US20130045387A1 - Articles, Coating Compositions, and Methods - Google Patents

Articles, Coating Compositions, and Methods Download PDF

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Publication number
US20130045387A1
US20130045387A1 US13/695,674 US201113695674A US2013045387A1 US 20130045387 A1 US20130045387 A1 US 20130045387A1 US 201113695674 A US201113695674 A US 201113695674A US 2013045387 A1 US2013045387 A1 US 2013045387A1
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US
United States
Prior art keywords
nanoparticles
nonspherical
coating composition
spherical
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/695,674
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English (en)
Inventor
Yiwen Chu
Zhigang Yu
Naiyong Jing
Rui Pan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
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3M Innovative Properties Co
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Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Assigned to 3M INNOVATIVE PROPERTIES COMPANY reassignment 3M INNOVATIVE PROPERTIES COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CHU, YIWEN, PAN, Rui, YU, ZHIGANG, JING, NAIYONG
Publication of US20130045387A1 publication Critical patent/US20130045387A1/en
Abandoned legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/02168Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/425Coatings comprising at least one inhomogeneous layer consisting of a porous layer
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/465Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific shape
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/47Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
    • C03C2217/475Inorganic materials
    • C03C2217/478Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31Surface property or characteristic of web, sheet or block
    • Y10T428/315Surface modified glass [e.g., tempered, strengthened, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31525Next to glass or quartz
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645Next to addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31667Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product

Definitions

  • 6,838,178 disclosed a color neutral absorbing film that is applied as a coating on a glass substrate, to which a conductive coating is first applied. An additional metal oxide layer is deposited on the absorbing film.
  • the coating is suitable for use in anti-reflective coatings containing other metal oxides to achieve a coated glass article having a visible light transmittance of 30% or greater and a reflectance of less than 5%.
  • the coated glass article is absorbing, anti-reflective and conducting.
  • U.S. Pat. No. 6,858,306 disclosed a coated article including a glass substrate, a coating of antimony doped tin oxide deposited on and adhering to the glass substrate and a coating of fluorine doped tin oxide.
  • the low emittance of the coated glass article when combined with the surprisingly selective solar absorption of the multilayer stack provides improved heat rejection in summer and heat retention in winter, while permitting the transmittance of a relatively high degree of visible light.
  • only spherical nanoparticles are functionalized. It should be understood that, in these embodiments, although a certain portion of the population of shperical nanoparticles can be bare particles upon applying the coating composition to a substrate, a large portion, and preferably a majority, of the shperical nanoparticles have functionalities (e.g., epoxy group, amine group, hydroxyl, olefin, alkyne, (meth) acrylato, mercapto, or combinations thereof) covalently bonded thereto.
  • functionalities e.g., epoxy group, amine group, hydroxyl, olefin, alkyne, (meth) acrylato, mercapto, or combinations thereof
  • the colloidal silica particles obtained by this method are elongate-shaped silica particles that have elongations of a uniform thickness within the range of 5 to 40 nm extending in only one plane.
  • the nonspherical silica sol may also be prepared as described by Watanabe et al. in U.S. Pat. No. 5,597,512.
  • the functional groups include various chemical groups that allow for binding to the nanoparticles. Such groups are typically provided by functional compound represented by the formula A-L-F2.
  • the functional group F1 includes the amine groups.
  • the group A is the nanoparticle surface-bonding group
  • L can be a bond or any of a variety of organic linkers.
  • Organic linkers L can be linear or branched alkylene, arylene, or a combination of alkylene and arylene groups, optionally including heteroatoms.
  • the silanol groups on the surfaces of the silica nanoparticles are reacted with at least one silanol, alkoxysilane, or chlorosilane group of a functional compound to form a functionalized nanoparticle.
  • exemplary conditions for reacting functional compounds with silica nanoparticles are described in the Examples Section.
  • the surface-bonding groups in the described in invention may not be limited to silanols or alkoxy silanes. Ionic bonds or hydrogen bonds and other types of covalent bonds to nanoparticle surfaces may also be included.
  • the coating composition includes more than 100 mole-% olefin, alkyne, (meth) acrylato, mercapto groups, more than a monolayer of the olefin, alkyne, (meth) acrylato, mercapto siloxane is created on the particle surface.
  • An excess of hydrolyzed olefin, alkyne, (meth) acrylato, mercapto alkoxysilane, when present, can also function as a primer on the surface of the substrate.
  • hydrophilic groups can be provided using hydrophilic compounds of the formula A-L-WD.
  • Suitable surface-bonding groups A of the hydrophilic compounds are described herein for the epoxy functional compounds, for example. Examples include silanols, alkoxysilanes, or chlorosilanes.
  • the surfactant concentration in coating compositions of the present invention is preferably at least 0.01 percent by weight of the coating composition, more preferably at least 0.04 wt %, and even more preferably at least 0.1 wt %. If used, the surfactant concentration is preferably no greater than 10 wt % of the coating composition, more preferably no greater than 5 wt % of the coating composition.
  • composition of claim 18 wherein the nonspherical nanoparticles have an average particle size between 1 and 200 nm and an aspect ratio between 2 and 100.
  • Nonspherical silica nanoparticles dispersions IPA-ST-UP, ST-OUP, ST-UP and ST-PS-S were obtained from Nissan Chemical Industries, LTD.
  • Coating solutions (3 wt %) were prepared by mixing appropriate amounts of SMN and BN solutions with water and surfactants to improve wetting as indicated in Table 1.
  • Example 23 was prepared by gradually adding 15.0 g BN5 to 21.0 g SMN5. Then 14.0 g deionized water was added to dilute the solution by the addition of 0.75 g of a 10% solution of TRITON BG10.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Sustainable Development (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Electromagnetism (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Composite Materials (AREA)
  • Dispersion Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Silicon Compounds (AREA)
  • Surface Treatment Of Glass (AREA)
  • Photovoltaic Devices (AREA)
US13/695,674 2010-05-11 2011-04-25 Articles, Coating Compositions, and Methods Abandoned US20130045387A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201010170156.6 2010-05-11
CN201010170156.6A CN102241899B (zh) 2010-05-11 2010-05-11 涂料组合物,改性基体表面的方法和制品
PCT/US2011/033723 WO2011142956A2 (fr) 2010-05-11 2011-04-25 Articles, compositions de revêtement, et procédés associés

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/033723 A-371-Of-International WO2011142956A2 (fr) 2010-05-11 2011-04-25 Articles, compositions de revêtement, et procédés associés

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/933,412 Division US10297698B2 (en) 2010-05-11 2018-03-23 Articles, coating compositions, and methods

Publications (1)

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US20130045387A1 true US20130045387A1 (en) 2013-02-21

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US13/695,674 Abandoned US20130045387A1 (en) 2010-05-11 2011-04-25 Articles, Coating Compositions, and Methods
US15/933,412 Active US10297698B2 (en) 2010-05-11 2018-03-23 Articles, coating compositions, and methods

Family Applications After (1)

Application Number Title Priority Date Filing Date
US15/933,412 Active US10297698B2 (en) 2010-05-11 2018-03-23 Articles, coating compositions, and methods

Country Status (6)

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US (2) US20130045387A1 (fr)
EP (1) EP2569260B1 (fr)
JP (2) JP5882989B2 (fr)
CN (1) CN102241899B (fr)
PL (1) PL2569260T3 (fr)
WO (1) WO2011142956A2 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120088106A1 (en) * 2009-07-03 2012-04-12 Naiyong Jing Hydrophilic Coatings, Articles, Coating Compositions and Methods
US20130078440A1 (en) * 2010-07-08 2013-03-28 Lg Chem, Ltd. Anti-reflection film and method for manufacturing the same
US10023750B2 (en) * 2013-04-26 2018-07-17 Nihon Parkerizing Co., Ltd. Aqueous hydrophilizing surface treatment agent, hydrophilic coating film and hydrophilizing surface treatment method
US20190338102A1 (en) * 2014-06-23 2019-11-07 Southwire Company, Llc Uv-resistant superhydrophobic coating compositions
CN114042614A (zh) * 2021-12-09 2022-02-15 大连理工大学 一种大面积制备超亲水薄膜的方法
US11713403B2 (en) 2017-06-02 2023-08-01 Samsung Display Co., Ltd. Nanocomposite body, method of manufacturing the same, and nanocomposite film including the nanocomposite body

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EP2590816B1 (fr) * 2010-07-07 2017-11-29 Saint Louis University Nanoparticules métalliques passivées présentant un revêtement oligomère à base d'époxyde
US20150059846A1 (en) * 2012-01-23 2015-03-05 Asahi Kasei E-Materials Corporation Coating composition and antireflection film
JP5968469B2 (ja) * 2012-02-27 2016-08-10 スリーエム イノベイティブ プロパティズ カンパニー 無機酸化物ナノ粒子及び有機塩基を含む塩基性組成物、コーティングされた基材、物品、及び方法
CN103311320B (zh) * 2012-03-14 2016-12-14 江苏新源动力有限公司 太阳能电池用透明导电薄膜及其制备方法
JP6371032B2 (ja) * 2012-08-01 2018-08-08 スリーエム イノベイティブ プロパティズ カンパニー 反射防止ハードコートおよび反射防止物品
JP6062680B2 (ja) * 2012-08-01 2017-01-18 スリーエム イノベイティブ プロパティズ カンパニー 防汚性ハードコートおよび防汚性ハードコート前駆体
JP2016500654A (ja) * 2012-09-26 2016-01-14 スリーエム イノベイティブ プロパティズ カンパニー コーティング可能な組成物、抗菌性組成物、抗菌性物品、及びそれらの作製方法
JP6216505B2 (ja) * 2012-12-07 2017-10-18 富士電機株式会社 太陽電池一体型膜材
EP2752386B1 (fr) * 2012-12-13 2019-08-28 Guardian Glass, LLC Procédé de fabrication d'article revêtu comprenant un revêtement antiréfléchissant doté de différences de porosité en deux couches et produits les contenant
CN103466958A (zh) * 2013-09-22 2013-12-25 四川世创达电子科技有限公司 一种光学玻璃湿法防眩方法
US10400109B2 (en) 2013-10-04 2019-09-03 3M Innovative Properties Company Coatable composition, antistatic composition, antistatic articles, and methods of making the same
CN103811588B (zh) * 2014-01-26 2016-07-13 晶澳太阳能有限公司 一种太阳能电池的双面扩散工艺
CN105440825B (zh) * 2014-09-01 2018-10-12 上海三银制漆有限公司 耐油污的水性氟碳涂料及其制备方法和应用
JP2016087561A (ja) * 2014-11-06 2016-05-23 富士フイルム株式会社 水性塗布液、膜及びその製造方法、積層体、並びに太陽電池モジュール
CN104362205B (zh) * 2014-11-14 2016-08-24 无锡中洁能源技术有限公司 一种基于改性含氟聚合物的太阳能电池背板的制备方法
JP2016123928A (ja) * 2014-12-26 2016-07-11 富士フイルム株式会社 水性塗布液、膜及びその製造方法、積層体、並びに太陽電池モジュール
EP3328946A4 (fr) 2015-07-29 2019-04-17 3M Innovative Properties Company Compositions antisalissures contenant des microparticules de silice et des composés silane fonctionnels et articles revêtus associés
EP3352895B8 (fr) * 2015-09-23 2020-11-04 Rhodia Operations Composition comprenant des particules d'oxyde de cérium rendues hydrophobes
EP3153550A1 (fr) * 2015-10-05 2017-04-12 3M Innovative Properties Company Revêtement antireflet hautement durable durcissant à température ambiante contenant des nanoparticules
KR20200072993A (ko) * 2018-12-13 2020-06-23 현대자동차주식회사 리튬 이차전지 및 그 제조방법
CN111592780B (zh) * 2020-06-08 2021-12-14 青岛浩普凯诚环保新材料有限公司 一种高铁列车外壳防护液及其制备方法
US11351570B2 (en) 2020-07-22 2022-06-07 Saudi Arabian Oil Company Apparatus for coating dust particles uniformly on flat surfaces for accelerated testing

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