Mittel
EP2477488B1 (de) Alkylpolypropylenglycolpolyethylenglycol enthaltende agrochemische zusammensetzungen
DE4422025B4 (de) Gegen Pilzbefall geschütztes Pflanzen-Vermehrungsgut und seine Herstellung unter Verwendung eines Wirkstoffs auf der Basis der Phosphorigen Säure
DE69016178T2 (de) Zusammensetzung von Nachlaufherbiziden, die Silikonglycole mit Acetoxyendgruppen sowie Dispergiermittel enthalten.
EP2002719A1 (de) Adjuvans-Zusammensetzung auf Ölbasis
EP0391171B1 (de) Verwendung von Di-styryl-phenyl-triglykolether als Kristallisationsinhibitor
DE68903450T2 (de) Silikonglykolhilfsmittel enthaltende zusammensetzungen von nachauflaufherbiziden.
EP2560485B1 (de) Triglyzerid-enthaltende winterspritzmittel
EP1467623B1 (de) Verwendung von alkoholethoxylaten als penetrationsförderer
DE3139060A1 (de) Herbizide mittel
DD252115A5 (de) Fungizides mittel und seine verwendung
DE69532476T2 (de) Benetzbare pulverformulierungen
DE10143086A1 (de) Verwendung von Calciumformiat in Pflanzenbehandlungsmitteln
DE69627682T2 (de) Insektizidhilfsmittel
EP2223598A1 (de) Insektizide Zusammensetzungen mit verbesserter Wirkung
DD210187A5 (de) Homogene waessrige formulierungen
CH670932A5 (https=)
DE3704068C2 (de) Wasserverdünnbares Konzentrat und dessen Verwendung
DE2827491A1 (de) Mischung zur bekaempfung von im boden lebenden schaedlingen und mikroorganismen als krankheitserreger bei landwirtschaftlichen kulturen
DE1044501B (de) Verfahren zur Herstellung stabiler Loesungen von Griseofulvin in organischen Loesungsmitteln fuer fungicide Zwecke
DD254130A5 (de) Fungizides mittel und seine verwendung

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 1200300887

Country of ref document: VN

Ref document number: P-789/03

Country of ref document: YU

AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1-2003-501011

Country of ref document: PH

WWE Wipo information: entry into national phase

Ref document number: 2002745202

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: AP/P/2003/002870

Country of ref document: AP

WWE Wipo information: entry into national phase

Ref document number: 2002316826

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 158180

Country of ref document: IL

WWE Wipo information: entry into national phase

Ref document number: 1020037012944

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2003/07848

Country of ref document: ZA

Ref document number: PA/a/2003/009191

Country of ref document: MX

Ref document number: 200307848

Country of ref document: ZA

Ref document number: 528728

Country of ref document: NZ

Ref document number: 2443741

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2003501280

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 028115805

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2002745202

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWE Wipo information: entry into national phase

Ref document number: 10474115

Country of ref document: US

WWP Wipo information: published in national office

Ref document number: 528728

Country of ref document: NZ

WWG Wipo information: grant in national office

Ref document number: 528728

Country of ref document: NZ

WWG Wipo information: grant in national office

Ref document number: 2002745202

Country of ref document: EP